technical data MERCEDES-BENZ S-Class 2014 W222 Owner's Manual

Index
....................................................... 4Introduction
......................................... 22 At a glance
........................................... 31 Safety
................................................... 43 Opening and closing
...........................83 Seats, steering wheel and mirrors
..109 Lights and windshield wipers
..........137 Climate control
................................. 151 Driving and parking
..........................169 On-board computer and displays
....247 Stowage and features
......................315 Maintenance and care
......................347 Breakdown assistance
.....................363 Wheels and tires
............................... 383 Technical data
................................... 421 Contents
3

Cup holder
Center console .............................. 322
Important safety notes ..................322
Rear compartment .........................322
Temperature controlled .................323
Cushion air bags .................................. 51
Customer Assistance Center (CAC) ...27
Customer Relations Department .......27 D
Data see Technical data
Daytime running lamps
Display message ............................ 282
Function/notes ............................. 138
Switching on/off (on-board
computer) ...................................... 262
Declarations of conformity ................. 26
Diagnostics connection ......................26
Digital speedometer .........................252
DIRECT SELECT lever see Automatic transmission
Display
see Display message
see Warning and indicator lamps
Display message
ASSYST PLUS ................................ 352
Display messages
Calling up (on-board computer) .....265
Driving systems ............................. 287
Engine ............................................ 283
General notes ................................ 265
Hiding (on-board computer) ...........265
Introduction ................................... 265
Lights ............................................ .280
Safety systems .............................. 266
SmartKey ....................................... 300
Tires ............................................... 295
Vehicle .......................................... .297
Distance warning (warning lamp) ....311
Distance warning function Activating/deactivating .................261
Function/notes ................................ 73
DISTRONIC PLUS
Activating ....................................... 203
Activation conditions .....................203
Cruise control lever .......................203Deactivating ................................... 208
Display message
............................ 292
Displays in the multifunction
displa y........................................... 207
Driving tips .................................... 208
Function/notes ............................. 201
Important safety notes ..................202
Setting the specified minimum
distance ......................................... 206
Doors
Automatic locking (switch) .............. .92
Central locking/unlocking
(SmartKey) ...................................... .85
Control panel ................................... 40
Display message ............................ 298
Emergency locking ........................... 93
Emergency unlocking .......................92
Important safety notes ....................90
Opening (from inside) ......................91
Power closing .................................. 92
Drinking and driving .........................194
Drive program Automatic ...................................... 183
Manual .......................................... .184
Manual (AMG vehicles) ..................185
SETUP (on-board computer) ..........264
Driver's/front-passenger seat
Stowage compartment ..................318
Driver's door
see Doors
Driver's seat
see Seats
Driving abroad
Mercedes-Benz Service .................353
Symmetrical low bea m.................. 138
Driving Assistance package .............240
Driving safety systems ABS (Anti-lock Braking System) .......71
ADAPTIVE BRAKE ............................. 78
Adaptive Brake Assist ......................75
BAS (Brake Assist System) ..............71
BAS PLUS with Cross-Traffic Assist .72
COLLISION PREVENTION ASSIST ....73
Distance warning function ...............73
Electronic brake force distribution ...78
ESP ®
(Electronic Stability Program) .768
Index

Cup holders
................................... 322
Door ............................................... 318
Eyeglasses compartment ...............317
Glove box ...................................... .317
Important safety information .........316
Rear ............................................... 318
Rear seat backrest ......................... 319
Stowage net ................................... 320
Under driver's seat/front-
passenger seat .............................. 318
Stowage net ....................................... 320
Stowage space Folding table .................................. 319
Parcel net retainers .......................320
Securing a loa d.............................. 320
Stowage well beneath the trunk
floor .................................................... 320
Summer tires In winter ........................................ 386
Sun visor ............................................ 324
Supplemental restraint system see SRS (Supplemental Restraint
System)
Suspension tuning
Active Body Control .......................214
AIRMATIC ...................................... 217
SETUP (on-board computer) ..........264
Switching air-recirculation mode
on/off ................................................. 163T
Tachometer ........................................ 248
Tail lamps Display message ............................ 281
see Lights
Tank content
Fuel gauge ....................................... 33
Technical data
Capacities ...................................... 423
Information .................................... 422
Tires/wheels ................................. 413
Vehicle data ................................... 429
Telephone
Accepting a call ............................. 257
Display message ............................ 300
Introduction ................................... 257
Menu (on-board computer) ............257 Number from the phone book .......
.257
Redialing ........................................ 258
Rejecting/ending a call .................257
Temperature
Coolant .......................................... 259
Engine oil (on-board computer) ...... 264
Outside temperature ..................... .248
Setting (climate control) ................159
Theft deterrent systems
ATA (Anti-Theft Alarm system) .........81
Immobilizer ...................................... 80
TIREFIT kit .......................................... 366
Tire pressure Calling up (on-board computer) .....391
Checking manually ........................390
Display message ............................ 295
Important safety notes ..................391
Maximum ....................................... 390
Notes ............................................. 389
Not reached (TIREFIT) ....................368
Reached (TIREFIT) ..........................368
Recommended ............................... 387
Tire pressure loss warning
system
General notes ................................ 394
Important safety notes ..................394
Restarting ...................................... 394
Tire pressure monitoring system
Checking the tire pressure
electronically ................................. 392
Function/notes ............................. 391
General notes ................................ 391
Important safety notes ..................391
Restarting ...................................... 393
Warning lamp ................................. 312
Warning message .......................... 393
Tires
Aspect ratio (definition) .................406
Average weight of the vehicle
occupants (definition) ....................405
Bar (definition) ............................... 404
Changing a wheel .......................... 407
Characteristics .............................. 404
Checking ........................................ 385
Definition of terms .........................404
Direction of rotatio n...................... 407
Display message ............................ 29518
Index

may lead to the vehicle failing to meet the
requirements of the next emissions test
during the main inspection. Qualified specialist workshop
An authorized Mercedes-Benz Center is a
qualified specialist workshop. It has the
necessary specialist knowledge, tools and
qualifications to correctly carry out the work
required on your vehicle. This is especially the
case for work relevant to safety.
Observe the notes in the Maintenance
Booklet.
Always have the following work carried out at
an authorized Mercedes-Benz Center:
R work relevant to safety
R service and maintenance work
R repair work
R alterations, installation work and
modifications
R work on electronic components Correct use
If you remove any warning stickers, you or
others could fail to recognize certain dangers.
Leave warning stickers in position.
Observe the following information when
driving your vehicle:
R the safety notes in this manual
R the Technical Data section in this manual
R traffic rules and regulations
R laws and safety standards pertaining to
motor vehicles Problems with your vehicle
If you should experience a problem with your
vehicle, particularly one that you believe may
affect its safe operation, we urge you to
contact an authorized Mercedes-Benz Center
immediately to have the problem diagnosed
and rectified. If the problem is not resolved to your satisfaction, please discuss the problem
again with a Mercedes-Benz Center or
contact us at one of the following addresses.
In the USA
Customer Assistance Center
Mercedes-Benz USA, LLC
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada
Customer Relations Department
Mercedes-Benz Canada, Inc.
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9
Reporting safety defects
USA only:
The following text is published as required of
manufacturers under Title 49, Code of U.S.
Federal Regulations, Part 575 pursuant to the
"National Traffic and Motor Vehicle Safety Act
of 1966".
If you believe that your vehicle has a defect
which could cause a crash or could cause
injury or death, you should immediately
inform the National Highway Traffic Safety
Administration (NHTSA) in addition to
notifying Mercedes-Benz USA, LLC.
If NHTSA receives similar complaints, it may
open an investigation, and if it finds that a
safety defect exists in a group of vehicles, it
may order a recall and remedy campaign.
However, NHTSA cannot become involved in
individual problems between you, your
dealer, or Mercedes-Benz USA, LLC.
To contact NHTSA, you may call the Vehicle
Safety Hotline toll-free at
1-888-327-4236(TTY: 1-800-424-9153); go
to http://www.safercar.gov ; or write to:
Administrator, NHTSA, 400 Seventh Street,
SW., Washington, DC 20590.
You can also obtain other information about
motor vehicle safety from
http://www.safercar.gov Introduction
27 Z

Useful information
............................422
Information regarding technical
data .................................................... 422
Identification plates .........................422
Service products and filling capaci-
ties ..................................................... 423
Vehicle data ...................................... 429 421Technical data

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible. Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Read the information on qualified
specialist workshops: (Y page 27).Information regarding technical data
i The data stated here specifically refers to
a vehicle with standard equipment. Consult
an authorized Mercedes-Benz Center for
the data for all vehicle variants and trim
levels. Identification plates
Vehicle identification plate with
vehicle identification number (VIN)
X
Open the driver's door.
You will see vehicle identification plate 0043. USA only
0044 VIN
0087 Paint code Canada only
0044 VIN
0087 Paint code
i The data shown on the vehicle
identification plate is used only as an
example. This data is different for every
vehicle and can deviate from the data
shown here. You can find the data
applicable to your vehicle on the vehicle
identification plate. 422
Identification platesTechnical data

VIN
X
Open the front right-hand door.
X Fold cover 0043down and remove it.
You will see the VIN.
The VIN can also be found in the following
locations:
R on the lower edge of the windshield
(Y page 423)
R on the vehicle identification plate
(Y page 422) Engine number
0043
Engine number (stamped into the
crankcase)
0044 VIN (on the lower edge of the windshield)
0087 Emission control information plate,
including the certification of both federal
and Californian emissions standards Service products and filling
capacities
Important safety notes
G
WARNING
Comply with all valid regulations with respect
to handling, storing and disposing of service
fluids. Otherwise, you could endanger
persons or the environment.
Keep service fluids out of the reach of
children.
For health reasons, you should prevent
service fluids from coming into direct contact
with your skin or clothing.
If a service fluid is swallowed, contact a
physician immediately. H
Environmental note
Dispose of service products in an
environmentally responsible manner.
Service products include the following:
R Fuels
R Lubricants (e.g. engine oil, transmission oil)
R Coolant
R Brake fluid
R Windshield washer fluid
R Climate control system refrigerant
Components and service products must be
matched. You should therefore only use
products that have been tested and approved
by Mercedes-Benz.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved
by Mercedes-Benz by the following
inscription on the containers:
R MB-Freigabe (e.g. MB-Freigabe 229.51)
R MB Approval (e.g. MB Approval 229.51)
Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g. Service products and filling capacities
423Technical data Z

MB 229.5). They have not necessarily been
approved by Mercedes-Benz. Fuel
Important safety notes G
WARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and
explosion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before
refueling. G
WARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come
into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
R Wash away fuel from skin immediately
using soap and water.
R If fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance
without delay.
R If fuel is swallowed, seek medical
assistance without delay. Do not induce
vomiting.
R Immediately change out of clothing which
has come into contact with fuel.
Tank capacity Model Total capacity
AMG vehicles
20.6 US gal
(78.0 l) All other models
21.1 US gal
(80.0 l) Model Of which
reserve AMG vehicles
Approx.
3.7 US gal (14.0 l) All other models
Approx.
2.1 US gal (8.0 l) Gasoline
Fuel grade
!
Do not use diesel to refuel vehicles with a
gasoline engine. Do not switch on the
ignition if you accidentally refuel with the
wrong fuel. Otherwise, the fuel will enter
the fuel system. Even small amounts of the
wrong fuel could result in damage to the
fuel system and the engine. Notify a
qualified specialist workshop and have the
fuel tank and fuel lines drained completely.
! Only refuel using unleaded gasoline with
a minimum octane rating of 91.
! Only use the fuel recommended.
Operating the vehicle with other fuels can
lead to engine failure.
! Do not use the following:
R E85 (gasoline with 85% ethanol)
R E100 (100% ethanol)
R M15 (gasoline with 15% methanol)
R M30 (gasoline with 30% methanol)
R M85 (gasoline with 85% methanol)
R M100 (100% methanol)
R Gasoline with metalliferous additives
R Diesel
Do not mix such fuels with the fuel
recommended for your vehicle. Do not use
additives. This can otherwise lead to engine
damage. This does not include cleaning
additives for the removal and prevention of
residue build-up. gasoline may only be
mixed with cleaning additives
recommended by Mercedes-Benz; see 424
Service products and filling capacitiesTechnical data

"Additives". You can obtain further
information from any authorized Mercedes-
Benz Center.
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline must be used.
If standard unleaded gasoline is
unavailable and you have to refuel with
unleaded gasoline of a lower grade,
observe the following precautions:
R Only fill the fuel tank to half full with
regular unleaded gasoline and fill the rest
with premium-grade unleaded gasoline
as soon as possible.
R Do not drive at the maximum speed.
R Avoid sudden acceleration and engine
speeds over 3,000 rpm.
Using mixtures of methanol and ethanol is not
permitted. E10 fuel or E15 fuel (unleaded
gasoline with 10% or 15% ethanol) can be
used.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or visit
http://www.mbusa.com (USA only).
Information on refueling (Y page 188).
AMG vehicles
Additives
! Operating the engine with fuel additives
added later can lead to engine failure. Do
not mix fuel additives with fuel. This does
not include additives for the removal and
prevention of residue buildup. gasoline
must only be mixed with additives
recommended by Mercedes-Benz. Comply
with the instructions for use on the product
label. More information about
recommended additives can be obtained
from any authorized Mercedes-Benz
Center. Mercedes-Benz recommends that you use
branded fuels that have additives.
The quality of the fuel available in some
countries may not be sufficient. Residue
could build up in the injection system as a
result. In such cases, and in consultation with
an authorized Mercedes-Benz Center, the
gasoline may be mixed with the cleaning
additive recommended by Mercedes-Benz.
You must observe the notes and mixing ratios
specified on the container. Engine oil
General notes !
Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
intervals than those prescribed. You could
otherwise cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
When handling engine oil, observe the
important safety notes on service products
(Y page 423).
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz
Center. Or visit the website
http://bevo.mercedes-benz.co m.
The table shows which engine oils have been
approved for your vehicle. Service products and filling capacities
425Technical data Z

Missing values were not available at time of
going to print. Model Engine
model MB
Approval AMG vehicles
157 229.5
All other models
278 229.5
i
MB approval is indicated on the oil
containers.
Filling capacities The following values refer to an oil change
including the oil filter.
Model Capacity
AMG vehicles
Without external oil
cooler: 9.0 US qt (8.5 l) All other models
8.5 qt (8.0 l)
Additives
!
Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE classification
(viscosity) suitable for the prevailing outside
temperatures. The table shows you which SAE classifications are to be used. The low-
temperature characteristics of engine oils
can deteriorate significantly, e.g. as a result
of aging, soot and fuel deposits. It is therefore
strongly recommended that you carry out
regular oil changes using an approved engine
oil with the appropriate SAE classification.
Brake fluid
G
WARNING
Over a period of time, the brake fluid absorbs
moisture from the air; this lowers its boiling
point.
If the boiling point of the brake fluid is too low,
vapor pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). This would impair braking
efficiency.
You should have the brake fluid renewed at
regular intervals. The brake fluid change
intervals can be found in the Maintenance
Booklet.
Only use brake fluid approved by Mercedes-
Benz according to MB Approval 331.0.
Information about approved brake fluid can
be obtained at any qualified specialist
workshop or on the Internet at
http://bevo.mercedes-benz.com.
i Have the brake fluid renewed regularly at
a qualified specialist workshop. Coolant
Important safety notes G
WARNING
If antifreeze comes into contact with hot
components in the engine compartment, it
may ignite. There is a risk of fire and injury.
Let the engine cool down before you add
antifreeze. Make sure that antifreeze is not
spilled next to the filler neck. Thoroughly 426
Service products and filling capacitiesTechnical data