engine MERCEDES-BENZ S-Class 2013 W221 Owner's Manual

Towing and tow-starting
Important safety notes
G
WARNING
Hybrid vehicles: be sure to read the "HYBRID"
supplement. Otherwise, you could fail to
recognize dangers. G
WARNING
If you tow the vehicle, you must use a rigid
towing ba rif:
R the engine is not running.
R there is a brake system malfunction.
R there is a malfunction in the power supply
or the vehicle's electrical system.
The power assistance for the steering and the
brake force booster do not work when the
engine is not running. You will need more
force to steer and brake, you may have to
depress the brake pedal with maximu mforce.
Before towing away, make sure that the
steering can be moved and is not locked.
If you tow or tow-start another vehicle, its
weight must not exceed the maximum
permissible gross vehicle weight of your
vehicle.
It is better to have the vehicle transported
than to have it towed.
! The vehicle can be towed a maximum of
30 miles (50km). The towing speed of
30 mph (50 km/h) must not be exceeded.
If the vehicle has to be towed more than
30 miles (50km), the entire vehicle must be
raised and transported.
! Make sure that the electric parking brake
is released. If the electric parking brake is
faulty, visit a qualified specialist workshop.
! Only secure the tow rope or tow bar at the
towing eyes. Otherwise, the vehicle could
be damaged.
! Do not use the towing eye for recovery,
as this could damage the vehicle. If in
doubt, recover the vehicle with a crane. !
When towing, pull away slowly and
smoothly. If the tractive power is too high,
the vehicles could be damaged.
! Do not tow with sling-type equipment.
This could damage the vehicle.
! When towing vehicles with KEYLESS-GO,
use the key instead of the Start/Stop
button. Otherwise, the automatic
transmission may shift to position Pwhen
the driver's or front-passenger door are
opened, which could lead to damage to the
transmission.
The automatic transmission must be in
position Nwhen the vehicle is being towed.
The battery must be connected and charged.
Otherwise, you:
R cannot turn the SmartKey to position 2in
the ignition lock
R cannot shift the automatic transmission to
position N
i Switch off the automatic locking feature
(Y page 269) You could otherwise be
locked out when pushing or towing the
vehicle. Installing/removing the towing eye
Installing the towing eye X
Remove the towing eye from the vehicle
tool kit (Y page 478). G
WARNING
The exhaust tail pipe may be hot. You could
burn yourself if you touch the tail pipe. Be
particularly careful when removing the rear
cover.
The mountings for the removable towing eyes
are located in the bumpers. They are at the
front and at the rear, under the covers. 490
Towing and tow-startingBreakdown assistance

X
Press the mark on cover 0002inwards in the
direction of the arrow.
X Take cover 0002off the opening.
X Screw the towing eye in clockwise to the
stop and tighten it.
Removing the towing eye X
Loosen the towing eye and unscrew it.
X Attach cover 0002to the bumper and press
until it engages.
X Place the towing eye in the vehicle tool kit. Towing the vehicle with the rear axle
raised
Only possible on vehicles without
4MATIC.
When towing your vehicle with the rear axle
raised, it is importan tthat you observe the
safety instructions (Y page 490).
! The ignition must be switched off if you
are towing the vehicle with the rear axle
raised. Intervention by ESP ®
could
otherwise damage the brake system. X
Switch on the hazard warning lamps
(Y page 283).
X Turn the SmartKey to position 0in the
ignition lock and remove the SmartKey
from the ignition lock.
X When leaving the vehicle, take the
SmartKey or the KEYLESS-GO key with you. Towing
avehicle with both axles on
the ground
When having your vehicle towed, observe the
important safety notes (Y page 490). G
WARNING
The power assistance for the steering and the
brake force booster do not work when the
engine is not running. You will then need
much more effort to brake and steer the
vehicle .Adapt your style of driving
accordingly.
The automatic transmission automatically
shifts to position Pwhen you open the driver's
or front-passenger door or when you remove
the SmartKey from the ignition lock. In order
to ensure that the automatic transmission
stays in position Nwhen towing the vehicle,
you must observe the following points:
X Make sure that the vehicle is stationary and
the SmartKey in the ignition lock is in
position 0.
X Turn the SmartKey to position 2in the
ignition lock.
On vehicles with KEYLESS-GO, use the key
instead of the Start/Stop button
(Y page 307).
X Depress and hold the brake pedal.
X Shift the automatic transmission to
position N.
X Release the brake pedal.
X Release the electric parking brake. Towing and tow-starting
491Breakdown assistance Z

specialist workshop, e.g. an authorized
Mercedes-Benz Center.
!
Only use fuses that have been approved
for Mercedes-Benz vehicles and which
have the correct fuse rating for the system
concerned. Otherwise, components or
systems could be damaged. Before changing a fuse
X Secure the vehicle against rolling away
(Y page 327).
X Switch off all electrical consumers.
X Remove the SmartKey from the ignition
lock.
The fuses are located in various fuse boxes:
R Fuse box on the right and left-hand sides of
the dashboard
R Fuse box in the rear
R Fuse box in the engine compartment on the
left-hand side of the vehicle, when viewed
in the direction of travel
R Fuse box in the engine compartment on the
right-hand side of the vehicle, when viewed
in the direction of travel
The fuse allocation chart is in the vehicle
document wallet. Dashboard fuse box
There is a fuse box located on both the
driver's side and the front-passenger side.
! Do not use a pointed object such as a
screwdriver to open the cover in the
dashboard. You could damage the
dashboard or the cover. Driver's side illustrated
X
To open: pull cover 0002outwards in the
direction of the arrow and remove it.
X To close: clip in cover 0002on the front of
the dashboard.
X Fold cover 0002inwards until it engages. Fuse box in the rear
The fuse box is behind the armrest in the rear. X
To open: fold down the armrest.
X Pull handle 0002on the trim behind the rear
seat armrest up in the direction of the
arrow.
X Fold down trim 0003. Fuses
493Breakdown assistance Z

X
Loosen cover 0025with a suitable object 0026.
X Remove cover 0025upwards in the direction
of the arrow.
! The cover must be seated properly,
otherwise moisture or dirt could impair the
function of the fuses. Fuse box in the engine compartment
Fuse box on the left in the direction of
travel X
Open the hood (Y page 462).X
Remove any existing moisture from the
fuse box using a dry cloth.
X AMG vehicles: remove the control unit
above the fuse box.
X To open: undo screws 0002with an Allen
key.
X Remove bracket 0026.
X Remove cover 0003. X
To close: check whether the rubber seal is
lying correctly in cover 0003.
X Put cover 0003back in position.
X Replace bracket 0026.
X Tighten screws 0002using an Allen key.
! The cover must be seated properly,
otherwise moisture or dirt could impair the
function of the fuses.
X Close the hood (Y page 463).
Fuse box on the right in the direction of
travel X
Open the hood (Y page 462). X
Remove any existing moisture from the
fuse box using a dry cloth.
X To open: open clamps 0003.
X Remove cover 0003upwards.
X To close: check whether the rubber seal is
lying correctly in cover 0003.
X Put cover 0003back in position.
X Fold down cover 0002and close clamps 0003.
! The cover must be seated properly,
otherwise moisture or dirt could impair the
function of the fuses.
X Close the hood (Y page 463).494
FusesBreakdown assistance

Engine emergency off
If the engine cannot be switched off as
described, observe the followin gprocedure:
X Take the fuse allocation chart out of the
vehicle document wallet.
X Search for “Emergency engine shutdown”
in the fuse allocation chart.
X Remove the fuses listed under "Emergency
engine shutdown". Fuses
495Breakdown assistance Z

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible. Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Please read the information on qualified
specialist workshops (Y page 31).Notes on technical data
G
WARNING
Hybrid vehicles :be sure to read the "HYBRID"
supplement .Otherwise, you could fail to
recognize dangers.
i The data stated here specifically refers to
a vehicle with standard equipment. Consult
a Mercedes-Benz Center for the data for all
vehicle variants and trim levels. Genuine Mercedes-Benz parts
All Mercedes-Benz Centers maintain a supply
of genuine Mercedes-Benz parts for
necessary service and repai rwork. In
addition, strategically located parts delivery
centers provide for quick and reliable parts
service.
There are more than 300,000 different
genuine Mercedes-Benz parts available for
Mercedes-Benz models.
Genuine Mercedes-Benz parts are subject to
strictq uality control .Each part has been
specially developed, manufactured or
selected for Mercedes-Ben zvehicles and
fine-tuned for them.
Therefore, only genuine Mercedes-Benzp arts
should be used. G
WARNING
Driving safety may be impaired if non-
approved parts, tires and wheels or safety-
relevan taccessories are used.
This could lead to malfunctions in safety-
relevant systems, e.g. the brake system. This
could cause you to lose control of your vehicle
and cause an accident.
For this reason, Mercedes-Benz recommends
that you use genuine Mercedes-Benz parts or
parts of equal quality .Only use tires, wheels
and accessories tha thave been specifically
approved for your vehicle.
! Air bags and Emergency Tensioning
Devices, as well as control units and
sensors for these restraint systems may be
installed in the following areas of your
vehicle:
R doors
R door pillars
R door sills
R seats
R dashboard
R instrument cluster
R center console
Do no tinstall accessories such as audio
systems in these areas. Do not carry out
repairs or welding .You could impair the
operating efficiency of the restraint
systems.
Have aftermarket accessories installed at
a qualified specialist workshop. Mercedes-
Benz recommends that you use an
authorized Mercedes-Benz Center for this
purpose. H
Environmental note
Daimler AG also supplies reconditioned major
assemblies and parts which are of the same
quality as new parts. They are covered by the
same Limited Warranty entitlements as new
parts.
Always specify the vehicle identification
number (VIN) (Y page 529) and the engine528
Genuine Mercedes-Benz partsTechnical data

i
The data shown on the identification plate
is example data. This data is different for
every vehicle and can deviate from the data
shown here. You can find the data
applicable to your vehicle on the vehicle's
identification plate. Vehicle identification number (VIN)
The vehicle identification number (VIN) can
be found in the following locations:
R on the vehicle identification plate
(Y page 529)
R at the lower edge of the windshield
(Y page 530)
In addition to being stamped on the vehicle
identification plate, the vehicle identification
number (VIN) is also stamped onto the vehicle
body. It is under the trim behind the rear seat
armrest. X
Fold down the rear seat armrest.
X Open the trim.
You will see vehicle identification number
(VIN) 0002. Engine number
0002
Emission control information plate,
including the certification of both federal
and Californian emissions standards
0003 Engine number (stamped into the
crankcase)
0026 VIN (on the lower edge of the windshield) Service products and filling
capacities
Important safety notes
G
WARNING
Comply with all valid regulations with respect
to handling, storing and disposing of service
fluids. Otherwise, you could endanger
persons or the environment.
Keep service fluids out of the reach of
children.
For health reasons, you should prevent
service fluids from coming into direct contact
with your skin or clothing.
If a service fluid is swallowed, contact a
physician immediately. H
Environmental note
Dispose of service products in an
environmentally responsible manner.
Service products include the following:
R fuels (e.g. gasoline, diesel)
R exhaust gas aftertreatmen tadditives, e.g.
DEF 530
Service products and filling capacitiesTechnical data

R
lubricants (e.g .engine oil, transmission oil)
R coolant
R brake fluid
R windshield washe rfluid
R climate control system refrigerant
Components and service products must be
matched .You should therefor eonly use
products tha thave been tested and approved
by Mercedes-Benz.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.co m.
You can recognize service products approved
by Mercedes-Ben zby the following
inscription on the containers:
R MB approval (e.g. MB approval 229.51)
R MB Approval (e.g. MB Approval 229.51)
Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g.
MB 229.5). The yhave no tnecessarily been
approved by Mercedes-Benz. Fuel
Important safety notes G
WARNING
Gasoline and diesel fuels are highly flammable
and poisonous. They burn violently and can
cause serious injury.
Never allow sparks, flames or smoking
materials near gasoline or diesel fuel!
Turn off the engine before refueling.
Whenever you are around gasoline or diesel
fuel, avoid inhaling fumes and any skin or
clothing contact. Extinguish all smoking
materials.
Direct skin contact with fuels and the
inhalation of fuel vapors are damaging your
health. Tank capacity Total capacity
S 550
30
S 550 4MATIC 30
S 350 BlueTEC 4MATIC 21.9 US gal
(83.0 l) S 600
AMG vehicles
23.8 US gal
(90.0 l) Of which reserve
Approx.
2.9 US gal (11.0 l) Of which reserve fuel in
AMG vehicles
Approx.
3.7 US gal (14.0 l) Gasoline
Fuel grade
!
Do not use diesel to refuel vehicles with a
gasoline engine. Even small amounts of the
wrong fuel result in damage to the fuel
system and engine.
! You should only refuel with unleaded
premium-grade gasoline as this avoids
damaging the catalytic converter.
If engine running problems are apparent,
have the cause checked immediately and
repaired. Excess unburned fuel can
otherwise enter the catalytic converter,
leading to overheating and possibly
causing a fire.
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline may be used.
If there is no premium-grade unleaded
gasoline available and regular unleaded
gasoline must be used, please observe the
following precautions:
R only fill the fuel tank to half full with
regular unleaded gasoline and fill the rest
30 BlueEFFICIENCY Service products and filling capacities
531Technical data Z

with premium-grade unleaded gasoline
as soon as possible.
R do not drive at the maximum speed.
R avoid sudden acceleration.
R if the vehicle is carrying a light load, e.g.
two passengers without luggage, do not
allow the engine to rev above 3000 rpm.
R if the vehicle is fully loaded or is being
operated in mountainous terrain, do not
depress the accelerator pedal further
than 0001of the pedal travel.
Only refuel using premium-grade unleaded
gasoline with a minimum octane rating of 91.
Reformulated Gasoline (RFG) and/or
unleaded gasoline with additives can be used.
The concentratio nofadditives in the fuel,
however, must not exceed 10 %, e.g.:
R Ethanol
R TAME
R ETBE
R IPA
R TBA
For MTBE, the concentration should not
exceed 15 %.
The concentration of methanol in gasoline,
including other additives, must not exceed
3 %.
Using mixtures of methanol and ethanol is not
permitted. Gasohol, a mixture of 10 % ethanol
and 90 % unleaded gasoline, may be used.
All of these mix fuels must fulfill the fuel
requirements, e.g.:
R knock resistance
R boiling point
R vapor pressure
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult an
authorized Mercedes-Benz Cente roron
the Internet at http://www.mbusa.com
(USA only). Information on refueling (
Ypage 321).
Additives
! Do not refuel with low-grade fuel and do
not use fuel additives tha tare not tested
and approved for Mercedes-Benz vehicles.
Damage to or malfunctions of the fuel
system may otherwise occur.
One of the main problems of poor fuel quality
is the forming of deposits that are created
during the gasoline combustion process.
Mercedes-Benz recommends that you use
branded fuels that have additives.
If you use fuels without these additives over
a longer period of time, carbon deposits may
build up. These deposits form at the inlet
valves and in the combustion chambe rin
particular.
This could lead to engine problems, e.g.:
R longer engine warm-up phase
R uneven idle
R engine noise
R misfiring
R loss of power
Carbon deposits may form if the availability
of gasoline with relevant additives is
insufficient (in certain regions). In this case,
Mercedes-Benz recommends additives
approved for use in Mercedes-Benz vehicles;
see http://bevo.mercedes-benz.com.
For a list of approved products, consult an
authorized Mercedes-Benz Center. Comply
with the instructions for use on the product
label.
Do not mix other fuel additives with fuel. This
causes unnecessary costs and could damage
the engine.
Diesel Fuel grade
G
WARNING
Do not use gasoline to refuel vehicles with a
diesel engine. Never mix diesel with gasoline.
This causes damage to the fuel system and 532
Service products and filling capacitiesTechnical data

engine and could result in the vehicle catching
fire.
! Only use commercially available vehicular
ULTRA-LOW SULFUR DIESEL FUEL (ULSD,
15 ppm maximum sulfur content) that
meets the ASTM D975 standard. If you do
not refuel with ULSD ,you may damage the
BlueTEC exhaust gas aftertreatment
system of the vehicle.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not mix diesel fuel with
gasoline, kerosene or paraffin. This may
otherwise result in damage to the fuel
system and engine.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or on the
Internet at http://www.mbusa.com (USA
only).
Information on refueling (Y page 321).
Bio-diesel -FAME (fatt yacid methyl ester)
Mercedes-Ben zUSA approves the use of bio-
diesel B5 for all BlueTEC diesel engines. The
concentration of bio-diesel in the ULSD may
not exceed 5%by volume.
Pure biodiesel and diesel fuel with a higher
percentage of biodiesel, such as B20, can
damage the engine and the fuel system. For
this reason, they are not approved.
For more information, consult the gas station
staff .The bio-diesel B5 label on the gasoline
pump must clearly state that the standard for
ULSD has been fulfilled. If the label is not
clear, do not refuel the vehicle.
Do not refuel your vehicle with fuels unless
they have been approved by Mercedes-Benz.
Information on refueling (Y page 321).Low outside temperatures
i
Diesel fuel with improved cold flow
properties is available during the winter
months. Further information about fuel
properties can be obtained from oil
companies, e.g. at gas stations.
Flow improver
To improve the low-temperature resistance of
diesel fuel, a flow improver can be attached.
The effectiveness of a flow improver is not
guaranteed for every fuel.
Only use flow improvers tested and approved
by Mercedes-Benz. During use, please
observe the information on operation.
Correct dosage and sufficient mixing are
decisive in improving low-temperature
resistance with the flow improver.
Overdosage can potentially even decrease
low-temperature resistance and must
therefore be avoided. Follow the
manufacturer's guidelines on dosage.
Mix the additive into the diesel in good time,
before the flow characteristics of the diesel
become insufficient .Otherwise, malfunctions
can arise through heating the fuel system,
e.g .through parking in a heated garage.
More information about recommended flow
improvers can be obtained from any qualified
specialist workshop. DEF
Please bear the following in mind DEF is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
High outside temperatures
G
WARNING
If you open the DEF tank cap, small amounts
of ammonia vapor may be released. This
depends in particular upon the age of the DEF. Service products and filling capacities
533Technical data
Z