Mobil MERCEDES-BENZ S350 2006 W221 Owner's Manual

Our company and staff congratulate you
on the purchase of your new
Mercedes-Benz.
Your selection of our product is a demon-
stration of your trust in our company
name. Furthermore, it exemplifies your de-
sire to own an automobile that will be as
easy as possible to operate and provide
years of service.
Your Mercedes-Benz represents the ef-
forts of many skilled engineers and crafts-
men. To help assure your driving pleasure,
and also the safety of you and your passen-
gers, we ask you to make a small invest-
ment of time:


Please read this manual carefully, then
return it to your vehicle where it will be
handy for your reference.


Please follow the recommendations
contained in this manual. They are de-
signed to acquaint you with the opera-
tion of your Mercedes-Benz.


Please pay attention to the warnings
and cautions contained in this manual.
They are designed to help improve the
safety of the vehicle operator and oc-
cupants.
We extend our best wishes for many miles
of safe, pleasurable driving.
Mercedes-Benz USA, LLC
A DaimlerChrysler Company

Contents
Introduction.......................................... 9
Product information ................................ 9
Operator’s Manual ............................... 10
Service and warranty information .. 10
Important notice for California
retail buyers and lessees of
Mercedes-Benz automobiles .......... 11
Maintenance .................................. 12
Roadside Assistance ...................... 12
Change of address or ownership.... 12
Operating your vehicle outside
the USA or Canada......................... 13
Where to find it .................................... 14
Symbols ............................................... 15
Operating safety .................................. 16
Proper use of the vehicle ............... 16
Problems with your vehicle .................. 17
Reporting safety defects...................... 18
Reporting safety defects ................ 18
Vehicle data recording......................... 19
Information regarding electronic
recording devices........................... 19
At a glance.......................................... 21
Cockpit ................................................. 22
Instrument cluster ................................ 24
Multifunction steering wheel ................ 26
Center console ..................................... 27
Upper part ...................................... 27
Lower part ...................................... 28
Overhead control panel ........................ 29
Door control panel................................ 30
Getting started................................... 31
Unlocking ............................................. 32
Unlocking with the SmartKey ......... 32
Unlocking with KEYLESS-GO*......... 33
Starter switch positions .................. 34
Adjusting .............................................. 37
Seats .............................................. 37
Steering wheel ................................ 40
Mirrors ............................................ 41
Driving .................................................. 43
Fastening the seat belts ................. 43
Starting the engine ......................... 46
Parking brake ................................. 48
Driving ............................................ 49
Switching on headlamps ................. 50
Turn signals .................................... 51
Windshield wipers ........................... 52
Problems while driving.................... 54
Parking and locking .............................. 55
Parking brake ................................. 56
Switching off headlamps................. 57
Turning off the engine ..................... 57
Locking ........................................... 58

ContentsSafety and Security........................... 59
Occupant safety................................... 60
Air bags .......................................... 61
Seat belts ....................................... 67
Preventive occupant safety
(PRE-SAFE
®)................................... 70
Children in the vehicle .................... 71
Override switch for rear
passenger compartment ................ 77
Panic alarm .......................................... 78
Activating ....................................... 78
Deactivating ................................... 78
Driving safety systems ......................... 79
ABS ................................................ 79
BAS ................................................ 80
ESP
®.............................................. 81
Four wheel electronic traction
system (4MATIC) with the ESP
®..... 84
Anti-theft systems................................ 85
Immobilizer..................................... 85
Anti-theft alarm system .................. 86
Tow-away alarm ............................. 88
Controls in detail............................... 91
Locking and unlocking ......................... 92
SmartKey ....................................... 92
SmartKey with KEYLESS-GO* ........ 96
Opening the doors
from the inside ............................. 102
Opening the trunk ........................ 103
Closing the trunk.......................... 105
Trunk lid emergency release ........ 111
Power closing assist for doors
and trunk lid ................................. 112
Automatic central locking ............ 112
Locking and unlocking
from the inside ............................. 113
Seats ................................................. 114
Easy-entry/exit feature ................ 114
Removing and installing front
seat head restraints ..................... 116
Rear seats .................................... 117
Rear seat head restraints ............. 120
Lumbar support............................ 122
Multicontour backrest* ................ 122
Drive-dynamic seat* .................... 124
Seat heating* ............................... 125
Seat ventilation* .......................... 127Memory function ............................... 128
Storing positions into memory ..... 129
Recalling positions from memory . 129
Storing exterior rear view
mirror parking position ................ 130
Lighting ............................................. 131
Exterior lamp switch .................... 131
Combination switch ..................... 135
Hazard warning flasher ................ 136
Interior lighting ............................ 137
Courtesy lighting .......................... 139
Door entry lamps ......................... 139
Trunk lighting ............................... 139
Instrument cluster ............................. 140
Instrument cluster illumination .... 140
Coolant temperature gauge ......... 141
Trip odometer .............................. 141
Tachometer .................................. 142
Outside temperature indicator ..... 142
Clock............................................ 142
Control system .................................. 143
Multifunction display.................... 143
Multifunction steering wheel........ 144
Menus .......................................... 146
Standard display menu ................ 148
AUDIO menu ................................ 148

11 Introduction
Operator’s Manual
Important notice for California retail
buyers and lessees of Mercedes-Benz automobiles
Under California law you may be entitled to
a replacement of your vehicle or a refund
of the purchase price or lease price, if
Mercedes-Benz USA, LLC and/or its au-
thorized repair or service facilities fail to fix
one or more substantial defects or mal-
functions in the vehicle that are covered by
its express warranty after a reasonable
number of repair attempts. During the pe-
riod of 18 months from original delivery of
the vehicle or the accumulation of
18 000 miles (approx. 29 000 km) on the
odometer of the vehicle, whichever occurs
first, a reasonable number of repair at-
tempts is presumed for a retail buyer or
lessee if one or more of the following oc-
curs: (1) the same substantial defect or mal-
function results in a condition that is
likely to cause death or serious bodily
injury if the vehicle is driven, that de-
fect or malfunction has been subject to
repair two or more times, and you have
directly notified Mercedes-Benz USA,
LLC in writing of the need for its repair,
(2) the same substantial defect or mal-
function of a less serious nature than
category (1) has been subject to repair
four or more times and you have direct-
ly notified us in writing of the need for
its repair, or(3) the vehicle is out of service by reason
of repair of the same or different sub-
stantial defects or malfunctions for a
cumulative total of more than
30 calendar days.
Written notification should be sent to us,
not a dealer, at Mercedes-Benz USA, LLC,
Customer Assistance Center,
One Mercedes Drive, Montvale,
NJ 07645-0350.

57 Getting started
Parking and locking
Switching off headlamps
Turn the exterior lamp switch toM.
For more information, see “Lighting”
(
page 131).
Turning off the engine 
Place the gear selector lever in
positionP.
Turning off with the SmartKey

Turn the SmartKey in the starter switch
(page 34) to position0 and remove
it.
The immobilizer is activated.

Press the seat belt release button
(page 44).
Allow the retractor to completely re-
wind the seat belt by guiding the latch
plate.
Turning off the engine with
KEYLESS-GO*

Place the gear selector lever in
positionP.

Press the KEYLESS-GO start/stop
button (
page 35) to shut off the en-
gine.With the driver’s door closed, the start-
er switch is now in position1. With the
driver’s door opened, the starter switch
is set to position0, same as SmartKey
removed from starter switch
(
page 34).

Press the seat belt release button
(page 44).
Allow the retractor to completely re-
wind the seat belt by guiding the latch
plate.
iAlways set the parking brake in addi-
tion to shifting to position P.
On slopes, turn the front wheels to-
wards the curb.
iThe SmartKey can only be removed
from the starter switch with the gear
selector lever in positionP.iWith the SmartKey removed and the
driver’s door open, a warning sounds if
the vehicle’s exterior lamps are not
switched off.
!If you hear a warning signal, you have
either

forgotten to turn off the lights be-
fore opening the driver’s door
or


tried to turn off the engine while the
gear selector lever is not inP.
Turn off the lights or place the gear se-
lector lever inP.

62 Safety and SecurityOccupant safety

Adjust the driver’s seat as far as possi-
ble rearward, still permitting proper op-
eration of vehicle controls. The distance
from the center of the driver’s breast-
bone to the center of the air bag cover
on the steering wheel must be at least
10 in (25 cm) or more. You should be
able to accomplish this by a combina-
tion of adjustments to the seat and
steering wheel. If you have any prob-
lems, please see an authorized
Mercedes-Benz Center.


Do not lean with your head or chest
close to the steering wheel or dash-
board.


Keep hands on the outside of steering
wheel rim. Placing hands and arms in-
side the rim can increase the risk and
potential severity of hand/arm injury
when driver front air bag inflates.


Adjust the front passenger seat as far as
possible rearward from the dashboard
when the seat is occupied.


Occupants, especially children, should
never lean their heads in the area of the
door where the side air bag inflates.
This could result in serious injuries or
death should the air bag be triggered.
Always sit nearly upright, properly use
the seat belts and appropriate size in-
fant or child restraint system.


Children 12 years old and under must
never ride in the front seat, except in a
Mercedes-Benz authorized
BabySmart
TM1
compatible child seat,
which operates with the BabySmart
TM
system installed in the vehicle to deacti-
vate the passenger front air bag when it
is properly installed. Otherwise they will
be struck by the air bag when it inflates
in a crash. If this happens, serious or fa-
tal injury will result.
Failure to follow these instructions can re-
sult in severe injuries to you or other occu-
pants.
If you sell your vehicle, it is important that
you make the buyer aware of this safety in-
formation. Be sure to give the buyer this Op-
erator’s Manual.
1BabySmart
TM is a trademark of Siemens Automo-
tive Corp.
Warning!
G
Accident research shows that the safest
place for children in an automobile is in the
rear seat. Should you choose to place a child
12 years old or under in the front passenger
seat of your vehicle, you must properly use
a BabySmart
TM child restraint which will
turn off the passenger front air bag.
BabySmart
TM will not, however, turn off any
side impact air bag.
It should be noted that with respect to both
front and rear side impact air bags there is a
possibility for a side air bag related injury if
occupants, especially children, are not prop-
erly seated or restrained when next to a side
air bag which needs to deploy rapidly in a
side impact in order to do its job.
To help avoid the possibility of injury, please
follow these guidelines:
(1) Occupants, especially children, should
never place their bodies or lean their
heads in the area of the door where the
side air bag inflates. This could result in


85 Safety and Security
Anti-theft systems
Anti-theft systems
Immobilizer
The immobilizer prevents unauthorized
persons from starting your vehicle.
Activating
With the SmartKey
Remove the SmartKey from the starter
switch.
The immobilizer is activated.
With KEYLESS-GO*

Turn off the engine by means of the
KEYLESS-GO start/stop button
(page 35).

Open the driver’s door.
The immobilizer is activated.Deactivating
With the SmartKey

Insert the SmartKey in the starter
switch.
The immobilizer is deactivated.With KEYLESS-GO*

Start the engine by means of the
start/stop button (
page 35) on the
gear selector lever.
The immobilizer is deactivated.
iIn case the engine cannot be started
(yet the vehicle’s battery is charged),
the system is not operational. Contact
an authorized Mercedes-Benz Center
or call 1-800-FOR-MERCedes (in the
USA), or 1-800-387-0100 (in Canada).

451 Index
A
ABC 232, 443
Messages in display 351
Setting vehicle level 230, 233
ABS 25, 79, 443
Malfunction indicator lamp 340
Messages in display 353
Warning lamp 340
Accelerator position, automatic
transmission 177
Accessory weight 323
Accident
In case of 54
Activating
Air conditioner (cooling) 202
Air conditioning 202
Air recirculation mode 198
Anti-theft alarm system 86
Central locking (control system) 168
Charcoal filter 200
Distance warning function* 227
Distronic* 223
Easy-entry/exit feature 170
ESP
®
83
Exterior lamps 132
Exterior rear view mirror parking position 187
Front and rear fog lamp 132, 134
Hazard warning flasher 136
Headlamps 50
High beams 135
Ignition 34
Ignition with KEYLESS-GO* start/stop
button 36
Immobilizer 57, 85
Limiting opening height of trunk
lid* 169
Manual shift program S 55 AMG and
S 65 AMG 184
Rear window defroster 201
Residual heat 202, 207
Seat heater 125, 126
Seat ventilation* 127
Tow-away alarm 88
Windshield wipers 52
Adaptive Damping System (ADS) 229,
443
Adding
Coolant 294
Engine oil 292
Additional turn signals 395
Adjustable air vents, rear passenger compartment 204
Adjusting 37
Air distribution 196, 206
Air volume 197
Backrest tilt 38
Drive-dynamic seat* 171
Exterior rear view mirrors 41
Head restraint height 39
Head restraint tilt 39
Instrument cluster illumination 140
Interior rear view mirror 41
Lumbar support 122
Mirrors 41
Multicontour backrest* 122
Power seat bench* 117
Seat cushion depth 38, 123
Seat cushion tilt 38
Seat fore and aft adjustment 38
Seat height 38
Seat in the lumbar region 123
Seat in the shoulder region 123
Seats 37
Steering column height 40
Steering column in or out 40
Steering column up or down 40
Steering wheel 40

452 IndexADS 229, 443
Air bag off indicator lamp 348
Air bags 61
BabySmart
TM air bag deactivation
system 73, 443
Children 62
Front 65
Passenger 65
Safety guidelines 64
Side impact 66
Window curtain 66
Air conditioning
Turning off 202
Turning on 202
Air pressure 323
Air pressure see Tire inflation pressure
Air recirculation mode 198
Activating 198
Deactivating 199
Air vents, rear passenger compartment
Adjustable 204
Air volume
Adjusting 197
AIRMATIC 229
Airmatic 229, 443
Messages in display 358Alarm
Audible 78, 87, 89
Canceling 87, 89
Visual 86
Alarm system
Anti-theft 86
Anti-theft alarm system indicator
lamp 27
Alignment bolt (vehicle tool kit) 385,
406, 443
Antiglare
Automatic 186
Antilock brake system (ABS) 443
Antilock Brake System see ABS 25
Anti-theft alarm system
Arming 86
Canceling alarm 87
Disarming 87
Anti-theft systems 85
Anti-theft alarm system 86
Anti-theft alarm system indicator
lamp 27
Immobilizer 85
Tow-away alarm 88
Aquaplaning see Hydroplaning 277Armrest
Storage compartment in front of 243,
244, 245, 246
Ashtray 249
Aspect ratio 323
At the gas station 284
ATF (Automatic Transmission Fluid) 293
AUDIO menu 148
Selecting CD track 150
Selecting MP3-CD track 150
Selecting radio station 149
Selecting satellite radio* station (USA
only) 149
Audio system
CD mode 151
Auto-dimming for rear view mirror 186
Automatic central locking
Activating/deactivating (control
system) 168
Automatic climate control 192
Air recirculation mode 198
Defrosting 197
Rear window defroster 201
Setting the temperature 195
Setting the temperature in the rear
passenger compartment 206

456 IndexConvenience submenu 169
Activating easy-entry/exit
feature 170
Adjusting drive-dynamic seat* 171
Setting key-dependency 169
Setting parking position for exterior
rear view mirror 170, 172
Coolant 294
Adding 294
Checking level 294
Messages in display 362, 363
Temperature 283
Temperature gauge 141
Warning lamp 363
Coolant level
Checking 294
Coolant temperature gauge 25
Courtesy lighting 139
Cruise control 215, 444
Canceling 216
Driving downhill 216
Driving uphill 216
Fine adjustment 217
Lever 222
Setting current speed 216Setting to last stored speed (“Resume”
function) 217
Cruise control lever 215
Cup holder
Cleaning 337
Closing 249
In front seat armrest 248
In rear seat armrest 249
Opening 249
Curb weight 323, 444
Customer Assistance Center (CAC) 444
D
Daytime running lamp mode 133
Setting 165
Deactivating
Air conditioner (cooling) 202
Air recirculation mode 199
Alarm 87
Anti-theft alarm system 87
Automatic climate control 195, 206
Central locking (control system) 168
Charcoal filter 200
Defrost 197
Distance warning function* 227Distronic* 225
Engine with the SmartKey 57
ESP
®
82
Exterior lamps 132
Hazard warning flasher 136
Headlamps 57
Immobilizer 85
Interior illumination delayed
switch-off 167
Limiting opening height of trunk
lid* 169
Manual shift program S 55 AMG and
S 65 AMG 185
Rear window defroster 201
Residual heat 203, 207
Seat heater 125, 126
Seat ventilation* 127
Tow-away alarm 88
Deceleration
With Distronic* 221
Deep water see Standing water 280
Defrosting 197
Delayed switch-off
Interior illumination 167
Department of Transportation see DOT