MERCEDES-BENZ S-CLASS SALOON LONG 2022 Owners Manual

5
Maximum permissible gross weight of vehicle
combination (k g) (for certain countries only,
optional)
6 Maximum permissible front axle load (kg)
7 Maximum permissible rear axle load (kg)
8 Paint code
% The data shown in the illustration is example
dat
a.
VIN at the lower edge of the windscreen 1
VIN (vehicle identiNcation number)
The VIN at the lower edge of the windscreen is
onl
y available in some countries. VIN in the engine compartment
1
VIN (vehicle identiNcation number)
Engine number
The engine number is s
tamped into the crank-
case.
% Further information can be obtained at a
q

ualiNed specialist workshop. Operating Ouids
Notes on operating
Ouids &
WARNING Risk of injur
y from operating
Ouids harmful to your health
Operating Ouids ma
y be poisonous and harm-
ful to your health. 
Observe the text on the original contain-
er
s when using, storing or disposing of
operating Ouids. 
Always store operating Ouids sealed in
t
heir original containers. 
Always keep children away from operat-
ing Ouids. +
ENVIRONMENTAL NOTE
P
ollution of the
environment due to irresponsible disposal
of operating Ouids Incorrect disposal of operating
Ouids can
cause consider
able damage to the environ-
ment. 488
Technical data


Dispose of operating Ouids in an en viron-
mentally responsible manner. Operating Ouids
include t
he following:
= fuels
= DeNOx agent AdBlue n
for exhaust gas aser-
treatment
= lubricants
= coolant
= Brake Ouid
= windscreen washer Ouid
= climate control system refrigerant
Only use products approved by Mercedes-Benz.
Damage caused by the use of products that have
not been approved is not covered by the
Mercedes-Benz warranty or goodwill gestures.
The operating Ouids approved by Mercedes-Benz
can be identiNed by the following inscriptions on
the container:
= MB-Freigabe (e.g. MB-Freigabe 229.51)
= MB-Approval (e.g. MB-Approval 229.51) Further information on approved operating
Ouids
= in t

he Mercedes-Benz SpeciNcations for Oper-
ating Fluids by entering the designation
- at https://bevo.mercedes-benz.com
- in the Mercedes-Benz BeVo App
= At a qualiNed specialist workshop &
WARNING Risk of Nr
e or explosion from
fuel
Fuels are highly Oammable. 
Fire, naked Oames, smoking and cr
eating
sparks must be avoided. 
Before and during refuelling, switch oM
t

he vehicle and, if Ntted, the stationary
heater. &
WARNING Risk of injur
y from fuels
Fuels are poisonous and hazardous to your
healt
h. 
Do not swallow fuel or let it come into
cont

act with skin, eyes or clothing. 
Do not inhale fuel vapour. 
Keep children away from fuel. 
Keep doors and windows closed during
t

he refuelling process.
If you or other people come into contact with
fuel, obser
ve the following: 
Immediately rinse fuel oM y
our skin with
soap and water. 
If fuel comes into contact with your eyes,
immediat
ely rinse them thoroughly with
clean water. Seek medical attention
immediately. 
If you swallow fuel, seek medical atten-
tion immediat

ely. Do not induce vomit-
ing. 
Change immediately out of clothing that
has come int
o contact with fuel. Flexible-fuel vehicles can be refuelled with the fol-
lo

wing fuel types:
= unleaded petrol
= E85 fuel Technical data
489

=
a mixtur e of E85 fuel and unleaded petrol
Flexible-fuel vehicles can be identiNed by the
Ethanol up to E85 sticker on the inside of the fuel
Nller Oap.
Depending on the country, the fuels you can use
in your vehicle may diMer from the information in
the Owner's Manual. The fuels that have been
approved for your vehicle can be found on the
instruction label on the inside of the fuel Nller Oap.Fuel
Information on fuel quality for vehicles with a pet-
r
ol engine
Observe the notes on operating Ouids
(  page 488).
* NOTE Damag
e caused by the wrong fuel Even small amounts of the wrong fuel could
r

esult in damage to the fuel system, the
engine and the emission control system. 
Only refuel using unleaded, sulphur-free
spar
k-ignition engine fuel that conforms to European EN 228, or an equivalent
speciNcation.
Fuel of this speciNcation ma
y contain up to
10% ethanol by volume. Your vehicle is suita-
ble for use with E10 fuel. 
See the information label in fuel Nller Oap
f
or other compatible fuels .
Never refuel with one of the following fuels: = Diesel
= R

egular petrol with an octane number
lower than 91 RON
= Petrol with more than 3% methanol by vol-
ume, e.g. M15, M30
= Petrol with additives containing metal
If you have accidentally refuelled with the
wrong fuel: 
Do not switch on the vehicle. 
Consult a q
ualiNed specialist workshop. According to European standard EN 16942, you
can Nnd t

he compatibility indications at the fol-
lowing locations:
= On the vehicle on the information label in the
fuel Nller Oap
= On the fuel dispenser or pump nozzle suitable
for your vehicle throughout Europe 1
For petrol with a maximum of 5% ethanol by
v
olume
2 For petrol with a maximum of 10% ethanol by
v
olume
If the available fuel is not suPcientl
y low in sul-
phur, it may produce unpleasant odours. 490
Technical data

Recommended fuel: t
he recommended octane
number for your vehicle can be found on the infor-
mation label on the fuel Nller Oap ( page 233).
% Vehicles with petrol engine M256: when using
95 R
ON, there may be slight limitations in per-
formance that have no further consequences.
All models: if y
ou wish to achieve maximum
engine output, refuel using only super unleaded
petrol with an octane number of at least 98 RON.
Alternatively, you can also refuel using premium-
grade petrol with an octane number of at least
95 RON.
All models: as a temporary measure, if the recom-
mended fuel is not available, you may also use
regular unleaded petrol with an octane number of
at least 91 RON. This may reduce engine output
and increase fuel consumption.
Never refuel using petrol with a lower RON.
Further information on fuel can be obtained at a
Nlling station or a qualiNed specialist workshop. Information on additives in petrol (vehicles with
pe

trol engine)
Observe the notes on operating Ouids
(  page 488).
* NOTE Damag
e from use of unsuitable
additives Even small amounts of the wrong additive may
lead t
o malfunctions occurring. 
Only add cleaning additives recommen-
ded b

y Mercedes-Benz to the fuel. Mercedes-Benz recommends that you use brand-
name fuels wit

h additives.
In some countries, the fuel available may not have
suPcient additives. Deposits could build up in the
fuel injection system as a result. In this case, in
consultation with a Mercedes-Benz service
centre, mix the fuel with the cleaning additive rec-
ommended by Mercedes-Benz. Observe the notes
and mixing ratios indicated on the tank. Information on fuel quality for vehicles with a die-
sel engine
Gener

al notes
Observe the notes on operating Ouids
(  page 488). &
WARNING Risk of Nr
e from fuel mixture
If you mix diesel fuel with petrol, the Oash
point of t
he fuel mixture is lower than that of
pure diesel fuel. 
Never refuel using petrol in diesel
engines. 
Never mix petrol with diesel fuel. *
NOTE Damag
e caused by the wrong fuel Even small amounts of the wrong fuel could
r

esult in damage to the fuel system, the
engine and the emission control system.
Vehicles with a diesel particulate Nlter Technical data
491


Only refuel using sulphur-free diesel fuel
t
hat conforms to European standard
EN 590, or an equivalent speciNcation.
In countries without sulphur-free diesel
fuel, refuel using only low-sulphur diesel
fuel with a sulphur content less than
50 ppm.
Vehicle without diesel particulate Nlt
er
Only refuel using diesel fuel with a sul-
phur cont

ent less than 500 ppm.
Never refuel with one of the following fuels: = P

etrol
= Marine diesel
= Heating oil
= Pure fatty acid methyl ester or vegetable
oil
= ParaPn or kerosene
If you have accidentally refuelled with the
wrong fuel: 
Do not switch on the vehicle. 
Consult a q
ualiNed specialist workshop. The following compatibility indications for fuel
appl

y to your vehicle: 1
For diesel fuel with a maximum of 7% fatty
acid me
thyl ester by volume (bio-diesel)
2 For diesel fuel with a maximum of 10% fatty
acid me
thyl ester by volume (bio-diesel)
According to European standard EN 16942 you
can Nnd t

he compatibility indications at the fol-
lowing locations:
= On the vehicle on the information label on the
fuel Nller Oap ( page 233) =
On t
he fuel dispenser or pump nozzle suitable
for your vehicle throughout Europe
Information on low outside temperatures
Refuel your vehicle with as much winter diesel fuel
as possible at the beginning of winter.
Before changing over to winter diesel fuel, the fuel
tank should be empty, if possible. When Nrst refu-
elling with winter diesel fuel, keep the fuel level
low, e.g. to reserve level. The fuel tank can be Nl-
led as usual when next refuelling.
Further information on fuel can be obtained at a
Nlling station or a qualiNed specialist workshop.
Tank content and fuel reserve
The total capacity of the fuel tank may vary,
depending on the vehicle equipment.
Not for plug-in hybrid: 492
Technical data

Total fuel tank capacity
Model
S 580 4MATIC
76.0 litres
All other models 65.0 litres
or
76.0 litr
es Fuel tank reserve
Model
All models
8.0 litresPlug-in hybrid:
T

otal fuel tank capacity Model
S 580 e
S 580 e 4MA

TIC 67.0 litres Fuel tank reserve
Model
S 580 e
S 580 e 4MA

TIC 8.0 litres AdBlue
n
(v
ehicles with a diesel engine only) Notes on AdBlue
n
Obser
ve the notes on operating Ouids
(  page 488).
AdBlue n
is a water-soluble Ouid for the NOx
exhaust gas asertreatment of diesel engines.
It may be improper or punishable in some coun-
tries to operate a vehicle that uses no AdBlue n
or
one that does not comply with the speciNcations
of this Owner's Manual. *
NOTE Malfunctions due t
o the dilution of
AdBlue n
or the use of additive-enhanced
AdBlue n The function of the NOx exhaust gas
aser
-
treatment can be impaired by the use of
unsuitable denoxiNcation agents. 
Only use AdBlue n
in accor
dance with
ISO 22241. 
Do not dilute AdBlue n
wit
h water. 
Do not use additive-enhanced AdBlue n
. *
NOTE Damag
e and malfunctions due to
impurities in AdBlue n Consequences of impurities in AdBlue
n
:
= incr

eased emission values
= damage to the catalytic converter
= NOx exhaust gas asertreatment malfunc-
tions 
Avoid impurities in AdBlue n
. Technical data
493

AdBlue
n
residues crystallise aser a period of
time, and contaminate the surfaces with which
they come into contact. Clean the dirty surfaces
with water as soon as possible.
When you open the AdBlue n
tank, small amounts
of ammonia vapour may escape. Do not inhale
any ammonia vapours that may be released. Only
Nll the AdBlue n
tank in well-ventilated areas.
AdBlue n
Nlling capacity and consumption
Total capacity of AdBlue n
tank Model
Total capacity
All models 25.0 litresAdBlue
n
consum
ption
The average AdBlue n
consumption is between 1%
and 5% of fuel consumption. Like fuel consump-
tion, AdBlue n
consumption is highly dependent
upon driving style and operating conditions. For
this reason, your vehicle's actual consumption Ng-
ures in day-to-day operating conditions may diMer
from the consumption Ngures calculated. The fre-
quency at which you will have to top up AdBlue nwill also vary. Have the AdBlue
n
suppl
y checked
at a qualiNed specialist workshop before making
journeys outside Europe. Before a longer stay out-
side Europe, consult a qualiNed specialist work-
shop.
AdBlue n
range and Nll level
The AdBlue n
Nll level and range can be displayed
via the driver's display. The AdBlue n
range shown
depends strongly on the driving style and operat-
ing conditions. The actual range therefore may
deviate from the range currently displayed on the
driver's display. The information supplied in the
operator's manual regarding the reserve quantity
at the Nrst driver's display warning and on the
minimum top-up quantity when the fuel tank is
empty is also to be understood as guide values. Engine oil
Notes on engine oil
Obser

ve the notes on operating Ouids
(  page 488). *
NOTE Engine damag
e caused by an incor-
rect oil Nlter, incorrect oil or additives 
Do not use engine oils or oil Nlt
ers other
than those which meet the speciNcations
necessary for the prescribed service
intervals. 
Do not alter the engine oil or oil Nlt
er in
order to achieve longer change intervals
than prescribed. 
Do not use additives. 
Have the engine oil changed aser t
he
prescribed intervals. 494
Technical data

Mercedes-Benz recommends having the oil
c
hanged at a qualiNed specialist workshop.
Only use engine oils approved for your vehicle by
Mercedes-Benz.
Petrol engines: for certain countries, diMerent
engine oils can be used in conjunction with
reduced maintenance intervals. Further informa-
tion on diMerent engine oils can be obtained at a
qualiNed specialist workshop.
Engine oil quality and Nlling capacity
Not for plug-in hybrid:
Engine oil speciNcations (petrol engines)Model
MB-Freigabe or MB-
Appr
oval
S 580 4MATIC 229.52
229.61*
All other models 229.51, 229.52, 229.61, 229.71
229.72* Engine oil speciNcations
(diesel engines) Model
MB-Freigabe or MB-
Appr
oval
S 350 d
S 350 d 4MA
TIC
S 400 d 4MATIC 229.52
229.61* Plug-in hybrid:
Engine oil speciNcations
Model
MB-Freigabe or MB-
Appr
oval
S 580 e
S 580 e 4MA
TIC 229.51, 229.52 * recommended for lowest possible fuel con-
sum

ption (lowest SAE viscosity class in each
case; observe possible restrictions of the
approved SAE viscosity classes)
To achieve the lowest possible fuel consumption,
it is recommended to use the engine oil speciNca-
tions marked in the table for the lowest SAE vis- cosity class. Possible restrictions of the approved
S
AE viscosity classes must be observed.
Plug-in hybrid: use only engine oils of viscosity
class SAE 0W-40 or SAE 5W-40.
% If the engine oils listed in the table are not
a

vailable, you may add a maximum of 1.0 litre
of the following engine oils once only.
Engine oils for one-time Nlling onl
y in exceptional
cases:
= Plug-in hybrid: MB-Freigabe or MB-Approval
229.31 or ACEA C3
= Petrol engines:
- S 580 4MATIC: MB-Freigabe or MB-
Approval 229.51 or ACEA C3
- All other models: MB-Freigabe or MB-
Approval 229.31 or ACEA C3
= Diesel engines: MB-Freigabe or MB-Approval
229.51 or ACEA C3
The following values refer to an oil change, includ-
ing the oil Nlter.
Not for plug-in hybrid: Technical data
495

Engine oil Nlling
capacityModel
Capacity
S 350 d 9 litres
S 500 4MATIC
S 580 4MA TIC 8.5 litres
All other models 8 litresPlug-in hybrid:
Engine oil Nlling
capacityModel
Capacity
S 580 e 7.8 litres
S 580 e 4MATIC 7.3 litresNotes on brake
OuidObserve the notes on operating
Ouids
(  pag

e 488). &
WARNING Risk of an accident due t
o
vapour pockets forming in the brake sys-
tem
The brake Ouid cons
tantly absorbs moisture
from the air. This lowers the boiling point of
the brake Ouid. If the boiling point is too low,
vapour pockets may form in the brake system
when the brakes are applied hard.
This impairs the braking eMect. 
Have the brake Ouid r
enewed at the
speciNed intervals. Have the brake
Ouid r
egularly replaced at a quali-
Ned specialist workshop.
Only use a brake Ouid appr
oved by Mercedes-
Benz according to MB-Freigabe or MB-Approval
331.0. Coolant
Notes on coolant
Obser

ve the notes on operating Ouids
(  page 488). &
WARNING Risk of Nr
e

-
A t https://bevo.mercedes-benz.com
- In the Mercedes-Benz BeVo App
= At a qualiNed specialist workshop *
NOTE Ov
erheating at high outside temper-
atures If an inappropriate coolant is used, the cooling
sy

stem is not suPciently protected against
overheating and corrosion at high outside
temperatures. 
Only use coolant approved for
Mer

cedes-Benz. 
Observe the instructions in the
Mer
cedes-Benz SpeciNcations for Oper-
ating Fluids 320.1. Have the coolant regularly replaced at a
q
ualiNed
specialist workshop.
Proportion of antifreeze concentrate in the cool-
ing system:
= A minimum of 50% (antifreeze protection down
to about -37°C) =
A maximum of 55% (antifr
eeze protection
down to -45°C) Notes on windscreen washer
Ouid Observe the notes on operating
Ouids
( pag
e 488). &
WARNING !