Perfume MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

Removing...................................... .185
Storing ...........................................1 83
Warming up ................................... 182
Charging the high-voltage battery
(important safety notes) ................... 180
Chauffeur mode
Display message ............................ 310
Fully reclined position .................... 114
General notes ................................ 111
Installing the head restraint ........... 113
Moving front-passenger seat into
the chauffeur position .................... 112
Moving the front-passenger seat
into the normal position ................. 113
Removing the head restraint .......... 113
Child
Restraint system .............................. 62
Child seat
Forward-facing restraint system ...... 66
LATCH-type (ISOFIX) child seat
anchors ............................................ 63
On the front-passenger seat ............ 65
Rearward-facing restraint system .... 66
Top Tether ....................................... 64
Child-proof locks
Important safety notes .................... 66
Rear doors ....................................... 67
Children
Special seat belt retractor ............... 62
Cigarette lighter ................................ 335
Cleaning
Mirror turn signal ........................... 362
Climate control
Automatic climate control ............. 141
Controlling automatically ............... 147
Cooling with air dehumidification .. 146
Defrosting the windows ................. 151
Defrosting the windshield .............. 151
ECO start/stop function ................ 145
General notes ................................ 140
Immediate pre-entry climate con-
trol ................................................. 158
Indicator lamp ................................ 147
Ionization ....................................... 155
Notes on using the automatic cli-
mate control .................................. 145
Overview of systems ...................... 140
Perfume atomizer .......................... 153 Pre-entry climate control at
departure time ............................... 157
Pre-entry climate control via
key ... 155
P

roblem with the rear window
defroster ........................................ 152
Problems with cooling with air
dehumidification ............................ 147
Rear control panel ......................... 141
Refrigerant ..................................... 432
Refrigerant filling capacity ............. 432
Setting the air distribution ............. 149
Setting the air vents ...................... 158
Setting the airflow ......................... 150
Setting the climate mode ............... 148
Setting the temperature ................ 148
Switching air-recirculation mode
on/off ............................................ 152
Switching on/off ........................... 145
Switching residual heat on/off ...... 152
Switching the rear window
defroster on/off ............................ 151
Switching the synchronization
function on and off ........................ 150
Climate control system
Climate control .............................. 145
Cockpit
Overview .......................................... 32
COLLISION PREVENTION ASSIST
PLUS
Activating/deactivating ................. 270
Display message ............................ 284
Operation/notes .............................. 71
COMAND display
Cleaning ......................................... 364
Combination switch .......................... 131
Consumption statistics (on-board
computer) .......................................... 262
Convenience closing feature .............. 96
Convenience opening feature ............ 95
Coolant (engine)
Checking the level ......................... 356
Display message ............................ 294
Displaying the temperature (on-
board computer) ............................ 269
Filling capacity ............................... 431
Important safety notes .................. 431
Temperature gauge ........................ 257
Warning lamp ................................. 320
6Index

Position of exterior mirror, front-
passenger side ...............................125
Rear view camera .......................... 220
Switching off the engine ................ 190
see PARKTRONIC
Parking aid
see 360° camera
see Active Parking Assist
see Exterior mirrors
see PARKTRONIC
see Rear view camera
Parking assistance
see PARKTRONIC
Parking brake
Applying automatically ................... 191
Applying or releasing manually ...... 191
Display message ............................ 281
Electric parking brake .................... 190
Emergency braking ........................ 192
General notes ................................ 190
Releasing automatically ................. 191
Warning lamp ................................. 319
Parking lamps
Switching on/off ........................... 131
PARKTRONIC
Deactivating/activating ................. 215
Driving system ............................... 214
Function/notes .............................2 14
Important safety notes .................. 214
Problem (malfunction) ................... 216
Range of the sensors ..................... 214
Warning display ............................. 215
PASSENGER AIR BAG
Display message ............................ 289
Indicator lamps ................................ 46
Problem (malfunction) ................... 289
Perfume atomizer
Operating ....................................... 153
Problem (malfunction) ................... 155
Vial ................................................ 153
Pets in the vehicle ............................... 67
Plastic trim (cleaning instruc-
tions) .................................................. 364
PLUG-IN HYBRID operating
Electrical energy generated ........... 249
PLUG-IN HYBRID operation
Automatic engine start (ECO
start/stop function) ....................... 253 Automatic engine switch-off (ECO
start/stop function) ....................... 252
Charge level of the high-voltage
battery ........................................... 245
Charging the high-voltage battery .. 246
Displaying the total range and
electric range ................................. 248
Driving tip
s .................................... 251
EC

O start/stop function ................ 252
Electric motor (power display) ....... 242
Electrical energy generated
(COMAND) ..................................... 249
Energy flow display ........................ 245
Fuel consumption .......................... 249
Fuel consumption (COMAND) ........ 249
General notes ................................ 240
Haptic accelerator pedal ................ 251
High-voltage battery (condition of
charge) .......................................... 245
Hybrid drive system overview ........ 241
HYBRID menu ................................ 272
Important safety notes .................. 240
Instrument cluster (power dis-
play) ............................................... 242
Instrument cluster overview .......... 242
Manual drive program .................... 250
Noiseless start ............................... 249
Operating (on-board computer) ..... 245
Operating mode ............................. 243
Overrun mode ................................ 253
Parking .......................................... 253
Power display ................................ 244
Power display (electric motor) ....... 242
Problems ....................................... 254
Problems with SRS (supplemental
restraint system) ............................ 255
Problems with the combustion
engine ............................................ 254
Problems with the hybrid drive
system ........................................... 255
Problems with the Recuperative
Brake System ................................ 254
Program selector button ................ 250
Pulling away ................................... 250
READY display ............................... 249
Recuperative Brake System ........... 240
Resetting the values (COMAND) .... 249
Route-based operating strategy ..... 253
Index15

Front control panel
XTurn theSmartKey to position 0in th eignition
loc kor remove it (Ypage 162).
XTo activate: press the! orÁ rocker
switch up or down .
The indicator lamp in th e! orÁ rocke r
switch lights up.
The blowe rwill run at alow spee dregardless of
th eairflow setting .
If you activat eth eresidual heat function at high
temperatures ,only th eventilation will be acti-
vated. The blowe rrun sat medium speed.
XTo deactivate: press the! orÁ
rocke rswitch up or down .
The indicator lamp in th e! orÁ rocke r
switch goes out .
Rear control panel
XTurn theSmartKey to position 0in th eignition
loc kor remove it (Ypage 162).
The RESTdisplay appear son th erear com-
partmen tdisplay.
XTo activate: press rockerswitch Lup or
down (Ypage 141).
The indicator lamp in rocke rswitch Llights
up.
XTo deactivate: press rockerswitch Lup or
down (Ypage 141).
The indicator lamp in rocke rswitch Lgoes
out .RES Tgoes out on th erear compartmen t
display.
iIf you do no tactivat eth eresidual heat func-
tion ,RES Tgoes out automatically after fiv e
minute son th erear compartmen tdisplay.
Residual heat is deactivated automatically:
Rafter approximately 30 minute sif the residual
heat function is activated in the front or rear
compartment
Rafter approximately 15 minutes if the residual
heat function is activated in the front and rear
compartments
Rwhen the ignition is switched on
Rif the battery voltage drops
Perfume atomizer
Operating the perfume atomizer
GWARNING
If children open the vial, they could drink the
perfume or it could come into contact with
their eyes. There is a risk of injury. Do not
leave children unsupervised in the vehicle.
If the perfume liquid has been drunk, consult
a doctor. If perfume comes into contact with
your eyes or skin, rinse the eyes with clean
water. If you continue to experience difficul-
ties, consult a doctor.
HEnvironmental note
Full vials must not be dis-
posed of with household
waste. They must be collec-
ted separately and recycled
to protect the environment.
Dispose of full vials in an
environmentally responsible
manner and take them to a
harmful substance collec-
tion point.
:Vial lid
;Vial
The perfume atomizer helps to improve driving
comfort.
Via the multimedia system you can:
Rswitch the perfume atomizer on or off
Rregulate the perfume intensity (see the sepa-
rate operating instructions)
Operating the climate control systems153
Climate control
Z

The following conditions can affect your percep-
tion of the perfume intensity:
Roperating mode of the climate control system
Rinterior temperature
Rtime of year or day
Rair humidity
Rphysiological condition of occupants, e.g. fati-
gue or hunger
The perfume atomizer can only be operated
when the climate control system is switched on
and is only active when the glove box is closed.
The perfume atomizer is provided with a pre-fil-
led vial. You can also choose from a variety of
filled perfume vials and an empty vial which you can fill yourself.
If you refill an empty perfume vial, observe the
separate information sheet attached to the vial.
!If you do not use genuine Mercedes-Benz
interior perfumes, observe the manufactur-
ers' safety notices on the perfume packaging.
Do not refill the pre-filled perfume vial when it is
empty. Dispose of the used vial after use.
XTo insert the perfume vial: open the glove
box (Ypage 326).
XSlide the perfume vial into the holder as far as
it will go.
XTo remove the perfume vial: pull out the
perfume vial.
XTo refill the perfume vial: unscrew the lid of
the empty perfume vial to refill it yourself.
XFill the perfume vial with a maximum of
0.5 fl. oz. (15 ml) of the desired liquid per-
fume.
XScrew the lid back on to the vial.
!Only refill the vial when you are outside the
vehicle. Otherwise, liquid perfume could drip
into the interior and contaminate it.
Always refill the empty refillable vial with the
same perfume. Otherwise, you might not ach-
ieve optimum results from the perfume atom-
izer.
154Operating the climate control systems
Climate control

Problems with the perfume atomizer
ProblemPossible causes/consequences andMSolutions
The vehicle interior is not
perfumed although the
perfume atomizer is acti-
vated.The perfume vial has not been pushed into the holder as far as it will
go.
XSlide the perfume vial into the holder as far as it will go.
The perfume vial is not filled sufficiently.
XPre-filled vials:dispose of the empty vial.
XUse a new pre-filled vial.
XRefillable vials: fill the perfume vial with a maximum of 0.5 fl. oz.
(15 ml) of the same perfume.
The perfume atomizer is faulty.
XHave the perfume atomizer checked at a qualified specialist work-
shop.
Ionization
You can use the "Ionization" function to purify
the air in the vehicle interior and attain an
improved interior climate.
The ionization of the interior air is odorless and
cannot be perceived directly in the vehicle inte-
rior.
You can switch ionization on or off using the
multimedia system (see the separate operating
instructions).
Ionization can only be switched on if the front
climate control system is activated. The side air
vent on the driver's side must be open.
Pre-entry climate control via Smart-
Key
General notes
The "Pre-entry climate control via SmartKey"
function is only available in PLUG-IN HYBRID
vehicles.
Before getting in, the driver's seat area or the
whole interior can be briefly warmed or ventila-
ted in advance with the air from the air vents
being pre-cooled.
The high-voltage battery must be sufficiently
charged before "Pre-entry climate control via
SmartKey" can be activated. When the vehicle is pre-cooled, the following
functions are activated if required:
RClimate control system
RBlower
RSeat ventilation
When the vehicle is pre-heated, the following
functions are activated if required:
RClimate control system
RBlower
RSeat heating
RSteering wheel heating
RExterior mirror heating
RRear window defroster
If you have activated the following functions
using the multimedia system, they are activated
together with the "Pre-entry climate control via
SmartKey" function:
RArmrest heating
RPerfume atomizer
RIonization
Activating the perfume atomizer or ionization
(see separate operating instructions).
Activating or deactivating "Pre-entry
climate control via SmartKey"
Before "Pre-entry climate control via SmartKey"
can be activated, you must activate the function
via the multimedia system (see separate oper-
ating instructions).
Operating the climate control systems155
Climate control
Z

XTo activate pre-entry climate control via
SmartKey:unlock the vehicle with the Smart-
Key or KEYLESS-GO.
The climate control functions are activated
for up to 5 minutes for pre-heating and pre-
cooling.
To deactivate "Pre-entry climate control via SmartKey": "Pre-entry climate control via
SmartKey" switches off automatically when the
engine is started.
The following functions remain active after the
engine is started:
RSeat heating (heating)
RSeat ventilation (ventilation)
RArmrest heating
RPerfume atomizer
RIonization
An activated "Pre-entry climate control via
SmartKey" function can be deactivated using
the rocker switch (
Ypage 158).
156Operating the climate control systems
Climate control

Problems with "Pre-entry climate control via SmartKey"
ProblemPossible causes/consequences andMSolutions
"Pre-entry climate con-
trol via SmartKey" can-
not be switched on or
has switched itself off.The condition of charge of the high-voltage battery is under the speci-
fied minimum condition of charge.
XStart the engine when the vehicle is at a standstill.
The engine powers the electric motor. The electric motor operates
as a generator. The high-voltage battery is being charged.
Further information on charging the high-voltage battery via:
Ra mains socket (Ypage 183)
Ra charging station (Ypage 186)
Ra wallbox (Ypage 185)
"Pre-entry climate control via SmartKey" has been started more than
twice with the engine switched off.
XSwitch on the engine and let it run for more than ten seconds.
XTry again to switch on "Pre-entry climate control via SmartKey".
Pre-entry climate control at time of
departure
Important safety notes
GWARNING
If persons, particularly children are subjected to prolonged exposure to extreme heat or
cold, there is a risk of injury, possibly even
fatal. Never leave children unattended in the
vehicle.
General notes
The "Pre-entry climate control at departure
time" function is only available in PLUG-IN
HYBRID vehicles.
You can use the "Pre-entry climate control at
departure time" function to cool or heat the
vehicle interior if the engine is not running.
The "Pre-entry climate control at departure
time" function can be activated regardless of
whether or not the vehicle is connected to an
electric power supply. The condition of charge of
the high-voltage battery must be higher than the
specified minimum condition of charge, how-
ever.
When the vehicle is connected to an electric
power supply, priority is given to charging the
high-voltage battery to the specified minimum charge. "Pre-entry climate control at departure
time" is only activated subsequently.
The running time of the "Pre-entry climate con-
trol at departure time" function may be reduced
if:
Rthe vehicle is not connected to an electric
power supply and
Rthe high-voltage battery is not fully charged
With active "Pre-entry climate control at depar-
ture time" the condition of charge of the high-
voltage battery can be reduced, even if the
charge cable connector is connected.
When the vehicle is cooled, the following func-
tions are activated if required:
RClimate control system
RBlower
RSeat ventilation
When the vehicle is heated, the following func-
tions are activated if required:
RClimate control system
RBlower
RSeat heating
RSteering wheel heating
RArmrest heating
RExterior mirror heating
RRear window defroster
If you have switched on the perfume atomizer or the ionization using the multimedia system,
Operating the climate control systems157
Climate control
Z

these will be activated together with the "Pre-
entry climate control at departure time".
Activating the perfume atomizer or ionization
(see separate operating instructions).
Setting the departure time
You can set the departure time using the on-
board computer or via the My Mercedes Electric
– Vehicle Homepage. The activation of the "Pre-
entry climate control at departure time" func-
tion can be linked to this departure time. Your
vehicle will then be cooled or heated until the
desired temperature is reached in time for the
set departure time. "Pre-entry climate control at departure time" will be activated a maximum of
55 minutes before departure. If the departure is
delayed, the vehicle will be heated or cooled for
another five minutes.
XTo set the departure time: set the departure
time using the on-board computer
(
Ypage 272). Set the departure time via the
My Mercedes Electric – Vehicle Homepage
(
Ypage 189).
XTo activate or deactivate "Pre-entry cli-
mate control at departure time": activate
or deactivate "Pre-entry climate control at
departure time" via the multimedia system
(see the separate operating instructions).
Activate or deactivate "Pre-entry climate con-
trol at departure time" via the My Mercedes
Electric – Vehicle Homepage (
Ypage 189).
When activating the "Pre-entry climate control
at departure time" function: you can sele ct
w

hether only the driver's area or the whole vehi-
cle interior should be heated or cooled.
The "Pre-entry climate control at departure
time" function switches off automatically when
the vehicle is started. The following functions
remain active:
RSeat heating
RSeat ventilation
RArmrest heating
RSteering wheel heating
RPerfume atomizer
RIonization
Switching off "Pre-entry climate control at
departure time": the activated "Pre-entry cli-
mate control at departure time" can be switched
off using the rocker switch (
Ypage 158).
Activating or deactivating "Immediate
pre-entry climate control" using the
rocker switch
You can activate "Immediate pre-entry climate
control" even if the vehicle interior is already at
the desired temperature. This means that the
vehicle interior continues to be cooled or
heated, e.g. if the journey is interrupted for up to 50 minutes, and the interior temperature is kept
constant.
XTo activate or deactivate "Immediate pre-
entry climate control": press rocker
switch :up or down.
The blue or red indicator lamp on the rocker
switch lights up or goes out.
The colors of the indicator lamps on rocker
switch :have the following meanings:
Rblue: cooling activated
Rred: heating activated
Ryellow: departure time is preselected
Setting the air vents
Important safety notes
GWARNING
Very hot or very cold air can flow from the air
vents. This could result in burns or frostbite in
the immediate vicinity of the air vents. There
is a risk of injury.
Make sure that all vehicle occupants always
maintain a sufficient distance to the air out-
lets. If necessary, redirect the airflow to
another area of the vehicle interior.
158Setting the air vents
Climate control