climate MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

Index....................................................... 3
Introduction......................................... 24
At a glance........................................... 32
Safety................................................... 42
Opening and closing...........................79
Seats, steering wheel and mirrors ..104
Lights and windshield wipers ..........130
Climate control ................................. 140
Driving and parking..........................161
On-board computer and displays ....256
Stowage and features ......................325
Maintenance and care ......................352
Breakdown assistance .....................367
Wheels and tires ............................... 384
Technical data................................... 425
2Contents

1, 2, 3 ...
4ETS (Electronic Traction System)see ETS/4ETS (Electronic Trac-
tion System)
4MATIC (permanent four-wheel
drive) .................................................. 213
12 V socket
see Sockets
115 V socket ...................................... 337
360° camera
Cleaning ........................................ .363
Function/notes .............................2 24
A
ABS (Anti-lock Braking System)
Display message ............................ 278
Function/notes ................................ 68
Warning lamp ................................. 316
Accident
Automatic measures after an acci-
dent ................................................. 61
Activating/deactivating cooling
with air dehumidification ................. 146
Activating/deactivating Night
View Assist Plus
With spotlight function ................... 232
Active Blind Spot Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 234
Active Body Control (ABC)
Display message ............................ 300
Function/notes ............................. 210
Active Lane Keeping Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 237
Active multicontour seat .................. 117
Active Parking Assist
Detecting parking spaces .............. 217
Display message ............................ 302
Exiting a parking space .................. 219
Function/notes ............................. 216
Important safety notes .................. 216 Parking .......................................... 218
ADAPTIVE BRAKE ................................. 75
Adaptive Brake Assist
Function/notes ................................ 72
Adaptive Damping System (ADS) ..... 212
Adaptive Highbeam Assist Plus
Display message ............................ 293
Function/notes ............................. 133
Switching on/off ........................... 133
Additional speedometer ................... 274
Additives (engine oil) ........................ 430
Air bags
Belt bags .......................................... 48
Cushion air bags .............................. 53
Deployment ..................................... 57
Display message ............................ 289
Front air bag (driver, front
passenger) ....................................... 52
Important safety notes .................... 50
Introduction ..................................... 50
Knee bag .......................................... 52
Occupant Classification System
(OCS) ............................................... 53
PASSENGER AIR BAG i
ndicator
lamps ............................................... 46
Side impact air bag .......................... 52
Window curtain air bag .................... 53
Air vents
Glove box ....................................... 159
Important safety notes .................. 158
Rear ............................................... 160
Setting ........................................... 158
Setting the center air vents ........... 159
Setting the side air vents ............... 159
Air-conditioning system
see Climate control
AIRMATIC
Display message ............................ 299
Function/notes ............................. 212
Alarm
ATA (Anti-Theft Alarm system) ......... 78
Switching off (ATA) .......................... 78
Switching the function on/off
(ATA) ................................................ 78
Alarm system
see ATA (Anti-Theft Alarm system)
Anti-lock braking system
see ABS (Anti-lock Braking System)
Index3

Removing...................................... .185
Storing ...........................................1 83
Warming up ................................... 182
Charging the high-voltage battery
(important safety notes) ................... 180
Chauffeur mode
Display message ............................ 310
Fully reclined position .................... 114
General notes ................................ 111
Installing the head restraint ........... 113
Moving front-passenger seat into
the chauffeur position .................... 112
Moving the front-passenger seat
into the normal position ................. 113
Removing the head restraint .......... 113
Child
Restraint system .............................. 62
Child seat
Forward-facing restraint system ...... 66
LATCH-type (ISOFIX) child seat
anchors ............................................ 63
On the front-passenger seat ............ 65
Rearward-facing restraint system .... 66
Top Tether ....................................... 64
Child-proof locks
Important safety notes .................... 66
Rear doors ....................................... 67
Children
Special seat belt retractor ............... 62
Cigarette lighter ................................ 335
Cleaning
Mirror turn signal ........................... 362
Climate control
Automatic climate control ............. 141
Controlling automatically ............... 147
Cooling with air dehumidification .. 146
Defrosting the windows ................. 151
Defrosting the windshield .............. 151
ECO start/stop function ................ 145
General notes ................................ 140
Immediate pre-entry climate con-
trol ................................................. 158
Indicator lamp ................................ 147
Ionization ....................................... 155
Notes on using the automatic cli-
mate control .................................. 145
Overview of systems ...................... 140
Perfume atomizer .......................... 153 Pre-entry climate control at
departure time ............................... 157
Pre-entry climate control via
key ... 155
P

roblem with the rear window
defroster ........................................ 152
Problems with cooling with air
dehumidification ............................ 147
Rear control panel ......................... 141
Refrigerant ..................................... 432
Refrigerant filling capacity ............. 432
Setting the air distribution ............. 149
Setting the air vents ...................... 158
Setting the airflow ......................... 150
Setting the climate mode ............... 148
Setting the temperature ................ 148
Switching air-recirculation mode
on/off ............................................ 152
Switching on/off ........................... 145
Switching residual heat on/off ...... 152
Switching the rear window
defroster on/off ............................ 151
Switching the synchronization
function on and off ........................ 150
Climate control system
Climate control .............................. 145
Cockpit
Overview .......................................... 32
COLLISION PREVENTION ASSIST
PLUS
Activating/deactivating ................. 270
Display message ............................ 284
Operation/notes .............................. 71
COMAND display
Cleaning ......................................... 364
Combination switch .......................... 131
Consumption statistics (on-board
computer) .......................................... 262
Convenience closing feature .............. 96
Convenience opening feature ............ 95
Coolant (engine)
Checking the level ......................... 356
Display message ............................ 294
Displaying the temperature (on-
board computer) ............................ 269
Filling capacity ............................... 431
Important safety notes .................. 431
Temperature gauge ........................ 257
Warning lamp ................................. 320
6Index

Coolbox.............................................. 339
Cooling
see Climate control
Copyright ............................................ .31
Cornering light function
Display message ............................ 291
Function/notes ............................ .132
Crash-responsive emergency light-
ing ....................................................... 135
Crosswind Assist (vehicles with
MAGIC BODY CONTROL) ................... 210
Crosswind Assist (vehicles with-
out MAGIC BODY CONTROL) ...............75
Cruise control
Calling up the speed last stored .... 198
Cruise control lever ....................... 197
Deactivating ................................... 199
Display message ............................ 305
Driving system ............................... 197
Function/notes ............................. 197
General notes ................................ 197
Important safety notes .................. 197
Setting a speed .............................. 198
Storing and maintaining current
speed ............................................. 198
Cup holder
Center console .............................. 331
Important safety notes .................. 330
Rear compartment ......................... 331
Temperature controlled ................. 332
Cushion air bags .................................. 53
Customer Assistance Center
(CAC) ..................................................... 29
Customer Relations Department ....... 29
D
Data
see Technical data
Data carrier
Selecting ........................................ 266
Daytime running lamps
Display message ............................ 293
Function/notes ............................. 130
Switching on/off (on-board com-
puter) ............................................. 274
Declarations of conformity ................. 28
Diagnostics connection ...................... 28Digital speedometer
......................... 263
DIRECT SELECT lever
Automatic transmission ................. 170
Display
see Display messages
see Warning and indicator lamps
Display message
Hybrid drive system ....................... 297
Display messages
ASSYST PLUS ................................ 357
Calling up (on-board computer) ..... 277
Driving systems ............................. 299
Engine ............................................ 294
General notes ................................ 277
Hiding (on-board computer) ........... 277
Introduction ................................... 277
Lights ............................................. 291
Safety systems .............................. 278
SmartKey ....................................... 312
Tires ............................................... 306
Vehicle ........................................... 308
Distance recorder
see Odometer
see Trip odometer
Distance warning (warning lamp) .... 322
Distance warning function
Function/notes ................................ 71
DISTRONIC PLUS
Activating ....................................... 201
Activation conditions ..................... 201
Cruise control lever ....................... 201
Deactivating ................................... 205
Display message ............................ 303
Displays in the instrument cluster .. 204
Driving tips .................................... 205
Driving with DISTRONIC PLUS ....... 202
Function/notes ............................. 199
Important safety notes .................. 200
Setting a speed .............................. 203
Setting the specified minimum
distance ......................................... 204
Stopping ........................................ 203
with Steering Assist and Stop&Go
Pilot ............................................... 207
Doors
Automatic locking (switch) ............... 87
Central locking/unlocking
(SmartKey) ....................................... 79
Index7

F
Features............................................ .330
Filling capacities (Technical data) ... 427
Flat tire
Changing a wheel/mounting the
spare wheel ................................... 405
MOExtended tires .......................... 368
Preparing the vehicle ..................... 367
TIREFIT kit ...................................... 369
Floormats ...........................................3 50
Folding table ...................................... 328
Frequencies
Mobile phone ................................. 425
Two-way radio ................................ 425
Front-passenger seat
Adjusting from the driver's seat ..... 108
Adjusting from the rear compart-
ment .............................................. 108
Fuel
Additives ........................................ 429
Consumption statistics .................. 262
Displaying the current consump-
tion ................................................ 261
Displaying the range ......................2 61
Driving tips ....................................1 92
Fuel gauge ....................................... 33
Grade (gasoline) ............................ 428
Important safety notes .................. 428
Problem (malfunction) ................... 180
Refueling ........................................ 177
Tank content/reserve fuel ............. 428
Fuel level
Calling up the range (on-board
computer) ...................................... 261
Fuel tank
Capacity ........................................ 428
Problem (malfunction) ................... 180
Fuses
Allocation chart ..................... 381, 383
Before changing .............................3 82
Dashboard fuse box ....................... 382
Fuse box in the engine compart-
ment .............................................. 383
Fuse box in the front-passenger
footwell .......................................... 382
Fuse box in the trunk ..................... 383
Important safety notes .................. 381
G
Garage door opener
Clearing the memory ..................... 350
General notes ................................ 347
Important safety notes .................. 348
Opening/closing the garage door .. 350
Problems when programming ........3 49
Programming (button in the rear-
view mirror) ................................... 348
Synchronizing the rolling code ....... 349
Gasoline ............................................. 428
Gear indicator (on-board com-
puter, Mercedes-AMG vehicles) ....... 275
Genuine parts ...................................... 24
Glove box ...........................................3 26
H
Handbrake
see Parking brake
HANDS-FREE ACCESS .......................... 91
Hazard warning lamps ......................132
Head restraints
Adjusting ....................................... 114
Adjusting (manually) ......................1 15
Adjusting (rear) .............................. 116
EASY ADJUST luxury head
restraint ......................................... 115
Luxury ............................................ 115
Supplementary cushion ................. 116
Head-up display
Adjusting the brightness ................ 273
Displays and operating .................. 259
Function/notes .............................2 59
Important safety notes .................. 259
Selecting displays .......................... 273
Setting the position ....................... 273
Headlamps
Fogging up ..................................... 134
see Automatic headlamp mode
Heating
see Climate control
High beam flasher .............................1 32
High-beam headlamps
Adaptive Highbeam Assist PLUS .... 133
Display message ............................ 292
Switching on/off ........................... 132
10Index

Starting .......................................... 249
When the vehicle is stationary ....... 251
Power locks ......................................... 87
Power washers .................................. 360
Power windows
see Side windows
Pre-entry climate control (via
SmartKey)
Problems (malfunctions) ................ 157
Pre-entry climate control at depar-
ture time
General notes ................................ 157
Pre-entry climate control at time of
departure
Setting departure time ................... 158
Pre-entry climate control via key
General notes ................................ 155
PRE-SAFE
®(anticipatory occupant
protection)
Display message ............................ 284
Operation ......................................... 59
PRE-SAFE
®Brake
Activating/deactivating ................. 271
Display message ............................ 284
Function/notes ................................ 75
Important safety notes .................... 76
Warning lamp ................................. 322
PRE-SAFE
®PLUS (anticipatory
occupant protection PLUS)
Display message ............................ 284
Operation ......................................... 60
Program selector button .................. 173
Protection against theft
ATA (Anti-Theft Alarm system) ......... 78
Immobilizer ...................................... 78
Protection of the environment
General notes .................................. 24
Pulling away
Automatic transmission ................. 165
General notes ................................ 165
Hill start assist ............................... 165
Q
QR codeMercedes-Benz Guide App ................. 1
Rescue card ..................................... 29
Qualified specialist workshop ........... 28
R
Radio
Selecting a station ......................... 265
Radio-wave reception/transmis-
sion in the vehicle
Declaration of conformity ................ 28
Rain closing feature
Panorama sliding sunroof ................ 99
RBS (Recuperative Brake System)
Warning lamp ................................. 315
Reading lamp ..................................... 134
Rear compartment
Activating/deactivating climate
control ........................................... 145
Setting the air distribution ............. 149
Setting the air vents ...................... 160
Setting the airflow ......................... 150
Setting the temperature ................ 148
Stowage compartment .................. 327
Rear lamps
see Lights
Rear seats
Adjusting ....................................... 107
Adjusting a rear reclining seat ....... 107
Overview .......................................... 41
Setting the reclined position .......... 107
Rear view camera
Cleaning instructions ..................... 363
Displays in the COMAND display ... 221
Function/notes ............................. 220
Rear window blind ............................ 334
Rear window defroster
Problem (malfunction) ................... 152
Switching on/off ........................... 151
Rear-view mirror
Anti-glare (manual) ........................ 123
Dipping (automatic) ....................... 124
Recuperative Brake System
Driving safety systems ..................... 44
Important safety notes .................... 44
Refrigerant (air-conditioning sys-
tem)
Important safety notes .................. 432
Refueling
Fuel gauge ....................................... 33
Important safety notes .................. 177
16Index

Refuelingprocess (PLUG-IN
HYBRID vehicles) .......................... .178
see Fuel
Remote control
Garage door opener ....................... 347
Programming (garage door
opener) .......................................... 348
Replacing bulbs
General notes ................................ 135
Reporting safety defects .................... 29
Rescue card ......................................... 29
Reserve (fuel tank)
see Fuel
Reserve fuel
Display message ............................ 296
Warning lamp ................................. 320
Residual heat (climate control) ........ 152
Restraint system
Display message ............................ 287
Introduction ..................................... 44
Warning lamp ................................. 319
Warning lamp (function) ................... 45
Reversing feature
Panorama sliding sunroof ................ 98
Roller sunblinds ............................... 99
Side windows ................................... 94
Trunk lid ........................................... 89
Reversing lamps (display mes-
sage) ................................................... 292
ROAD SURFACE SCAN ....................... 211
Roadside Assistance (breakdown) .... 26
Roller sunblind
Panorama roof with power tilt/
sliding panel ..................................... 99
Rear side windows ......................... 333
Rear window .................................. 334
Roller sunblind of the panorama
roof with power tilt/sliding panel
Operating (front roller sunblind) .... 100
Operating (rear roller sunblind) ...... 100
Roof carrier ........................................ 330
Roof lining and carpets (cleaning
guidelines) ......................................... 366
Roof load (maximum) ........................ 433S
Safety
Children in the vehicle ..................... 61
Hybrid drive system ......................... 42
see Occupant safety
see Operating safety
Safety notes
Hybrid vehicles ................................ 42
Safety system
see Driving safety systems
SD memory card
Selecting ........................................ 266
Seat
Adjusting the front-passenger
seat from the driver's seat ............. 108
Multicontour seat in the rear com-
partment ........................................ 117
Seat belt buckle extender
Display message ............................ 285
Seat belt extender
Function/notes ................................ 49
Seat belts
Adjusting the driver's and front-
passenger seat belt ......................... 50
Adjusting the height ......................... 49
Cleaning ......................................... 366
Correct usage .................................. 48
Fastening ......................................... 49
Important safety guidelines ............. 47
Introduction ..................................... 46
Releasing ......................................... 50
Seat belt extender ........................... 49
Warning lamp ................................. 313
Warning lamp (function) ................... 50
Seating
Seating comfort package ............... 117
Seating comfort package ................. 117
Seats
Active multicontour seat ................ 117
Adjusting (electrically) ................... 106
Adjusting (rear compartment) ........ 107
Adjusting the 4-way lumbar sup-
port ................................................ 118
Adjusting the head restraint .......... 114
Calling up a stored setting (mem-
ory function) .................................. 127
Chauffeur mode ............................. 111
Index17

Coolant (on-board computer) .........269
Engine oil (on-board computer,
Mercedes-AMG vehicles) ...............2 75
Outside temperature ......................2 57
Setting (climate control) ................ 148
Transmission oil (on-board com-
puter, Mercedes-AMG vehicles) ..... 275
Tire pressure
Calling up (on-board computer) ..... 390
Checking manually ........................ 390
Display message ............................ 306
Maximum ....................................... 390
Not reached (TIREFIT) .................... 370
Notes ............................................. 389
Reached (TIREFIT) .......................... 371
Recommended ............................... 387
Tire pressure loss warning system
General notes ................................ 393
Important safety notes .................. 393
Restarting ...................................... 394
Tire pressure monitor
Checking the tire pressure elec-
tronically ........................................ 392
Function/notes .............................3 90
General notes ................................ 390
Important safety notes .................. 391
Radio type approval for the tire
pressure monitor ........................... 393
Restarting ...................................... 392
Warning lamp ................................. 323
Warning message .......................... 392
TIREFIT kit
Important safety notes .................. 369
Storage location ............................ 367
Tire pressure not reached .............. 370
Tire pressure reached .................... 371
Using ............................................. 369
Tires
Aspect ratio (definition) ................. 404
Average weight of the vehicle
occupants (definition) .................... 403
Bar (definition) ............................... 403
Changing a wheel .......................... 405
Characteristics .............................. 403
Checking ........................................ 385
Curb weight (definition) ................. 404
Definition of terms ......................... 403
Direction of rotation ...................... 405 Displa
y message ............................ 306
Distribution of the vehicle occu-
pants (definition) ............................ 405
DOT (Department of Transporta-
tion) (definition) ............................. 403
DOT, Tire Identification Number
(TIN) ............................................... 402
GAWR (Gross Axle Weight Rating)
(definition) ..................................... 403
General notes ................................ 410
GVW (Gross Vehicle Weight) (def-
inition) ........................................... 403
GVWR (Gross Vehicle Weight Rat- ing) (definition) .............................. 404
Important safety notes .................. 384
Increased vehicle weight due to
optional equipment (definition) ...... 403
Information on driving .................... 384
Kilopascal (kPa) (definition) ........... 404
Labeling (overview) ........................ 400
Load bearing index (definition) ...... 405
Load index ..................................... 402
Load index (definition) ................... 404
Maximum load on a tire (defini-
tion) ............................................... 404
Maximum loaded vehicle weight
(definition) ..................................... 404
Maximum permissible tire pres-
sure (definition) ............................. 404
Maximum tire load ......................... 402
Maximum tire load (definition) ....... 404
MOExtended tires .......................... 386
Optional equipment weight (defi-
nition) ............................................ 404
PSI (pounds per square inch) (def-
inition) ........................................... 404
Replacing ....................................... 405
Service life ..................................... 385
Sidewall (definition) ....................... 404
Snow chains .................................. 386
Speed rating (definition) ................ 403
Storing ........................................... 405
Structure and characteristics
(definition) ..................................... 403
Summer tires in winter .................. 386
Temperature .................................. 399
TIN (Tire Identification Number)
(definition) ..................................... 404
20Index

Cockpit
FunctionPage
:Steering wheel paddle shift-
ers174
;Combination switch131
=Horn
?Instrument cluster33
ADIRECT SELECT lever170
BOverhead control panel39
CControl panel for:
ÜLowering the rear seat
head restraints116
u Extending/retracting
the rear roller sunblind334
PASSENGER AIR BAG indica-
tor lamp46
Adjusting the brightness of
the instrument lighting and
the multimedia system dis-
play
DIgnition lock162
Start/Stop button162
FunctionPage
EClimate control systems140
FAdjusts the steering wheel120
Steering wheel heating120
GCruise control lever197
HElectric parking brake190
IDiagnostics connection28
JOpening the hood352
KLight switch130
LControl panel for:
Activating Steering Assist
and Stop&Go Pilot207
Switching on Active Lane
Keeping Assist237
Deactivating PARKTRONIC214
Switching on the 360° cam-
era224
Activating Night View Assist230
Switching on the head-up
display259
32Cockpit
At a glance

Deactivate the hybrid system manually if:
Rthe6 restraint system warning lamp in the
instrument cluster lights up after an accident
Rthe vehicle is badly damaged, e.g. after an
accident, and the restraint system compo-
nents were not activated
Rthe vehicle is badly damaged and has to be
towed or transported
XIf possible, move the vehicle out of the
danger zone: shift the automatic transmis-
sion into position N.
XRelease the electric parking brake.
XRoll the vehicle to a safe place and park it
safely.
Get assistance from others if necessary.
iThe vehicle is locked automatically when
the ignition is switched on and the wheels are
turning. There is therefore a risk of being
locked out if the vehicle is being pushed or
tested on a dynamometer.
XSwitch the ignition off.
XShift the automatic transmission to park posi-
tion P(Ypage 170).
Depress the electric parking brake
(
Ypage 190).
Secure the vehicle against rolling away
(
Ypage 406).
XTo use the high-voltage switch-off device:
open the trunk lid.
XLift the trunk floor upwards (Ypage 329).
XRemove the right-hand paneling in the trunk.
XPress release clip :in the direction of the
arrow and pull it out.
XPull the high voltage switch-off device ;
apart until it engages in the stop position.
If the hybrid drive system has been deactivated
due to reasons mentioned above, have it checked at a qualified specialist workshop
before reactivation.
High-voltage battery
GWARNING
In the event of a vehicle fire, the internal pres- sure of the high-voltage battery can exceed a
critical value. In this case flammable gas
escapes through a ventilation valve on the
underbody. The gas can ignite. There is a risk
of injury.
Leave the danger zone immediately. Secure
the danger area at a suitable distance, whilst
observing legal requirements.
GWARNING
If the housing of the high-voltage battery has
been damaged, electrolyte and gases may
leak out. These are poisonous and caustic.
There is a risk of injury.
Avoid contact with skin, eyes or clothing.
Immediately rinse electrolyte splashes off
with water and seek medical attention
straight away.
!Exhaustive discharge caused by the vehicle
standing idle for lengthy periods can damage
the high-voltage battery.
Hybrid vehicles: if the vehicle is idle for
lengthy periods, run it for a few minutes once every six weeks to charge up the high-voltage
battery. During the charging process, switch
off all electrical consumers, e.g. the auto-
matic climate control or the seat heating.
PLUG-IN HYBRID vehicles: make sure that
the high-voltage battery is connected to a
charging station during long periods when the
vehicle is standing idle.
PLUG-IN HYBRID vehicles: charging the high-
voltage battery (
Ypage 180).
Engine compartment
Before opening the hood:
XApply the electric parking brake.
XShift the automatic transmission to park posi-
tion P.
XSwitch the ignition off.
Hybrid vehicles43
Safety
Z