octane MERCEDES-BENZ S600 2006 W221 Owner's Manual

13 Introduction
Operator’s Manual
Operating your vehicle outside the USA or Canada
If you plan to operate your vehicle in for-
eign countries, please be aware that:

service facilities or replacement parts
may not be readily available,


unleaded gasoline for vehicles with cat-
alytic converters may not be available;
the use of leaded fuels will damage the
catalysts,


gasoline may have a considerably low-
er octane rating, and improper fuel can
cause engine damage.Certain Mercedes-Benz models are avail-
able for delivery in Europe under our Euro-
pean Delivery Program. For details, consult
your authorized Mercedes-Benz Center or
write to:
In the USA:
Mercedes-Benz USA, LLC
European Delivery Department
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada:
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9

285 Operation
At the gas station

Replace fuel cap by turning it clockwise
until it audibly engages.

Close the fuel filler flap.
Check regularly and before a long trip
1Windshield washer and headlamp
cleaning system*
2Coolant level
3Brake fluid
Warning!
G
Overfilling of the fuel tank may create pres-
sure in the system which could cause a gas
discharge. This could cause the gas to spray
back out when removing the fuel pump noz-
zle, which could cause personal injury.
iOnly use premium unleaded gasoline
with a minimum Posted Octane Rating
of 91 (average of 96 RON/86 MON).
Information on gasoline quality can
normally be found on the fuel pump.
More information on gasoline can be
found in the Factory Approved Service
Products pamphlet.iLeaving the engine running and the fuel
cap open can cause the yellow engine
malfunction indicator lamp ?
(USA only),
±
(Canada only)
to illuminate.
For more information, see the “Practi-
cal hints” section (
page 343).
iOpening the hood, see (
page 287).

424 Technical dataEngineModel
S 350 (220.067)
1
S 430 (220.070, 220.170)
1
S 430 4MATIC (220.183)
1
1The quoted data apply only to the standard vehicle. See an authorized Mercedes-Benz Center for the corresponding data of all special bodies and special equipment.
S 500 (220.175)
1
S 500 4MATIC (220.184)
1
Engine
112
113
113
Mode of operation
4-stroke engine, gasoline injec-
tion
4-stroke engine, gasoline injec-
tion
4-stroke engine, gasoline injec-
tion
No. of cylinders
6
8
8
Bore
3.82 in (97.00 mm)
3.54 in (89.90 mm)
3.82 in (97.00 mm)
Stroke
3.31 in (84.00 mm)
3.31 in (84.00 mm)
3.31 in (84.00 mm)
Total piston displacement
227.3 cu in (3724 cm
3)
260.3 cu in (4266 cm
3)
303.0 cu in (4966 cm
3)
Compression ratio
10:1
10:1
10:1
Output acc. to SAE J 1349
241 hp/5700 rpm
2
(180 kW/5700 rpm)
275 hp/5750 rpm
2
(205 kW/5750 rpm)
2Premium fuel required. Performance may vary with fuel octane rating.
302 hp/5600 rpm
2
(225 kW/5600 rpm)
Maximum torque
acc. to SAE J 1349
258 lb-ft/3000 - 4500 rpm
(350 Nm/3000 - 4500 rpm)
295 lb-ft/3000 - 4400 rpm
(400 Nm/3000 - 4400 rpm)
339 lb-ft/2700 - 4250 rpm
(460 Nm/2700 - 4250 rpm)
Maximum engine speed
6000 rpm
6000 rpm
6000 rpm
Firing order
1-4-3-6-2-5
1-5-4-2-6-3-7-8
1-5-4-2-6-3-7-8
Poly-V-belt
2380 mm
2380 mm
2380 mm

425 Technical data
Engine
Model
S 55 AMG (220.174)
1
S 600 (220.176)
1
S 65 AMG (220.179)
1
Engine
113
275
275
Mode of operation
4-stroke engine, gasoline injec-
tion
4-stroke engine, gasoline injec-
tion
4-stroke engine, gasoline injec-
tion
No. of cylinders
8
12
12
Bore
3.82 in (97.00 mm)
3.23 in (82.00 mm)
3.25 in (82.60 mm)
Stroke
3.62 in (92.00 mm)
3.43 in (87.00 mm)
3.66 in (93.00 mm)
Total piston displacement
331.8 cu in (5439 cm
3)
336.4 cu in (5513 cm
3)
364.9 cu in (5980 cm
3)
Compression ratio
9:1
9:1
9:1
Output acc. to SAE J 1349
493 hp/6100 rpm
2
(368 kW/6100 rpm)
493 hp/5000 rpm
2
(368 kW/5000 rpm)
603 hp/4800 - 5100 rpm
2
(450 kW/4800 - 5100 rpm)
Maximum torque
acc. to SAE J 1349
516 lb-ft/2750 - 4000 rpm
(700 Nm/2750 - 4000 rpm)
590 lb-ft/1800 - 3500 rpm
(800 Nm/1800 - 3500 rpm)
738 lb-ft/2000 - 4000 rpm
(1000 Nm/2000 - 4000 rpm)
Maximum engine speed
6500 rpm
5950 rpm
5950 rpm
Firing order
1-5-4-2-6-3-7-8
1-12-5-8-3-10-6-7-2-11-4-9
1-12-5-8-3-10-6-7-2-11-4-9
Poly-V-belt
Belt one: 1289 mm
Belt two: 2462 mm
2335 mm
2335 mm
1The quoted data apply only to the standard vehicle. See an authorized Mercedes-Benz Center for the corresponding data of all special bodies and special equipment.2Premium fuel required. Performance may vary with fuel octane rating.

436 Technical dataFuels, coolants, lubricants, etc.
Model
Capacity
Fuels, coolants, lubricants, etc.
Fuel tank
All models
23.2 US gal (88.0 l)
Premium unleaded gasoline:
Minimum Posted Octane 91
(Avg. of 96 RON/86 MON)
including a reserve of
All models except
S55AMG, S65AMG
2.9 US gal (11.0 l)
including a reserve of
S55AMG, S65AMG
3.7 US gal (14.0 l)
Air conditioning system
All models
R-134a refrigerant and special PAG
lubricant oil (never R-12)
Windshield washer
S 350
S 430, S 430 4MATIC
3.2 US qt. (3.0 l)
MB Windshield Washer Concentrate
1
1Use MB Windshield Washer Concentrate “S” and water for temperatures above freezing or MB Windshield Washer Concentrate “S” and commercially available pre-
mixed windshield washer solvent/antifreeze for temperatures below freezing point. Follow suggested mixing ratios (page 442).Windshield washer and
headlamp cleaning system*
All models
7.1 US qt (6.7 l)
MB Windshield Washer Concentrate
1

438 Technical dataFuels, coolants, lubricants, etc.Premium unleaded gasoline
Fuel requirements
Use only premium unleaded fuel:

The octane number (posted at the
pump) must be 91 min. It is an average
of both the Research (R) octane num-
ber and the Motor (M) octane number:
(R+M)/2). This is also known as the
ANTI-KNOCK INDEX.
Unleaded gasoline containing oxygenates
such as ethanol, IPA, IBA and TBA can be
used provided the ratio of any one of these
oxygenates to gasoline does not exceed
10%; MTBE must not exceed 15%.
The ratio of methanol to gasoline must not
exceed 3% plus additional co-solvents.
Using mixtures of ethanol and methanol is
not allowed. Gasohol, which contains
10% ethanol and 90% unleaded gasoline,
can be used.
These blends must also meet all other fuel
requirements, such as resistance to spark
knock, boiling range, vapor pressure, etc.
Warning!
G
Gasoline is highly flammable and poisonous.
It burns violently and can cause serious
injury. Whenever you are around gasoline,
avoid inhaling fumes and skin contact, extin-
guish all smoking materials. Never allow
sparks, flame or smoking materials near
gasoline!
!To maintain the engine’s durability and
performance, premium unleaded gaso-
line must be used. If premium unleaded
gasoline is not available and low octane
fuel is used, follow these precautions:

Have the fuel tank only partially
filled with unleaded regular and fill
up with premium unleaded as soon
as possible.


Avoid full throttle driving and abrupt
acceleration.


Do not exceed an engine speed of
3000 rpm if the vehicle is loaded
with a light load such as two
persons and no luggage.


Do not exceed
2/3 of maximum
accelerator pedal position if the ve-
hicle is fully loaded or operating in
mountainous terrain.

447 Technical terms
MON
(M
otor O
ctane N
umber)
The Motor Octane Number for gasoline
as determined by a standardized meth-
od. It is an indication of a gasoline’s
ability to resist undesired detonation
(knocking). The average of both the
MON (Motor Octane Number) and
->RON (Research Octane Number) is
posted at the pump, also known as
ANTI-KNOCK INDEX.
Multifunction display
Display field in the speedometer used
to present information provided by the
control system.
Multifunction steering wheel
Steering wheel with buttons for operat-
ing the control system.
Normal occupant weight
(
page 324)Overspeed range
Engine speeds within the red marking
of the tachometer dial. Avoid this en-
gi ne s pe ed r ange , as it m a y re su lt i n se -
rious engine damage that is not
covered by the Mercedes-Benz Limited
Warranty.
Parktronic system (Parking assist)*
System which uses visual and acoustic
signals to assist the driver during park-
ing maneuvers.
Poly-V-belt drive
Drives engine components (alternator,
AC compressor, etc.) from the engine.Power train
Collective term designating all compo-
nents used to generate and transmit
motive power to the drive axles, includ-
ing:


Engine


Clutch/torque converter


Transmission


Transfer case


Drive shaft


Differential


Axle shafts/axles
PRE-SAFE
®
(Pre
ventive occupant Safe
ty system)
Vehicles equipped with PRE-SAFE take
preventive measures when the system
senses certain driving dynamics sug-
gesting a possible accident.
Production options weight
(
page 324)

448 Technical termsProgram mode selector switch
Used to switch the automatic transmis-
sion between standard operationS and
comfort operationC.
S55 AMG and S65 AMG with steering
wheel gearshift control and manual
shift program: in addition toS andC
(see above), you can useM for manual
operation.
PSI
(P
ounds per s
quare i
nch)
(
page 324)
Recommended tire inflation pressure
(page 324)
REST
(Residual engine heat utilization)
Feature that uses the engine heat
stored in the coolant to heat the vehi-
cle interior for a short time after the en-
gine has been turned off.Restraint systems
Seat belts, belt tensioners, air bags
and child restraint systems. As inde-
pendent systems, their protective func-
tions complement one another.
Rim
(
page 324)
RON
(Research O
ctane N
umber)
The Research Octane Number for gaso-
line as determined by a standardized
method. It is an indication of a gaso-
line’s ability to resist undesired detona-
tion (knocking). The average of both
the ->MON (Motor Octane Number)
and RON (Research Octane Number) is
posted at the pump, also known as AN-
TI-KNOCK INDEX.
Shift lock
When the vehicle is parked, this lock
prevents the transmission selector le-
ver from being inadvertently moved out
of positionP without the SmartKey
turned and the brake pedal depressed.Sidewall
(
page 324)
SRS
(Supplemental R
estraint S
ystem)
Seat belts, emergency tensioning de-
vice and air bags. Though independent
systems, they are closely interfaced to
provide effective occupant protection.
Tele Aid System
(T
elematic A
larm I
dentification on
D
emand)
The Tele Aid system consists of three
types of response: automatic and man-
ual emergency, Roadside Assistance
and information. Tele Aid is initially ac-
tivated by completing a subscriber
agreement and placing an acquain-
tance call.
The Tele Aid system is operational pro-
vided that the vehicle’s battery is
charged, properly connected, not dam-
aged and cellular and GPS coverage is
available.

464 IndexMaintenance System (U.S. vehicles) 446
Manual headlamp mode 132
Manual operations
Closing the power tilt/sliding
sunroof 391
Fuel filler flap 390
Interior lighting control 137
Locking the vehicle 389
Opening the power tilt/sliding
sunroof 391
Power tilt/sliding sunroof 391
Unlocking the driver’s door 388
Manual shift program S 55 AMG and
S 65 AMG
Activating 184
Automatic transmission 183
Deactivating 185
Massage function 123
MAXCOOL
Maximum cooling 197
Maximum inflation pressure 324Maximum load rating 324
Maximum loaded vehicle weight 324
Mechanical key 388
Memory function 128, 446
Recalling positions from
memory 129
Storing exterior rear view mirror park-
ing positions 130
Storing key dependent settings 129
Menus 145
AUDIO 148
Distronic* 156, 221
In control system 146, 147
NAVI 155
Settings menu 160
Standard display 148
Submenus 145
TEL* 153
Trip computer 157
Vehicle status message memory 159Microphone
Hands-free microphone 29
Miles/kilometers in speedometer
Setting 163
Mirrors
Activating exterior rear view mirror
parking position 187
Adjusting 41
Auto-dimming for rear view
mirror 186
Exterior rear view mirror parking
position 170
Exterior rear view mirrors 41
Interior rear view mirror 41
Storing exterior rear view mirror park-
ing position 130
MON 285
MON (Motor Octane Number) 447
MP3-CD operation
Selecting tracks 150

469 Index
Reinstalling vehicle battery 409
Remote control
SmartKey 92
SmartKey with KEYLESS-GO* 96
Remote controls
Integrated 265
Remote door unlock
With Tele Aid 261
Removing
Vehicle battery 409
Wheel 406
Wiper blades 401
Replacing
Backup lamp bulbs 399
Battery (SmartKey with
KEYLESS-GO*) 393
Brake fluid 437
Brake lamp bulbs 399
Bulbs 394
Front lamp bulbs 397
License plate lamp bulbs 400
Parking lamp bulbs 399
Rear fog lamp bulbs 399, 400
Rear lamp bulbs 395, 399
Rear turn signal bulbs 399
Side marker lamp bulbs 399Standing lamp bulbs 399
Wiper blades 401
Reporting
Safety defects 18
Reset button in the instrument
cluster 160
Resetting
All functions (control system) 160
All functions of a submenu 161
Fuel consumption 158
Maintenance service indicator 331
Trip odometer 141
Residual heat utilization 202, 207, 448
Residual ventilation 202, 207
REST (Residual engine heat
utilization) 448
Restraint system see Infant and child re-
straint systems 71, 74
Rim 324
Rims and Tires 426
Roadside assistance 12
Tele Aid 257
Rolling code programming 266
RON (Research Octane Number) 285,
448
Roof rack 239Rubber parts
Cleaning 338
S
Safety
Occupant 60
Safety belts see Seat belts 43
Safety defects
Reporting 18
Safety systems
Driving 79
Screwdriver (vehicle tool kit) 385
Seat belt force limiter 69
Seat belts 67
Cleaning 337
Fastening 43
Proper use of 45, 68
Safety guidelines 64
Telltale 345
Seat cushion depth
Adjusting 123
Seat for and aft adjustment 118
Seat heater
Switching off 125
Switching on 125
Seat height 118