fuel additives BMW 3 SERIES 1991 E30 Workshop Manual

On some models, it will be necessary to
release the retaining clip (see illustration).
13Visually examine the canister for leakage
or damage.
14Renew the canister if you find evidence of
damage or leakage.
7 Catalytic converter
1
General description
1To reduce emissions of unburnt
hydrocarbons (HC), carbon monoxide (CO)
and oxides of nitrogen (NOx), the later
vehicles covered by this manual are equipped
with a catalytic converter (see illustration).
The converter contains a ceramic honeycomb
coated with precious metals, which speed up
the reaction between the pollutants listed
previously and the oxygen in the exhaust gas.
The pollutants are oxidised to produce water
(H
2O), nitrogen and carbon dioxide (CO2).
Check
2Visually examine the converter(s) for cracks
or damage. Make sure all nuts and bolts are
tight.
3Inspect the insulation cover (if applicable)
welded onto the converter - it should not be
loose.
Caution: If an insulation cover is
dented so that it touches the
converter housing inside,
excessive heat may be
transferred to the floor.
4Start the engine and run it at idle speed.
5Check for exhaust gas leakage from the
converter flanges. Check the body of each
converter for holes.
Component renewal
6See Chapter 4 for removal and refitting
procedures.
Precautions
7The catalytic converter is a reliable and
simple device, which needs no maintenance
in itself, but there are some facts of which an
owner should be aware, if the converter is to
function properly for its full service life.
(a) DO NOT use leaded (eg UK “4-star”)
petrol in a car equipped with a catalytic
converter - the lead will coat the precious
metals, reducing their converting
efficiency, and will eventually destroy the
converter.
(b) Always keep the ignition and fuel systems
well-maintained in accordance with the
manufacturer’s schedule, as given in
Chapter 1. In particular, ensure that the air
cleaner filter element, the fuel filter (where
fitted) and the spark plugs are renewed at
the correct interval. If the intake air/fuel
mixture is allowed to become too rich due
to neglect, unburned fuel will enter the
catalytic converter, overheating the
element and eventually destroying the
converter.
(c) If the engine develops a misfire, do not
drive the car at all (or at least as little as
possible) until the fault is cured - the
misfire will allow unburned fuel to enter
the converter, which will result in its
overheating, as noted above.
(d) DO NOT push- or tow-start the car - this
will soak the catalytic converter in
unburned fuel, causing it to overheat
when the engine does start - see (b) or (c)
above.
(e) DO NOT switch off the ignition at high
engine speeds - ie do not “blip” the
throttle immediately before switching offthe engine. If the ignition is switched off
at anything above idle speed, unburned
fuel will enter the (very hot) catalytic
converter, with the possible risk of its
igniting on the element and damaging the
converter.
(f) DO NOT use fuel or engine oil additives -
these may contain substances harmful to
the catalytic converter.
(g) DO NOT continue to use the car if the
engine burns oil to the extent of leaving a
visible trail of blue smoke - the unburned
carbon deposits will clog the converter
passages, and reduce its efficiency; in
severe cases, the element will overheat.
(h) Remember that the catalytic converter
operates at very high temperatures -
hence the heat shields on the car’s
underbody - and the casing will become
hot enough to ignite combustible
materials which brush against it. DO NOT,
therefore, park the car in dry
undergrowth, or over long grass or piles
of dead leaves.
(i) Remember that the catalytic converter is
FRAGILE - do not strike it with tools
during servicing work, and take great care
when working on the exhaust system.
Ensure that the converter is well clear of
any jacks or other lifting gear used to raise
the car, and do not drive the car over
rough ground, road humps, etc, in such a
way as to “ground” the exhaust system.
(j) In some cases, particularly when the car
is new and/or is used for stop/start
driving, a sulphurous smell (like that of
rotten eggs) may be noticed from the
exhaust. This is common to many
catalytic converter-equipped cars, and
seems to be due to the small amount of
sulphur found in some petrols reacting
with hydrogen in the exhaust, to produce
hydrogen sulphide (H
2S) gas; while this
gas is toxic, it is not produced in sufficient
amounts to be a problem. Once the car
has covered a few thousand miles, the
problem should disappear - in the
meanwhile, a change of driving style, or of
the brand of petrol used, may effect a
solution.
(k) The catalytic converter, used on a well-
maintained and well-driven car, should
last for 50 000 to 100 000 miles - from
this point on, the CO level should be
carefully checked regularly, to ensure that
the converter is still operating efficiently. If
the converter is no longer effective, it
must be renewed.
6•6 Engine management and emission control systems
7.1 Typical catalytic converter (M10
engine type shown, others similar)6.12 EVAP system charcoal canister
viewed from under the vehicle (316i model)

REF•18Automotive chemicals and lubricants
A number of automotive chemicals and
lubricants are available for use during vehicle
maintenance and repair. They include a wide
variety of products ranging from cleaning
solvents and degreasers to lubricants and
protective sprays for rubber, plastic and
vinyl.
Cleaners
Carburettor cleaner and choke cleaner
is a strong solvent for gum, varnish and
carbon. Most carburettor cleaners leave a
dry-type lubricant film which will not harden or
gum up. Because of this film, it is not
recommended for use on electrical
components.
Brake system cleaneris used to remove
grease and brake fluid from the brake system,
where clean surfaces are absolutely
necessary. It leaves no residue, and often
eliminates brake squeal caused by
contaminants.
Electrical cleaner removes oxidation,
corrosion and carbon deposits from electrical
contacts, restoring full current flow. It can also
be used to clean spark plugs, carburettor jets,
voltage regulators and other parts where an
oil-free surface is desired.
Moisture dispersantsremove water and
moisture from electrical components such as
alternators, voltage regulators, electrical
connectors and fuse blocks. They are non-
conductive and non-corrosive.
Degreasersare heavy-duty solvents used
to remove grease from the outside of the
engine and from chassis components. They
can be sprayed or brushed on, and are usually
rinsed off with water.
Lubricants
Engine oilis the lubricant formulated for
use in engines. It normally contains a wide
variety of additives to prevent corrosion and
reduce foaming and wear. Engine oil comes in
various weights (viscosity ratings) from 5 to
60. The recommended weight of the oil
depends on the season, temperature and the
demands on the engine. Light oil is used in
cold climates and under light load conditions.
Heavy oil is used in hot climates, and where
high loads are encountered. Multi-viscosity
(multigrade) oils are designed to have
characteristics of both light and heavy oils,
and are available in a number of weights from
5W-20 to 20W-50.
Gear oilis designed to be used in
differentials, manual transmissions and other
areas where high-temperature lubrication is
required.
Chassis and wheel bearing greaseis a
heavy grease used where increased loads and
friction are encountered, such as for wheel
bearings, balljoints, tie-rod ends and universal
joints.High-temperature wheel bearing grease
is designed to withstand the extreme
temperatures encountered by wheel bearings
in disc brake-equipped vehicles. It usually
contains molybdenum disulphide (moly),
which is a dry-type lubricant.
White greaseis a heavy grease for metal-
to-metal applications where water is a
problem. White grease stays soft at both low
and high temperatures, and will not wash off
or dilute in the presence of water.
Assembly lubeis a special extreme-
pressure lubricant, usually containing moly,
used to lubricate high-load parts (such as
main and rod bearings and cam lobes) for
initial start-up of a new engine. The assembly
lube lubricates the parts without being
squeezed out or washed away until the engine
oiling system begins to function.
Silicone lubricants are used to protect
rubber, plastic, vinyl and nylon parts.
Graphite lubricantsare used where oils
cannot be used due to contamination
problems, such as in locks. The dry graphite
will lubricate metal parts while remaining
uncontaminated by dirt, water, oil or acids. It
is electrically conductive, and will not foul
electrical contacts in locks such as the
ignition switch.
Penetrating oilsloosen and lubricate
frozen, rusted and corroded fasteners and
prevent future rusting or freezing.
Heat-sink greaseis a special electrically
non-conductive grease that is used for
mounting electronic ignition modules where it
is essential that heat is transferred away from
the module.
Sealants
RTV sealantis one of the most widely-
used gasket compounds. Made from silicone,
RTV is air-curing; it seals, bonds, waterproofs,
fills surface irregularities, remains flexible,
doesn’t shrink, is relatively easy to remove,
and is used as a supplementary sealer with
almost all low- and medium-temperature
gaskets.
Anaerobic sealantis much like RTV in that
it can be used either to seal gaskets or to form
gaskets by itself. It remains flexible, is solvent-
resistant, and fills surface imperfections. The
difference between an anaerobic sealant and
an RTV-type sealant is in the curing. RTV
cures when exposed to air, while an anaerobic
sealant cures only in the absence of air. This
means that an anaerobic sealant cures only
after the assembly of parts, sealing them
together.
Thread and pipe sealant is used for
sealing hydraulic and pneumatic fittings and
vacuum lines. It is usually made from a Teflon
compound, and comes in a spray, a paint-on
liquid and as a wrap-around tape.
Chemicals
Anti-seize compoundprevents seizing,
chafing, cold welding, rust and corrosion in
fasteners. High-temperature anti-seize,
usually made with copper and graphite
lubricants, is used for exhaust system and
exhaust manifold bolts.
Anaerobic locking compoundsare used
to keep fasteners from vibrating or working
loose, and cure only after installation, in the
absence of air. Medium-strength locking
compound is used for small nuts, bolts and
screws that may be removed later. High-
strength locking compound is for large nuts,
bolts and studs which aren’t removed on a
regular basis.
Oil additivesrange from viscosity index
improvers to chemical treatments that claim
to reduce internal engine friction. It should be
noted that most oil manufacturers caution
against using additives with their oils.
Fuel additivesperform several functions,
depending on their chemical make-up. They
usually contain solvents that help dissolve
gum and varnish that build up on carburettor,
fuel injection and intake parts. They also serve
to break down carbon deposits that form on
the inside surfaces of the combustion
chambers. Some additives contain upper
cylinder lubricants for valves and piston rings,
and others contain chemicals to remove
condensation from the fuel tank.
Miscellaneous
Brake fluidis specially-formulated
hydraulic fluid that can withstand the heat and
pressure encountered in brake systems. It is
poisonous and inflammable. Care must be
taken so this fluid does not come in contact
with painted surfaces or plastics. An opened
container should always be resealed, to
prevent contamination by water or dirt. Brake
fluid absorbs moisture from the air, if left in an
unsealed container.
Weatherstrip adhesiveis used to bond
weatherstripping around doors, windows and
boot lids. It is sometimes used to attach trim
pieces.
Undersealis a petroleum-based, tar-like
substance that is designed to protect metal
surfaces on the underside of the vehicle from
corrosion. It also acts as a sound-deadening
agent by insulating the bottom of the vehicle.
Waxes and polishesare used to help
protect painted and plated surfaces from the
weather. Different types of paint may require
the use of different types of wax and polish.
Some polishes utilise a chemical or abrasive
cleaner to help remove the top layer of
oxidised (dull) paint on older vehicles. In
recent years, many non-wax polishes
containing a wide variety of chemicals such as
polymers and silicones have been introduced.
These non-wax polishes are usually easier to
apply, and last longer than conventional
waxes and polishes.