octane MERCEDES-BENZ C-Class SEDAN 2012 W204 Owner's Manual

Multifunction displayFunction/notes ............................. 196
Permanent display .........................206
Multifunction steering wheel
Operating the on-board computer . 195
Overview .......................................... 31
Multifunction steering wheel (4
buttons) see 4-button multifunction
steering wheel
N
Navigation Menu (on-board computer) ............200
see separate operating instructions
NECK-PRO head restraints
Operation ......................................... 47
Resetting after being triggered ........47
NECK-PRO luxury head restraints
Operation ......................................... 47
Resetting after being triggered ........47
Notes on breaking-in a new
vehicle ................................................ 136
O
Occupant Classification System
(OCS) Faults ............................................... 46
Operation ......................................... 42
System self-test ............................... 45
Occupant safety
Children in the vehicle .....................53
System overview .............................. 36
Octane number (fuel) ........................ 348
Odometer ........................................... 199
see Trip odometer
Oil
see Engine oil
On-board computer
AMG menu ..................................... 210
Assistance menu ........................... 204
Audio menu ................................... 201
Convenience submenu ..................209
Displaying a service message ........283
Display messages ..........................213
DISTRONIC PLUS ........................... 168
Factory settings submenu .............210
Important safety notes ..................194
Instrument cluster submenu ..........206
Lighting submenu .......................... 207
Menu overview .............................. 198
Message memory .......................... 213
Navigation menu ............................ 200
Operation ....................................... 195
RACETIMER ................................... 211
Service menu ................................. 206
Settings menu ............................... 206
Standard display ............................ 199
Telephone menu ............................ 202
Trip menu ...................................... 199
Vehicle submenu ........................... 208
Video DVD operation .....................202
On-board diagnostics interface .......... 24
Opening and closing the side trim
panels ................................................. 115
Operating safety On-board diagnostics interface ........24
Operating system
see On-board computer
Outside temperature display ........... 195
Overhead control panel ...................... 33
Override feature Rear side windows ...........................57
P
Paint code number ............................ 343
Paintwork (cleaning instructions) ... 285
Panic alarm .......................................... 58
Panorama roof with power tilt/
sliding panel Opening/closing .............................. 87
Opening/closing the roller
sunblind ........................................... 88
Problem (malfunction) .....................89
Resetting ......................................... 88
Panorama sliding sunroof
Important safety notes ....................86
Parcel net ........................................... 256
Parking ............................................... 153
Important safety notes ..................153
Parking brake ................................ 154
Index13

If you bought this vehicle used, be sure to
send in the "Notice of Purchase of Used Car"
found in the Service and Warranty
Information Booklet, or call the Mercedes-
Benz Customer Assistance Center (in the
USA) at
1-800-FOR-MERCedes(1-800-367-6372) or
Customer Service (in Canada) at
1-800-387-0100.
Vehicle operation outside the USA
and Canada
If you plan to operate your vehicle in foreign
countries, please be aware that:
R service facilities or replacement parts may
not be readily available.
R unleaded fuel for vehicles with a catalytic
converter may not be available. Leaded fuel
may cause damage to the catalytic
converter.
R the fuel may have a considerably lower
octane rating. Unsuitable fuel can cause
engine damage.
Some Mercedes-Benz models are available
for delivery in Europe through our European
Delivery Program. For details, consult an
authorized Mercedes-Benz Center or write to
one of the following addresses.
In the USA
Mercedes-Benz USA, LLC
European Delivery Department
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9
Operating safety
Safety notes
GWARNING
Work improperly carried out on electronic
components and associated software could
cause them to cease functioning. Because the
vehicle's electronic components are
interconnected, any modifications made may
produce an undesired effect on other
systems. Electronic malfunctions could
seriously impair the operating safety of your
vehicle.
Contact an authorized Mercedes-Benz Center
for repairs or modifications to electronic
components.
Other improper work or modifications on the
vehicle could also have a negative impact on
the operating safety of the vehicle.
Some safety systems only function when the
engine is running. You should therefore never
turn off the engine while driving.
GWARNING
Heavy blows against the vehicle underbody or
tires/wheels may cause serious damage and
impair the operating safety of your vehicle.
Such blows can be caused, for example, by
running over an obstacle, road debris or a
pothole.
If you feel a sudden significant vibration or
ride disturbance, or you suspect that damage
to your vehicle has occurred:
R turn on your hazard warning flashers.
R slow down carefully.
R drive with caution to an area which is a safe
distance from the road.
Inspect the vehicle underbody and tires/
wheels for possible damage. If the vehicle
appears unsafe, have it towed to the nearest
authorized Mercedes-Benz Center or other
qualified maintenance or repair facility for
further inspection or repairs.
Introduction23Z

an authorized Mercedes-Benz Center for
this purpose.
! If the parking brake is being tested on a
brake dynamometer, the ignition must be
switched off (SmartKey or Start/Stop
button in position 0 or 1), as ESP ®
will
otherwise automatically intervene. The
brake system could otherwise be damaged.
Refueling
Important safety notes
GWARNING
Gasoline is highly flammable and poisonous.
It burns violently and can cause serious
personal injury.
Never allow sparks, flames or smoking
materials near gasoline.
Turn off the engine before refueling.
Whenever you are around gasoline, avoid
inhaling fumes and any skin or clothing
contact.
Direct skin contact with fuels and the
inhalation of fuel vapors are damaging to your
health.
GWARNING
Overfilling of the fuel tank may create
pressure in the system which could cause a
gas discharge. This could cause the gasoline
to spray back out when removing the fuel
pump nozzle, which could cause personal
injury.
GWARNING
C 300 and C 300 Sport with automatic
transmission:
Flexible fuel vehicle (with Ethanol up to
E85! sticker on the fuel filler flap):
Ethanol fuel (E85) and its vapors are highly
flammable, poisonous and fast burning.
Ethanol fuel can cause serious injury if ignited,
or if you come into contact with it or inhale its
vapors. Avoid inhaling ethanol vapors. Avoid
skin contact with ethanol. Extinguish any
naked flames before refueling. Never allow
sparks or smoking materials near ethanol.
! Do not use diesel to refuel vehicles with a
gasoline engine. Even small amounts of the
wrong fuel result in damage to the fuel
system and engine.
! Do not switch on the ignition if you
accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel lines.
Notify a qualified specialist workshop and
have the fuel tank and fuel lines drained
completely.
Gasoline
Fuel grade
! You should only refuel with premium-
grade unleaded gasoline, as this avoids
damaging the catalytic converter.
Flexible fuel vehicles, identifiable from the
label inside the fuel filler flap, can be
refueled with E85. For further information
on flexible fuel, see "Fuel".
If engine running problems are apparent,
have the cause checked immediately and
repaired. Excess unburned fuel can
otherwise enter the catalytic converter,
leading to overheating and possibly
causing a fire.
! Use a filter when refueling from a fuel can.
Otherwise, the fuel lines and/or injection
system could be blocked by particles from
the fuel can.
i Only refuel with premium-grade unleaded
gasoline with a specified minimum octane
number of 91 (average value of 96 RON/
86 MON).
You will usually find information about the
fuel grade on the pump. If you cannot find
the label on the pump, ask the staff for
assistance.
150RefuelingDriving and parking

Capacities
Missing values were not available at time of going to print.ModelCapacityFuel, coolant,
lubricants, etc.Engine oil and
filterC 2505.8 US qt (5.5 l)Approved engine
oilsC 250 4MATIC 31
C 300 4MATIC7.4 US qt (7.0 l)C 350
C 350 4MATIC 31C 63 AMG329.0 US qt (8.5 l)Cooling systemC 250Approximately 7.6 US qt
(7.2 l)MB 325.0 or
MB 326.0
antifreeze/
corrosion inhibitorC 250 4MATIC 31
C 300 4MATICApproximately 8.9 US qt
(8.4 l)C 350
C 350 4MATIC 31C 63 AMGApproximately 12.4 US qt
(11.7 l)Tank capacityC 25015.6 US gal (59.0 l)Premium-grade
unleaded gasoline
(at least 91 octane,
average value
between 96 RON/
86 MON)All models except
C 25017.4 US gal (66.0 l)ReserveAll models except
AMG vehiclesApproximately 2.1 US gal
(8.0 l)C 63 AMGApproximately 3.7 US gal
(14.0 l)Windshield/
headlamp
cleaning
systemC 250
C 350
C 350 4MATIC 31
C 63 AMG3.7 US qt (3.5 l)MB windshield
washer
concentrate 33
( Y page 351)
Mixing ratio for
washer fluid
( Y page 351)C 250 4MATIC 31
C 300 4MATIC6.3 US qt (6.0 l)31 Canada only.
32 Including external oil cooler.
33 Mixed with water or premixed washer fluid with antifreeze protection.346Service products and capacitiesTechnical data

Fuel consumption
Ethanol (E85) contains less energy per gallon
than gasoline. To ensure that the engine
performance with ethanol (E85) is similar to
that when using gasoline, the engine must
burn more ethanol. As a result, it is to be
expected that fuel consumption will increase
when using ethanol fuel (E85), compared to
gasoline.
Maintenance
Inform your authorized Mercedes-Benz
Center that you are operating or have
operated the vehicle with ethanol (E85).
Low outside temperatures
Starting times may significantly increase at
temperatures below 32 ‡ (0 † ). At low
outside temperatures, Mercedes-Benz
recommends the use of an auxiliary heater.
For further information, consult an authorized
Mercedes-Benz Center.
Rough idling may also be experienced at low
outside temperatures until the engine is fully
warmed up.
Ethanol (E85) is unsuitable for use if outside
temperatures fall below 14 ‡ (-10 † ).
High outside temperatures
At outside temperatures above 95 ‡ (35 † ),
the time required for the starting procedure
may increase and be accompanied by rough
idling following the start.
Fuel requirements
Use only premium-grade unleaded gasoline.
The octane number should be at least 91.
Details can be found on the gas pump. The
octane number is the average value of the
Research Octane Number (RON) and the
Motor Octane Number (MON): (RON +
MON) / 2, also known as knock resistance.
Reformulated gasoline (RFG) and/or
unleaded gasoline with additives can be used.
However, the concentration of additives in
the fuel must be less than 10%, e.g.
R Ethanol
R TAME
R ETBE
R IPA
R TBA
For MTBE, the concentration should not
exceed 15%.
The concentration of methanol in gasoline
including other additives must not exceed 3%.
Using mixtures of methanol and ethanol is not
permitted. Gasohol, a mixture of 10% ethanol
and 90% unleaded gasoline, can be used.
All of these mix fuels must fulfill the fuel
requirements, e.g.:
R knock resistance
R boiling point
R vapor pressure
Additives in gasoline
One of the main problems of poor fuel quality
is the forming of deposits that are created
during the gasoline combustion process.
Mercedes-Benz recommends that you use
fuel brands that have the additives.
Deposits may form if you use fuels without
additives over a longer period of time. These
deposits are most likely to form on the inlet
valves and in the combustion chamber.
This could lead to engine problems, e.g.:
R longer engine warm-up phase
R uneven idle
R engine noise
R misfiring
R loss of power
Carbon deposits may form if the availability
of gasoline with relevant additives is
insufficient (in certain regions). In this case,
Mercedes-Benz recommends the use of
348Service products and capacitiesTechnical data