222 MERCEDES-BENZ E-Class SEDAN 2013 W212 Owner's Manual

1, 2, 3 ...
115 V socket ......................................
310
12 V socket see Sockets
4ETS
see ETS/4ETS (Electronic
Traction System)
4MATIC (permanent four-wheel
drive) .................................................. 202
4MATIC off-road system ................... 202A
ABS (Anti-lock Braking System) Display message

............................ 247
Function/notes ................................ 67
Important safety notes .................... 67
Warning lamp ................................. 278
Activating/deactivating cooling
with air dehumidification ................. 143
Active Blind Spot Assist Activating/deactivating (on-
board computer) ............................ 237
Display message ............................ 264
Function/information .................... 218
Active Driving Assistance package . 218
Active Lane Keeping Assist Activating/deactivating (on-
board computer) ............................ 237
Display message ............................ 263
Function/information .................... 222
Active light function .........................126
Active multicontour seat ..................107
Active Service System see ASSYST PLUS
ADAPTIVE BRAKE ................................. 72
Adaptive Highbeam Assist Display message ............................ 257
Function/notes ............................. 126
Switching on/off (on-board
computer) ...................................... 239
Additives (engine oil) ........................411
Air bags Display message ............................ 253
Front air bag (driver, front
passenger) ....................................... 44
Important safety notes .................... 43Knee bag .......................................... 45
PASSENGER AIR BAG OFF
indicator lamp
.................................. 48
Pelvis air bag

................................... 46
Safety guidelines ............................. 42
Side impact air bag .......................... 45
Window curtain air bag ....................47
Air-conditioning system
see Climate control
Air filter (display message) ..............260
AIRMATIC Display message ............................ 261
Function/notes ............................. 199
Air vents
Glove box ....................................... 149
Important safety notes .................. 148
Rear ............................................... 149
Setting ........................................... 148
Setting the center air vents ...........148
Setting the side air vents ............... 148
Alarm system
see ATA (Anti-Theft Alarm system)
Ambient lighting
Setting the brightness (on-board
computer) ...................................... 239
AMG adaptive sport suspension
system ................................................ 200
Anti-lock braking system
see ABS (Anti-lock Braking System)
Anti-theft alarm system
see ATA (Anti-Theft Alarm system)
Ashtray ............................................... 308
Assistance menu (on-board
computer) .......................................... 236
ASSYST PLUS Displaying a service message ........ 333
Hiding a service message .............. 333
Notes ............................................. 332
Resetting the service interval
display ........................................... 333
Service message ............................ 332
Special service requirements ......... 333
ATA (Anti-Theft Alarm system)
Activating/deactivating ................... 75
Function ........................................... 75
Switching off the alarm .................... 754
Index

G
WARNING
If you open the DEF tank cap, small amounts
of ammonia vapor may be released. This
depends
in particular upon the age of the DEF.
Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released. Fill the DEF tank only in well-
ventilated areas.
! Only use DEF in accordance with
ISO 22241. Do not mix any additives with
DEF, and do not dilute DEF with water. This
may destroy the BlueTEC exhaust gas
aftertreatment system.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF
residues crystallize after time and
contaminate the affected surfaces.
! DEF is not a fuel additive and must not be
added to the fuel tank. If DEF is added to
the fuel tank, this can lead to engine
damage.
! Only screw on the DEF refill bottle hand-
tight. It could otherwise be damaged.
The DEF filler neck is under the trunk floor.
X Switch the ignition off.
X Open the trunk.
X Lift up the trunk floor ( Y page 301). X
Turn DEF cap : counter-clockwise and
remove it. X
Turn DEF filler cap ; counter-clockwise
and open it.
Filler

cap ; is secured with a plastic strip. X
Unscrew the protective cap from DEF refill
bottle =.
X Position DEF refill bottle = as shown on
the filler neck and screw it on hand-tight.
X Press DEF refill bottle = downwards.
The DEF tank is filled. This may take up to
one minute.
i To add between service intervals, fill the
DEF

tank with approximately 1 gal (3.8 l) of174
Refueling
Driving and parking

lane marking, the system recognizes certain
conditions and warns you accordingly.
The warning vibration occurs earlier if:
R
you approach the outer lane marking on a
bend.
R the road has very wide lanes, e.g. a
freeway.
R the
system recognizes solid lane markings.
The warning vibration occurs later if:
R the road has narrow lanes.
R you cut the corner on a bend. Active Driving Assistance package
General notes The Active Driving Assistance package
consists of DISTRONIC PLUS

(Y page 185),
Active Blind Spot Assist (Y page 218) and
Active Lane Keeping Assist (Y page 222).
Active Blind Spot Assist Important safety notes
G
WARNING
Active Blind Spot Assist is only an aid, and
may detect vehicles/obstacles incorrectly or
not at all.
The system may be impaired or may not
function if:
R there is poor visibility, e.g. due to snow,
rain, fog or spray.
R the rear and/or front sensors are dirty.
Active Blind Spot Assist may not detect
narrow vehicles, such as motorcycles or
bicycles, or may only detect them too late. It
cannot detect vehicles that are overtaken at
a

small distance and then enter the blind spot
area.
Active Blind Spot Assist cannot detect road
and traffic conditions. It is not a substitute for
attentive driving. You are responsible for the
vehicle's speed, braking in good time, and
steering correctly. Always adapt your driving style to suit the prevailing road and weather
conditions. Always pay attention to traffic
conditions

and your surroundings. Otherwise,
you may fail to recognize dangers in time,
cause an accident and injure yourself and
others.
i USA only:
This device has been approved by the FCC
as a “Vehicular Radar System”. The radar
sensor is intended for use in an automotive
radar system only. Removal, tampering, or
altering of the device will void any
warranties, and is not permitted by the
FCC. Do not tamper with, alter, or use in
any non-approved way.
Any unauthorized modification to this
device could void the user’s authority to
operate the equipment.
i Canada only: This device complies with
RSS-210 of Industry Canada. Operation is
subject to the following two conditions:
1. This device may not cause interference,
and
2. this device must accept any interference
received, including interference that may
cause undesired operation of the device.
Removal, tampering, or altering of the
device will void any warranties and is not
permitted. Do not tamper with, alter, or use
the device in any non-approved way.
Any unauthorized modification to this
device could void the user's authority to
operate the equipment.
General notes
Active Blind Spot Assist uses a radar sensor
system to monitor the side areas of your
vehicle which are in back of the driver. A
warning display in the exterior mirrors draws
your attention to vehicles detected in the
monitored area. If you then switch on the
corresponding turn signal to change lane, you
will also receive an optical and audible
warning. If a risk of lateral collision is
detected, corrective braking may help you 218
Driving systems
Driving and parking

R
the lane markings change quickly, e.g.
branch off, cross or merge.
R the road is narrow and winding.
Active Lane Keeping Assist cannot detect
road and traffic conditions. It is not a
substitute for attentive driving. You are
responsible
for the vehicle's speed, braking in
good time and steering correctly. Always
adapt your driving style to suit the prevailing
road and weather conditions. Always pay
attention to traffic conditions and your
surroundings. Otherwise, you may fail to
recognize dangers in time, cause an accident
and injure yourself and others.
General notes Active Lane Keeping Assist monitors the area
in front of your vehicle by means of a
camera
:

at the top of the windshield. Active
Lane Keeping Assist detects lane markings on
the road and warns you before you leave your
lane unintentionally. If you do not react to the
warning, a lane-correcting application of the
brakes can bring the vehicle back into the
original lane.
In the Display Unit Speed-/Odometer:
on-board computer function (Y page 238), if
you select the km display unit, Active Lane-
Keeping Assist is activated at a speed of
60 km/h. If the Miles display unit is selected,
the assistance range begins at 40 mph.
Warning vibration in the steering wheel
A warning may be given if a front wheel
passes over a lane marking. It will warn you by means of intermittent vibration in the
steering wheel for up to 1.5 seconds.
In order that you are warned only when
necessary and in good time if you cross the
lane marking, the system recognizes certain
conditions and warns you accordingly.
The warning vibration occurs earlier if:
R
you approach the outer lane marking on a
bend.
R the road has very wide lanes, e.g. a
freeway.
R the

system recognizes solid lane markings.
The warning vibration occurs later if:
R the road has narrow lanes.
R you cut the corner on a bend.
Lane-correcting brake application G
WARNING
Active Lane Keeping Assist does not keep
your vehicle in its lane. It is only an aid
designed

to assist driving. It is not a substitute
for attentive driving. In some cases, the lane-
correcting brake application is not sufficient
to bring your vehicle back to the original lane.
In such cases, you must steer the vehicle
yourself to ensure that it does not leave the
lane.
Active Lane Keeping Assist does not detect
road and traffic conditions. Always make sure
that there is sufficient distance to the side for
other traffic or obstacles. In rare cases,
unclear markings or particular structures on
the roadway can be recognized as solid lane
markings. An inappropriate brake application,
e.g. after intentionally driving over a solid lane
marking, may be interrupted at any time by
steering slightly in the opposite direction.
Active Lane Keeping Assist cannot take
weather conditions into account.
You are responsible for the driving at
appropriate speeds, braking in good time, and
steering correctly. Always adapt your driving
style to suit the prevailing road and weather
conditions. Always pay attention to traffic
conditions and your surroundings. Otherwise, 222
Driving systems
Driving and parking

Maintenance
Inform your authorized Mercedes-Benz
Center that you are operating or have
operated the vehicle with E85 fuel.
Low outside temperatures
The
starting procedure may take much longer
when operating the vehicle with E85 fuel at
outside temperatures below 32 ‡ (0 †).
E85 fuel is not suitable for use at outside
temperatures below -4 ‡ (-20 †). DEF
General notes DEF is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
High outside temperatures
G
WARNING
If you open the DEF tank cap, small amounts
of ammonia vapor may be released. This
depends

in particular upon the age of the DEF.
Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released. Fill the DEF tank only in well-
ventilated areas.
Low outside temperatures DEF freezes at a temperature of
approximately

12 ‡ (-11 †). The vehicle is
equipped with a DEF preheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (-11 †). Additives !
Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity !
Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions

in the BlueTEC exhaust gas
aftertreatment system
Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the BlueTEC exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
Filling capacities Model Total capacity
E 350 BlueTEC
6.5 US gal
(24.5 l)
Engine oil
General notes !
Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
intervals than those prescribed. You could
otherwise

cause engine damage or damage
to the exhaust gas aftertreatment. 410
Service products and filling capacities
Technical data