catalytic converter MERCEDES-BENZ E-Class WAGON 2016 W213 Owner's Manual

the Service and Guarantee booklet or simply
call the Mercedes-Benz Customer Assistance
Center (USA) at the hotline number
1-800-FOR-MERCedes(1-800-367-6372) or
Customer Service (Canada) at
1-800-387-0100.
Vehicle operation outside the USA
and Canada
If you plan to operate your vehicle in foreign
countries, please be aware that:
Rservice facilities or replacement parts may
not be readily available.
Runleaded fuel for vehicles with a catalytic
converter may not be available. Leaded fuel may cause damage to the catalytic con-
verter.
Rthe fuel may have a considerably lower
octane rating. Unsuitable fuel can cause
engine damage.
Some Mercedes-Benz models are available
for delivery in Europe through our European
Delivery Program. For details, consult an
authorized Mercedes-Benz Center or write to
one of the following addresses.
In the USA
Mercedes-Benz USA, LLC
European Delivery Department
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9
Operating safety
Important safety notes
GWARNING
If you do not have the prescribed service/
maintenance work or any required repairs
carried out, this can result in malfunctions or system failures. There is a risk of an accident.
Always have the prescribed service/mainte-
nance work as well as any required repairs
carried out at a qualified specialist workshop.
GWARNING
Flammable material such as leaves, grass or
twigs may ignite if they come into contact with
hot parts of the exhaust system. There is a risk of fire.
When driving off road or on unpaved roads,
check the vehicle's underside regularly. In
particular, remove parts of plants or other
flammable materials which have become
trapped. In the case of damage, contact a
qualified specialist workshop.
GWARNING
Modifications to electronic components, their software as well as wiring can impair their
function and/or the function of other net-
worked components. In particular, systems
relevant to safety could also be affected. As a
result, these may no longer function as inten-
ded and/or jeopardize the operating safety of
the vehicle. There is an increased risk of an
accident and injury.
Never tamper with the wiring as well as elec-
tronic components or their software. You
should have all work to electrical and elec-
tronic equipment carried out at a qualified
specialist workshop.
!There is a risk of damage to the vehicle if:
Rthe vehicle becomes stuck, e.g. on a high
curb or an unpaved road
Ryou drive too fast over an obstacle, e.g. a
curb or a hole in the road
Ra heavy object strikes the undercarriage
or parts of the chassis
In situations like this, the body, the under-
carriage, chassis parts, wheels or tires
could be damaged without the damage
being visible. Components damaged in this
way can unexpectedly fail or, in the case of
30Introduction

General notes
iVehicles with a gasoline engine:the
catalytic converter is preheated for up to
30 seconds after a cold start. The sound of
the engine may change during this time.
Automatic transmission
XShift the transmission to position P.
The transmission position display in the
multifunction display shows P.
iYou can start the engine in transmission
position Pand N.
Starting procedure with the SmartKey
iTo start the engine using the SmartKey
instead of KEYLESS-GO, pull the Start/
Stop button out of the ignition lock.
XVehicles with diesel engine: turn the key
to position 2in the ignition lock
(
Ypage 137).
The % preglow indicator lamp in the
instrument cluster lights up.
XTurn the key to position 3in the ignition
lock and release it as soon as the engine is
running (
Ypage 137).
iVehicles with a diesel engine: you can
start the engine without preglow if the
engine is warm.
Using KEYLESS-GO to start the engine
iThe Start/Stop button can be used to
start the vehicle manually without inserting
the SmartKey into the ignition lock. The
Start/Stop button must be inserted in the
ignition lock and the SmartKey must be in
the vehicle. This mode for starting the
engine operates independently of the ECO
start/stop automatic engine start function.
XDepress the brake pedal and keep it
depressed.
XPress the Start/Stop button once
(
Ypage 138).
Vehicles with a gasoline engine: the
engine starts.
Vehicles with a diesel engine: preglow is
activated and the engine starts.
Pulling away
General notes
GWARNING
If the engine speed is above the idling speed
and you engage transmission position Dor R,
the vehicle could pull away suddenly. There is
a risk of an accident.
When engaging transmission position Dor R,
always firmly depress the brake pedal and do not simultaneously accelerate.
!If a warning tone sounds and the
Release Park. Brake
message appears
in the multifunction display, the parking
brake is still applied. Release the parking
brake.
Depress the accelerator carefully when pull-
ing away.
The vehicle locks centrally once you have
pulled away. The locking knobs in the doors
drop down.
You can open the doors from the inside at any
time.
You can also deactivate the automatic locking
feature (
Ypage 190).
It is only possible to shift the transmission
from position Pto the desired position if you
depress the brake pedal. If you do not
depress the brake pedal, the DIRECT SELECT
lever can still be moved but the parking lock
remains engaged.
iUpshifts take place at higher engine
speeds after a cold start. This helps the
140Driving
Driving and parking

catalytic converter to reach its operating
temperature more quickly.
Hill start assist
Hill start assist helps you when pulling away
forwards or in reverse on an uphill gradient. It
holds the vehicle for a short time after you
have removed your foot from the brake pedal.
This gives you enough time to move your foot
from the brake pedal to the accelerator pedal
and to depress it before the vehicle begins toroll.
GWARNING
After a short time, hill start assist will no lon-
ger brake your vehicle and it could roll away.
There is a risk of an accident and injury.
Therefore, quickly move your foot from the
brake pedal to the accelerator pedal. Never
leave the vehicle when it is held by hill start
assist.
Hill start assist is not active if:
Ryou are pulling away on a level road or on a downhill gradient.
Rthe transmission is in position N.
Rthe parking brake is applied.
RESP®is malfunctioning.
ECO start/stop function
Introduction
The ECO start/stop function switches the
engine off automatically if the vehicle is stop-
ped under certain conditions.
The engine starts automatically when the
driver wants to pull away again. The ECO
start/stop function thereby helps you to
reduce the fuel consumption and emissions
of your vehicle.
Important safety notes
GWARNING
If the engine is switched off automatically and
you exit the vehicle, the engine is restarted
automatically. The vehicle may begin moving.
There is a risk of accident and injury.
If you wish to exit the vehicle, always turn off
the ignition and secure the vehicle against
rolling away.
General notes
:ECO start/stop display
Hybrid vehicles: observe the notes on the
ECO start/stop function in the "HYBRID" sup-
plement.
The ECO start/stop function is activated
whenever you start the engine using the
SmartKey or the Start/Stop button.
If the engine has been switched off automat-
ically by the ECO start/stop function, the
¤ symbol is shown in the multifunction
display.
AMG vehicles: the AMG menu in the multi-
function display additionally shows the Stop/
Start activemessage.
AMG vehicles: the ECO start/stop function
is only available in drive program C.
Information in the Digital Operator's
Manual
In the Digital Operator's Manual you will find
information on the following topics:
RAutomatic engine switch-off
RAutomatic engine start
RDeactivating or activating the ECO start/
stop function
Driving141
Driving and parking
Z

engine or to the catalytic converter. Have
excess engine oil siphoned off.
Example
XTurn cap:counter-clockwise and remove
it.
XAdd engine oil.
If the oil level is at or below the MIN mark on
the oil dipstick, add 1.1 US qt (1.0 l)of
engine oil.
XReplace cap :on the filler neck and turn
clockwise.
Ensure that the cap locks into place
securely.
XCheck the oil level again with the oil dip-
stick (
Ypage 264).
Further information on engine oil
(
Ypage 341).
Additional service products
Checking coolant level
GWARNING
Certain components in the engine compart-
ment, such as the engine, radiator and parts
of the exhaust system, can become very hot.
Working in the engine compartment poses a
risk of injury.
Where possible, let the engine cool down and touch only the components described in the
following.
GWARNING
The engine cooling system is pressurized, par-
ticularly when the engine is warm. When
opening the cap, you could be scalded by hot
coolant spraying out. There is a risk of injury.
Let the engine cool down before opening the
cap. Wear eye and hand protection when
opening the cap. Open the cap slowly half a
turn to allow pressure to escape.
XPark the vehicle on a level surface.
Only check the coolant level when the vehi-
cle is on a level surface and the engine has
cooled down.
XTurn the SmartKey to position 2in the igni-
tion lock (
Ypage 137).
On vehicles with KEYLESS-GO, press the
Start/Stop button twice (
Ypage 138).
XCheck the coolant temperature display in
the instrument cluster.
The coolant temperature must be below
158 ‡ (70 †).
XTurn the SmartKey to position 0in the igni-
tion lock (
Ypage 137).
XSlowly turn cap :half a turn counter-
clockwise to allow excess pressure to
escape.
XTurn cap :further counter-clockwise and
remove it.
If the coolant is at the level of marker bar =
in the filler neck when cold, there is enough
coolant in coolant expansion tank ;.
If the coolant level is approximately 0.6 in
(1.5 cm) above marker bar =in the filler
Engine compartment265
Maintenance and care
Z

Jump-starting
For the jump-starting procedure, use only the jump-starting connection point, consisting of a
positive terminal and a ground point, in the engine compartment.
GWARNING
Battery acid is caustic. There is a risk of injury.
Avoid contact with skin, eyes or clothing. Do not inhale any battery gases. Do not lean over the
battery. Keep children away from batteries. Wash away battery acid immediately with plenty of
clean water and seek medical attention.
GWARNING
During charging and jump-starting, explosive gases can escape from the battery. There is a risk of an explosion.
Particularly avoid fire, open flames, creating sparks and smoking. Ensure there is sufficient ven-
tilation while charging and jump-starting. Do not lean over a battery.
GWARNING
During the charging process, a battery produces hydrogen gas. If a short circuit occurs or sparks
are created, the hydrogen gas can ignite. There is a risk of an explosion.
RMake sure that the positive terminal of a connected battery does not come into contact with
vehicle parts.
RNever place metal objects or tools on a battery.
RIt is important that you observe the described order of the battery terminals when connecting
and disconnecting a battery.
RWhen jump-starting, make sure that the battery poles with identical polarity are connected.
RIt is particularly important to observe the described order when connecting and disconnecting
the jumper cables.
RNever connect or disconnect the battery terminals while the engine is running.
GWARNING
A discharged battery can freeze at temperatures below freezing point. When jump-starting the
vehicle or charging the battery, gases can escape from the battery. There is a risk of an explosion. Allow the frozen battery to thaw out before charging it or jump-starting.
!Vehicles with a gasoline engine: avoid repeated and lengthy starting attempts. Other-
wise, the catalytic converter could be damaged by non-combusted fuel.
HYBRID vehicles : make sure that you read the "HYBRID" supplement included in the vehicle
literature. You could otherwise fail to recognize dangers e.g. due to high voltage.
Jump-starting279
Roadside Assistance
Z

DEF
Important safet ynotes
Comply wit hth eimportant safet ynote sfo r
servic eproducts when handlin gDE F
(
Ypage 337).
DE Fis awater-soluble flui dfo rth eexhaus t
gas aftertreatmen tof diesel engines. It is:
Rno tpoisonous
Rcolorles sand odorless
Rno tflammable
Whe nyou ope nth eDE Fcontainer, small
amount sof ammonia vapor may be released.
Ammoni avapor shav e apungen todo rand are
particularly irritatin gto th eskin ,to mucous
membrane sand to th eeyes .You may expe-
rienc e aburning sensation in your eyes ,nose
and throat .Coughin gand watering of th e
eyes are possible.
Do no tinhale ammonia vapors. Fil lth eDE F
tank only in well-ventilated areas.
Low outsid etemperatures
DE Ffreezes at atemperature of approx -
imately 12 ‡(-11 †). The vehicle is delivered
from the factory equipped with a DEF pre-
heating system. Winter operation can thus be guaranteed even at temperatures below 12 ‡
(-11 †).
Additives
!Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas after-
treatment system.
Purity
!Impurities in DEF (e.g. due to other ser-
vice products, cleaning agents or dust) lead
to:
Rincreased emission values
Rdamage to the catalytic converter
Rengine damage
Rmalfunctions in the BlueTEC exhaust gas
aftertreatment system
Assuring the purity of DEF is particularly
important with respect to avoiding malfunc-
tions in the BlueTEC exhaust gas aftertreat-
ment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to the tank. The purity of the fluid can no longer
be guaranteed.
Filling capacities
ModelTotal capacity
All models6.7 US gal
(25.5 l)
Engine oil
General notes
!Never use engine oil or an oil filter of a
specification other than is necessary to ful- fill the prescribed service intervals. Do not
change the engine oil or oil filter in order to
achieve longer replacement intervals than
those prescribed. You could otherwise
cause engine damage or damage to the
exhaust gas aftertreatment.
Follow the instructions in the service inter-
val display regarding the oil change. Other-
wise, you may damage the engine and the
exhaust gas aftertreatment.
When handling engine oil, observe the impor-
tant safety notes on service products
(
Ypage 337).
The engine oils are matched to the perform-
ance of Mercedes-Benz engines and service
intervals. You should therefore only use
engine oils and oil filters that are approved for
vehicles with maintenance systems.
For a list of approved engine oils and oil filters, consult an authorized Mercedes-Benz Cen-
Service products and filling capacities341
Technical data
Z