engine MERCEDES-BENZ M-Class 2014 W166 Owner's Manual

Service products and filling
capacities Important safety notes
G
WARNING
Service products may be poisonous and
hazardous to health. There is a risk of injury.
Comply with instructions on the use, storage
and disposal of service products on the labels
of the respective original containers. Always
store service products sealed in their original
containers. Always keep service products out
of the reach of children. H
Environmental note
Dispose of service products in an
environmentally responsible manner.
Service products include the following:
R Fuels (e.g. gasoline, diesel)
R Exhaust gas aftertreatment additives, e.g.
DEF
R Lubricants (e.g. engine oil, transmission oil)
R Coolant
R Brake fluid
R Windshield washer fluid
R Climate control system refrigerant
Comply with all valid regulations with respect
to handling, storing, and disposing of service
fluids.
Components and service products must be
matched. You should therefore only use
products that have been tested and approved
by Mercedes-Benz.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved
by Mercedes-Benz by the following
inscription on the containers:
R MB-Freigabe (e.g. MB-Freigabe 229.51)
R MB Approval (e.g. MB Approval 229.51) Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g.
MB 229.5). They have not necessarily been
approved by Mercedes-Benz. Fuel
Important safety notes G
WARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and
explosion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before
refueling. G
WARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come
into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
R Wash away fuel from skin immediately
using soap and water.
R If fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance
without delay.
R If fuel is swallowed, seek medical
assistance without delay.Don ot induce
vomiting.
R Immediately change out of clothing which
has come into contact with fuel. 444
Service products and filling capacitiesTechnical data

Tank capacity
Model Total
capacity All models
24.6 US gal
(93.0 l) Model Of which
reserve ML 63 AMG 4MATIC
Approx.
3.7 US gal (14.0 l) All other models
Approx.
3.2 US gal (12.0 l) Gasoline
Fuel grade
!
Do not use diesel to refuel vehicles with a
gasoline engine .Do not switch on the
ignition if you accidentally refuel with the
wrong fuel. Otherwise, the fuel will enter
the fuel system. Even small amounts of the
wrong fuel could result in damage to the
fuel system and the engine. Notify a
qualified specialist workshop and have the
fuel tank and fuel lines drained completely.
! Only refuel using unleaded gasoline with
a minimum octane rating of 91.
! Only use the fuel recommended.
Operating the vehicle with other fuels can
lead to engine failure.
! Do not use the following:
R E85 (gasoline with 85% ethanol)
R E100 (100% ethanol)
R M15 (gasoline with 15% methanol)
R M30 (gasoline with 30% methanol)
R M85 (gasoline with 85% methanol)
R M100 (100% methanol)
R Gasoline with metalliferous additives
R Diesel Do not mix such fuels with the fuel
recommended for your vehicle. Do not use
additives. This can otherwise lead to engine
damage. This does not include cleaning
additives for the removal and prevention of
residue build-up. gasoline may only be
mixed with cleaning additives
recommended by Mercedes-Benz; see
"Additives". You can obtain further
information from any authorized Mercedes-
Benz Center.
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline must be used.
If standard premium-grade unleaded
gasoline is unavailable and unleaded
gasoline of a lower grade is used for
refueling, observe the following
precautions:
R only fill the fuel tank to half full with
regular unleaded gasoline and fill the rest
with premium-grade unleaded gasoline
as soon as possible.
R do not drive at the maximum speed.
R avoid sudden acceleration and engine
speeds above 3000 rpm.
R never refuel using fuel with an octane
number lower than 87. Otherwise,
engine failure could occur.
Using mixtures of methanol and ethanol is not
permitted. E10 fuel or E15 fuel (unleaded
gasoline with 10% or 15% ethanol) can be
used.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or on the
Internet at http://www.mbusa.com (USA
only).
Information on refueling (Y page 174). Service products and filling capacities
445Technical data Z

Additives
!
Operating the engine with fuel additives
added later can lead to engine failure. Do
no tm ix fuel additives with fuel. This does
not include additives for the removal and
prevention of residue buildup. gasoline
must only be mixed with additives
recommended by Mercedes-Benz. Comply
with the instructions for use on the product
label. More information about
recommended additives can be obtained
fro ma ny authorized Mercedes-Benz
Center.
Mercedes-Benz recommends tha tyou use
fuel brands that have the additives.
The quality of the fuel available in some
countries may not be sufficient .Residue
could build up as a result. In such cases, and
in consultation with an authorized Mercedes-
BenzC enter, the gasoline may be mixed with
the cleaning additive recommended by
Mercedes-Benz (part no. A000989254512).
You must observe the notes and mixing ratios
specified on the container.
Diesel Fuel grade
G
WARNING
If you mix diesel fuel with gasoline, the flash
point is lower than that of pure diesel fuel.
When the engine is running, exhaust system
components could overheat without being
noticed. There is a risk of fire.
Never refuel with gasoline. Never mix gasoline
with diesel fuel.
! Only use commercially available vehicular
ULTRA-LOW SULFUR DIESEL FUEL (ULSD,
15 ppm maximum sulfur content) that
meets the ASTM D975 standard. If you do
not refuel with ULSD ,you may damage the
BlueTEC exhaust gas aftertreatment
system of the vehicle.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not mix diesel fuel with gasoline, kerosene or paraffin. This may
otherwise result in damage to the fuel
system and engine.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or on the
Internet at http://www.mbusa.com (USA
only).
Information on refueling (Y page 174).
Bio-diesel -FAME (fatt yacid methyl ester)
Mercedes-Ben zUSA approves the use of bio-
diesel B5 for all BlueTEC diesel engines. The
concentration of bio-diesel in the ULSD may
not exceed 5% by volume.
Pure bio-diesel and diesel fuel with a higher
percentage of bio-diesel, such as B20, can
damage the engine and the fuel system. For
this reason, they are not approved.
For more information, consult the gas station
staff. The bio-diesel B5 label on the gasoline
pump mus tclearly state that the standard for
ULS Dhas been fulfilled. If the label is not
clear, do no trefuel the vehicle.
Do not refuel your vehicle with fuels unless
they have been approved by Mercedes-Benz.
Information on refueling (Y page 174).
Low outside temperatures
i Diesel fuel with improved cold flow
properties is available during the winter
months. Further information about fuel
properties can be obtained from oil
companies, e.g. at gas stations.
Flow improver
To improve the low-temperature resistance of
diesel fuel, a flow improver can be attached.
The effectiveness of a flow improver is not
guaranteed for every fuel.
Only use flow improvers tested and approved
by Mercedes-Benz. Durin guse, please
observe the information on operation. 446
Service products and filling capacitiesTechnical data

Correct dosage and sufficient mixing are
decisive in improving low-temperature
resistance with the flow improver.
Overdosage can potentially eve ndecrease
low-temperature resistance and must
therefore be avoided. Follow the
manufacturer's guidelines on dosage.
Mix the additive into the diesel in good time,
before the flow characteristics of the diesel
become insufficient .Otherwise, malfunctions
can arise through heating the fuel system,
e.g .through parking in a heated garage.
More information about recommended flow
improvers can be obtained from any qualified
specialist workshop.
Flexible Fuel vehicles Important safety notes
G
WARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and
explosion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before
refueling. G
WARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come
into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
R Wash away fuel from skin immediately
using soap and water.
R If fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance
without delay. R
If fuel is swallowed, seek medical
assistance without delay.Don ot induce
vomiting.
R Immediately change out of clothing which
has come into contact with fuel.
Flexible Fuel vehicles can be refueled with the
following fuel types:
R premium-grade unleaded gasoline
R E85 fuel
R a mixture of E85 fuel and premium-grade
unleaded gasoline
i Flexible Fuel vehicles can be recognized
by the Ethanol up to E85 sticker on the
inside of the fuel filler flap.
Fuel consumption
The energy content of E85 fuel is less than
that of the same amount of premium-grade
gasoline. The amount of fuel consumed when
operating the vehicle with E85 fuel is
therefore higher than with premium-grade
gasoline.
Maintenance
Informy our authorized Mercedes-Benz
Center that you are operating or have
operated the vehicle with E85 fuel.
Low outside temperatures
If the outside temperature is below 32 ‡
(0 †) the starting procedure can take
noticeably longer when operating with E85
fuel.
E85 fuel is not suitable for use at outside
temperatures under -4 ‡ (-20 †). DEF
Important safety notes Comply with the important safety notes for
service products when handling DEF
(Y
page 444). Service products and filling capacities
447Technical data Z

DEF is a water-soluble fluid for the exhaust
gas aftertreatment of diesel engines. It is:
R
not poisonous
R colorless and odorless
R not flammable
When you open the DEF container, small
amounts of ammonia vapo rmay be released.
Ammonia vapors have a pungen todor and are
particularly irritating to the skin, to mucous
membranes and to the eyes. You may
experience a burning sensation in your eyes,
nose and throat. Coughing and watering of
the eyes are possible.
Do not inhale ammonia vapors. Fill the DEF
tank only in well-ventilated areas.
Low outside temperatures DEF freezes at a temperature of
approximately 12
‡(-11 †). The vehicl eis
delivered from the factory equipped with a
DEFp reheating system. Winter operation can
thus be guaranteed even at temperatures
below 12 ‡ (-11 †).
Additives !
Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity !
Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system
Assuring the purity of DEF is particularly
important with respect to avoiding malfunctions in the BlueTEC exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
Filling capacities Model Total capacity
ML 250 BlueTEC
4MATIC
ML 350 BlueTEC 4MAT
IC
7.3 US gal
(27.5 l) Engine oil
General notes !
Never use engine oil or an oil filter of a
specificatio nothe rthan is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
intervals than those prescribed. You could
otherwise cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
Comply with the important safety notes for
service products when handling engine oil
(Y page 444).
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz
Center. Or visit the website
http://bevo.mercedes-benz.com. 448
Service products and fillingc
apacitiesTechnical data

The table shows which engine oils have been
approved for your vehicle. Model Engine
model MB
Approval ML 250 BlueTEC
4MATIC
651 228.51,
229.31,
229.51 ML 350
ML 350 4MATIC
276 229.5
ML 350 BlueTEC
4MATIC
642 228.51,
229.31,
229.51 ML 550 4MATIC
278 229.5
ML 63 AMG
4MATIC
157 229.5
i
MB approval is indicated on the oil
containers.
Filling capacities The following values refer to an oil change
including the oil filter.
Missing values were not available at time of
going to print. Model Capacity
ML 250 BlueTEC
4MATIC
6.9 US qt (6.5 l)
ML 350
ML 350 4MATIC
7.4 US qt (7.0 l)
ML 350 BlueTEC 4
MATIC
8.5 US qt (8.0 l)
ML 550 4MATIC
9.0 US qt (8.5 l)
ML 63 AMG
4MATIC
Without external oil
cooler: 9.0 US qt (8.5 l) Additives
!
Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE classification
(viscosity) suitable for the prevailing outside
temperatures. The table shows you which
SAE classifications are to be used. The low-
temperature characteristics of engine oils
can deteriorate significantly, e.g. as a result
of aging, soot and fuel deposits. It is therefore
strongly recommended that you carry out
regular oil changes using an approved engine
oil with the appropriate SAE classification.
Brake fluid
G
WARNING
The brake fluid constantly absorbs moisture
from the air. This lowers the boiling point of
the brake fluid. If the boiling point of the brake
fluid is too low, vapor pockets may form in the
brake system when the brakes are applied
hard. This would impair braking efficiency.
There is a risk of an accident.
You should have the brake fluid renewed at
the specified intervals. Service products and filling capacities
449Technical data Z

Comply with the important safety notes for
service products when handlin
gbrake fluid
(Y page 444).
The brake fluid change intervals can be found
in the Maintenance Booklet.
Only use brake fluid approved by Mercedes-
Benz according to MB Approval 331.0.
Information about approved brake fluid can
be obtained at any qualified specialist
workshop or on the Internet at
http://bevo.mercedes-benz.com.
i Have the brake fluid regularly replaced at
a qualified specialist workshop and the
replacement confirmed in the Maintenance
Booklet. Coolant
Important safety notes G
WARNING
If antifreeze comes into contact with hot
components in the engine compartment, it
may ignite. There is a risk of fire and injury.
Let the engine cool down before you add
antifreeze. Make sure that antifreeze is not
spilled next to the filler neck. Thoroughly
clea nthe antifreeze from components before
starting the engine.
! Only add coolant that has been premixed
with the desired antifreezep rotection. You
could otherwise damage the engine.
Further information on coolants can be
found in the Mercedes-Benz Specifications
for Service Products, MB Specifications for
Service Products 310.1, e.g. on the
Internet at
http://bevo.mercedes-benz.com. Or
contact a qualified specialist workshop.
! Always use a suitable coolant mixture,
even in countries where high temperatures
prevail. Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
i Have the coolant regularly replaced at a
qualified specialist workshop and the
replacement confirmed in the Maintenance
Booklet.
Comply with the important safety precautions
for service products when handling coolant
(Y page 444).
The coolant is a mixture of water and
antifreeze/corrosion inhibitor. It performs
the following tasks:
R corrosio nprotection
R antifreeze protection
R raising the boiling point
If the coolant has antifreeze protection down
to -35 ‡ (-37 †),the boiling point of the
coolant during operatio nis approximately
266 ‡ (130 †).
The antifreeze/corrosion inhibitor
concentration in the engine cooling system
should:
R be at least 50%. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 †).
R not exceed 55% (antifreeze protection
down to -49 ‡ [-45 †]). Otherwise, heat
will not be dissipated as effectively.
If the vehicle has lost coolant, add equal
amounts of water and antifreeze/corrosion
inhibitor.
Mercedes-Benz recommends an antifreeze/
corrosion inhibitor concentrate in
accordance with
MB Specifications for Service Products 310.1.
i When the vehicle is first delivered, it is
filled with a coolant mixture that ensures
adequate antifreeze and corrosion
protection.
i The coolant is checked with every
maintenance interval at a qualified
specialist workshop. 450
Service products and filling capacitiesTechnical data

Filling capacities
Model Capacity
ML 250 BlueTEC
4MATIC
Approx. 10.7 US qt
(10.1 l) ML 350
ML 350 4MATIC
Approx. 11.1 US qt
(10.5 l) ML 350 BlueTEC 4
MATIC
Approx. 12.2 US qt
(11.5 l) ML 550 4MATIC
Approx. 11.6 US qt
(11.0 l) ML 63 AMG
4MATIC
Approx. 12.5 US qt
(11.8 l) i
Use MB 325.0 or MB 326.0 corrosion
inhibitor/antifreeze. Windshield washer system
Important safety notes G
WARNING
Windshield washe rconcentrate is highly
flammable. If it comes into contact with hot
engine components or the exhaust system it
could ignite. There is a risk of fire and injury.
Make sure that no windshield washer
concentrate is spilled next to the filler neck.
! Do not add distilled or de-ionized water to
the washer fluid container. Otherwise, the
level sensor may be damaged.
! Only MB SummerFit and MB WinterFit
washer fluid should be mixed together. The
spray nozzles may otherwise become
blocked.
When handling washer fluid, observe the
important safety notes on service products
(Y page 444). At temperatures above freezing:
X
Fill the washer fluid reservoir with a mixture
of water and windshield washer fluid, e.g.
MB SummerFit.
Add 1 part MB SummerFit to 100 parts water.
At temperatures below freezing:
X Fill the washer fluid reservoir with a mixture
of water and washer fluid, e.g. MB
WinterFit.
Adapt the mixing ratio to the outside
temperature.
R Down to 14 ‡ (001910 †): mix 1 part MB
WinterFit to 2 parts water.
R Down to 00194 ‡ (001920 †): mix 1 part MB
WinterFit to 1 part water.
R Down to 001920.2 ‡ (001929 †): mix 2 parts MB
WinterFit to 1 part water.
i Add windshield washer fluid, e.g. MB
SummerFit or MB WinterFit, to the washer
fluid all year round. Climate control system refrigerant
Important safety notes The climate control system of your vehicle is
filled with refrigerant R-134a.
The instruction label regarding the refrigerant
type used can be found on the radiator cross
member.
!
Only the refrigerant R-134a and the PAG
oil approved by Mercedes-Benz may be
used. The approved PAG oil may not be
mixed with any other PAG oil that is not
approved for R-134a refrigerant.
Otherwise, the climate control system may
be damaged.
Service work, such as topping-up refrigerant
or replacing components, may only be carried
out by a qualified specialist workshop. All
applicable regulations must be adhered to,
SAE standard J639 included. Service products and filling capacities
451Technical data Z