octane MERCEDES-BENZ ML350 2003 W163 Owner's Manual

13 Introduction
Operator’s Manual
Operating your vehicle outside the USA or Canada
If you plan to operate your vehicle in for-
eign countries, please be aware that:

Service facilities or replacement parts
may not be readily available,


unleaded gasoline for vehicles with cat-
alytic converters may not be available;
the use of leaded fuels will damage the
catalysts,


gasoline may have a considerably low-
er octane rating, and improper fuel can
cause engine damage.

200 OperationAt the gas station
At the gas stationThe fuel filler flap is located on the
left-hand side of the vehicle towards the
rear. Locking/unlocking the vehicle with
the remote control automatically
locks/unlocks the fuel filler flap.

Remove the key from the steering lock.

Open the fuel filler flap1 by pulling in
direction of the arrow.

Turn the fuel cap2 to the left and hold
on to it until possible pressure is re-
leased.

Take off the cap.

Only fill your tank until the filler nozzle
unit cut out – do not top up or overfill.

Replace the fuel cap by turning it to the
right.
You will hear when the fuel cap is tight-
ened.

Close the fuel filler flap.
Warning!
G
Gasoline is highly flammable and poisonous.
It burns violently and can cause serious inju-
ry. Whenever you are around gasoline, avoid
inhaling fumes and skin contact, extinguish
all smoking materials. Never allow sparks,
flame or smoking materials near gasoline!.
!The fuel filler cap is tethered to the fuel
filler neck. Do not drop the cap. It could
damage the vehicle paint finish.!To prevent damaging the lens of the
plastic tail lamp, make certain that no
gasoline comes into contact with it.
Warning!
G
Overfilling of the fuel tank may create pres-
sure in the system which could cause a gas
discharge. This could cause the gas to spray
back out when removing the fuel pump noz-
zle, which could cause personal injury.iUse only premium unleaded gasoline
with a minimum Posted Octane Rating
of 91 (average of 96 RON / 86 MON).
Information on gasoline quality can
normally be found on the fuel pump.
More information on gasoline can be
found in the Factory Approved Service
Products pamphlet.

285 Technical data
Fuels, coolants, lubricants etc.
Model
Capacity
Fuels, coolants, lubricants etc.
Cooling system
approx. 12.7 US qt (12.0 l)
MB Anticorrosion / Antifreeze
Fuel tank
ML 320, ML 350,
ML 500
22.0 US gal (83.0 l)
Premium unleaded gasoline:
Posted Octane 91 (Avg. of 96 RON/86 MON
ML 55 AMG
25.0 US gal (95.0 l)
Premium unleaded gasoline:
Posted Octane 91 (Avg. of 96 RON/86 MON
including a reserve of
approx. 3.2 US qt (12.0 l)
Air conditioning system
R-134a refrigerant and special PAG lubricant
oil (never R-12)
Windshield washer and
headlamp cleaning sys-
tem
8.0 US qt (7.6 l)
MB Windshield Washer Concentrate
1
1Use MB Windshield Washer Concentrate “S” and water for temperatures above freezing or MB Windshield Washer Concentrate “S” and commercially available pre-
mixed windshield washer solvent / antifreeze for temperatures below freezing. Follow suggested mixing ratios (
page 290).

286 Technical dataFuels, coolants, lubricants etc.Engine oils
Engine oils are specifically tested for their
suitability in our engines. Therefore, use
only engine oils recommended by
Mercedes-Benz. Information on recom-
mended brands is available in the Factory
Approved Service Products pamphlet, or at
your authorized Mercedes-Benz Light
Truck Center.Engine oil additives
Do not blend oil additives with engine oil.
They may be harmful to the engine opera-
tion.
Damage or malfunctions resulting from
blending oil additives are not covered by
the Mercedes-Benz Limited Warranty.Air conditioning refrigerant
R-134a (HFC) refrigerant and special PAG
lubricating oil is used in the air condition-
ing system.Never use R-12 (CFC) or mineral-based lu-
bricating oil, otherwise damage to the
system will occur.
Brake fluid
During vehicle operation, the boiling point
of the brake fluid is continuously reduced
through the absorption of moisture from
the atmosphere. Under extremely strenu-
ous operating conditions, this moisture
content can lead to the formation of bub-
bles in the system, thus reducing the sys-
tem’s efficiency.
Therefore, the brake fluid must be re-
placed every two years, preferably in the
spring.
Only brake fluid approved by
Mercedes-Benz is recommended. Your au-
thorized Mercedes-Benz Center will pro-
vide you with additional information.
Premium unleaded gasoline
!To maintain the engine’s durability and
performance, premium unleaded gaso-
l i n e m u s t b e u s e d . I f p r e m i u m u n l e a d e d
is not available and low octane fuel is
used, follow these precautions:

Have the fuel tank only partially
filled with unleaded regular and fill
up with premium unleaded as soon
as possible.


Avoid full throttle driving and abrupt
acceleration.


Do not exceed an engine speed of
3000 rpm if the vehicle is loaded
with a light load such as two per-
sons and no luggage.


Do not exceed 2/3 of maximum ac-
celerator pedal position if the vehi-
cle is fully loaded or operating in
mountainous terrain.

287 Technical data
Fuels, coolants, lubricants etc.
Fuel requirements
Use only premium unleaded meeting
ASTM standard D 439:

The octane number (posted at the
pump) must be 91 min. It is an average
of both the Research (R) octane num-
ber and the Motor (M) octane number:
(R+M) / 2). This is also known as the
ANTI-KNOCK INDEX.
Unleaded gasoline containing oxygenates
such as ethanol, IPA, IBA and TBA can be
used provided the ratio of any one of these
oxygenates to gasoline does not exceed
10%; MTBE not to exceed 15%.
The ratio of methanol to gasoline must not
exceed 3% plus additional cosolvents.
Using mixtures of ethanol and methanol is
not allowed. Gasohol, which contains 10%
ethanol and 90% unleaded gasoline, can be
used.
These blends must also meet all other fuel
requirements, such as resistance to spark
knock, boiling range, vapor pressure etc.
Gasoline additives
A major concern among engine manufac-
turers is carbon build-up caused by gaso-
line. Mercedes-Benz recommends only the
use of quality gasoline containing additives
that prevent the build up of carbon depos-
its.
After an extended period of using fuels
without such additives, carbon deposits
can build up especially on the intake valves
and in the combustion area, leading to en-
gine performance problems such as:

Warm-up hesitation


Unstable idle


Knocking/pinging


Misfire


Power loss
Do not blend other specific fuel additives
with fuel. This only results in unnecessary
costs and may be harmful to the engine op-
eration.Damage or malfunctions resulting from
poor fuel quality or from blending specific
fuel additives are not covered by the
Mercedes-Benz Limited Warranty.
Coolants
The engine coolant is a mixture of water
and anticorrosion / antifreeze, which pro-
vides:

Corrosion protection


Freeze protection


Boiling protection (by increasing the
boiling point)
The cooling system was filled at the factory
with a coolant providing freeze protection
to approximately -35°F (-37°C) and corro-
sion protection.
If the antifreeze mixture is effective to
-22°F (-30°C), the boiling point of the cool-
ant in the pressurized cooling system is
reached at approximately 266°F (130°C).

295 Technical terms
Memory function*
Used to store three individual seat,
steering wheel and mirror positions.
MON
(M
otor O
ctane N
umber)
The Motor Octane Number for gasoline
as determined by a standardized meth-
od. It is an indication of a gasoline's
ability to resist undesired detonation
(knocking). The average of both the
MON (Motor Octane Number) and
->RON (Research Octane Number) is
posted at the pump, also known as AN-
TI-KNOCK INDEX.
Multifunction display
A display field in the instrument cluster
used to present information provided
by the control system.
Parktronic*
System which uses visual and acoustic
signals to assist the driver during park-
ing maneuvers.Poly-V-belt drive
Drives engine-components (alternator,
AC compressor, etc.) from the engine.
Power train
Collective term designating all compo-
nents used to generate and transmit
motive power to the drive axles, includ-
ing


engine


clutch/torque converter


transmission


transfer case


drive shaft


differential


axle shafts/axlesRemote Vehicle Diagnostics
Transmission of vehicle data and cur-
rent location to the Mercedes-Benz
Customer Assistance Center for sub-
scribers to Tele Aid service.
REST
(Residual engine heat utilization)
Feature that uses the engine heat
stored in the coolant to heat the vehi-
cle interior for a short time after the en-
gine has been turned off.
Restraint system
Seat belts, belt tensioner, airbags and
child seat restraint systems. As inde-
pendent systems, their protective func-
tions complement one another.

296 Technical termsRON
(R
esearch O
ctane N
umber)
The Research Octane Number for gaso-
line as determined by a standardized
method. It is an indication of a gaso-
line's ability to resist undesired detona-
tion (knocking). The average of both
the ->MON (Motor Octane Number)
and RON (Research Octane Number) is
posted at the pump, also known as AN-
TI-KNOCK INDEX.
Shift lock
When the vehicle is parked, this lock
prevents the transmission selector le-
ver from being moved out of positionP
without key turned and brake pedal de-
pressed.
SRS
(S
upplemental R
estraint S
ystem)
Seat belts, emergency tensioning de-
vice and airbags. Though independent
systems, they are closely interfaced to
provide effective occupant protection.Tele Aid System*
(T
elematic A
larm I
dentification on
D
emand)
The Tele Aid system consists of three
types of response: automatic and man-
ual emergency, roadside assistance
and information. Tele Aid is initially ac-
tivated by completing a subscriber
agreement and placing an acquain-
tance call.
The Tele Aid system is operational pro-
viding that the vehicle’s battery is
charged, properly connected, not dam-
aged and cellular and GPS coverage is
available.
Telematics*
A combination of the terms “telecom-
munications” and “informatics”.
Tightening torque
Force times lever arm (e.g. a lug
wrench) with which threaded fasteners
such as wheel bolts are tightened.Tire speed rating
Part of tire designation; indicates the
speed range for which a tire is ap-
proved.
Traction
Force exerted by the vehicle on the
road via the tires.
Transfer case
Speed of rotation/torque converter
that works together with the ->auto-
matic transmission. In the LOW mode
off-road position, the transfer case de-
creases the output rotational speed of
the ->automatic transmission by ap-
proximately half. This results in a corre-
sponding increase of torque on the
drive axles.
The vehicle then has nearly double the
driving force but drives only approxi-
mately half as fast.

310 IndexMB Tex upholstery
Cleaning 222
MCS
Modular Control System 294
Mechanical key 242
Memory function 99, 295
Storing exterior rear view mirror
parking positions 100
Memory function* 100
Recalling positions from memory 100
Mirror
Inside rear view mirror 38
Mirrors
Activating exterior mirror parking posi-
tion 101
Adjusting 38
Automatic antiglare for rear view
mirror 119
Exterior rear view mirror 38
Storing exterior rear view mirror
parking position 101
MON 200
MON (Motor Octane Number) 295
Monitoring reach
Parktronic* 150
Multifunction display 295N
Night security illumination 104
Deactivation temporarily 104
Setting time 104
O
Occupant safety 54
Children and airbags 56
Children in the vehicle 63
Fastening the seat belt 40
Infant and child restraint systems 63
LATCH child seat mounts 68
Seat belts 40, 57
Odometer display 111
Odometer, main 25
Off-road driving
Checklist 187, 191
Crossing obstacles 190
Driving instructions off-road
driving 186
Driving through water 189
Returning 191
Rules 186
Special driving features 186
Steep terrain 187Oil
Adding 204, 205
Checking level 203
Consumption 203
Dipstick 203, 205
Filler neck 205
Viscosity 294
Oil dipstick 205
Oil level
Checking 201
One-touch gearshifting 113
Canceling gear range limit 114
Downshifting 113
Upshifting 114
Opening
Doors from the inside 86
Fuel filler flap 200
Fuel filler flap manually 244
Glove box 152
Hood 202
Liftgate 85, 87
Liftgate from inside 87
Liftgate from outside 87
Rear quarter windows 136
Side windows 135
Sliding/pop-up roof 246

313 Index
Regular checks 201
Reinstalling vehicle battery 262
Remote control
Changing battery 243
Global locking 85
Global unlocking 85
Synchronizing 244
Unlocking liftgate 85
Unlocking the driver’s door, fuel filler
flap 85
Unlocking with 32
Remote control with folding key 84
Remote controls
Integrated 169
Remote door unlock
With Tele Aid* 167
Remote Vehicle Diagnostics 295
Removing
Head restraint 92
Vehicle battery 262
Wheel 257
Wiper blades 254
Removing spare wheel (except
ML 55 AMG) 239
Removing spare wheel (ML 55 AMG) 240Replacing
Backup lamp bulbs 251
Brake lamp bulbs 251
Bulbs 247
Front lamp bulbs 249
Front turn signal bulbs 249
Fuses 271
High beam bulbs 250
High mounted brake lamp 252
License plate lamp bulbs 252
Low beam bulbs 249
Rear fog lamp bulbs 251
Rear lamp bulbs 248, 251
Rear parking lamp bulbs 251
Rear side marker lamp bulbs 251
Rear standing lamp bulbs 251
Rear turn signal bulbs 251
Wiper blades 254
Replacing front fog lamp bulb 251
Reporting
Safety defects 19
Resetting
Service indicator (FSS) 216
Trip odometer 112
Residual heat utilization 130, 295Residual ventilation 130
REST (Residual engine heat utilization) 295
Restraint system 295
Restraint system see Infant and child re-
straint systems 63, 67
Restraint systems 54
Airbags 54
Child seat recognition 54
Child seats 54
Emergency tensioning device (ETD) 54
Lower anchors and tethers for children
(LATCH) 54
Seat belts 54
Returning from off-road driving 191
Rims 279
Roadside assistance 12
Tele Aid* 163
Rolling code programming 170
RON 200
RON (Research Octane Number) 296
Roof rack 145
Rotating wheels 212
Rubber parts
Cleaning 222