ad blue MERCEDES-BENZ ML350 2010 W164 Owner's Manual

Symbols
Trademarks ®
:
R AdBlue ®
is a registered trademark of the
German Association of the Automotive
Industry (VDA).
R BabySmart TM
is a trademark of Siemens
Automotive Corp.
R Bluetooth ®
is a registered trademark of
Bluetooth SIG Inc.
R ESP ®
and PRE-SAFE ®
are registered
trademarks of Daimler.
R HomeLink ®
is a registered trademark of
Prince, a Johnson Controls Company.
R SIRIUS and related marks are trademarks
of SIRIUS XM Radio Inc.
The following symbols are found in this
Operator’s Manual:GWarning!
Warning notices draw your attention to
hazards that may endanger your health or life,
or the health or life of others.
! Highlights hazards that may result in
damage to your vehicle.
i Helpful hints or further information you
may find useful.
XThis symbol points to instructions
for you to follow.XA number of these symbols
appearing in succession indicates
a multiple-step procedure.Y pageThis symbol tells you where to look
for further information on a topic.YYThis continuation symbol marks a
warning or procedure which is
continued on the next page.DisplayText in displays, such as the control
system, are printed in the type
shown here.164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 2

1, 2, 3 ...
115V AC Socket ................................. 198
3-zone automatic climate control see Climate control system
4-ETS
see ETS/4-ETS
4MATIC
see All-wheel drive (4MATIC)
A
ABS (Antilock Brake System) ............. 62
Indicator lamp ................................ 298
Messages in the multifunction
display ................................... 273, 284
Accessory weight .............................. 239
Accidents ........................................... 107
Air bags ........................................... 37
Distance warning function .............151
Emergency calls (Tele Aid) .............200
NECK-PRO active front head
restraints ........................................ 53
Active Bi-Xenon headlamps
Messages in the multifunction
display ........................................... 293
see Headlamps
Adaptive Damping System
see ADS
AdBlue ®
...................................... 331, 361
Capacity, AdBlue ®
tank ................. 358
Refilling ......................................... 332
Additives
Engine oil ....................................... 359
Gasoline ......................................... 361
Address change ................................... 22
ADS (Adaptive Damping System) ..... 156
Advanced Tire Pressure
Monitoring System (Advanced
TPMS) ................................................. 223
Messages in the multifunction
display ................................... 281, 296
Air bags ................................................ 37
Emergency call upon deployment ..200
Front, driver and passenger .............40
Front passenger front air bag off
indicator lamp (Canada
only) ........................................ 46, 305
Front passenger front air bag off
indicator lamp (USA only) ........42, 305
Messages in the multifunction
display ........................................... 275
OCS (Occupant Classification
System) ........................................... 42
Safety guidelines ............................. 39
Side impact ...................................... 40
Window curtain ................................ 41
Air conditioning refrigerant and
lubricant ............................................. 359
Air distribution .......................... 171, 180
Air filter .............................................. 292
AIRMATIC/Compass menu ............... 127
Air pressure see Tire inflation pressure
Air pressure (tires) ............................ 240
Air pump (electric) ............................ 328
Air recirculation mode .............. 172, 182
Air suspension program
Comfortable driving style ...............156
Introduction ................................... 155
Messages in the multifunction
display ........................................... 285
Sporty driving style ........................156
Suspension tuning .........................156
Vehicle level control ......................156
Air volume ................................. 171, 181
Alarm system see Anti-theft systems
Alignment bolt (vehicle tool
kit) .............................................. 268, 327
All-wheel drive (4MATIC) .................. 159
Alternator
Messages in the multifunction
display ................................... 280, 290
Alternator (Technical data)
see Vehicle specification
AMG menu ......................................... 123
Anticorrosion/antifreeze .................. 363
Antilock Brake System see ABS
Anti-theft systems ............................... 66
Anti-theft alarm system ...................66
Immobilizer ...................................... 66
Aquaplaning
see Hydroplaning 4Index164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 4

Armrest, front
Storage compartment ....................193
Ashtrays ............................................. 196
Aspect ratio (tires) ............................ 240
Audio/DVD menu .............................. 126
Auto-dimming rear view mirrors ........ 90
Automatic central locking .......... 74, 135
Automatic headlamp mode ................ 93
Automatic interior lighting control .... 97
Automatic locking when driving ...... 135
Automatic shift program .................. 114
Automatic transmission ................... 109
Automatic shift program ................114
Emergency operation (limp-home
mode) ............................................ 117
Gear range indicator ......................114
Gear ranges ................................... 113
Gear selector lever ........................109
Hill-start assist system ..................152
Kickdown ....................................... 113
Kickdown (manual shift program) ..117
Manual shift program ..................... 115
One-touch gearshifting ..................115
Program mode indicator ................114
Program mode selector switch
(automatic shift program) ..............114
Program mode selector switch
(manual shift program) ..................116
Shifting procedure .........................111
Steering wheel gearshift control ....115
Towing a trailer .............................. 113
Transmission position indicator .....112
Transmission positions ..................112
AUX socket ........................................ 193
Axle oils .............................................. 357
B
BabySmart™
Air bag deactivation system .............46
Self-test ........................................... 47
Backrest
see Seats
Backup lamps
Messages in the multifunction
display ........................................... 293
Bar (air pressure unit) ....................... 240
BAS (Brake Assist System) ................. 63
Batteries, SmartKey
Checking condition ..........................73
Replacing ....................................... 309
Battery, Vehicle ................................. 334
Charging ........................................ 336
Jump starting ................................. 336
Messages in the multifunction
display ................................... 280, 290
Bead (tire) .......................................... 240
Beverage holders see Cup holders
Bleeding the fuel system (diesel
engine) ............................................... 331
BlueTEC
AdBlue ®
tank ................................. 331
AdBlue ®
tank capacity ...................358
Brake fluid
Checking level ............................... 217
Messages in the multifunction
display ........................................... 284
Brake lamps
Cleaning lenses ............................. 263
Brake pads
Messages in the multifunction
display ........................................... 283
Brakes ................................................ 245
High-performance brake system ....246
Parking brake ........................ 107, 247
Warning lamp ................................. 299
Break-in period .................................. 210
Bug cover (Radiator) ......................... 214
Bulbs see Replacing bulbs
C
CAC (Customer Assistance Center) ... 23
California retail buyers and
lessees, important notice for ............. 21
Calls (phone) ...................................... 139
Can holders see Cup holders
Capacities and recommended
fuel/lubricants .................................. 356
Cargo compartment
Cargo net ....................................... 191
Cargo volume, expanding ..............189
Cover blind .................................... 190
Index5164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 5

Oil dipstick ..................................... 215
Recommended engine oils and oil
filter ............................................... 359
ESP ®
(Electronic Stability
Program) .............................................. 63
ETS/4-ETS ....................................... 64
Messages in the multifunction
display ................................... 273, 284
Off-road ESP ®
.................................. 65
Trailer stabilization ........................... 66
Warning lamp ................................. 301
ETD (Emergency Tensioning
Device) ................................................. 52
Safety guidelines ............................. 39
ETS/4-ETS (Electronic Traction
System) ................................................ 64
Express operation
Power windows .............................. 100
Tilt/sliding sunroof ........................184
Exterior lamp switch ........................... 93
Exterior rear view mirrors .................. 89
Fold-in function ........................ 91, 137
Parking position ............................... 90
Power-folding ................................... 91
Exterior view of vehicle ...................... 26
F
Fastening the seat belts ..................... 50
First aid kit ......................................... 268
Flat tire ............................................... 319
Lowering the vehicle ......................329
Mounting the spare wheel .............324
Preparing the vehicle .....................320
Spare wheel ........................... 319, 356
TIREFIT (tire repair kit) ...................320
Floormats ........................................... 208
Fluids
AdBlue ®
......................................... 358
Automatic transmission fluid .........357
Brake fluid ..................................... 358
Capacities ...................................... 356
Engine coolant ............................... 358
Engine oil ....................................... 357
Power steering fluid .......................357
Washer and headlamp cleaning
system ........................................... 358
Fog lamps ............................................. 95
Messages in the multifunction
display ................................... 293, 294
Fold-in function for exterior rear
view mirrors ................................ 91, 137
Four-wheel drive see All-wheel drive (4MATIC)
Front air bags
see Air bags
Front axle oil ...................................... 357
Front lamps see Headlamps
Front passenger front air bag ............ 40
Messages in the multifunction
display ........................................... 275
Front passenger front air bag off
indicator lamp (Canada only) ..... 46, 305
Front passenger front air bag off
indicator lamp (USA only) .......... 42, 305
Front seat head restraints see Head restraints
Fuel ..................................................... 210
Additives ........................................ 361
Capacity, fuel tank .........................358
Diesel fuel ............................. 358, 360
Drive sensibly–safe fuel .................244
Fuel consumption statistics ...........138
Fuel filler flap and cap ...................212
Fuel tank reserve warning
lamp ........................................ 29, 303
Premium unleaded gasoline ... 358, 360
Refueling ........................................ 210
Requirements ................................ 360
Fuel filler flap ..................................... 212
Opening manually ..........................308
Fuels, coolants, lubricants etc.
Capacities ...................................... 356
Fuel system, bleeding (diesel
engine) ............................................... 331
Fuel tank
Capacity ........................................ 358
Fuel filler flap and cap ...................212
Refueling ........................................ 210
Fuses .................................................. 342Index9164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 9

Program mode selector switch
Automatic shift program ................114
Manual shift program ..................... 116
Proximity key
see Key, SmartKey
PSI (air pressure unit) ....................... 241
R
RACETIMER ........................................ 124
Radiator ..................................... 214, 242
Radio
Selecting stations ..........................126
Radio transmitters ............................ 257
Rain sensor see Intermittent wiping
Rear axle oil ....................................... 357
Rear center console ashtray see Ashtrays
Rear doors
Child safety locks ............................ 60
Rear door window
Override switch ................................ 60
Rear fog lamp
see Fog lamps
Rear lamps
see Tail lamps
Rear seat head restraints
see Head restraints
Rear view camera .............................. 163
Cleaning the camera lens ..............263
Rear window defroster ..................... 183
Rear window wiper/washer ............. 100
Recommended tire inflation
pressure ..................................... 219, 241
Refilling
AdBlue ®
......................................... 332
Refrigerant, air conditioning ............ 359
Refueling ............................................ 210
Regular checks .................................. 212
Reminder, Seat belt see Seat belts, Telltale
Remote control
see Key, SmartKey
Remote door unlock (Tele Aid) ......... 203
Replacing
Key .................................................. 74
Replacing bulbs ................................. 311
Reporting safety defects .................... 24
Research Octane Number see RON
Reserve fuel
Messages in the multifunction
display ........................................... 291
Warning lamp ................................... 29
Reset button ................................ 28, 118
Reset tool (NECK-PRO active front
head restraints) ................................. 309
Restraint systems see Occupant safety
Rims ........................................... 241, 352
Roadside Assistance ................... 21, 201
RON (Research Octane Number) ..... 360
Rubber parts, cleaning ...................... 264
Run-flat tires see MOExtended tires
S
Safety
Driving safety systems .....................61
Occupant safety ............................... 36
Reporting defects ............................ 24
Safety belts
see Seat belts
Seat belt force limiter ......................... 52
Seat belts ............................................. 48
Adjustment function ........................51
Children in the vehicle .....................55
Cleaning ......................................... 265
Fastening ......................................... 50
Height adjustment ...........................51
Proper use of ................................... 48
Safety guidelines ............................. 39
Safety notes ..................................... 48
Telltale ..................................... 29, 300
Seat heating ......................................... 86
Seating capacity ................................ 228
Seats ..................................................... 81
Adjustment ...................................... 81
Easy-entry/exit feature ....................87
Folding (expanding cargo volume) . 189
Heating ............................................ 86
Memory function .............................. 92
Multicontour seat ............................ 85
Ventilation ....................................... 85
Index15164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 15

Capacities fuels, coolants,
lubricants etc. ................................ 356
Coolant .......................................... 362
Engine oil additives ........................359
Engine oils ..................................... 359
Fuel requirements .......................... 360
Gasoline additives .......................... 361
Identification labels .......................346
Premium unleaded gasoline ...........360
Rims and tires ................................ 352
Spare wheel ................................... 356
Vehicle specification ML 350 ......... 348
Vehicle specification
ML 350 4MATIC ............................. 349
Vehicle specification
ML 350 BlueTEC 4MATIC ...............348
Vehicle specification
ML 550 4MATIC ............................. 350
Vehicle specification ML 63 AMG ..351
Washer and headlamp cleaning
system ................................... 358, 364
Technical data (dimensions)
see Vehicle specification
Technical data (electrical system)
see Vehicle specification
Technical data (engine)
see Vehicle specification
Technical data (weights)
see Vehicle specification
Tele Aid ............................................... 199
Emergency calls ............................. 200
Information button .........................202
Initiating an emergency call
manually ........................................ 201
Messages in the multifunction
display ........................................... 285
Remote door unlock ......................203
Roadside Assistance button ..........201
Search & Send ............................... 203
SOS button .................................... 201
Stolen Vehicle Recovery Services ..204
System self-test ............................. 199
Telephone ............................................. 30
Answering/ending a call ................140
Hands-free microphone ...................33
Menu ............................................. 139
Operation ....................................... 139Phone book .................................... 140
Redialing ........................................ 141
Temperature
Interior temperature ..............170, 179
Outside .................................. 123, 131
Tether anchorage points
see Children in the vehicle
Tie-down rings ................................... 188
Tightening torque
Wheels ........................................... 330
Time setting ....................................... 132
TIN (Tire Identification Number) ...... 241
Tire and Loading Information
placard ............................................... 227
Tire and loading terminology ........... 239
TIREFIT ............................................... 320
Tire Identification Number see TIN
Tire inflation pressure
Checking ........................................ 221
Important notes on ........................220
Label on the inside of fuel filler
flap ................................................ 220
Placard on driver’s door B-pillar .....227
Tire labeling ....................................... 235
Tire load rating .................................. 240
Tire ply composition and material
used .................................................... 241
Tire pressure loss warning system . 222
Tire repair kit see TIREFIT
Tires ........................................... 218, 352
Advanced Tire Pressure
Monitoring System (Advanced
TPMS) ............................................ 223
Air pressure ................................... 219
Care and maintenance ...................232
Cleaning ......................................... 233
Direction of rotation, spinning .......231
Important notes on tire inflation
pressure ........................................ 220
Inflation pressure ........................... 221
Information placard .......................227
Inspection ...................................... 232
Labeling ......................................... 235
Load index ............................. 236, 240
Load rating .................................... 240Index17164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 17

Modifications and alterations,
Operating safety .............................. 23
Towing ........................................... 338
Unlocking/locking manually ..........306
Vehicle configuration menu ............. 137
Vehicle dimensions see Vehicle specification
Vehicle Identification Number
(VIN) ................................................... 346
Vehicle jack see Jack
Vehicle level control
see Air suspension program
Vehicle lighting .................................... 92
Vehicle loading
Cargo tie-down rings ...................... 188
Cargo volume, expanding ..............189
Carriers .......................................... 187
Instructions .................................... 186
Load limit ....................................... 228
Terminology ................................... 239
Vehicle maximum load on the tire ... 242
Vehicle specification
ML 350 .......................................... 348
ML 350 4MATIC ............................. 349
ML 350 BlueTEC 4MATIC ...............348
ML 550 4MATIC ............................. 350
ML 63 AMG ................................... 351
Vehicle status message memory .... 128
Vehicle tool kit .................................. 268
Vehicle washing see Vehicle care
Vehicle weights
see Vehicle specification
W
Warning lamps see Lamps, Indicator and warning
Warning sounds
Distance warning function .............151
Distronic ........................................ 146
Driver’s or passenger’s seat belt .....51
Parking brake ................................ 284
Parktronic system ..........................163
Seat belt telltale ............................ 300
Warranty coverage ............................ 346
Washer and headlamp cleaning
system ................................................ 364
Washer fluid
Messages in the multifunction
display ........................................... 288
Mixing ratio .................................... 364
Refilling .......................................... 217
Washing the vehicle .......................... 260
Wear pattern (tires) .......................... 234
Weights (vehicle) see Vehicle specification
Wheel
Changing ....................................... 319
Removing ....................................... 327
Spare ............................................. 319
Tightening torque ........................... 330
Wheels, sizes ..................................... 352
Wheels, Tires and .............................. 218
Window curtain air bags ..................... 41
Windows see Power windows
Windows, cleaning ............................ 264
Windshield
Cleaning wiper blades .................... 264
Infrared reflecting ..........................208
Washer fluid ................................... 364
Wipers ............................................. 98
Windshield wipers
Replacing wiper blades ..................318
Winter cover .............................. 214, 242
Winter driving
Instructions .................................... 243
Radiator cover ............................... 242
Snow chains .................................. 243
Tires ............................................... 242
Winter tires ................................ 242, 352
Wood trims, cleaning ........................ 266Index19164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 19

XWhile seated, reach behind you with both
hands and find lower edge of the head
restraint.
XAdjust the head restraint to the desired
position by pushing or pulling on the lower
edge of the head restraint cushion.
Rear seat head restraints, removing
and installing
XRemoving: Pull head restraint : to its
uppermost position.
XPress release button ; and pull out head
restraint.
XInstalling: Insert head restraint : into
openings on the seat backrest.
XPush head restraint : down until it audibly
engages.
XPress release button ; and adjust head
restraint : to the desired position.
Multicontour seats
The multicontour seat has a movable seat
cushion and inflatable air cushions built into
the seat backrest to provide additional
lumbar and side support.
XSwitch on the ignition.XSeat cushion depth: Adjust the seat
cushion depth to the length of your upper
leg using switch :.
XSeat backrest contour: Adjust the
contour of the seat backrest to the desired
position using W or X.
XMove the seat backrest support cushion to
the bottom with button ? or to the center
with button =.
XSeat backrest side bolsters: Adjust the
side bolsters so that they provide good
lateral support using switch ;.
Seat ventilation
The blue indicator lamps ; in seat ventilation
switch : come on to show which ventilation
level you have selected.
iThe seat ventilation for the driver’s seat
can be activated using the summer opening
feature (Y page 102).
Seats85Controls in detail164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 85Z

XSwitch on the ignition.XSwitching on: Press respective seat
ventilation switch :.
Three blue indicator lamps ; in seat
ventilation switch : come on.
XPress seat ventilation switch : repeatedly
until the desired ventilation level is set.
XSwitching off: Press seat ventilation
switch : repeatedly until all indicator
lamps ; go out.
If there is insufficient voltage the seat
ventilating switches off automatically.
Seat heating
Front seat heating switches
The switches for the outboard rear seat
heating are located in the rear center console.
Rear seat heating switches
The red indicator lamps ; in front or rear
seat heating switch : come on to show
which heating level you have selected.
The seat heating switches from level 3 (high)
to level 2 after approximately 5 minutes.
The seat heating switches from level 2 to level
1 (low) after approximately 10 minutes.
After approximately 20 minutes in level 1, the
seat heating switches off automatically.
XSwitch on the ignition.XSwitching on: Press respective seat
heating switch :.
Three red indicator lamps ; in the
respective seat heating switch : come on.
XContinue pressing respective seat heating
switch : until desired seat heating level is
reached.
XSwitching off: Press respective seat
heating switch : repeatedly until all
indicator lamps ; go out.
If one or more of indicator lamps ; in
respective seat heating switch : are
flashing, there is insufficient voltage available
since too many electrical consumers are
turned on. The seat heating switches off
automatically.
The seat heating will switch back on again
automatically as soon as sufficient voltage is
available.
Multifunction steering wheel
Safety notes
GWarning!
Do not adjust the steering wheel while driving.
Adjusting the steering wheel while driving, or
driving without the steering wheel adjustment
feature locked could cause the driver to lose
control of the vehicle.
The electrical steering wheel adjustment
feature can be operated at any time.
Therefore, do not leave children unattended
in the vehicle, or with access to an unlocked
vehicle. A child’s unsupervised access to a
vehicle could result in an accident and/or
serious personal injury.
86Multifunction steering wheelControls in detail
164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 86

:Distance driven since last reset;Time elapsed since last reset=Average speed since last reset?Average fuel consumption since last reset
Resetting fuel consumption statistics
XPress button U or V repeatedly until
the message From Start appears in the
multifunction display.
XPress button & or * repeatedly until
the reading that you want to reset appears
in the multifunction display.
XPress and hold the reset button in the
instrument cluster until the respective
values are reset to 0.
The fuel consumption statistics reset
automatically to 0 after 99 999 miles or
9 999 hours, whichever occurs first.
Distance to empty
XPress button U or V repeatedly until
the message From Start appears in the
multifunction display.
XPress button & or * repeatedly until
the message Range: appears in the
multifunction display.
The calculated remaining driving range
based on the current fuel tank level
appears in the multifunction display.
If only very little fuel is left in the tank, a
vehicle at the fuel pump C appears
instead of the remaining driving range.Current fuel consumption
XPress button U or V repeatedly until
the message From Start appears in the
multifunction display.
XPress button & or * repeatedly until
the message Consumption appears in the
multifunction display.
The current fuel consumption appears in
the multifunction display.
Telephone menu
GWarning!
A driver’s attention to the road must always
be his/her primary focus when driving. For
your safety and the safety of others, we
recommend that you pull over to a safe
location and stop before placing or taking a
telephone call. If you choose to use the
telephone while driving, please use the hands-
free device and only use the telephone when
weather, road and traffic conditions permit.
Some jurisdictions prohibit the driver from
using a mobile phone while driving a vehicle.
Bear in mind that at a speed of just 30 mph
(approximately 50 km/h), your vehicle is
covering a distance of 44 feet (approximately
14 m) every second.
You can connect your telephone to the
COMAND system via Bluetooth®, see
Control system139Controls in detail164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 139Z