adblue MERCEDES-BENZ ML350 2010 W164 Owner's Manual

Symbols
Trademarks ®
:
R AdBlue ®
is a registered trademark of the
German Association of the Automotive
Industry (VDA).
R BabySmart TM
is a trademark of Siemens
Automotive Corp.
R Bluetooth ®
is a registered trademark of
Bluetooth SIG Inc.
R ESP ®
and PRE-SAFE ®
are registered
trademarks of Daimler.
R HomeLink ®
is a registered trademark of
Prince, a Johnson Controls Company.
R SIRIUS and related marks are trademarks
of SIRIUS XM Radio Inc.
The following symbols are found in this
Operator’s Manual:GWarning!
Warning notices draw your attention to
hazards that may endanger your health or life,
or the health or life of others.
! Highlights hazards that may result in
damage to your vehicle.
i Helpful hints or further information you
may find useful.
XThis symbol points to instructions
for you to follow.XA number of these symbols
appearing in succession indicates
a multiple-step procedure.Y pageThis symbol tells you where to look
for further information on a topic.YYThis continuation symbol marks a
warning or procedure which is
continued on the next page.DisplayText in displays, such as the control
system, are printed in the type
shown here.164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 2

1, 2, 3 ...
115V AC Socket ................................. 198
3-zone automatic climate control see Climate control system
4-ETS
see ETS/4-ETS
4MATIC
see All-wheel drive (4MATIC)
A
ABS (Antilock Brake System) ............. 62
Indicator lamp ................................ 298
Messages in the multifunction
display ................................... 273, 284
Accessory weight .............................. 239
Accidents ........................................... 107
Air bags ........................................... 37
Distance warning function .............151
Emergency calls (Tele Aid) .............200
NECK-PRO active front head
restraints ........................................ 53
Active Bi-Xenon headlamps
Messages in the multifunction
display ........................................... 293
see Headlamps
Adaptive Damping System
see ADS
AdBlue ®
...................................... 331, 361
Capacity, AdBlue ®
tank ................. 358
Refilling ......................................... 332
Additives
Engine oil ....................................... 359
Gasoline ......................................... 361
Address change ................................... 22
ADS (Adaptive Damping System) ..... 156
Advanced Tire Pressure
Monitoring System (Advanced
TPMS) ................................................. 223
Messages in the multifunction
display ................................... 281, 296
Air bags ................................................ 37
Emergency call upon deployment ..200
Front, driver and passenger .............40
Front passenger front air bag off
indicator lamp (Canada
only) ........................................ 46, 305
Front passenger front air bag off
indicator lamp (USA only) ........42, 305
Messages in the multifunction
display ........................................... 275
OCS (Occupant Classification
System) ........................................... 42
Safety guidelines ............................. 39
Side impact ...................................... 40
Window curtain ................................ 41
Air conditioning refrigerant and
lubricant ............................................. 359
Air distribution .......................... 171, 180
Air filter .............................................. 292
AIRMATIC/Compass menu ............... 127
Air pressure see Tire inflation pressure
Air pressure (tires) ............................ 240
Air pump (electric) ............................ 328
Air recirculation mode .............. 172, 182
Air suspension program
Comfortable driving style ...............156
Introduction ................................... 155
Messages in the multifunction
display ........................................... 285
Sporty driving style ........................156
Suspension tuning .........................156
Vehicle level control ......................156
Air volume ................................. 171, 181
Alarm system see Anti-theft systems
Alignment bolt (vehicle tool
kit) .............................................. 268, 327
All-wheel drive (4MATIC) .................. 159
Alternator
Messages in the multifunction
display ................................... 280, 290
Alternator (Technical data)
see Vehicle specification
AMG menu ......................................... 123
Anticorrosion/antifreeze .................. 363
Antilock Brake System see ABS
Anti-theft systems ............................... 66
Anti-theft alarm system ...................66
Immobilizer ...................................... 66
Aquaplaning
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Armrest, front
Storage compartment ....................193
Ashtrays ............................................. 196
Aspect ratio (tires) ............................ 240
Audio/DVD menu .............................. 126
Auto-dimming rear view mirrors ........ 90
Automatic central locking .......... 74, 135
Automatic headlamp mode ................ 93
Automatic interior lighting control .... 97
Automatic locking when driving ...... 135
Automatic shift program .................. 114
Automatic transmission ................... 109
Automatic shift program ................114
Emergency operation (limp-home
mode) ............................................ 117
Gear range indicator ......................114
Gear ranges ................................... 113
Gear selector lever ........................109
Hill-start assist system ..................152
Kickdown ....................................... 113
Kickdown (manual shift program) ..117
Manual shift program ..................... 115
One-touch gearshifting ..................115
Program mode indicator ................114
Program mode selector switch
(automatic shift program) ..............114
Program mode selector switch
(manual shift program) ..................116
Shifting procedure .........................111
Steering wheel gearshift control ....115
Towing a trailer .............................. 113
Transmission position indicator .....112
Transmission positions ..................112
AUX socket ........................................ 193
Axle oils .............................................. 357
B
BabySmart™
Air bag deactivation system .............46
Self-test ........................................... 47
Backrest
see Seats
Backup lamps
Messages in the multifunction
display ........................................... 293
Bar (air pressure unit) ....................... 240
BAS (Brake Assist System) ................. 63
Batteries, SmartKey
Checking condition ..........................73
Replacing ....................................... 309
Battery, Vehicle ................................. 334
Charging ........................................ 336
Jump starting ................................. 336
Messages in the multifunction
display ................................... 280, 290
Bead (tire) .......................................... 240
Beverage holders see Cup holders
Bleeding the fuel system (diesel
engine) ............................................... 331
BlueTEC
AdBlue ®
tank ................................. 331
AdBlue ®
tank capacity ...................358
Brake fluid
Checking level ............................... 217
Messages in the multifunction
display ........................................... 284
Brake lamps
Cleaning lenses ............................. 263
Brake pads
Messages in the multifunction
display ........................................... 283
Brakes ................................................ 245
High-performance brake system ....246
Parking brake ........................ 107, 247
Warning lamp ................................. 299
Break-in period .................................. 210
Bug cover (Radiator) ......................... 214
Bulbs see Replacing bulbs
C
CAC (Customer Assistance Center) ... 23
California retail buyers and
lessees, important notice for ............. 21
Calls (phone) ...................................... 139
Can holders see Cup holders
Capacities and recommended
fuel/lubricants .................................. 356
Cargo compartment
Cargo net ....................................... 191
Cargo volume, expanding ..............189
Cover blind .................................... 190
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Oil dipstick ..................................... 215
Recommended engine oils and oil
filter ............................................... 359
ESP ®
(Electronic Stability
Program) .............................................. 63
ETS/4-ETS ....................................... 64
Messages in the multifunction
display ................................... 273, 284
Off-road ESP ®
.................................. 65
Trailer stabilization ........................... 66
Warning lamp ................................. 301
ETD (Emergency Tensioning
Device) ................................................. 52
Safety guidelines ............................. 39
ETS/4-ETS (Electronic Traction
System) ................................................ 64
Express operation
Power windows .............................. 100
Tilt/sliding sunroof ........................184
Exterior lamp switch ........................... 93
Exterior rear view mirrors .................. 89
Fold-in function ........................ 91, 137
Parking position ............................... 90
Power-folding ................................... 91
Exterior view of vehicle ...................... 26
F
Fastening the seat belts ..................... 50
First aid kit ......................................... 268
Flat tire ............................................... 319
Lowering the vehicle ......................329
Mounting the spare wheel .............324
Preparing the vehicle .....................320
Spare wheel ........................... 319, 356
TIREFIT (tire repair kit) ...................320
Floormats ........................................... 208
Fluids
AdBlue ®
......................................... 358
Automatic transmission fluid .........357
Brake fluid ..................................... 358
Capacities ...................................... 356
Engine coolant ............................... 358
Engine oil ....................................... 357
Power steering fluid .......................357
Washer and headlamp cleaning
system ........................................... 358
Fog lamps ............................................. 95
Messages in the multifunction
display ................................... 293, 294
Fold-in function for exterior rear
view mirrors ................................ 91, 137
Four-wheel drive see All-wheel drive (4MATIC)
Front air bags
see Air bags
Front axle oil ...................................... 357
Front lamps see Headlamps
Front passenger front air bag ............ 40
Messages in the multifunction
display ........................................... 275
Front passenger front air bag off
indicator lamp (Canada only) ..... 46, 305
Front passenger front air bag off
indicator lamp (USA only) .......... 42, 305
Front seat head restraints see Head restraints
Fuel ..................................................... 210
Additives ........................................ 361
Capacity, fuel tank .........................358
Diesel fuel ............................. 358, 360
Drive sensibly–safe fuel .................244
Fuel consumption statistics ...........138
Fuel filler flap and cap ...................212
Fuel tank reserve warning
lamp ........................................ 29, 303
Premium unleaded gasoline ... 358, 360
Refueling ........................................ 210
Requirements ................................ 360
Fuel filler flap ..................................... 212
Opening manually ..........................308
Fuels, coolants, lubricants etc.
Capacities ...................................... 356
Fuel system, bleeding (diesel
engine) ............................................... 331
Fuel tank
Capacity ........................................ 358
Fuel filler flap and cap ...................212
Refueling ........................................ 210
Fuses .................................................. 342Index9164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 9

Program mode selector switch
Automatic shift program ................114
Manual shift program ..................... 116
Proximity key
see Key, SmartKey
PSI (air pressure unit) ....................... 241
R
RACETIMER ........................................ 124
Radiator ..................................... 214, 242
Radio
Selecting stations ..........................126
Radio transmitters ............................ 257
Rain sensor see Intermittent wiping
Rear axle oil ....................................... 357
Rear center console ashtray see Ashtrays
Rear doors
Child safety locks ............................ 60
Rear door window
Override switch ................................ 60
Rear fog lamp
see Fog lamps
Rear lamps
see Tail lamps
Rear seat head restraints
see Head restraints
Rear view camera .............................. 163
Cleaning the camera lens ..............263
Rear window defroster ..................... 183
Rear window wiper/washer ............. 100
Recommended tire inflation
pressure ..................................... 219, 241
Refilling
AdBlue ®
......................................... 332
Refrigerant, air conditioning ............ 359
Refueling ............................................ 210
Regular checks .................................. 212
Reminder, Seat belt see Seat belts, Telltale
Remote control
see Key, SmartKey
Remote door unlock (Tele Aid) ......... 203
Replacing
Key .................................................. 74
Replacing bulbs ................................. 311
Reporting safety defects .................... 24
Research Octane Number see RON
Reserve fuel
Messages in the multifunction
display ........................................... 291
Warning lamp ................................... 29
Reset button ................................ 28, 118
Reset tool (NECK-PRO active front
head restraints) ................................. 309
Restraint systems see Occupant safety
Rims ........................................... 241, 352
Roadside Assistance ................... 21, 201
RON (Research Octane Number) ..... 360
Rubber parts, cleaning ...................... 264
Run-flat tires see MOExtended tires
S
Safety
Driving safety systems .....................61
Occupant safety ............................... 36
Reporting defects ............................ 24
Safety belts
see Seat belts
Seat belt force limiter ......................... 52
Seat belts ............................................. 48
Adjustment function ........................51
Children in the vehicle .....................55
Cleaning ......................................... 265
Fastening ......................................... 50
Height adjustment ...........................51
Proper use of ................................... 48
Safety guidelines ............................. 39
Safety notes ..................................... 48
Telltale ..................................... 29, 300
Seat heating ......................................... 86
Seating capacity ................................ 228
Seats ..................................................... 81
Adjustment ...................................... 81
Easy-entry/exit feature ....................87
Folding (expanding cargo volume) . 189
Heating ............................................ 86
Memory function .............................. 92
Multicontour seat ............................ 85
Ventilation ....................................... 85
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Vehicle equipment ............................268
Where will I find ...? ..........................268
Vehicle status messages in the
multifunction display .......................272
What to do if … ..................................297
Unlocking/locking manually ...........306
Resetting activated NECK-PRO
active front head restraints .............309
Replacing SmartKey batteries .........309
Replacing bulbs .................................311
Replacing wiper blades ....................318
Flat tire ..............................................319
Bleeding the fuel system (diesel
engine only) .......................................331
AdBlue® (diesel engine only) ...........331
Battery ...............................................334
Jump starting ....................................336
Towing the vehicle ............................338
Fuses ..................................................342
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Display messagesPossible causes/consequences and M Solutions8Gas Cap
OpenA loss of pressure has been detected in the fuel system. The
fuel cap may not be closed properly or the fuel system may
be leaking.XCheck the fuel cap ( Y page 212).XIf it is not closed properly: Close the fuel cap.XIf it is closed properly: Have the fuel system checked at
an authorized Mercedes-Benz Center.¸Replace
air filterThe air filter is clogged.XHave the air filter checked at an authorized Mercedes-Benz
Center.·Clean
Fuel
FilterThere is water in the fuel filter.XHave the water drained at an authorized Mercedes-Benz
Center as soon as possible.ØCheck
Additive
See
Operator's
ManualThe AdBlue ®
supply is almost depleted.XHave the AdBlue ®
tank refilled as soon as possible
( Y page 331).
Contact an authorized Mercedes-Benz Center.ØRemaining
Starts: 20The AdBlue ®
supply has dropped to the minimum level.XHave the AdBlue ®
tank refilled immediately ( Y page 331).
Contact an authorized Mercedes-Benz Center.i When the message Remaining
Starts: 20 appears in the multifunction
display, you can start the engine 20 more
times. If you do not add AdBlue ®
, the
engine cannot be started beyond that
point. Therefore, fill the AdBlue ®
tank withapproximately 1 gal (3.79 l) AdBlue ®
(corresponds to approximately 2 refill
containers AdBlue ®
) or have the AdBlue ®
tank filled at an authorized Mercedes-Benz
Center. After AdBlue ®
was refilled, the
engine can be started again.292Vehicle status messages in the multifunction displayPractical hints
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significantly shorter or, if the vehicle is driven
cautiously, somewhat longer.
Do not continue driving in emergency mode if
R you notice knocking sounds
R the vehicle starts to shake
R smoke develops and you smell rubber
R ESP ®
is intervening continuously
R you notice tears on the tire sidewalls
After driving in emergency mode, you must
have the rims inspected by an authorized
Mercedes-Benz Center to check if they are
suitable for further use. The failed tire must
be replaced in any case.
When replacing individual or all tires on the
vehicle, make sure only tires marked with
“MOExtended” are mounted in the size
specified for your vehicle ( Y page 352).
Bleeding the fuel system (diesel
engine only)
Driving the vehicle until the fuel tank is empty
is not recommended. Otherwise, air may be
sucked into the fuel system. If this happens,
the malfunction indicator lamp = (USA
only) or ; (Canada only) comes on and the
engine may not start immediately after
refueling the vehicle.
After refueling:
XMake sure the automatic transmission is in
park position P.
The transmission position indicator in the
multifunction display should be on P.XDo not depress the accelerator.XIf necessary, remove the KEYLESS-GO
start/stop button from the starter switch.XTurn the SmartKey in the starter switch to
position 2 for at least 10 seconds.XReturn the SmartKey in the starter switch
to position 0.XTurn the SmartKey in the starter switch to
position 3 and hold it there for a maximumof 10 seconds or until the engine runs
surge-free.
If the engine does not start:
XTurn the SmartKey in the starter switch
once more to position 2 for at least
10 seconds.XReturn the SmartKey in the starter switch
to position 0.XTurn the SmartKey in the starter switch
once more to position 3 and hold it there
for a maximum of 10 seconds or until the
engine runs surge-free.XIf necessary, repeat the above steps.
If the engine still does not start after
3 attempts:
Do not make any further attempts to start the
engine. Contact an authorized Mercedes-
Benz Center or call Roadside Assistance
( Y page 201).
i When the malfunction indicator lamp
= (USA only) or ; (Canada only) in
the instrument cluster has been illuminated
for the above condition, it will remain
illuminated until the engine was cycled on
and off four times in a row.
AdBlue ®
(diesel engine only)
The BlueTEC exhaust gas aftertreatment
system requires a reducing agent (AdBlue ®
)
in order to function properly. Refilling with
AdBlue ®
is part of the regular maintenance
service work. A tankful of AdBlue ®
should
suffice until the next maintenance service
under normal driving conditions.
When the AdBlue ®
tank is low, the message
Check Additive See Operator’s
Manual appears in the multifunction display.
When the AdBlue ®
level drops to the
minimum level, the message Remaining
Starts: 20 appears in the multifunction
display.
AdBlue ®
(diesel engine only)331Practical hints164_AKB; 7; 31, en-USd2ureepe,Version: 2.11.8.12009-09-11T12:07:36+02:00 - Seite 331Z

iWhen the message Remaining Starts:
20 appears in the multifunction display, you
can start the engine 20 more times. If you
do not add AdBlue ®
, the engine cannot be
started beyond that point. Fill the
AdBlue ®
tank with approximately 1 gal
(3.79 l) AdBlue ®
(corresponds to
approximately 2 AdBlue ®
refill containers)
or have the AdBlue ®
tank filled by an
authorized Mercedes-Benz Center.
i For refilling outside the maintenance
service intervals, refill the AdBlue ®
tank
with approximately 1 gal (3.79 l) AdBlue ®
(corresponds to approximately 2 AdBlue ®
refill containers).
Always use the particular AdBlue ®
refill
containers for refilling outside the
maintenance service interval. Contact an
authorized Mercedes-Benz Center or call
Roadside Assistance if necessary
( Y page 201).
Additional information on BlueTEC exhaust
gas aftertreatment and AdBlue ®
is available
at any authorized Mercedes-Benz Center.
Refilling with AdBlue ®

GWarning!
Make sure
R AdBlue ®
does not come into contact with
skin, eyes, or clothing
R to keep AdBlue ®
out of the reach of children
If you and/or others have come into contact
with AdBlue ®
:
R If AdBlue ®
has gotten into contact with
eyes, flush with plenty of water immediately
and seek medical help.
R Clean affected skin immediately with plenty
of water.
R If AdBlue ®
was swallowed, rinse mouth
immediately with plenty of water and drink
plenty of water. Consult a physician.GWarning!
When opening the filler cap of the AdBlue ®
tank ammonia gas vapors may escape. Refill
AdBlue ®
in a well ventilated area only.
Ammonia gas vapors have a pungent odor and
are particularly irritating for your skin,
mucous membranes, and eyes. Inhaling
ammonia gas vapors will cause burning eyes,
nose, and throat, as well as coughing and
watering eyes.
! Only use AdBlue ®
complying with
ISO 22241. Do not add additives to
AdBlue ®
and do not dilute AdBlue ®
with
water. Otherwise, the BlueTEC exhaust gas
aftertreatment system could be damaged.
Damage caused by using additives or
diluting with water are not covered by the
Mercedes-Benz Limited Warranty.
! Rinse surfaces that have come into
contact with AdBlue ®
, or remove AdBlue ®
with a moist cloth and cold water
immediately. If AdBlue ®
has crystallized
already, use cold water and a sponge.
AdBlue ®
residues will crystallize and soil
the affected surfaces.
! AdBlue ®
is not a fuel additive and must
not be added to the diesel fuel tank. If
AdBlue ®
reaches the diesel fuel tank, the
engine could be damaged which is not
covered by the Mercedes-Benz Limited
Warranty.
332AdBlue ®
(diesel engine only)Practical hints
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For more information on AdBlue®, see
(Y page 361).
The AdBlue® filler neck is located under the
cargo compartment floor.
XSwitch off the ignition.XOpen the tailgate (Y page 75).XLift the cargo compartment floor
(Y page 268).
XTurn AdBlue® filler cap cover :
counterclockwise and remove it.
XTurn AdBlue® filler cap ;
counterclockwise and open it.
Filler cap ; is tethered with a plastic strap.
XPull dust cap off of AdBlue® refill container
=.
XPlace AdBlue® refill container = on the
filler neck as illustrated and tighten it
moderately (hand-tight) by turning it
clockwise.
! Make sure to tighten the AdBlue® refill
container only moderately, i.e. hand-tight,
as you could otherwise damage it.
XPush AdBlue® refill container = down.
The AdBlue® tank is filled. This may take up
to 1 minute.
iWhen you stop pushing the AdBlue® refill
container down, the filling process is
stopped and you can remove the refill
container.
XRelease AdBlue® refill container =.XTurn AdBlue® refill container =
counterclockwise and remove it.
XPlace AdBlue® filler cap ; (Y page 332) on
filler neck and turn it clockwise.
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