key MERCEDES-BENZ S-Class 2012 W221 Owner's Guide

XTo activate/deactivate: press button :.
If indicator lamp ; is lit, the rear-
compartment functions are deactivated.
The rear side windows can then only be
operated using the switches on the driver's
door. If indicator lamp ; is off, the
functions are enabled. The rear side
windows can be operated using the
switches in the rear compartment.
Panic alarm
X To activate: press ! button : for at
least one second.
An alarm sounds and the exterior lighting
flashes.XTo deactivate: press ! button :
again.
or
XInsert the SmartKey into the ignition lock.
or
XPress the KEYLESS-GO Start/Stop button.The KEYLESS-GO key must be in the
vehicle.
i USA only:
This device complies with Part 15 of the
FCC Rules. Operation is subject to the
following two conditions:
1. This device may not cause harmful
interference, and
2. this device must accept any interference
received, including interference that may
cause undesired operation.
Any unauthorized modification to this
device could void the user's authority to
operate the equipment.
The product label with FCC ID and IC
certification number can be found in the
battery case of the SmartKey.
i Canada only:
This device complies with RSS-Gen of
Industry Canada. Operation is subject to
the following two conditions:
1. This device may not cause interference,
and
2. this device must accept any interference
received, including interference that may
cause undesired operation.
Any unauthorized modification to this
device could void the user's authority to
operate the equipment.
The product label with FCC ID and IC
certification number can be found in the
battery case of the SmartKey.
Driving safety systems
Driving safety systems overview
In this section, you will find information about
the following driving safety systems:
R ABS ( Anti-lock Braking System)
R BAS ( Brake Assist System)
R BAS PLUS ( Brake Assist System Plus*)
R ESP ®
(E lectronic Stability Program)
R EBD ( Electronic Brake force Distribution)
68Driving safety systemsSafety

GWARNING
PRE-SAFE®
Brake cannot always detect
complex traffic situations properly.
In these cases, PRE-SAFE(R) Brake may:
R give an unnecessary warning and then
brake the vehicle
R neither give a warning nor intervene
There is a risk of an accident. Always pay
particular attention to the traffic situation and
be ready to brake, especially if PRE-SAFE(R)
Brake warns you. Terminate the intervention
in a non-critical driving situation.
In particular, the detection of obstacles can
be impaired if there is:
R dirt on the sensors or anything else
covering the sensors
R snow or heavy rain
R interference by other radar sources
R the possibility of strong radar reflections,
for example in parking garages
R a narrow vehicle traveling in front, e.g. a
motorbike
R a vehicle traveling in front on a different line
GWARNING
PRE-SAFE ®
Brake does not react:
R to people or animals
R to oncoming vehicles
R to crossing traffic
R in curves
As a result, PRE-SAFE ®
Brake cannot
intervene in critical situations. There is a risk
of an accident. Always pay careful attention
to the traffic situation and be ready to brake.
In order to maintain the appropriate distance
to the vehicle in front and thus prevent a
collision, you must apply the brakes yourself.
XTo activate/deactivate: activate or
deactivate PRE-SAFE ®
Brake in the on-
board computer ( Y page 384).
After activation, the Ä symbol is
displayed on the left in the instrument
cluster.
For PRE-SAFE ®
Brake to assist you when
driving, the radar sensor system must be
switched on ( Y page 387) and operational.
Following damage to the front end of the
vehicle, have the configuration and operation
of the radar sensors checked at a qualified
specialist workshop. This also applies to
collisions at low speeds where there is no
visible damage to the front of the vehicle.
Theft deterrent locking systems
Immobilizer
The immobilizer prevents your vehicle from
being started without the correct SmartKey.
When leaving the vehicle, always take the
SmartKey with you and lock the vehicle. The
engine can be started by anyone with a valid
SmartKey that is left inside the vehicle.
XTo activate with the SmartKey: remove
the SmartKey from the ignition lock.XTo activate with KEYLESS-GO: switch the
ignition off and open the driver's door.XTo deactivate: switch on the ignition.
i
The immobilizer is always deactivated
when you start the engine.
ATA (Anti-Theft Alarm system)
A visual and audible alarm is triggered if the
alarm system is armed and you open:
R a door
R the vehicle with the mechanical key
R the trunk lid
R the hood
Theft deterrent locking systems75SafetyZ

The alarm is not switched off, even if you
close the open door that has triggered it, for
example.
i If the alarm stays on for more than 30
seconds, the emergency call system
mbrace (USA only) or TELE AID (Canada
only) initiates a call to the Customer
Assistance Center automatically. The
emergency call system initiates the call
provided that:
R you have subscribed to the mbrace/
TELE AID service.
R the mbrace/TELE AID service has been
activated properly.
R the required mobile phone, power supply
and GPS are available.XTo arm: lock the vehicle with the SmartKey
or KEYLESS-GO.
Indicator lamp : flashes. The alarm
system is armed after approximately 30
seconds.XTo deactivate: unlock the vehicle with the
SmartKey or KEYLESS-GO.XTo stop the alarm using the SmartKey:
insert the SmartKey into the ignition lock.
The alarm is switched off.
or
XPress the % or & button on the
SmartKey.
The alarm is switched off.XTo stop the alarm using KEYLESS-GO:
grasp the outside door handle. The
SmartKey must be outside the vehicle.
The alarm is switched off.
or
XPress the Start/Stop button on the
dashboard. The SmartKey must be inside
the vehicle.
The alarm is switched off.76Theft deterrent locking systemsSafety

Useful information ..............................78
SmartKey ............................................. 78
Doors .................................................... 85
Trunk .................................................... 88
Side windows ...................................... 92
Sliding sunroof .................................... 9577Opening/closing

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible. Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Please read the information on qualified
specialist workshops ( Y page 31).
SmartKey
Important safety notes
GWARNING
When leaving the vehicle, always remove the
SmartKey from the ignition lock. Always take
the SmartKey with you and lock the vehicle.
Do not leave children unsupervised in the
vehicle, even if they are secured in a child
restraint system, and do not give them access
to an unlocked vehicle. A child's unsupervised
access to a vehicle could result in an accident
and/or serious personal injury. They could:
R injure themselves on vehicle parts
R be seriously or fatally injured by extreme
heat or cold
R injure themselves or have an accident with
vehicle equipment that may still be in
operation even after the SmartKey has
been removed from the ignition, such as the
seat adjustment, steering wheel
adjustment or memory function.
If children open a door, they could cause
severe or even fatal injury to other persons; if
they get out of the vehicle, they could injure
themselves when doing so or be seriously or
even fatally injured by any passing traffic.
Do not expose the child restraint system to
direct sunlight. The child restraint system's
metal parts, for example, could become very
hot, and a child could be burned on these
parts.GWARNING
If a key ring is too heavy or too large, the
weight acting on the key could cause it to turn
in the ignition lock or catch on the steering
wheel. This could cause the engine to be
switched off suddenly. You could lose control
of the vehicle and cause an accident. Do not
attach any heavy or large key rings to the key
that is inserted in the ignition.
General notes
If you cannot lock or unlock the vehicle with
the SmartKey, either the battery in the
SmartKey is discharged, the SmartKey is
faulty or the starter battery is discharged.
XCheck the battery in the SmartKey and
replace it if necessary ( Y page 82).XUnlock the driver's door using the
mechanical key ( Y page 87).XLock the vehicle ( Y page 88).XHave the starter battery and the battery
contacts checked at a qualified specialist
workshop.
If the SmartKey is faulty, contact Roadside
Assistance or a qualified specialist workshop.
SmartKey functions
General notes
i USA only:
This device complies with Part 15 of the
FCC Rules. Operation is subject to the
following two conditions:
1. This device may not cause harmful
interference, and
2. this device must accept any interference
received, including interference that may
cause undesired operation.
78SmartKeyOpening/closing

Any unauthorized modification to this
device could void the user’s authority to
operate the equipment.
The Product label with FCC ID and IC
certification number can be found in the
battery case of the SmartKey.
i Canada only:
This device complies with RSS-210 of
Industry Canada. Operation is subject to
the following two conditions:
1. This device may not cause interference,
and
2. this device must accept any interference
received, including interference that may
cause undesired operation of the device.
Any unauthorized modification to this
device could void the user’s authority to
operate the equipment.
The Product label with FCC ID and IC
certification number can be found in the
battery case of the SmartKey.
Locking and unlocking centrally
The SmartKey centrally locks/unlocks:
R the doors
R the trunk lid
R the fuel filler flap
:& Locks the vehicle;F Unlocks the trunk lid=% Unlocks the vehicle
When unlocking, the turn signals flash once.
When locking, they flash three times.
When it is dark, the surround lighting also
comes on if it is activated in COMAND
( Y page 264).
If you activate the acoustic locking
confirmation function, you will hear the
following, depending on the date of
production of the vehicle:
R an acoustic signal when locking
or
R one acoustic signal when unlocking and
three when locking.
The audible signal can be activated and
deactivated using the on-board computer
( Y page 386).XTo unlock centrally: press the %
button.
If you do not open the vehicle within
approximately 40 seconds of unlocking:
R the vehicle is locked again.
R the theft deterrent locking system is armed
again.
XTo lock centrally: press the & button.
KEYLESS-GO
General notes
i USA only:
This device complies with Part 15 of the
FCC Rules. Operation is subject to the
following two conditions:
1. This device may not cause harmful
interference, and
2. this device must accept any interference
received, including interference that may
cause undesired operation.
Any unauthorized modification to this
device could void the user’s authority to
operate the equipment.
The Product label with FCC ID and IC
certification number can be found in the
battery case of the SmartKey.
i Canada only:
SmartKey79Opening/closingZ

This device complies with RSS-210 of
Industry Canada. Operation is subject to
the following two conditions:
1. This device may not cause harmful
interference, and
2. this device must accept any interference
received, including interference that may
cause undesired operation.
Any unauthorized modification to this
device could void the user’s authority to
operate the equipment.
The Product label with FCC ID and IC
certification number can be found in the
battery case of the SmartKey.
Important notes on the use of KEYLESS-
GO
R The KEYLESS-GO key can be used like a
conventional key.
R You can combine KEYLESS-GO functions
with those of a conventional key, e.g.
unlock with KEYLESS-GO and lock with the
& button.
R Always carry your KEYLESS-GO key on your
person.
R Do not keep the KEYLESS-GO key together
with:
- electronic devices, e.g. a mobile phone
or another key
- metallic objects, e.g. coins or metal foil.
This can affect the functionality of
KEYLESS-GO.
R When locking and unlocking using
KEYLESS-GO, the distance between the
SmartKey and the corresponding door
handle must not exceed 3 ft (1 m).
R If the vehicle is parked for more than
72 hours, the KEYLESS-GO function is
deactivated. Pull the outer door handle and
switch on the ignition to reactivate the
KEYLESS-GO function.
R If the KEYLESS-GO key is removed from the
vehicle, it is possible that the system may
not recognize the SmartKey. The vehicle
can then not be locked or started using
KEYLESS-GO.
R If the KEYLESS-GO key has been removed
from the vehicle, e.g. if a passenger leaves
the vehicle with a KEYLESS-GO key:
- if the start/stop button is pressed or if
an attempt is made to lock the vehicle
with the locking button on the outer door
handle, the Key Not Detected message
appears in the multifunction display
- when the engine is running, the red Key
Not Detected message appears in the
multifunction display as you pull away.
Find the KEYLESS-GO key and change its
position in the vehicle. Carry the
KEYLESS-GO key in your shirt pocket, for
example.
R If you have started the engine with the
Start/Stop button, you can switch it off
again by:
- pressing the Start/Stop button again
- inserting the KEYLESS-GO key into the
ignition lock if the vehicle is stationary
and the automatic transmission is in park
position P.
R You could unlock the vehicle by mistake if
the distance between the KEYLESS-GO key
and the vehicle is less than 3 ft (1 m) and:
- an exterior door handle is hit by a water
jet
or
- you clean an exterior door handle.
R Bear in mind that the engine can be started
by any of the vehicle occupants if there is
a KEYLESS-GO key in the vehicle.80SmartKeyOpening/closing

X To unlock the vehicle: pull the door
handle.XTo lock the vehicle: touch sensor
surface :.XConvenience closing feature: touch
recessed sensor surface ; for an
extended period ( Y page 94).
If you pull on the handle of the trunk lid, only
the trunk of the vehicle is unlocked.
Changing the settings of the locking
system
You can change the setting of the locking
system in such a way that only the driver's
door and the fuel filler flap are unlocked. This
is useful if you frequently travel on your own.
XTo change the setting: press and hold
down the % and & buttons
simultaneously for approximately six
seconds until the battery check lamp
( Y page 82) flashes twice.
i
If the setting of the locking system is
changed within the signal range of the
vehicle, pressing the & or % button
locks or unlocks the vehicle.
The SmartKey now functions as follows:
XTo unlock the driver's door: press the
% button once.XTo unlock centrally: press the %
button twice.XTo lock centrally: press the & button.
The KEYLESS-GO function is changed as
follows:
XTo unlock the driver's door : pull the door
handle on the driver's door.XTo unlock centrally: pull the door handle
on the front-passenger door or on the rear
doors.XTo lock centrally: touch the outer sensor
surface on one of the door handles.Restoring the factory settingsXPress the % and & buttons
simultaneously for approximately six
seconds until the battery check lamp
flashes twice.
Mechanical key
General notes
If you use the mechanical key to unlock and
open the driver's door or the trunk lid, the
anti-theft alarm system will be triggered
( Y page 75).
There are several ways to turn off the alarm:
XTo turn the alarm off with the
SmartKey: press the % or & button
on the SmartKey.
or
XInsert the SmartKey into the ignition lock.
or
XTo deactivate the alarm with KEYLESS-
GO: press the Start/Stop button in the
ignition lock. The SmartKey must be in the
vehicle.
or
XLock or unlock the vehicle using KEYLESS-
GO. The SmartKey must be outside the
vehicle.
Removing the mechanical key
SmartKey81Opening/closingZ

XPush release catch : in the direction of
the arrow and at the same time, remove
mechanical key ; from the SmartKey.
SmartKey battery
Important safety notes
Have the batteries changed at a qualified
specialist workshop.
GWARNING
Batteries contain toxic substances.
Swallowing batteries can lead to serious
health issues or death.
Keep batteries out of the reach of children.
Seek medical attention immediately if a
battery is swallowed.
GWARNING
The SmartKey batteries contain perchlorate
material, which may require special handling
and regard for the environment. Observe
government disposal guidelines. California
residents, see www.dtsc.ca.gov/
HazardousWaste/Perchlorate/
index.cfm .
Checking the battery
XPress the & or % button.
The battery is working properly if battery
check lamp : lights up briefly
If battery check lamp : does not light up
briefly during the test, the battery is
discharged.
XChanging the battery ( Y page 82)
i
You can obtain the battery at a qualified
specialist workshop.
i If the SmartKey battery is checked within
the signal reception range of the vehicle,
pressing the & or % button locks or
unlocks the vehicle.
Changing the battery
You require a CR 2025 3 V cell battery.
XTake the mechanical key out of the
SmartKey ( Y page 81).XPress mechanical key ; into the opening
in the SmartKey in the direction of the
arrow until battery tray cover : opens.
When doing so, do not hold cover : shut.XRemove battery tray cover :.XRepeatedly tap the SmartKey against your
palm until battery = falls out.XInsert the new battery with the positive
terminal facing upwards. Use a lint-free
cloth to do so.82SmartKeyOpening/closing

XMake sure that the surface of the battery is
free from lint, grease and all other forms of
contamination.XInsert the front tabs of battery tray
cover : and then press to close it.XInsert the mechanical key into the
SmartKey.XCheck the function of all SmartKey buttons
on the vehicle.SmartKey83Opening/closingZ