fuel cap MERCEDES-BENZ S-Class 2012 W221 Owner's Manual

Exterior lightingsee Exterior lighting
Exterior mirror parking position
Adjusting (COMAND) .....................262
Exterior mirrors
Adjusting ....................................... 111
Dipping (automatic) .......................112
Folding in/out (automatically) .......112
Folding in/out (electrically) ...........112
Out of position (troubleshooting) ...112
Storing settings (memory
function) ........................................ 113
Storing the parking position ..........113
Eyeglasses compartment ................. 433
F
Factory setting (reset function) ....... 150
Fader, setting .................................... 135
Fast forward Audio mode (CD, DVD, MP3) .........225
Rear Seat Entertainment System ...255
Video DVD ..................................... 242
Fast rewind
Audio mode (CD, DVD, MP3) .........225
Rear Seat Entertainment System ...255
Video DVD ..................................... 242
Favorites (COMAND) ......................... 120
Filler cap see Fuel filler flap
First-aid kit ......................................... 472
Flat tire Changing a wheel/mounting the
spare wheel ................................... 473
MOExtended run-flat system .........477
Preparing the vehicle .....................473
Raising the vehicle .........................474
Floormat ............................................. 453
Freeway information ......................... 187
Front fog lamps ................................. 278
Display message ............................ 402
Switching on/off ........................... 278
Front-passenger seat
Adjusting from the driver's seat ..... 105
Adjusting from the rear
compartment ................................. 105
Front windshield
see Windshield
Fuel
Additives ........................................ 526
Displaying the current
consumption .................................. 376
Displaying the range ......................376
Driving tips .................................... 326
Fuel gauge ....................................... 35
Important safety notes ..................525
Premium-grade unleaded gasoline . 525
Problem (malfunction) ...................320
Refueling ........................................ 317
Specifications ................................ 525
Tank content/reserve fuel .............524
Fuel filler flap, opening/closing ....... 319
Fuel filter (display message) ............ 408
Fuel level Calling up the range (on-board
computer) ...................................... 376
Fuel tank
Capacity ........................................ 524
Problem (malfunction) ...................320
Function buttons (COMAND) ............ 119
Fuses Allocation chart ............................. 486
Before changing ............................. 486
Dashboard fuse box .......................486
Engine emergency stop .................487
Fuse box in the engine
compartment ................................. 487
Fuse box in the rear compartment . 486
Important safety notes ..................485
G
Garage door opener Clearing the memory .....................453
Notes ............................................. 450
Opening/closing the garage door ..453
Programming (button in the rear-
view mirror) ................................... 451
Gasoline ............................................. 318
Gear indicator (on-board
computer) .......................................... 379
Gear or selector lever (cleaning
guidelines) ......................................... 468
Genuine Mercedes-Benz parts ......... 520
Glove box ........................................... 432
GPS reception .................................... 151
12Index

Servicesee ASSYST PLUS service interval
display
Service interval display
Displaying service messages .........462
Hiding service messages ...............462
Notes ............................................. 462
Service messages ..........................462
Service menu (on-board computer) . 385
Service products Brake fluid ..................................... 528
Capacities ...................................... 524
Coolant (engine) ............................ 529
DEF special additives .....................527
Engine oil ....................................... 527
Fuel ................................................ 525
Important safety notes ..................522
Refrigerant (air-conditioning
system) .......................................... 528
Washer fluid ................................... 529
Setting a station (radio)
Via manual frequency entry ...........212
Settings
Display ........................................... 143
Menu overview .............................. 121
On-board computer .......................385
Picture (COMAND) .........................240
Picture (Rear Seat Entertainment
System) ......................................... 249
Sound settings ............................... 135
System settings ............................. 143
Setting the language
COMAND ....................................... 149
Rear Seat Entertainment System ...258
Setting the night design ................... 143
Setting the text reader speed .......... 145
Setting the vehicle level ................... 345
Setting the volume Telephone calls .............................. 134
Video AUX ..................................... 246
Side impact air bag ............................. 48
Side marker lamp (display
message) ............................................ 403
Side windows Convenience closing feature ............94
Convenience opening feature ..........93
Important safety information ...........92
Opening/closing .............................. 93Problem (malfunction) .....................95
Resetting ......................................... 95
Sliding sunroof
Important safety notes ....................95
Opening/closing .............................. 96
Problem (malfunction) ...................100
Resetting ......................................... 97
see Panorama roof with power
tilt/sliding panel
SmartKey
Changing the battery .......................82
Changing the programming .............81
Checking the battery .......................82
Convenience closing feature ............94
Convenience opening feature ..........93
Display message ............................ 419
Door central locking/unlocking .......78
Important safety notes ....................78
Loss ................................................. 84
Mechanical key ................................ 81
Positions (ignition lock) .................303
Problem (malfunction) .....................84
Starting the engine ........................305
SMS message
see Text message
Snow chains ...................................... 493
Socket Glove box ....................................... 442
Sockets
Points to observe before use .........441
Rear compartment .........................442
Trunk ............................................. 442
Sound menu ....................................... 135
Sounds see Sound settings
Sound settings
Balance and fader ..........................135
Calling up the sound menu ............135
Rear Seat Entertainment System ...248
Surround sound ............................. 136
Treble and bass ............................. 135
Spare wheel
Storage location ............................ 472
see Emergency spare wheel
Specialist workshop ............................ 31
Speech control see Voice Control System Index21

Low outside temperatures
! Do not use gasoline to refuel vehicles with
a diesel engine. Never mix diesel with
gasoline or kerosene, as this may result in
damage to the engine or fuel system.
Diesel fuel with improved cold flow properties
is available during the winter months. Further
information on fuel properties can be
obtained from oil companies, e.g. at gas
stations.
Refueling
Fuel filler flap
The fuel filler flap is unlocked or locked
automatically when you open or close the
vehicle with the SmartKey or using KEYLESS-
GO.
The position of the fuel filler cap is displayed
in the instrument cluster 8. The arrow
next to the filling pump indicates the side of
the vehicle.
:To open the fuel filler flap;To insert the fuel filler cap=Tire pressure table?Fuel type
Opening
XSwitch off the engine.XRemove the SmartKey from the ignition
lock.KEYLESS-GO: open the driver’s door. This
switches the ignition to position 0, which
corresponds to having removed the
SmartKey. The driver’s door can be closed
again.XPress the fuel filler flap in the direction of
arrow :.
The fuel filler flap opens slightly.XOpen the fuel filler flap.XTurn the fuel filler cap counter-clockwise
and remove it.XInsert the fuel filler cap into the holder
bracket on the inside of filler flap ;.XCompletely insert the pump nozzle into the
filler neck and refuel.XOnly fill the tank until the pump nozzle
switches off.
! Overfilling the fuel tank could damage the
fuel system.
Closing
XReplace the fuel filler cap and turn it
clockwise. The fuel filler cap audibly
engages.XClose the fuel filler flap.
i If you drive with the fuel filler cap open,
the reserve fuel warning lamp flashes. In
addition, the ; Check Engine warning
lamp may light up. A message appears in
the multifunction display ( Y page 407).
For further information on warning and
indicator lamps in the instrument cluster,
see ( Y page 427).
i Close the fuel filler flap before locking the
vehicle. A locking pin otherwise prevents
the fuel filler flap from closing after the
vehicle has been locked.
Refueling319Driving and parkingZ

DEF
Important notes on use
To function properly, BlueTEC exhaust gas
aftertreatment must be operated with the
reducing agent DEF. Adding DEF is one of the
tasks performed during maintenance. Under
normal operating conditions, a tank of DEF
lasts until the next service due date.
When the DEF supply has almost run out, the
Check Additive See Operator's
Manual message is shown in the
multifunction display.
When the DEF supply sinks to a minimum
level, the Remaining Starts: 16 message
is shown in the multifunction display.
When the Remaining Starts: 16 message
is shown in the multifunction display, you can
start the engine 16 more times. If DEF is not
added, it is then not possible to start the
engine again. Fill the DEF tank with about
1 gal (3.8 l) DEF or have the DEF tank refilled
at a qualified specialist workshop.
Use the special DEF refill bottle when filling
between maintenance intervals. Contact an
authorized Mercedes-Benz Center with any
questions or, if necessary, contact Roadside
Assistance ( Y page 29).
Further information about BlueTEC exhaust
gas aftertreatment and DEF is available at any
authorized Mercedes-Benz Center.
Adding DEF
GWARNING
Make sure
R DEF does not come into contact with skin,
eyes, or clothing
R to keep DEF out of the reach of children
If you and/or others have come into contact
with DEF:
R If DEF has gotten into contact with eyes,
flush with plenty of water immediately and
seek medical help.
R Clean affected skin immediately with plenty
of water.
R If DEF was swallowed, rinse mouth
immediately with plenty of water and drink
plenty of water. Consult a physician.GWARNING
If you open the DEF tank cap at high
temperatures, ammonia vapors can be
released.
Ammonia vapors have a pungent odor and are
particularly irritating to:
R skin
R mucous membranes
R eyes
You may experience a burning sensation in
your eyes, nose and throat, as well as
coughing and watering of the eyes.
Do not inhale any ammonia vapors that may
be released. Only refill the DEF tank in well
ventilated areas.
! Only use DEF that complies with
ISO 22241. Do not add any special
additives to DEF and do not thin DEF with
water. This could destroy the BlueTEC
exhaust gas aftertreatment.
If the outside temperature is lower than
Ò 11 †, damage may occur when topping up.
If DEF is frozen and there is an active warning
indicator, topping up may not be possible.
Park the vehicle in a warmer place, e.g. in a
garage, until DEF has become fluid again.
Filling is then possible again. Alternatively,
have the DEF tank refilled at a qualified
specialist workshop.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
Refueling321Driving and parkingZ

use a sponge and cold water to clean it. DEF
residues crystallize after time and
contaminate the affected surfaces.
! DEF is not a fuel additive and must not be
added to the fuel tank. If DEF is added to
the fuel tank, this can lead to engine
damage.
i If you are adding between maintenance
intervals, add approximately 1 gallon (3.8 l)
of DEF to the DEF tank. One gallon (3.8 l)
of DEF is approximately 2 DEF refill bottles.
Then, have the DEF supply checked and
filled completely if necessary. For this
purpose, Mercedes-Benz recommends a
qualified specialist workshop.
Further information on DEF ( Y page 527).
The filler neck for DEF is located under the
"Minispare" emergency spare wheel in the
trunk floor.XSwitch off the ignition.XOpen the trunk.XLift up the trunk floor ( Y page 436).XTurn the "Minispare" emergency spare
wheel fastening in the direction of the
arrow and remove it.XRemove the "Minispare" emergency spare
wheel.XTurn DEF cap : counter-clockwise and
remove it.XTurn DEF filler cap ; counter-clockwise
and open it.
Filler cap ; is secured with a plastic strap.XUnscrew the covering cap from DEF refill
bottle =.XPlace DEF refill bottle = on the filler neck
as shown and screw on clockwise hand-
tight.
! Only screw on the DEF refill bottle hand-
tight. It could otherwise be damaged.
322RefuelingDriving and parking

! The oil level is too low. Avoid long journeys with too little engine oil. There is a risk of
engine damage.
The display messages and the corresponding symbol that indicate that the oil level is too
low must not be ignored.Display messagesPossible causes/consequences and M Solutions4
Engine Oil Level
Low Stop Vehicle
Turn Engine OffVehicles without an oil dipstick: the engine oil level is too low.
There is a risk of engine damage.XPull over and stop the vehicle safely and switch off the engine,
paying attention to road and traffic conditions.XApply the parking brake.XAdd engine oil ( Y page 459) and check the oil level
( Y page 457).4
Engine Oil Level
Too HighVehicles without an oil dipstick: you have added too much engine
oil. There is a risk of damage to the engine or to the catalytic
converter.XHave the excess oil siphoned off at a qualified specialist
workshop. Observe the legal requirements.4
Engine Oil Level
Cannot Be MeasuredVehicles without an oil dipstick: the measuring system is
defective.XVisit a qualified specialist workshop.8
Reserve FuelThe fuel level has dropped into the reserve range.XRefuel at the nearest gas station.CThere is only a very small amount of fuel in the fuel tank.XRefuel at the nearest gas station without fail.8
Gas Cap LooseThe fuel system pressure is too low. The fuel filler cap is not closed
correctly or the fuel system is leaking.XCheck that the fuel filler cap is correctly closed.
If the fuel filler cap is not correctly closed:
XClose the fuel filler cap.
If the fuel filler cap is correctly closed:
XVisit a qualified specialist workshop.8
Ultra Low-sulfur
Diesel Fuel OnlyVehicles with a diesel engine: the fuel level has fallen below the
reserve range.XRefuel at the nearest gas station.XOnly use commercially available vehicular ULTRA-LOW SULFUR
HIGHWAY DIESEL FUEL (ULSD, 15 ppm SULFUR MAXIMUM).Display messages407On-board computer and displaysZ

ProblemPossible causes/consequences and M SolutionsThe yellow reserve fuel
warning lamp flashes
while the vehicle is in
motion.
In addition, the ;
yellow Check Engine
warning lamp may light
up.The fuel system pressure is too low. The fuel filler cap is not closed
correctly or the fuel system is leaking.XObserve the additional display messages in the multifunction
display.XCheck that the fuel filler cap is correctly closed.XIf the fuel filler cap is not correctly closed: close the fuel filler
cap.XIf the fuel filler cap is closed: visit a qualified specialist
workshop.The yellow reserve fuel
warning lamp lights up
while the engine is
running.The fuel level has dropped into the reserve range.XRefuel at the nearest gas station.
Driving systems
ProblemPossible causes/consequences and M Solutions·
The red distance
warning lamp lights up
while the vehicle is in
motion. A warning tone
also sounds.GRisk of accident
The warning is issued if you approach a stationary vehicle or a
vehicle driving ahead of you at too high a speed.
XBe prepared to brake immediately.XPay careful attention to the traffic situation. You may have to
brake or take evasive action.
More information about DISTRONIC PLUS ( Y page 332) and
PRE-SAFE ®
Brake ( Y page 73).
428Warning and indicator lamps in the instrument clusterOn-board computer and displays

impairs cornering ability and reduces driving
stability. Adapt your driving style accordingly.
Have the spare wheel replaced by a normal
wheel with an M+S tire at the nearest
Mercedes-Benz Center.
Snow chains
For safety reasons, Mercedes-Benz
recommends that you only use snow chains
which have been specially approved for your
vehicle by Mercedes-Benz, or are of a
corresponding standard of quality.
! You must drive at raised vehicle level if
snow chains have been mounted. The
vehicle could otherwise be damaged.
! There is not enough space for snow
chains on some wheel sizes. Observe the
information under "Tires and wheels" in the
"Technical Data" section to avoid damage
to the vehicle or the wheels.
R Only use snow chains when driving on
roads completely covered by snow. Do not
exceed the maximum permissible speed of
30 mph (50 km/h). Remove the snow
chains as soon as possible when you are no
longer driving on snow-covered roads.
R Local regulations may restrict the use of
snow chains. Applicable regulations must
be observed if you wish to mount snow
chains.
R Snow chains must not be mounted on
emergency spare wheels.
If you intend to mount snow chains, please
bear the following points in mind:
R you may not attach snow chains to all
wheel-tire combinations; see the
information under "Wheel and tire
combinations" in the "Wheels and tires"
section.
R mount snow chains only in pairs and only
to the rear wheels. Observe the
manufacturer's installation instructions.
! If snow chains are mounted on the front
wheels, the snow chains could grind
against the bodywork or components of the
chassis. This could result in damage to the
vehicle or the tires.
! Vehicles with steel wheels: if you wish
to mount snow chains on steel wheels,
make sure that you remove the respective
wheels' hubcaps first. The hubcaps may
otherwise be damaged.
i You may wish to deactivate
ESP ®
(Y page 71) when pulling away with
snow chains mounted. This way you can
allow the wheels to spin in a controlled
manner, achieving an increased driving
force (cutting action).
Tire pressure
Tire pressure specifications
GWARNING
Follow recommended tire inflation pressures.
Do not underinflate tires. Underinflated tires
wear excessively and/or unevenly, adversely
affect handling and fuel economy, and are
more likely to fail from being overheated.
Do not overinflate tires. Overinflated tires can
adversely affect handling and ride comfort,
wear unevenly, increase stopping distance,
and result in sudden deflation (blowout)
because they are more likely to become
punctured or damaged by road debris,
potholes etc.
Do not overload the tires by exceeding the
specified load limit as indicated on the Tire
and Loading Information placard on the
driver's door B-pillar. Overloading the tires
can overheat them, possibly causing a
blowout. Overloading the tires can also result
in handling or steering problems, or brake
failure.
The recommended tire pressures for the tires
mounted at the factory can be found on the
labels described here.
Tire pressure493Wheels and tiresZ

Checking the tire pressures
Important safety notesGWARNING
Follow recommended tire inflation pressures.
Do not underinflate tires. Underinflated tires
wear excessively and/or unevenly, adversely
affect handling and fuel economy, and are
more likely to fail from being overheated.
Do not overinflate tires. Overinflated tires can
adversely affect handling and ride comfort,
wear unevenly, increase stopping distance,
and result in sudden deflation (blowout)
because they are more likely to become
punctured or damaged by road debris,
potholes etc.
Do not overload the tires by exceeding the
specified load limit as indicated on the Tire
and Loading Information placard on the
driver's door B-pillar. Overloading the tires
can overheat them, possibly causing a
blowout. Overloading the tires can also result
in handling or steering problems, or brake
failure.
Check the tire pressure at least once a month.
Only check and correct tire pressures when
the tires are cold ( Y page 493).
Checking tire pressure manually
To determine and set the correct tire
pressure, proceed as follows:
XRemove the valve cap of the tire that is to
be checked.XPress the tire pressure gauge securely onto
the valve.XRead the tire pressure and compare it with
the recommended value on the Tire and
Loading Information placard on the
B-pillar on the driver's side of your vehicle.XIf necessary, increase the tire pressure to
the recommended value ( Y page 493).XIf the tire pressure is too high, release air
by pressing down the metal pin in the valve
using the tip of a pen, for example. Thencheck the tire pressure again using the tire
pressure gauge.XScrew the valve cap onto the valve.XRepeat these steps for the other tires.
Tire pressure monitor
Important safety notes
If a tire pressure monitor system is installed,
the vehicle's wheels have sensors that
monitor the tire pressures in all four tires. The
tire pressure monitor warns you when the
pressure drops in one or more of the tires. The
tire pressure monitor only functions if the
correct wheel electronics units are installed
on all wheels.
The tire pressure monitor has a yellow
warning lamp in the instrument cluster for
indicating pressure loss/malfunctions (USA)
or pressure loss (Canada). Whether the
warning lamp flashes or lights up indicates
whether a tire pressure is too low or the tire
pressure monitoring system is
malfunctioning:
R if the warning lamp is lit continuously, the
tire pressure on one or more tires is
significantly too low. The tire pressure
monitor is not malfunctioning.
R USA only: if the warning lamp flashes for
60 seconds and then remains lit constantly,
the tire pressure monitor is malfunctioning.
GWARNING
Each tire, including the spare (if provided),
should be checked at least once a month
when cold and inflated to the pressure
recommended by the vehicle manufacturer
on the Tire and Loading Information placard
on the driver's door B-pillar or the tire
pressure label on the inside of the fuel filler
flap. If your vehicle has tires of a different size
than the size indicated on the Tire and Loading
Information placard or the tire pressure label,
you should determine the proper tire pressure
for those tires.
Tire pressure497Wheels and tiresZ

Kilopascal (kPa)
Metric unit for tire pressure. 6.9 kPa is the
equivalent of 1 psi. Another unit for tire
pressure is bar. There are 100 kilopascals
(kPa) to 1 bar.
Load index
In addition to the load bearing index, the load
index may also be imprinted on the sidewall
of the tire. This specifies the load bearing
capacity more precisely.
Curb weight
The weight of a vehicle with standard
equipment including the maximum capacity
of fuel, oil and coolant. It also includes the air-
conditioning system and optional equipment
if these are installed in the vehicle, but does
not include passengers or luggage.
Maximum load rating
The maximum load rating in kilograms or
pounds is the maximum weight for which a
tire is approved.
Maximum permissible tire pressure
Maximum permissible tire pressure for one
tire.
Maximum load on one tire
Maximum load on one tire. This is calculated
by dividing the maximum axle load of one axle
by two.
PSI (pounds per square inch)
A standard unit of measure for tire pressure.
Aspect ratio
Relationship between tire height and tire
width in percent.
Tire pressure
This is pressure inside the tire applying an
outward force to each square inch of the tire's
surface. The tire pressure is specified in
pounds per square inch (psi), in kilopascal
(kPa) or in bar. The tire pressure should only
be corrected when the tires are cold.
Tire pressure of cold tires
The tires are cold:
R if the vehicle has been parked without
direct sunlight on the tires for at least three
hours and
R if the vehicle has not been driven more than
1 mile (1.6 km).
Tread
The part of the tire that comes into contact
with the road.
Bead
The tire bead ensures that the tire sits
securely on the wheel. There are several steel
wires in the bead to prevent the tire from
coming loose from the wheel rim.
Sidewall
The part of the tire between the tread and the
bead.
Weight of optional extras
The combined weight of those optional extras
that weigh more than the replaced standard
part and more than 2.3 kilograms (5 lbs).
512Definition of terms for tires and loadingWheels and tires