cooling MERCEDES-BENZ S-Class 2014 W222 Owner's Manual

1, 2, 3 ...
115 V socket ...................................... 329
12 V socket see Sockets
360° camera
Cleaning .........................................3 58
Function/notes ............................. 230
4ETS
see ETS/4ETS (Electronic
Traction System)
4MATIC (permanent four-wheel
drive) .................................................. 218A
ABS (Anti-lock Braking System) Display message ............................ 266
Function/notes ................................ 71
Important safety notes ....................71
Warning lamp ................................. 304
Accident
Automatic measures after an
accident ........................................... 57
Activating/deactivating cooling
with air dehumidification .................156
Activating/deactivating Night
View Assist Plus
With spotlight function ................... 238
Active Blind Spot Assist
Activating/deactivating (on-
board computer) ............................ 261
Display message ............................ 290
Function/informatio n.................... 240
Active Body Control (ABC)
Display message ............................ 288
Function/notes ............................. 214
Active Lane Keeping Assist
Activating/deactivating (on-
board computer) ............................ 262
Display message ............................ 289
Function/informatio n.................... 243
Active multicontour seat ..................125
Active Parking Assist Detecting parking spaces ..............222
Display message ............................ 290
Exiting a parking space ..................224
Function/notes ............................. 221Important safety notes
..................221
Parking .......................................... 223
ADAPTIVE BRAKE ................................. 78
Adaptive Brake Assist Function/notes ................................ 75
Adaptive Damping System (ADS) ..... 217
Adaptive Highbeam Assist Display message ............................ 283
Function/notes ............................. 141
Switching on/off ........................... 142
Adaptive Highbeam Assist PLUS
Display messages ..........................283
Function/notes ............................. 143
Switching on/off ........................... 144
Additional speedometer ...................263
Additives (engine oil) ........................426
Air bags Belt bags .......................................... 63
Cushion air bag s.............................. 51
Display message ............................ 279
Front air bag (driver, front
passenger) ....................................... 48
Important safety notes ....................46
Knee bag .......................................... 49
PASSENGER AIR BAG OFF
indicator lamp .................................. 51
Safety guidelines ............................. 45
Side impact air bag ..........................49
Window curtain air bag ....................50
Air-conditioning system
see Climate control
AIRMATIC
Display message ............................ 287
Function/notes ............................. 216
Air vents
Glove box ...................................... .167
Important safety notes ..................166
Rear ............................................... 167
Setting ........................................... 166
Setting the center air vents ...........166
Setting the side air vents ...............167
Alarm
ATA (Anti-Theft Alarm system) .........81
Switching off (ATA) ..........................81
Switching the function on/off
(ATA) ................................................ 81
Alarm system
see ATA (Anti-Theft Alarm system) 4
Index

Children
In the vehicle ................................... 63
Restraint systems ............................ 63
Special seat belt retractor ...............66
Child seat
LATCH-type (ISOFIX) child seat
anchors ............................................ 67
Top Tether ....................................... 68
Cigarette lighter ................................ 326
Cleaning Mirror turn signal ........................... 357
Climate control
Automatic climate control .............153
Controlling automatically ...............157
Cooling with air dehumidification ..156
Defrosting the windows .................162
Defrosting the windshield ..............161
ECO start/stop function ................155
Important safety notes ..................152
Indicator lamp ................................ 157
Ionization ....................................... 166
Notes on using automatic climate
control ........................................... 155
Overview of systems ......................152
Perfume atomizer .......................... 164
Problems with cooling with air
dehumidification ............................ 157
Problem with the rear window
defroster ........................................ 163
Rear control panel .........................153
Refrigerant ..................................... 428
Refrigerant filling capacity .............428
Setting the air distribution .............160
Setting the airflow .........................160
Setting the air vents ......................166
Setting the climate mode .............. .159
Setting the temperature ................159
Switching air-recirculation mode
on/off ............................................ 163
Switching on/off ........................... 155
Switching residual heat on/off ......163
Switching the rear window
defroster on/off ............................ 162
Switching the synchronization
function on and off ........................161
Cockpit
Overview .......................................... 32COLLISION PREVENTION ASSIST
Activating/deactivating the
distance warning function .............. 261
Display message ............................ 273
Operation/notes .............................. 73
COMAND display
Cleaning ......................................... 359
Combination switch ..........................140
Consumption statistics (on-board
computer) .......................................... 251
Convenience closing feature ............100
Convenience opening feature ..........100
Coolant (engine) Checking the level .........................351
Display message ............................ 283
Filling capacity ............................... 427
Important safety notes ..................426
Temperature gauge ........................ 259
Warning lamp ................................. 309
Coolbox .............................................. 331
Cooling see Climate control
Copyright ............................................. 29
Cornering light function Display message ............................ 280
Function/notes ............................. 141
Crash-responsive emergency
lighting ............................................... 145
Crosswind, driving assistance
(vehicles without MAGIC BODY
CONTROL) ............................................ 77
Crosswind driving assistance
(vehicles with Magic Body
Control) .............................................. 214
Crosswind driving assistance
(vehicles without MAGIC BODY
CONTROL) ............................................ 77
Cruise control Cruise control lever .......................200
Deactivating ................................... 201
Display message ............................ 294
Driving system ............................... 199
Function/notes ............................. 199
Important safety notes ..................199
Setting a speed .............................. 201
Storing and maintaining current
speed ............................................ .200 Index
7

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible. Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Read the information on qualified
specialist workshops: (Y page 27).Overview of climate control systems
Important safety notes
Observe the settings recommended on the
following pages. The windows could
otherwise fog up.
To prevent the windows from fogging up:
R switch off climate control only briefly
R switch on air-recirculation mode only
briefly
R switch on the cooling with air
dehumidification function
R switch on the defrost windshield function
briefly, if required
Climate control regulates the temperature
and air humidity in the vehicle interior. The air
filter cleans the air, thus improving the
interior climate.
The "Cooling with air dehumidification"
function is only available when the engine is
running. Optimum climate control is only
achieved with the side windows and roof
closed.
The residual heat function can only be
activated or deactivated with the ignition
switched off (Y page 163).
i Ventilate the vehicle for a brief period
during warm weather, e.g. using the
convenience opening feature
(Y page 100). This will speed up the cooling process and the desired interior
temperature will be reached more quickly.
i The integrated filter filters out most
particles of dust and soot and completely
filters out pollen. It also reduces gaseous
pollutants and odors. A clogged filter
reduces the amount of air supplied to the
vehicle interior. For this reason, you should
always observe the interval for replacing
the filter, which is specified in the
Maintenance Booklet. As it depends on
environmental conditions, e.g. heavy air
pollution, the interval may be shorter than
stated in the Maintenance Booklet.
i It is possible that the blower may be
activated automatically 60 minutes after
the key has been removed depending on
various factors, e.g. the outside
temperature. The vehicle is then ventilated
for 30 minutes to dry the automatic climate
control. 152
Overview of climate control systemsClimate control

Switching the front climate control on/
off using the control panel Observe the notes on controlling the rear-
compartment climate control using the front
control panel (Y page 155).
X Turn the SmartKey to position 2in the
ignition lock (Y page 171).
X To activate: press the008Arocker switch
up or down.
The COMAND climate control menu opens.
X Select "Rear adjustment" in the air-
conditioning setting bar (see the separate
COMAND operating instructions).
You can control the rear-compartment
climate control using the front control
panel or COMAND.
X Activate rear-compartment climate control
via the air-conditioning setting bar.
X To deactivate: press the008Arocker
switch up or down.
The COMAND climate control menu opens.
X Select "Rear adjustment" in the air-
conditioning setting bar (see the separate
COMAND operating instructions).
X Deactivate rear-compartment climate
control via the air-conditioning setting bar.
Switching rear-compartment climate
control on/off using the control panel X
Turn the SmartKey to position 2in the
ignition lock (Y page 171).
X To activate: press rocker switch 0074up or
down (Y page 153).
The indicator lamp in rocker switch 0074goes
out. All settings are displayed in full in the
rear-compartment display.
X To deactivate: press rocker switch 0074up
or down (Y page 153).
The indicator lamp in rocker switch 0074
lights up. OFF
OFF is displayed in the rear-
compartment display. Activating/deactivating cooling with
air dehumidification
General notes If you deactivate the "Cooling with air-
dehumidification" function, the air inside the
vehicle will not be cooled. The air inside the
vehicle will also not be dehumidified. The
windows can fog up more quickly. Therefore,
deactivate the cooling with air-
dehumidification function only briefly.
The "Cooling with air dehumidification"
function is only available when the engine is
running. The air inside the vehicle is cooled
and dehumidified according to the
temperature selected.
Condensation may drip from the underside of
the vehicle when it is in cooling mode. This is
normal and not a sign that there is a
malfunction.
Activating/deactivating cooling with
air dehumidification You can activate or deactivate the "Cooling
with air dehumidification" function using
COMAND (see the separate operating
instructions).156
Operating the climate control systemsClimate control

Problems with the "Cooling with air dehumidification" function
Problem Possible causes/consequences and
0050
0050Solutions Cooling with air
dehumidification can
no longer be switched
on using COMAND (see
the separate operating
instructions). Cooling with air dehumidification has been deactivated due to a
malfunction.
X
Visit a qualified specialist workshop. Setting climate control to automatic
General notes In automatic mode, the set temperature is
maintained automatically at a constant level.
The system automatically regulates the
temperature of the dispensed air, the airflow
and the air distribution.
The automatic mode functions optimally
when the "Cooling with air dehumidification"
function is activated. If necessary, cooling
with air dehumidification can be deactivated.
If you deactivate the "Cooling with air-
dehumidification" function, the air inside the
vehicle will not be cooled. The air inside the
vehicle will also not be dehumidified. The
windows can fog up more quickly. Therefore,
deactivate the cooling with air-
dehumidification function only briefly. Controlling front climate control
automatically using the front control
panel X
Turn the SmartKey to position 2in the
ignition lock (Y page 171).
X Set the desired temperature using the
0082 rocker switch on the front control
unit.
or
X Set the desired temperature using
COMAND (see the separate operating
instructions).
X To activate: press rocker switch 0058up
or down.
The indicator lamp in the 0058rocker
switch lights up.
X To switch to manual operation: press the
0097 rocker switch up or down.
or
X Set the airflow using COMAND (see the
separate operating instructions).
or
X Set the air distribution using COMAND (see
the separate operating instructions).
The indicator lamp in the 0058rocker
switch goes out.
In automatic mode, if you adjust the airflow
or air distribution manually, the indicator
lamp on the 0058rocker switch goes out. The
function which has not been changed
manually, however, continues to be
controlled automatically. When the manually
set function switches back to automatic Operating the climate control systems
157Climate control

or
X
Use the 008Arocker switch to call up the
COMAND climate control menu. Defrosting the windows
Windows fogged up on the inside X
Activate the "Cooling with air
dehumidification" function via COMAND
(see the separate operating instructions).
X Switch on automatic mode using the
0058 rocker switch.
X If the windows continue to fog up, activate
the "Windshield defrosting" function using
the 0064 rocker switch. The windshield
heating is switched on.
i You should only select this setting until
the windshield is clear again.
Windows fogged up on the outside X
Activate the windshield wipers.
X Switch on automatic mode using the
0058 rocker switch.
i If you clean the windows regularly, they
do not fog up so quickly. Rear window defroster
General notes The rear window defroster has a high current
draw. You should therefore switch it off as
soon as the rear window is clear. Otherwise,
the rear window defroster switches off
automatically after several minutes.
If the battery voltage is too low, the rear
window defroster may switch off. Activating/deactivating X
Turn the SmartKey to position 2in the
ignition lock (Y page 171).
X Press the 006Crocker switch up or down.
The indicator lamp in the 006Crocker
switch lights up or goes out. 162
Operating the climate control systemsClimate control

Problems with the rear window defroster
Problem Possible causes/consequences and
0050
0050Solutions The rear window
defroster has
deactivated
prematurely or cannot
be activated. The battery has not been sufficiently charged.
X
Switch off any consumers that are not required, e.g. reading
lamps, interior lighting or the seat heating.
When the battery is sufficiently charged, the rear window
defroster can be activated again. Activating/deactivating air-
recirculation mode
General notes You can also temporarily deactivate the flow
of fresh air manually if unpleasant odors are
entering the vehicle from outside. The air
already inside the vehicle will then be
recirculated.
If you switch on air-recirculation mode, the
windows can fog up more quickly, in
particular at low temperatures. Only use air-
recirculation mode briefly to prevent the
windows from fogging up.
Activating/deactivating X
Turn the SmartKey to position 2in the
ignition lock (Y page 171).
X To activate: press the0072rocker switch
up or down.
The indicator lamp in the 0072rocker
switch lights up.
i Air-recirculation mode is automatically
activated at high levels of pollution or at
high outside temperatures. The indicator
lamp in the 0072rocker switch is not lit
when automatic air-recirculation mode is
activated.
Outside air is added after about
30 minutes.
X To deactivate: press the0072rocker
switch up or down.
The indicator lamp in the 0072rocker
switch goes out. i
Air-recirculation mode deactivates
automatically:
R after approximately five minutes at
outside temperatures below
approximately 41 ‡ (5 †)
R after approximately five minutes if
cooling with air dehumidification is
deactivated
R after approximately 30 minutes at
outside temperatures above
approximately 41 ‡(5 †) if the "Cooling
with air dehumidification" function is
activated Activating/deactivating the residual
heat function
General notes Vehicles with rear-compartment climate
control:
once the engine is switched off, it is
possible to make use of the residual heat of
the engine to continue heating or ventilating
the rear and front compartment of the vehicle
for approximately 15 minutes. If the "Residual
heat" function is set for only the front or only
the rear compartment, it is possible to
continue heating or ventilating for
approximately 30 minutes.
Vehicles without rear-compartment
climate control: once the engine is switched
off, it is possible to make use of the residual
heat of the engine to continue heating or
ventilating the front compartment of the
vehicle for approximately 30 minutes. Operating the climate control systems
163Climate control

0087
Center vent thumbwheel, right
0085 Center vent thumbwheel, left
0083 Center air vent, left
X To open/close: press thumbwheel 0087
or 0085.
The thumbwheel pops out.
X Turn thumbwheel 0087or0085 clockwise or
counter-clockwise.
X To adjust the air direction: hold rear air
vent 0044or0083 by the middle fin and move
up or down or to the left or right. Setting the side air vents
0043
Side window defroster vent
0044 Side air vent
0087 Thumbwheel for left side air vent
X To open/close: press thumbwheel 0087.
The thumbwheel pops out.
X Turn thumbwheel 0087clockwise or counter-
clockwise.
X To adjust the air direction: hold side air
vent 0044by the middle fin and move it up or
down or to the left or right. Setting the glove box air vent
! Close the air vent when heating the
vehicle.
At high outside temperatures, open the air
vent and activate the "cooling with air
dehumidification" function. Otherwise, temperature-sensitive items stored in the
glove box could be damaged.
When automatic climate control is activated,
the glove box can be ventilated, for instance
to cool its contents. The level of airflow
depends on the airflow and air distribution
settings. 0043
Air vent thumbwheel
0044 Air vent
X To open/close: turn thumbwheel 0043
clockwise or counter-clockwise. Setting the rear-compartment air
vents
Setting the center vents in the rear
compartment 0043
Rear-compartment air vent, left
0044 Rear-compartment air vent, right
0087 Rear-compartment air vent thumbwheel,
right Setting the air vents
167Climate control Z

Display messages Possible causes/consequences and
0050
0050Solutions 0049
Switch Off Lights Switch Off Lights The lights are still switched on when you leave the vehicle. A
warning tone also sounds.
X
Turn the light switch to 0058.Adaptive Highbeam Adaptive Highbeam
Assist Assist
Inoperative Inoperative
or
Adaptive Highbeam
Adaptive Highbeam
Assist Plus Assist Plus
Inoperative Inoperative Adaptive Highbeam Assist or Adaptive Highbeam Assist Plus is
faulty.
X
Visit a qualified specialist workshop. Adaptive Highbeam Adaptive Highbeam
Assist Currently Assist Currently
Unavailable See Unavailable See
Operator's Manual Operator's Manual
or
Adaptive Adaptive
Highbeam Assist
Highbeam Assist
Plus Currently Plus Currently
Unavailable See Unavailable See
Operator's Manual Operator's Manual Adaptive Highbeam Assist or Adaptive Highbeam Assist Plus is
deactivated and temporarily not operational. Possible causes are:
R
the windshield in the camera's field of vision is dirty.
R visibility is impaired due to heavy rain, snow or fog.
X Clean the windshield.
If the system detects that the camera is fully operational, display
message Adaptive Highbeam Assist Now Available Adaptive Highbeam Assist Now Available or
Adaptive Highbeam Assist Plus Available Again
Adaptive Highbeam Assist Plus Available Again is
displayed.
Adaptive Highbeam Assist or Adaptive Highbeam Assist Plus is
operational again. Engine
Display messages Possible causes/consequences and
0050 0050Solutions 00BD
Check Coolant Check Coolant
Level See Level See
Operator's Manual Operator's Manual The coolant level is too low.
!
Avoid making long journeys with too little coolant in the engine
cooling system. The engine will otherwise be damaged.
X Add coolant, observing the warning notes before doing so
(Y page 351).
X If coolant needs to be added more often than usual, have the
engine coolant system checked at a qualified specialist
workshop. 00AC 00AC The fan motor is faulty.
X
At coolant temperatures below 248 ‡ (120 †), drive to the
nearest qualified specialist workshop.
X Avoid subjecting the engine to heavy loads, e.g. driving in
mountainous terrain, and stop-and-go traffic. Display
messages
283On-board computer and displays Z

When you use the warming function, the
metal insert of the cup holder is heated.
Therefore, do not touch the cup holder insert.
X Turn the SmartKey to position 2in the
ignition lock (Y page 171).
X To switch on the cooling function: press
and hold button 0044until the blue indicator
lamp on the button lights up.
X To switch on the heating function: press
and hold button 0044until the red indicator
lamp on the button lights up.
X To switch off the function: press and hold
button 0044until the indicator lamp on the
button goes out.
The rubber mat can be removed for cleaning.
Clean with clear, lukewarm water only.
Do not use hard or sharp objects to clean the
cup holder. Use only a soft cloth to clean it. Sun visors
Overview G
WARNING
If the mirror cover of the vanity mirror is folded
up when the vehicle is in motion, you could be
blinded by incident light. There is a risk of an
accident.
Always keep the mirror cover folded down
while driving. 0043
Mirror light
0044 Bracket
0087 Retaining clip, e.g. for a car park ticket 0085
Vanity mirror
0083 Mirror cover
Vanity mirror in the sun visor Mirror light
0043only functions if the sun visor
is clipped into bracket 0044and mirror cover
0083 has been folded up.
Glare from the side X
Fold down sun visor 0043.
X Pull sun visor 0043out of bracket 0087.
X Swing sun visor 0043to the side.
X Slide sun visor 0043horizontally as required.
X Fold down additional sun visor 0044to the
windshield. Rear side window sunblinds
0043
Front left
0044 Front right 324
FeaturesStowage and features