engine MERCEDES-BENZ S CLASS 2016 Owners Manual

Mounting a wheel
Preparing the vehicle X
Stop the vehicle on solid, non-slippery and
level ground. X
Apply the electric parking brake manually. X
Bring the front wheels into the straight-ahead
position. X
Shift the transmission to position P .X
Make sure that "normal" level is selected for
AIRMATIC ( Y
page 212) or Active Body Con-
trol (ABC) ( Y
page 210).X
Switch off the engine. X
Open the driver's door.
The on-board electronics now have status 0 .
This is the same as the SmartKey having been
removed. X
Remove Start/Stop button from ignition lock
( Y
page 162).
or, if the SmartKey is inserted in the ignition
lock: X
Remove the SmartKey from the ignition lock. X
Make sure that the engine cannot be started
via your smartphone ( Y
page 164).X
If included in the vehicle equipment, remove
the tire-change tool kit from the vehicle. X
Safeguard the vehicle against rolling away.
Securing the vehicle to prevent it from
rolling away
If your vehicle is equipped with a wheel chock, it
can be found in the tire-change tool kit
( Y
page 367).
The folding wheel chock is an additional safety
measure to prevent the vehicle from rolling
away, for example when changing a wheel. X
Fold both plates upwards C .X
Fold out lower plate D .X
Guide the lugs on the lower plate fully into the
openings in base plate

inserting wheel chocks. Do not disengage the
parking brake while the vehicle is raised. R
The jack must be placed on a firm, flat and
non-slip surface. On a loose surface, a large,
flat, load-bearing underlay must be used. On a
slippery surface, a non-slip underlay must be
used, e.g. rubber mats. R
Do not use wooden blocks or similar objects
as a jack underlay. Otherwise, the jack will not
be able to achieve its load-bearing capacity
due to the restricted height. R
Make sure that the distance between the
underside of the tires and the ground does not
exceed 1.2 in (3 cm). R
Never place your hands and feet under the
raised vehicle. R
Do not lie under the vehicle. R
Do not start the engine when the vehicle is
raised. R
Do not open or close a door or the trunk lid
when the vehicle is raised. R
Make sure that no persons are present in the
vehicle when the vehicle is raised.
Vehicles with AMG wheels and hub caps: the
hub cap covers the wheel bolts. Before you can
unscrew the wheel bolts, you must remove the
hub cap. Two different variants can be installed.
Vehicles with AMG wheels and plastic hub
caps: X
To remove: turn the center cover of hub
cap C counter-clockwise and remove.X
To install: before installing, ensure that hub
cap C is in the open position. To do this, turn
the center cover counter-clockwise. X
Position hub cap C and turn the center cover
clockwise until hub cap C engages physically
and audibly. X
Make sure that hub cap C is installed
securely. Vehicles with AMG wheels and aluminum
hub caps: X
To remove: take socket D and lug wrench

i The data shown on the vehicle identification
plate is used only as an example. This data is
different for every vehicle and can deviate
from the data shown here. You can find the
data applicable to your vehicle on the vehicle
identification plate.
Vehicle identification number (VIN) X
Open the front right-hand door. X
Fold cover C down and remove it.
You will see the VIN.
The VIN can also be found in the following loca-
tions: R
on the lower edge of the windshield
( Y
page 427) R
on the vehicle identification plate
( Y
page 426)
Engine number
C
Engine number (stamped into the crank-
case)
D
VIN (on the lower edge of the windshield)

Other identifications, for example: R
0 W-30 R
5 W-30 R
5 W-40
Fuel
Important safety notes
G WARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and explo-
sion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before
refueling.
G WARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come
into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following: R
Wash away fuel from skin immediately
using soap and water. R
If fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance with-
out delay. R
If fuel is swallowed, seek medical assis-
tance without delay. Do not induce vomit-
ing. R
Immediately change out of clothing which
has come into contact with fuel. Tank capacity Missing values were not available at time of
going to print.
Model Total capacity
S 400 4MATIC
PLUG-IN HYBRID vehi-
cles 16.6 US gal
(63.0 l)
Al l ot her models
21.1 US gal
(80.0 l)
Model Of which
reserve
S 400 4MATIC
Mercedes ‑ AMG vehicles
Approx.
3.2 US gal
(12.0 l)
Al l ot her models
Approx.
2.1 US gal (8.0 l)
Gasoline
Fuel grade
! Do not use diesel to refuel vehicles with a
gasoline engine. Do not switch on the ignition
if you accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel system.
Even small amounts of the wrong fuel could
result in damage to the fuel system and the
engine. Notify a qualified specialist workshop
and have the fuel tank and fuel lines drained
completely.
! Only refuel using unleaded premium grade
gasoline with at least 91 AKI/95 RON.
i E10 fuel contains up to 10% bioethanol.
Your vehicle is E10-compatible. You can
refuel your vehicle using E10 fuel.
! Only use the fuel recommended. Operating
the vehicle with other fuels can lead to engine
failure.
! Do not use the following: R
E15 (gasoline with 15% ethanol) R
E85 (gasoline with 85% ethanol) R
E100 (1 00% ethanol) R
M15 (gasoline with 15% methanol)428
Service products and filling capacities
Technical data

R
M30 (gasoline with 30% methanol) R
M85 (gasoline with 85% methanol) R
M100 (100% methanol) R
Gasoline with metalliferous additives R
Diesel
Do not mix such fuels with the fuel recom-
mended for your vehicle.
! To ensure the longevity and full perform-
ance of the engine, only premium-grade
unleaded gasoline must be used.
If standard unleaded gasoline is unavailable
and you have to refuel with unleaded gasoline
of a lower grade, observe the following pre-
cautions: R
Only fill the fuel tank to half full with regular
unleaded gasoline and fill the rest with pre-
mium-grade unleaded gasoline as soon as
possible. R
Do not drive at the maximum speed. R
Avoid sudden acceleration and engine
speeds over 3,000 rpm.
You will usually find information about the fuel
grade on the pump. If you cannot find the label
on the pump, ask the staff for assistance.
i For further information, consult a qualified
specialist workshop or visit
http://www.mbusa.com (USA only).
As a temporary measure, if the recommended
fuel is not available, you may also use regular
unleaded gasoline with an octane rating of
87 AKI/91 RON. This may reduce engine per-
formance and increase fuel consumption. Avoid
driving at full throttle and sudden acceleration.
Never refuel using fuel with a lower AKI.
Information on refueling .
Additives
! Operating the engine with fuel additives
added later can lead to engine failure. Do not
mix fuel additives with fuel. This does not
include additives for the removal and preven-
tion of residue buildup. gasoline must only be
mixed with additives recommended by
Mercedes-Benz. Comply with the instructions
for use on the product label. More information
about recommended additives can be
obtained from any authorized Mercedes-Benz
Center.
Mercedes-Benz recommends that you use bran-
ded fuels that have additives. The quality of the fuel available in some coun-
tries may not be sufficient. Residue could build
up in the injection system as a result. In such
cases, and in consultation with an authorized
Mercedes-Benz Center, the gasoline may be
mixed with the cleaning additive recommended
by Mercedes-Benz. You must observe the notes
and mixing ratios specified on the container.
Engine oil
General notes
! Never use engine oil or an oil filter of a spec-
ification other than is necessary to fulfill the
prescribed service intervals. Do not change
the engine oil or oil filter in order to achieve
longer replacement intervals than those pre-
scribed. You could otherwise cause engine
damage or damage to the exhaust gas after-
treatment.
Follow the instructions in the service interval
display regarding the oil change. Otherwise,
you may damage the engine and the exhaust
gas aftertreatment.
When handling engine oil, observe the important
safety notes on service products ( Y
page 427).
The engine oils are matched to the performance
of Mercedes-Benz engines and service intervals.
You should therefore only use engine oils and oil
filters that are approved for vehicles with main-
tenance systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz Center.
Or visit the website
http://bevo.mercedes-benz.com.
The table shows which engine oils have been
approved for your vehicle.Service products and filling capacities 429
Technical data Z

Model MB-Freigabe or
MB-Approval
All models
229.5
Use only SAE 0W-40 or SAE 5W-40 engine oils
for Mercedes-AMG vehicles.
i MB approval is indicated on the oil contain-
ers.
Filling capacities The following values refer to an oil change
including the oil filter.
Missing values were not available at time of
going to print.
Model Capacity
S 400 4MATIC
S 550 e
6.9 US qt (6.5 l)
S 600
Mercedes ‑ May-
bach S 600
Mercedes ‑ AMG
S 65 11.1 US qt (10.5 l)
Mercedes ‑ AMG
S 63 4MATIC 9.0 US qt (8.5 l)
Al l ot her models
8.5 US qt (8.0 l)
Ad ditives
! Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity Viscosity describes the flow characteristics of a
fluid. If an engine oil has a high viscosity, this
means that it is thick; a low viscosity means that
it is thin.
Select an engine oil with an SAE classification
(viscosity) suitable for the prevailing outside
temperatures. The table shows you which SAE
classifications are to be used. The low-temper-
ature characteristics of engine oils can deterio-
rate significantly, e.g. as a result of aging, soot
and fuel deposits. It is therefore strongly rec-
ommended that you carry out regular oil
changes using an approved engine oil with the
appropriate SAE classification.
Brake fluid
G WARNING
The brake fluid constantly absorbs moisture
from the air. This lowers the boiling point of
the brake fluid. If the boiling point of the brake
fluid is too low, vapor pockets may form in the
brake system when the brakes are applied
hard. This would impair braking efficiency.
There is a risk of an accident.
You should have the brake fluid renewed at
the specified intervals.
Comply with the important safety notes for ser-
vice products when handling brake fluid
( Y
page 427).
The brake fluid change intervals can be found in
the Maintenance Booklet.
Only use brake fluid approved by Mercedes-
Benz according to MB-Freigabe or MB-Approval
331.0.
Information about approved brake fluid can be
obtained at any qualified specialist workshop or
on the Internet at
http://bevo.mercedes-benz.co m.
i Have the brake fluid regularly replaced at a
qualified specialist workshop and the replace-
ment confirmed in the Maintenance Booklet.430
Service products and filling capacities
Technical data

Coolant
Important safety notes
G WARNING
If antifreeze comes into contact with hot com-
ponents in the engine compartment, it may
ignite. There is a risk of fire and injury.
Let the engine cool down before you add anti-
freeze. Make sure that antifreeze is not spilled
next to the filler neck. Thoroughly clean the
antifreeze from components before starting
the engine.
! Only add coolant that has been premixed
with the desired antifreeze protection. You
could otherwise damage the engine.
Further information on coolants can be found
in the Mercedes-Benz Specifications for Ser-
vice Products, MB BeVo 310.1, e.g. on the
Internet at http://bevo.mercedes-benz.com.
Or contact a qualified specialist workshop.
! Always use a suitable coolant mixture, even
in countries where high temperatures prevail.
Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
i Have the coolant regularly replaced at a
qualified specialist workshop and the replace-
ment confirmed in the Maintenance Booklet.
The coolant is a mixture of water and anti-
freeze/corrosion inhibitor. It performs the fol-
lowing tasks: R
corrosion protection R
antifreeze protection R
raising the boiling point
If the c oolant has antifreeze protection down to
- 35 ‡ (-37 †), the boiling point of the coolant
during operation is approximately 266 ‡
(130 †).
The antifreeze concentrate/corrosion inhibitor
concentration in the engine cooling system
should: R
be at least 50%. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 †). R
not exceed 55% (antifreeze protection down
to -49 ‡ [-45 †]). Otherwise, heat will not be
dissipated as effectively. Mercedes-Benz recommends an antifreeze/
corrosion inhibitor concentrate in accordance
with
MB Specifications for Service Products 310. 1.
i When the vehicle is first delivered, it is filled
with a coolant mixture that ensures adequate
antifreeze and corrosion protection.
i The coolant is checked with every mainte-
nance interval at a qualified specialist work-
shop.
Filling capacities Missing values were not available at time of
going to print.
Model Capacity
S 400 4MATIC
S 550 e
13.3 US qt (12.6 l)
S 600
Mercedes ‑ May-
bach S 600 15.7 US qt (14.9 l)
Mercedes ‑ AMG
S 63 4MATIC 8.5 US qt (8.0 l)
Mercedes ‑ AMG
S 65 11.3 US qt (10.7 l)
Al l ot her models
12.8 US qt (12.1 l)
Windshield washer system
Important safety notes
G WARNING
Windshield washer concentrate could ignite if
it comes into contact with hot engine compo-
nents or the exhaust system. There is a risk of
fire and injury.
Make sure that no windshield washer con-
centrate is spilled next to the filler neck.
! Do not add distilled or de-ionized water to
the washer fluid container. Otherwise, the
level sensor may be damaged.
! Only MB SummerFit and MB WinterFit
washer fluid should be mixed together. TheService products and filling capacities 431
Technical data Z