MERCEDES-BENZ S CLASS 2016 Manual Online

Useful information
i This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
i Read the information on qualified specialist
workshops ( Y
page 28).
SmartKey
Important safety notes
G WARNING
If children are left unsupervised in the vehicle,
they could: R
open the doors, thus endangering other
people or road users. R
get out and disrupt traffic. R
operate the vehicle's equipment.
Additionally, children could set the vehicle in
motion if, for example, they: R
release the parking brake. R
shifting the automatic transmission out of
park position PR
Start the engine.
There is a risk of an accident and injury.
When leaving the vehicle, always take the
SmartKey with you and lock the vehicle. Never
leave children or animals unattended in the
vehicle. Always keep the SmartKey out of
reach of children.
G WARNING
If you attach heavy or large objects to the
SmartKey, the SmartKey could be uninten-
tionally turned in the ignition lock. This could
cause the engine to be switched off. There is a
risk of an accident. Do not attach any heavy or large objects to the
SmartKey. Remove any bulky key rings before
inserting the SmartKey into the ignition lock.
! Keep the SmartKey away from strong mag-
netic fields. Otherwise, the remote control
function could be affected.
Strong magnetic fields can occur in the vicin-
ity of powerful electrical installations.
Do not keep the SmartKey: R
with electronic devices, e.g. a mobile phone
or another SmartKey. R
with metallic objects, e.g. coins or metal foil. R
inside metallic objects, e.g. a metal case.
This can affect the functionality of the Smart-
Key.
Do not keep the SmartKey in the temperature-
controlled cup holder ( Y
page 332). On vehicles
with the KEYLESS-GO start function, do not
keep it on the parcel shelf or in the trunk. Oth-
erwise, the SmartKey may not be detected, e.g.
when starting the engine using the Start/Stop
button.
A check which periodically establishes a radio
connection between the vehicle and the Smart-
Key determines whether a valid SmartKey is in
the vehicle. This occurs, for example: R
when starting the engine R
whilst driving R
when using HANDS-FREE ACCESS R
when the external door handles are touched R
during convenience closing
SmartKey functions
C
7 To lock the vehicle
D
T To open/close the trunk lid

X
To unlock centrally: press the 6 button.
If you do not open the vehicle within approx-
imately 40 seconds of unlocking: R
the vehicle is locked again. R
anti-theft protection is reactivated. X
To lock centrally: press the 7 button.
The SmartKey centrally locks and unlocks the
following components: R
the doors R
the trunk lid R
the fuel filler flap
The turn signals flash once when unlocking and
three times when locking.
You can also set an audible signal to confirm
that the vehicle has been locked. The audible
signal can be activated and deactivated via the
multimedia system; see the separate operating
instructions.
You will receive visual and acoustic locking con-
firmation if all components were able to be
locked.
When the locator lighting is activated via the
multimedia system, it lights up when it is dark
after the vehicle is unlocked with the SmartKey.
Information on activating and deactivating the
locator lighting can be found in the separate
operating instructions. X
To open the trunk lid automatically from
outside the vehicle: press and hold the T
button until the trunk lid opens. X
To open the trunk lid automatically from
outside the vehicle: if the SmartKey is loca-
ted in the immediate vicinity of the vehicle ,
p
ress the T button on the SmartKey.
When the trunk lid closes you can then
release the button.
KEYLESS-GO
General notes
Bear in mind that the engine can be started by
any of the vehicle occupants if there is a Smart-
Key in the vehicle ( Y
page 164).
Locking/unlocking centrally
You can start, lock or unlock the vehicle using
KEYLESS-GO. To do this, you only need carry the
SmartKey with you. You can combine the func- tions of KEYLESS-GO with those of a conven-
tional SmartKey. Unlock the vehicle by using
KEYLESS-GO, for instance, and lock it using the
7 button on the SmartKey.
The driver's door and the door at which the han-
dle is used, must both be closed. The SmartKey
must be outside the vehicle. When locking or
unlocking with KEYLESS-GO, the distance
between the SmartKey and the corresponding
door handle must not be greater than 3 ft (1 m).
A brief radio connection between the vehicle
and the SmartKey determines whether a valid
SmartKey is in, or in the direct vicinity of, the
vehicle. This occurs, for example: R
when starting the engine R
while driving R
when using HANDS-FREE ACCESS R
when the external door handles are touched R
during convenience closing
X
To unlock the vehicle: touch the inner sur-
face of the door handle. X
To lock the vehicle: touch sensor surface C
or D .
Make sure that you do not touch the inner
surface of the door handle. X
Convenience closing feature: touch
recessed sensor surface D for an extended
period.
Further information on the convenience clos-
ing feature ( Y
page 96). X
To unlock the trunk lid: pull the handle on
the trunk lid.
Deactivating and activating
If you do not intend to use a SmartKey for an
extended period of time, you can deactivate the
KEYLESS-GO function of the SmartKey. The
SmartKey will then use very little power, thereby80
SmartKey
Opening and closing

conserving battery power. For the purposes of
activation/deactivation, the vehicle must not be
nearby. X
To deactivate: press the 7 button on the
SmartKey twice in rapid succession.
The battery check lamp ( Y
page 82) of the
SmartKey flashes twice briefly and lights up
once, then KEYLESS-GO is deactivated . X
To activate: press any button on the Smart-
Key.
or X
Insert the SmartKey into the ignition lock.
KEYLESS-GO and all of its associated features
are available again.
KEYLESS-GO start function
General notes Bear in mind that the engine can be started by
any of the vehicle occupants if there is a Smart-
Key in the vehicle ( Y
page 164).
Changing the settings of the locking
system You can change the settings of the locking sys-
tem. This means that only the driver's door and
the fuel filler flap are unlocked when the vehicle
is unlocked. This is useful if you frequently travel
on your own. X
To change the setting: press and hold down
the 6 and 7 buttons simultaneously
for approximately six seconds until the bat-
tery check lamp flashes twice ( Y
page 82).
If the setting of the locking system is changed
within the signal range of the vehicle, pressing
the 7 or 6 button:R
locks or R
unlocks the vehicle
The SmartKey now functions as follows: X
To unlock: press the 6 button once.X
To unlock centrally: press the 6 button
twice. X
To lock: press the 7 button. The KEYLESS-GO function is changed as fol-
lows: X
To unlock the driver's door: touch the inner
surface of the door handle on the driver's
door. X
To unlock centrally: touch the inner surface
of the door handle on the front-passenger
door or the rear door. X
To lock centrally: touch the outer sensor
surface on one of the door handles. X
To restore the factory settings: press and
hold the 6 and 7 buttons simultane-
ously for approximately six seconds until the
battery check lamp flashes twice
( Y
page 82).
Mechanical key
General notes If the vehicle can no longer be locked or
unlocked with the SmartKey or KEYLESS-GO,
use the mechanical key.
If you use the mechanical key to unlock and
open the driver's door, the anti-theft alarm sys-
tem will be triggered. Switch off the alarm
( Y
page 78).
If you unlock the vehicle using the mechanical
key, the fuel filler flap will not be unlocked auto-
matically. X
To unlock the fuel filler flap: insert the
SmartKey into the ignition lock.
Removing the mechanical key
X
Push release catch C in the direction of the
arrow and at the same time remove mechan-
ical key D from the SmartKey.SmartKey 81
Opening and closing Z

For further information about: R
unlocking the driver's door ( Y
page 87)R
unlocking the trunk ( Y
page 93)R
locking the vehicle ( Y
page 88)
Inserting the mechanical key X
Push mechanical key D completely into the
SmartKey until it engages and release
catch C is back in its basic position.
SmartKey battery
Important safety notes
G WARNING
Batteries contain toxic and corrosive substan-
ces. If batteries are swallowed, it can result in
severe health problems. There is a risk of fatal
injury.
Keep batteries out of the reach of children. If
a battery is swallowed, seek medical attention
immediately.
H Environmental note
Batteries contain dangerous
substances. It is against the
law to dispose of them with
the household rubbish. They
must be collected separately
and recycled to protect the
environment.
Dispose of batteries in an
environmentally friendly
manner. Take discharged
batteries to a qualified spe-
cialist workshop or a special
collection point for used bat-
teries.
The SmartKey batteries contain perchlorate
material, which may require special handling
and regard for the environment. National guide-
lines must be observed during disposal. In Cal-
ifornia, see www.dtsc.ca.gov/
HazardousWaste/Perchlorate/index.cfm . Mercedes-Benz recommends that you have the
batteries replaced at a qualified specialist work-
shop.
Checking the battery X
Press the 7 or 6 button.
The battery is working properly if battery
check lamp C lights up briefly.
The battery is discharged if battery check
lamp C does not light up briefly. X
Change the battery ( Y
page 82).
If the SmartKey battery is checked within the
signal reception range of the vehicle, pressing
the 7 or 6 button: R
locks or R
unlocks the vehicle
i You can obtain a battery from any qualified
specialist workshop.
Replacing the battery You require a CR 2025 3 V cell battery. X
Take the mechanical key out of the SmartKey
( Y
page 81).
X
Press mechanical key D into the SmartKey
opening in the direction of the arrow until bat-82
SmartKey
Opening and closing

tery compartment cover C opens. Do not
hold battery compartment cover C closed
while doing so. X
Remove battery compartment cover C .
X
Repeatedly tap the SmartKey against your
palm until battery

Problems with the SmartKey Problem
Possible causes/consequences and P Solutions
You can no longer lock or
unlock the vehicle using
the SmartKey. The SmartKey battery is discharged or nearly discharged. X
Check the SmartKey battery ( Y
page 82) and replace it if necessary
( Y
page 82).
If this does not work: X
Unlock ( Y
page 87) or lock ( Y
page 88) the vehicle using the
mechanical key.
There is interference from a powerful source of radio waves. X
Unlock ( Y
page 87) or lock ( Y
page 88) the vehicle using the
mechanical key.
The SmartKey is faulty. X
Unlock ( Y
page 87) or lock ( Y
page 88) the vehicle using the
mechanical key. X
Have the SmartKey checked at a qualified specialist workshop.
You can no longer lock or
unlock the vehicle using
KEYLESS-GO. KEYLESS-GO was deactivated. X
Reactivate KEYLESS-GO ( Y
page 80).
The SmartKey battery is discharged or nearly discharged. X
Check the SmartKey battery ( Y
page 82) and replace it if necessary
( Y
page 82).
If this does not work: X
Unlock ( Y
page 87) or lock ( Y
page 88) the vehicle using the
mechanical key.
There is interference from a powerful source of radio waves. X
Unlock ( Y
page 87) or lock ( Y
page 88) the vehicle using the
mechanical key.
KEYLESS-GO is malfunctioning. X
Lock/unlock the vehicle using the remote control function of the
SmartKey. X
Have the vehicle and SmartKey checked at a qualified specialist
workshop.
If the vehicle can also not be locked/unlocked using the remote con-
trol function: X
Lock ( Y
page 87) or unlock ( Y
page 88) the vehicle using the
mechanical key. X
Have the vehicle and SmartKey checked at a qualified specialist
workshop.84
SmartKey
Opening and closing

Problem
Possible causes/consequences and P Solutions
The engine cannot be
started using the Smart-
Key. The on-board voltage is too low. X
Switch off non-essential consumers, e.g. seat heating or interior
lighting, and try to start the engine again.
If this does not work: X
Check the starter battery and charge it if necessary ( Y
page 374).
or X
Jump-start the vehicle ( Y
page 376).
or X
Consult a qualified specialist workshop.
The engine cannot be
started using the Start/
Stop button. The Smart-
Key is in the vehicle. The vehicle is locked. X
Unlock the vehicle and try to start the vehicle again.
The SmartKey battery is discharged or nearly discharged. X
Check the SmartKey battery ( Y
page 82) and replace it if necessary
( Y
page 82).
If this does not work: X
Start your vehicle with the SmartKey in the ignition lock.
There is interference from a powerful source of radio waves. X
Start your vehicle with the SmartKey in the ignition lock.
You have lost a Smart-
Key. X
Have the SmartKey deactivated at a qualified specialist workshop. X
Report the loss immediately to the vehicle insurers. X
If necessary, have the locks changed as well.
You have lost the
mechanical key. X
Report the loss immediately to the vehicle insurers. X
If necessary, have the locks changed as well.
Doors
Important safety notes
G WARNING
If children are left unsupervised in the vehicle,
they could: R
open the doors, thus endangering other
people or road users. R
get out and disrupt traffic. R
operate the vehicle's equipment. Additionally, children could set the vehicle in
motion if, for example, they: R
release the parking brake. R
shifting the automatic transmission out of
park position P R
Start the engine.
There is a risk of an accident and injury.
When leaving the vehicle, always take the
SmartKey with you and lock the vehicle. Never
leave children or animals unattended in the
vehicle. Always keep the SmartKey out of
reach of children. Doors 85
Opening and closing Z

Unlocking and opening doors from
the inside You can open a door from inside the vehicle
even if it has been locked. You can only open the
rear doors from inside the vehicle if they are not
secured by the child-proof locks ( Y
page 67). If
the vehicle has been locked with the SmartKey
or with KEYLESS-GO, opening a door from the
inside will trigger the anti-theft alarm system.
Switch off the alarm ( Y
page 78).
X
To unlock and open a front door: pull door
handle D .
If the door is locked, locking knob C pops up.
The door is unlocked and opens. X
To unlock a rear door: pull door handle D .
Locking knob C pops up and the door
unlocks. X
To open a rear door: pull door handle D
again.
The door opens.
Centrally locking and unlocking the
vehicle from the inside You can centrally lock and unlock the vehicle
from the inside. The buttons are located on both
front doors. X
To unlock: press button C .X
To lock: press button D .
If the front-passenger door is closed, the vehi-
cle locks.
If the driver's door is open, the door stays
unlocked.
Meanwhile, the fuel filler flap will not be locked
or unlocked.
You cannot unlock the vehicle centrally from the
inside if the vehicle has been locked with the
SmartKey or KEYLESS-GO.
The doors can be opened from the inside. You
can only open the rear doors from inside the
vehicle if they are not secured by the child-proof
locks ( Y
page 67).
If the vehicle has been locked with the SmartKey
or with KEYLESS-GO, opening a door from the
inside will trigger the anti-theft alarm system.
Switch off the alarm ( Y
page 78).
If a locked door is opened from the inside, the
previous unlock status of the vehicle will be
taken into consideration if: R
the vehicle was locked using the locking but-
ton for the central locking, or R
if the vehicle was locked automatically
The vehicle will be fully unlocked if it had previ-
ously been fully unlocked. If only the driver's
door had been previously unlocked, only the
door which has been opened from the inside is
unlocked.86
Doors
Opening and closing

Aut oma tic locking featu reX
To deactivate: press and hold butto n C for
approximately fiv e seconds until a tone
sounds. X
To activate: press and hold butto n D for
approximately fiv e seconds until a tone
sounds.
If you press on e of th e two buttons and do no t
hear a tone , th e relevan t setting has already
been selected.
The vehicl e is locke d automatically when th e
ignition is switched on and th e wheels are turn-
ing .
You could therefor e be locke d out if:R
th e vehicl e is bein g pushed.R
th e vehicl e is bein g towed.R
th e vehicl e is on a roller dynamometer.
You can also switch th e automatic locking func-
tion on and off usin g th e multimedia system; see
th e separat e operating instructions.
Power closing Powe r closin g pulls th e door s and trunk lid int o
their locks automatically eve n if they are only
partly closed. X
To power close a door : push th e door int o
th e loc k up to th e first deten t position .
Powe r closin g will pull th e door fully closed.X
To power close th e trunk lid : lightl y push
th e trunk lid closed.
The powe r closin g function pulls th e trunk lid
closed. Unlocking the driver's door (mechan-
ical key) If th e vehicl e can no longer be locke d or
unlocke d wit h th e SmartKey or KEYLESS-GO ,
use th e mechanical key. X
Tak e th e mechanical ke y out of th e SmartKey
( Y
page 81).
X
Inser t th e mechanical ke y as far as it will go
int o opening C in th e protective cap .X
Pull and hold th e door handle. X
Pull th e protective cap on th e mechanical ke y
as straight as possibl e away from th e vehicl e
until it releases. X
Releas e th e door handle.
X
Inser t th e mechanical ke y int o th e loc k of th e
driver's door as far as it will go. X
Turn th e mechanical ke y counter-clockwise
as far as it will go to position G .
The locking knob pops up and th e door
unlocks . X
Turn th e mechanical ke y bac k and remove it .X
Inser t th e mechanical ke y int o th e SmartKey
( Y
page 82) . X
Carefully press th e protective cap onto th e
loc k cylinder until it engage s and is seatedDoors 87
Opening and closing Z

firmly. Do not pull the door handle when doing
so.
If you use the mechanical key to unlock and
open the driver's door, the anti-theft alarm sys-
tem will be triggered. Switch off the alarm
( Y
page 78).
Locking the vehicle (mechanical key) If the vehicle can no longer be locked with the
SmartKey or KEYLESS-GO, use the mechanical
key. X
Open the driver's door. X
Close the front-passenger door, the rear
doors and the trunk lid. X
Press the locking button ( Y
page 86).X
Check whether the locking knobs on the
front-passenger door and the rear doors are
still visible. Press down the locking knobs by
hand, if necessary. X
Close the driver's door. X
Take the mechanical key out of the SmartKey
( Y
page 81).
X
Insert the mechanical key as far as it will go
into opening C in the protective cap.X
Pull and hold the door handle. X
Pull the protective cap on the mechanical key
as straight as possible away from the vehicle
until it releases. X
Release the door handle. X
Insert the mechanical key into the lock of the
driver's door as far as it will go. X
Turn the mechanical key clockwise as far as it
will go to position G .
The locking knob drops down and the driver's
door is locked. X
Turn the mechanical key back and remove it. X
Make sure that the doors and the trunk lid are
locked. X
Insert the mechanical key into the SmartKey
( Y
page 82). X
Carefully press the protective cap onto the
lock cylinder until it engages and is seated
firmly. Do not pull the door handle when doing
so.
If you lock the vehicle as described above, the
fuel filler flap is not locked. The anti-theft alarm
system is not armed.
Trunk
Important safety notes
G WARNING
Combustion engines emit poisonous exhaust
gases such as carbon monoxide. Exhaust
gases can enter the vehicle interior if the
trunk lid is open when the engine is running,
especially if the vehicle is in motion. There is a
risk of poisoning.
Always switch off the engine before opening
the trunk lid. Never drive with the trunk lid
open.
G WARNING
If objects, luggage or loads are not secured or
not secured sufficiently, they could slip, tip88
Trunk
Opening and closing