Coolant MERCEDES-BENZ S-Class SEDAN 2016 W222 User Guide

Engine
Display messagesPossible causes/consequences andMSolutions
+
CheckCoolantLevelSee Operator's Man‐ual
The coolant level is too low.
!Avoid making long journeys with too little coolant in the engine
cooling system. The engine will otherwise be damaged.
XAdd coolant, observing the warning notes before doing so
(Ypage 356).
If you have to add coolant frequently:
XContact a qualified specialist workshop and have the engine cooling
system checked.
?The fan motor is faulty.
XAt coolant temperatures below 257 ‡(125 †), drive to the nearest
qualified specialist workshop.
XAvoid heavy loads on the engine as you do so, e.g. driving in moun-
tainous terrain and stop-start traffic.
?
Coolant Too HotStop Vehicle TurnEngine Off
The coolant is too hot.
A warning tone also sounds.
GWARNING
Do not drive when your engine is overheated. This can cause some
fluids which may have leaked into the engine compartment to catch
fire.
Steam from the overheated engine can also cause serious burns which
can occur just by opening the hood.
There is a risk of injury.
XPull over and stop the vehicle safely and switch off the engine, pay- ing attention to road and traffic conditions.
XSecure the vehicle against rolling away (Ypage 189).
XWait until the engine has cooled down.
XMake sure that the air supply to the engine radiator is not blocked,e.g. by snow, slush or ice.
XDo not start the engine again until the display message goes out and
the coolant temperature is below 257 ‡ (125 †). Otherwise, the
engine could be damaged.
XPay attention to the coolant temperature display.
If the temperature increases again:
XVisit a qualified specialist workshop immediately.
Under normal operating conditions and with the specified coolant
level, the coolant temperature may rise to 255 ‡ (124 †).
294Display messages
On-board computer and displays

Engine
Warning/
indicator
lampNSignal type
Possible causes/consequences and M
Solutions
;NThe yellow Check Engine warning lamp lights up while the engine is running.
There may be a malfunction, for example:
Rin the engine management
Rin the fuel injection system
Rin the exhaust system
Rin the ignition system
Rin the fuel system
The emission limit values may be exceeded and the engine may be in emergency
mode.
XVisit a qualified specialist workshop immediately.
iIn some states, you must immediately visit a qualified specialist workshop as
soon as the yellow Check Engine warning lamp lights up. This is due to the legal
requirements in effect in these states. If in doubt, check whether such legal
regulations apply in the state in which you are currently driving.
8N The yellow reserve fuel warning lamp lights up while the engine is running.
The fuel level has dropped into the reserve range.
XRefuel at the nearest gas station.
8N The yellow reserve fuel warning lamp flashes while the vehicle is in motion.
In addition, the ;Check Engine warning lamp may light up.
The fuel filler cap is not closed correctly or the fuel system is leaking.
XCheck that the fuel filler cap is correctly closed.
XIf the fuel filler cap is not correctly closed: close the fuel filler cap.
XIf the fuel filler cap is closed:visit a qualified specialist workshop.
?NThe red coolant warning lamp comes on while the engine is running. The coolant
temperature gauge is at the beginning of the cold range.
The temperature sensor for the coolant temperature gage is defective.
The coolant temperature is no longer being monitored. There is a risk of engine
damage if the coolant temperature is too high.
XPull over and stop the vehicle safely and switch off the engine, paying attention
to road and traffic conditions. Do not continue driving under any circumstances.
XSecure the vehicle against rolling away (Ypage 189).
XConsult a qualified specialist workshop.
320Warning and indicator lamps in the instrument cluster
On-board computer and displays

Warning/
indicator
lampNSignal type
Possible causes/consequences and M
Solutions
?NThe red coolant warning lamp comes on while the engine is running.
The coolant level is too low.
If the coolant level is correct, the airflow to the engine radiator may be blocked or
the electric engine radiator fan may be malfunctioning.
The coolant is too hot and the engine is no longer being cooled sufficiently.
XObserve the additional display messages in the multifunction display.
XPull over and stop the vehicle safely and switch off the engine, paying attention
to road and traffic conditions.
XSecure the vehicle against rolling away (Ypage 189).
XLeave the vehicle and keep a safe distance from the vehicle until the engine has cooled down.
XCheck the coolant level and add coolant, observing the warning notes
(Ypage 356).
XIf you have to add coolant frequently, have the engine cooling system checked.
XMake sure that the air supply to the engine radiator is not blocked, e.g. by snow,
slush or ice.
XDo not start the engine again until the coolant temperature is below 257 ‡
(125 †). Otherwise, the engine could be damaged.
XDrive to the nearest qualified specialist workshop.
XAvoid heavy loads on the engine as you do so, e.g. driving in mountainous terrain
and stop-start traffic.
?N The red coolant warning lamp comes on while the engine is running. A warning
tone also sounds.
The coolant temperature has exceeded 255 ‡(124 †). The airflow to the engine
radiator may be blocked or the coolant level may be too low.
GWARNING
The engine is not being cooled sufficiently and may be damaged.
Do not drive when your engine is overheated. This can cause some fluids which
may have leaked into the engine compartment to catch fire.
Steam from the overheated engine can also cause serious burns which can occur
just by opening the hood.
There is a risk of injury.
XObserve the additional display messages in the multifunction display.
XPull over and stop the vehicle safely and switch off the engine, paying attention
to road and traffic conditions.
XSecure the vehicle against rolling away (Ypage 189).
XLeave the vehicle and keep a safe distance from the vehicle until the engine has
cooled down.
XCheck the coolant level and add coolant, observing the warning notes
(Ypage 356).
XIf you have to add coolant frequently, have the engine cooling system checked.
XMake sure that the air supply to the engine radiator is not blocked, e.g. by snow,
slush or ice.
Warning and indicator lamps in the instrument cluster321
On-board computer and displays
Z

Warning/
indicator
lampNSignal type
Possible causes/consequences and M
Solutions
XAt coolant temperatures below 257‡(125 †), you can continue driving to the
nearest qualified specialist workshop.
XAvoid heavy loads on the engine as you do so, e.g. driving in mountainous terrain
and stop-start traffic.
Driving systems
Warning/
indicator
lampNSignal type
Possible causes/consequences and M
Solutions
·NThe red distance warning lamp lights up while the vehicle is in motion. A warning
tone also sounds.
You are approaching a vehicle, a pedestrian or a stationary obstacle in your line of travel at too high a speed.
XBe prepared to brake immediately.
XPay careful attention to the traffic situation. You may have to brake or take
evasive action.
Further information on PRE ‑SAFE
®Brake (Ypage 75).
For further information about the distance warning function of COLLISION PRE-
VENTION ASSIST PLUS, see (
Ypage 71).
322Warning and indicator lamps in the instrument cluster
On-board computer and displays

GWARNING
If engine oil comes into contact with hot com- ponents in the engine compartment, it may
ignite. There is a risk of fire and injury.
Make sure that engine oil is not spilled next to
the filler neck. Let the engine cool down and
thoroughly clean the engine oil off the com-
ponents before starting the engine.
HEnvironmental note
When adding oil, take care not to spill any. If
oil enters the soil or waterways, it is harmful to
the environment.
!Only use engine oils and oil filters that have
been approved for vehicles with a service sys-
tem. You can obtain a list of the engine oils
and oil filters tested and approved in accord- ance with the Mercedes-Benz Specifications
for Service Products at any Mercedes-Benz
Service center.
Damage to the engine or exhaust system is
caused by the following:
Rusing engine oils and oil filters that have notbeen specifically approved for the service
system
Rreplacing engine oil and oil filters after the
interval for replacement specified by the
service system has been exceeded
Rusing engine oil additives.
!Do not add too much oil. adding too much
engine oil can result in damage to the engine
or to the catalytic converter. Have excess
engine oil siphoned off.
Example
XTurn cap :counter-clockwise and remove it.
XAdd engine oil.
If the oil level is at or below the MIN mark on
the oil dipstick, add 1.1 US qt (1.0 liter) of
engine oil.
XReplace cap :on the filler neck and tighten
clockwise.
Ensure that the cap locks into place securely.
XCheck the oil level again with the oil dipstick
(Ypage 353).
Further information on engine oil (
Ypage 429).
Additional service products
Checking coolant level
GWARNING
Certain components in the engine compart-
ment, such as the engine, radiator and parts
of the exhaust system, can become very hot.
Working in the engine compartment poses a
risk of injury.
Where possible, let the engine cool down and touch only the components described in the
following.
GWARNING
The cooling system is pressurized, particularly
when the motor is warm. If you open the cap,
you could be scalded if hot coolant sprays out.
There is a risk of injury.
Let the engine cool down before you open the
cap. Wear gloves and eye protection. Slowly
open the cap to relieve pressure.
356Engine compartment
Maintenance and care

XPark the vehicle on a level surface.
Only check the coolant level when the vehicleis on a level surface and the engine has cooled
down.
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
or
XPress Start/Stop button twice (Ypage 162).
XCheck the coolant temperature display in the
instrument cluster.
The coolant temperature must be below
158 ‡ (70 †).
XTurn the SmartKey to position 0(Ypage 162)
in the ignition lock.
or
XRemove Start/Stop button from ignition lock
(Ypage 162).
XSlowly turn cap :counter-clockwise and to
relieve excess pressure.
XTurn cap :further counter-clockwise and
remove it.
If the coolant is at the level of marker bar =
in the filler neck when cold, there is enough
coolant in coolant expansion tank ;.
If the coolant level is approximately 0.6 in
(1.5 cm) above marker bar =in the filler neck
when warm, there is enough coolant in expan-
sion tank ;.
XIf necessary, add coolant that has been tested
and approved by Mercedes-Benz.
XReplace cap :and turn it clockwise as far as
it will go.
Vehicles with PLUG-IN HYBRID operation: the
second coolant expansion tank must not be fil-
led.
For further information on coolant, see
(
Ypage 431).
Adding washer fluid to the windshield
washer system
GWARNING
Certain components in the engine compart-
ment, such as the engine, radiator and parts
of the exhaust system, can become very hot.
Working in the engine compartment poses a
risk of injury.
Where possible, let the engine cool down and touch only the components described in the
following.
GWARNING
Windshield washer concentrate could ignite if it comes into contact with hot engine compo-
nents or the exhaust system. There is a risk of
fire and injury.
Make sure that no windshield washer con-
centrate is spilled next to the filler neck.
XTo open: pull cap:upwards by the tab.
XPlace cap :on the edge of the filler neck and
engage in place.
XAdd the premixed washer fluid.
XTo close: press cap :onto the filler neck
until it engages.
If the washer fluid level drops below the recom-
mended minimum of 1 liter, a message appears
in the multifunction display prompting you to
add washer fluid (
Ypage 311).
Further information on windshield washer fluid/
antifreeze (
Ypage 431).
ASSYST PLUS
Service message
The ASSYST PLUS service interval display
informs you of the next service due date.
Information on the type of service and service
intervals (see the separate Maintenance Book-
let).
You can obtain further information from an
authorized Mercedes-Benz Center or at
http://www.mbusa.com (USA only).
ASSYST PLUS357
Maintenance and care
Z

!If the SmartKey is within the rear detection
range of KEYLESS-GO, the following situa-
tions, for example, could lead to the uninten-
tional opening of the trunk:
Rusing a car wash
Rusing a power washer
Make sure that the SmartKey is at least 10 ft
(3 m) away from the vehicle.
Cleaning the paintwork
!Do not affix:
Rstickers
Rfilms
Rmagnetic plates or similar items
to painted surfaces. You could otherwise
damage the paintwork.
Scratches, corrosive deposits, areas affected by corrosion and damage caused by inadequate
care cannot always be completely repaired. In
such cases, visit a qualified specialist workshop.
XRemove dirt immediately, where possible,
while avoiding rubbing too hard.
XSoak insect remains with insect remover and
rinse off the treated areas afterwards.
XSoak bird droppings with water and rinse off
the treated areas afterwards.
XRemove coolant, brake fluid, tree resin, oils,
fuels and greases by rubbing gently with a
cloth soaked in petroleum ether or lighter
fluid.
XUse tar remover to remove tar stains.
XUse silicone remover to remove wax.
If water no longer forms "beads" on the paint
surface, use the paint care products recommen-
ded and approved by Mercedes-Benz. This is the
case approximately every three to five months,
depending on the climate conditions and the
care product used.
If dirt has penetrated the paint surface or if the
paint has become dull, the paint cleaner recom-
mended and approved by Mercedes-Benz
should be used.
Do not use these care products in the sun or on
the hood while the hood is hot.
XUse a suitable touch-up stick, e.g. MB Touch-
Up Stick, to repair slight damage to the paint-
work quickly and provisionally.
Matte finish care
!Never polish the vehicle or the light alloy
wheels. Polishing causes the finish to shine.
!The following may cause the paint to
become shiny and thus reduce the matte
effect:
Rstrong rubbing of the paintwork with
unsuitable materials
Rfrequent use of automatic car washes
Rwashing the vehicle in direct sunlight
!Never use paint cleaner, buffing or polishing
products, or gloss preserver, e.g. wax. These
products are only suitable for high-gloss sur-
faces. Their use on vehicles with matte finish
leads to considerable surface damage (shiny,
mottled areas).
Always have paintwork repairs carried out at a
qualified specialist workshop.
!Do not use wash programs with a hot wax
treatment under any circumstances.
Observe these notes if your vehicle has a clear
matte finish. This will help you to avoid damage
to the paintwork due to incorrect treatment.
These notes also apply to light alloy wheels with a clear matte finish.
The vehicle should preferably be washed by
hand using a soft sponge, car shampoo and
plenty of water.
Use only insect remover and car shampoo from
the range of approved Mercedes-Benz care
products.
Cleaning the vehicle parts
Cleaning the wheels
GWARNING
The water jet from a circular jet nozzle (dirt
blasters) can cause invisible exterior damage
to the tires or chassis components. Compo-
nents damaged in this way may fail unexpect-
edly. There is a risk of an accident.
Do not use power washers with circular jet
nozzles to clean the vehicle. Have damaged
tires or chassis components replaced imme-
diately.
Care361
Maintenance and care
Z

GVWR (Gross Vehicle Weight Rating)
The GVWR is the maximum permissible gross
weight of a fully loaded vehicle (the weight of thevehicle including all accessories, occupants,
fuel, luggage and the drawbar noseweight, if
applicable). The gross vehicle weight rating is
specified on the vehicle identification plate on
the B-pillar on the driver's side.
Maximum loaded vehicle weight
The maximum weight is the sum of:
Rthe curb weight of the vehicle
Rthe weight of the accessories
Rthe load limit
Rthe weight of the factory installed optional
equipment
Kilopascal (kPa)
Metric unit for tire pressure. 6.9 kPa corre-
sponds to 1 psi. Another unit for tire pressure is
bar. 100 kilopascals (kPa) are the equivalent of
1 bar.
Load index
In addition to the load-bearing index, the load
index may also be imprinted on the sidewall of
the tire. This specifies the load-bearing capacity
more precisely.
Curb weight
The weight of a vehicle with standard equipment
including the maximum capacity of fuel, oil and
coolant. It also includes the air-conditioning sys-
tem and optional equipment if these are instal-
led in the vehicle, but does not include passen-
gers or luggage.
Maximum load rating
The maximum tire load is the maximum permis-
sible weight in kilograms or lbs for which a tire is
approved.
Maximum permissible tire pressure
Maximum permissible tire pressure for one tire.
Maximum load on one tire
Maximum load on one tire. This is calculated bydividing the maximum axle load of one axle by
two.
PSI (pounds per square inch)
A standard unit of measure for tire pressure.
Aspect ratio
Relationship between tire height and tire width
in percent.
Tire pressure
This is pressure inside the tire applying an out-
ward force to each square inch of the tire's sur-
face. The tire pressure is specified in pou

nds per
square inch (psi), in kilopascal (kPa) or in bar.
The tire pressure should only be corrected when
the tires are cold.
Cold tire pressure
The tires are cold:
Rif the vehicle has been parked with the tires
out of direct sunlight for at least three hours
and
Rif the vehicle has not been driven further than
1 mile (1.6 km)
Tread
The part of the tire that comes into contact with
the road.
Bead
The tire bead ensures that the tire sits securely
on the wheel. There are several steel wires in the
bead to prevent the tire from coming loose from
the wheel rim.
Sidewall
The part of the tire between the tread and the
bead.
Weight of optional extras
The combined weight of those optional extras
that weigh more than the replaced standard
parts and more than 5 lbs (2.3 kg). These
optional extras, such as high-performance
brakes, level control, a roof rack or a high-per-
formance battery, are not included in the curb
weight and the weight of the accessories.
TIN (Tire Identification Number)
This is a unique identifier which can be used by
a tire manufacturer to identify tires, for example
for a product recall, and thus identify the pur-
chasers. The TIN is made up of the manufactur- er's identity code, tire size, tire type code and
the manufacturing date.
404All about wheels and tires
Wheels and tires

iThe data shown on the vehicle identification
plate is used only as an example. This data is
different for every vehicle and can deviate
from the data shown here. You can find the
data applicable to your vehicle on the vehicle
identification plate.
Vehicle identification number (VIN)
XOpen the front right-hand door.
XFold cover :down and remove it.
You will see the VIN.
The VIN can also be found in the following loca-
tions:
Ron the lower edge of the windshield
(Ypage 427)
Ron the vehicle identification plate
(Ypage 426)
Engine number
:Engine number (stamped into the crank-
case)
;VIN (on the lower edge of the windshield)
=Emission control information plate, includ-
ing the certification of both federal and Cali-
fornian emissions standards
Service products and filling capaci-
ties
Important safety notes
GWARNING
Service products may be poisonous and haz-
ardous to health. There is a risk of injury.
Comply with instructions on the use, storage
and disposal of service products on the labels
of the respective original containers. Always
store service products sealed in their original
containers. Always keep service products out
of the reach of children.
HEnvironmental note
Dispose of service products in an environ-
mentally responsible manner.
Service products include the following:
RFuels
RLubricants (e.g. engine oil, transmission oil)
RCoolant
RBrake fluid
RWindshield washer fluid
RClimate control system refrigerant
Components and service products must be
matched. Only use products recommended by
Mercedes-Benz. Damage which is caused by the
use of products which have not been recom-
mended is not covered by the Mercedes-Benz
warranty or goodwill gestures. They are listed in
this Mercedes-Benz Operator's Manual in the
appropriate section.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved by
Mercedes-Benz by the following inscription on
the containers:
RMB-Freigabe (e.g. MB-Freigabe 229.51)
RMB-Approval (e.g. MB-Approval 229.51)
Other designations or recommendations indi-
cate a level of quality or a specification in
accordance with an MB Sheet Number (e.g. MB 229.5). They have not necessarily been
approved by Mercedes-Benz.
Service products and filling capacities427
Technical data
Z

Coolant
Important safety notes
GWARNING
If antifreeze comes into contact with hot com- ponents in the engine compartment, it may
ignite. There is a risk of fire and injury.
Let the engine cool down before you add anti-
freeze. Make sure that antifreeze is not spilled
next to the filler neck. Thoroughly clean the
antifreeze from components before starting
the engine.
!Only add coolant that has been premixed
with the desired antifreeze protection. You
could otherwise damage the engine.
Further information on coolants can be found
in the Mercedes-Benz Specifications for Ser-
vice Products, MB BeVo 310.1, e.g. on the
Internet at http://bevo.mercedes-benz.com.
Or contact a qualified specialist workshop.
!Always use a suitable coolant mixture, even
in countries where high temperatures prevail.
Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
iHave the coolant regularly replaced at a
qualified specialist workshop and the replace-
ment confirmed in the Maintenance Booklet.
The coolant is a mixture of water and anti-
freeze/corrosion inhibitor. It performs the fol-
lowing tasks:
Rcorrosion protection
Rantifreeze protection
Rraising the boiling point
If th e c
oolant has antifreeze protection down to
-35 ‡ (-37 †), the boiling point of the coolant
during operation is approximately 266 ‡
(130 †).
The antifreeze concentrate/corrosion inhibitor
concentration in the engine cooling system
should:
Rbe at least 50%. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 †).
Rnot exceed 55% (antifreeze protection down
to -49 ‡ [-45 †]). Otherwise, heat will not be dissipated as effectively. Mercedes-Benz recommends an antifreeze/
corrosion inhibitor concentrate in accordance
with
MB Specifications for Service Products 310.
1.
iWhen the vehicle is first delivered, it is filled
with a coolant mixture that ensures adequate
antifreeze and corrosion protection.
iThe coolant is checked with every mainte-
nance interval at a qualified specialist work-
shop.
Filling capacities
Missing values were not available at time of
going to print.
ModelCapacity
S 400 4MATIC
S 550 e13.3 US qt (12.6 l)
S 600
Mercedes‑May-
bach S 60015.7 US qt (14.9l)
Mercedes‑AMG
S 63 4MATIC8.5 US qt (8.0l)
Mercedes‑AMG
S 6511.3 US qt (10.7 l)
Allot her models12.8 US qt (12.1 l)
Windshield washer system
Important safety notes
GWARNING
Windshield washer concentrate could ignite if it comes into contact with hot engine compo-
nents or the exhaust system. There is a risk of
fire and injury.
Make sure that no windshield washer con-
centrate is spilled next to the filler neck.
!Do not add distilled or de-ionized water to
the washer fluid container. Otherwise, the
level sensor may be damaged.
!Only MB SummerFit and MB WinterFit
washer fluid should be mixed together. The
Service products and filling capacities431
Technical data
Z