cooling MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

1, 2, 3 ...
4ETS (Electronic Traction System)see ETS/4ETS (Electronic Trac-
tion System)
4MATIC (permanent four-wheel
drive) .................................................. 213
12 V socket
see Sockets
115 V socket ...................................... 337
360° camera
Cleaning ........................................ .363
Function/notes .............................2 24
A
ABS (Anti-lock Braking System)
Display message ............................ 278
Function/notes ................................ 68
Warning lamp ................................. 316
Accident
Automatic measures after an acci-
dent ................................................. 61
Activating/deactivating cooling
with air dehumidification ................. 146
Activating/deactivating Night
View Assist Plus
With spotlight function ................... 232
Active Blind Spot Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 234
Active Body Control (ABC)
Display message ............................ 300
Function/notes ............................. 210
Active Lane Keeping Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 237
Active multicontour seat .................. 117
Active Parking Assist
Detecting parking spaces .............. 217
Display message ............................ 302
Exiting a parking space .................. 219
Function/notes ............................. 216
Important safety notes .................. 216 Parking .......................................... 218
ADAPTIVE BRAKE ................................. 75
Adaptive Brake Assist
Function/notes ................................ 72
Adaptive Damping System (ADS) ..... 212
Adaptive Highbeam Assist Plus
Display message ............................ 293
Function/notes ............................. 133
Switching on/off ........................... 133
Additional speedometer ................... 274
Additives (engine oil) ........................ 430
Air bags
Belt bags .......................................... 48
Cushion air bags .............................. 53
Deployment ..................................... 57
Display message ............................ 289
Front air bag (driver, front
passenger) ....................................... 52
Important safety notes .................... 50
Introduction ..................................... 50
Knee bag .......................................... 52
Occupant Classification System
(OCS) ............................................... 53
PASSENGER AIR BAG i
ndicator
lamps ............................................... 46
Side impact air bag .......................... 52
Window curtain air bag .................... 53
Air vents
Glove box ....................................... 159
Important safety notes .................. 158
Rear ............................................... 160
Setting ........................................... 158
Setting the center air vents ........... 159
Setting the side air vents ............... 159
Air-conditioning system
see Climate control
AIRMATIC
Display message ............................ 299
Function/notes ............................. 212
Alarm
ATA (Anti-Theft Alarm system) ......... 78
Switching off (ATA) .......................... 78
Switching the function on/off
(ATA) ................................................ 78
Alarm system
see ATA (Anti-Theft Alarm system)
Anti-lock braking system
see ABS (Anti-lock Braking System)
Index3

Removing...................................... .185
Storing ...........................................1 83
Warming up ................................... 182
Charging the high-voltage battery
(important safety notes) ................... 180
Chauffeur mode
Display message ............................ 310
Fully reclined position .................... 114
General notes ................................ 111
Installing the head restraint ........... 113
Moving front-passenger seat into
the chauffeur position .................... 112
Moving the front-passenger seat
into the normal position ................. 113
Removing the head restraint .......... 113
Child
Restraint system .............................. 62
Child seat
Forward-facing restraint system ...... 66
LATCH-type (ISOFIX) child seat
anchors ............................................ 63
On the front-passenger seat ............ 65
Rearward-facing restraint system .... 66
Top Tether ....................................... 64
Child-proof locks
Important safety notes .................... 66
Rear doors ....................................... 67
Children
Special seat belt retractor ............... 62
Cigarette lighter ................................ 335
Cleaning
Mirror turn signal ........................... 362
Climate control
Automatic climate control ............. 141
Controlling automatically ............... 147
Cooling with air dehumidification .. 146
Defrosting the windows ................. 151
Defrosting the windshield .............. 151
ECO start/stop function ................ 145
General notes ................................ 140
Immediate pre-entry climate con-
trol ................................................. 158
Indicator lamp ................................ 147
Ionization ....................................... 155
Notes on using the automatic cli-
mate control .................................. 145
Overview of systems ...................... 140
Perfume atomizer .......................... 153 Pre-entry climate control at
departure time ............................... 157
Pre-entry climate control via
key ... 155
P

roblem with the rear window
defroster ........................................ 152
Problems with cooling with air
dehumidification ............................ 147
Rear control panel ......................... 141
Refrigerant ..................................... 432
Refrigerant filling capacity ............. 432
Setting the air distribution ............. 149
Setting the air vents ...................... 158
Setting the airflow ......................... 150
Setting the climate mode ............... 148
Setting the temperature ................ 148
Switching air-recirculation mode
on/off ............................................ 152
Switching on/off ........................... 145
Switching residual heat on/off ...... 152
Switching the rear window
defroster on/off ............................ 151
Switching the synchronization
function on and off ........................ 150
Climate control system
Climate control .............................. 145
Cockpit
Overview .......................................... 32
COLLISION PREVENTION ASSIST
PLUS
Activating/deactivating ................. 270
Display message ............................ 284
Operation/notes .............................. 71
COMAND display
Cleaning ......................................... 364
Combination switch .......................... 131
Consumption statistics (on-board
computer) .......................................... 262
Convenience closing feature .............. 96
Convenience opening feature ............ 95
Coolant (engine)
Checking the level ......................... 356
Display message ............................ 294
Displaying the temperature (on-
board computer) ............................ 269
Filling capacity ............................... 431
Important safety notes .................. 431
Temperature gauge ........................ 257
Warning lamp ................................. 320
6Index

Coolbox.............................................. 339
Cooling
see Climate control
Copyright ............................................ .31
Cornering light function
Display message ............................ 291
Function/notes ............................ .132
Crash-responsive emergency light-
ing ....................................................... 135
Crosswind Assist (vehicles with
MAGIC BODY CONTROL) ................... 210
Crosswind Assist (vehicles with-
out MAGIC BODY CONTROL) ...............75
Cruise control
Calling up the speed last stored .... 198
Cruise control lever ....................... 197
Deactivating ................................... 199
Display message ............................ 305
Driving system ............................... 197
Function/notes ............................. 197
General notes ................................ 197
Important safety notes .................. 197
Setting a speed .............................. 198
Storing and maintaining current
speed ............................................. 198
Cup holder
Center console .............................. 331
Important safety notes .................. 330
Rear compartment ......................... 331
Temperature controlled ................. 332
Cushion air bags .................................. 53
Customer Assistance Center
(CAC) ..................................................... 29
Customer Relations Department ....... 29
D
Data
see Technical data
Data carrier
Selecting ........................................ 266
Daytime running lamps
Display message ............................ 293
Function/notes ............................. 130
Switching on/off (on-board com-
puter) ............................................. 274
Declarations of conformity ................. 28
Diagnostics connection ...................... 28Digital speedometer
......................... 263
DIRECT SELECT lever
Automatic transmission ................. 170
Display
see Display messages
see Warning and indicator lamps
Display message
Hybrid drive system ....................... 297
Display messages
ASSYST PLUS ................................ 357
Calling up (on-board computer) ..... 277
Driving systems ............................. 299
Engine ............................................ 294
General notes ................................ 277
Hiding (on-board computer) ........... 277
Introduction ................................... 277
Lights ............................................. 291
Safety systems .............................. 278
SmartKey ....................................... 312
Tires ............................................... 306
Vehicle ........................................... 308
Distance recorder
see Odometer
see Trip odometer
Distance warning (warning lamp) .... 322
Distance warning function
Function/notes ................................ 71
DISTRONIC PLUS
Activating ....................................... 201
Activation conditions ..................... 201
Cruise control lever ....................... 201
Deactivating ................................... 205
Display message ............................ 303
Displays in the instrument cluster .. 204
Driving tips .................................... 205
Driving with DISTRONIC PLUS ....... 202
Function/notes ............................. 199
Important safety notes .................. 200
Setting a speed .............................. 203
Setting the specified minimum
distance ......................................... 204
Stopping ........................................ 203
with Steering Assist and Stop&Go
Pilot ............................................... 207
Doors
Automatic locking (switch) ............... 87
Central locking/unlocking
(SmartKey) ....................................... 79
Index7

Useful information
i
This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
iRead the information on qualified specialist
workshops (Ypage 28).
Overview of climate control systems
General notes
Observe the settings recommended on the fol-
lowing pages. The windows could otherwise fog
up.
To prevent the windows from fogging up:
Rswitch off climate control only briefly
Rswitch on air-recirculation mode only briefly
Rswitch on the cooling with air dehumidifica-
tion function
Rswitch on the defrost windshield function
briefly, if required
Climate control regulates the temperature and
air humidity in the vehicle interior. The air filter
cleans the air, thus improving the interior cli-
mate.
For vehicles with a combustion engine, the
"Cooling with air dehumidification" function is
only available when the engine is running. For
hybrid vehicles, the "Cooling with air dehumidi-
fication" function is also available via the elec-
tric refrigerant compressor when the engine is
not running. Optimum climate control is only
achieved with the side windows and roof closed.
If you start the engine using your smartphone,
the last selected climate control setting is reac-
tivated (
Ypage 164).
The residual heat function can only be activated
or deactivated with the ignition switched off
(
Ypage 152).
iVentilate the vehicle for a brief period during
warm weather, e.g. using the convenience
opening feature (
Ypage 95). This will speed
up the cooling process and the desired inte- rior temperature will be reached more
quickly.
iThe integrated filter filters out most parti-
cles of dust and soot and completely filters
out pollen. It also reduces gaseous pollutants
and odors. A clogged filter reduces the
amount of air supplied to the vehicle interior.
For this reason, you should always observe
the interval for replacing the filter, which is
specified in the Maintenance Booklet. As it
depends on environmental conditions, e.g.
heavy air pollution, the interval may be
shorter than stated in the Maintenance Book- let.
iIt is possible that the blower may be activa-
ted automatically 60 minutes after the Smart-
Key has been removed depending on various
factors, e.g. the outside temperature. The
vehicle is then ventilated for 30 minutes to dry
the climate control system.
140Overview of climate control systems
Climate control

Canada only
Front control panel
:Sets climate control to automatic, left (Ypage 147)
;Sets the temperature, left (Ypage 148)
=Sets the airflow, left (Ypage 150)
?Switches air-recirculation mode on/off (Ypage 152)
ADefrosts the windshield (Ypage 151)
BCalls up the climate control menu of the multimedia system (see separate operating instruc-
tions)
CSwitches the rear window defroster on/off (Ypage 151)
DSwitches cooling with air dehumidification on/off (Ypage 146)
Switches the residual heat on or off (
Ypage 152)
ESets the airflow, right (Ypage 150)
FSets the temperature, right (Ypage 148)
GSets climate control to automatic, right (Ypage 147)
Rear control panel (vehicles with rear-compartment climate control)
HSets the temperature, left (Ypage 148)
ISets the air distribution, left (Ypage 149)
JSets climate control to automatic (Ypage 147)
KSets the airflow (Ypage 150)
LActivates/deactivates climate control (Ypage 145)
Switches the residual heat on or off (
Ypage 152)
MSets the air distribution, right (Ypage 149)
NSets the temperature, right (Ypage 148)
142Overview of climate control systems
Climate control

XTurn the SmartKey to position2in the ignition
lock (Ypage 162).
XTo activate: press thetor! rocker
switch up or down.
The climate control menu opens.
XSelect "Rear adjustment" in the air-condition-
ing setting bar (see the separate operating
instructions).
You can control the rear-compartment cli-
mate control using the front control panel or
via the multimedia system.
XActivate rear-compartment climate control
via the air-conditioning setting bar.
XTo deactivate: press thetor!
rocker switch up or down.
The climate control menu opens.
XSelect "Rear adjustment" in the air-condition- ing setting bar (see the separate operating
instructions).
XDeactivate rear-compartment climate control
via the air-conditioning setting bar.
Activating/deactivating rear-compart-
ment climate control using the rear con-
trol panel
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XTo activate: press rocker switch Lup or
down (Ypage 141).
The indicator lamp in rocker switch Lgoes
out. All settings are displayed in full in the
rear-compartment display.
XTo deactivate: press rocker switch Lup or
down (Ypage 141).
The indicator lamp in rocker switch Llights
up. OFF is displayed in the rear-compartment
display.
Switching cooling with air dehumidi-
fication on/off
General notes
If you deactivate the "Cooling with air-dehumid-
ification" function, the air inside the vehicle will
not be cooled. The air inside the vehicle will also
not be dehumidified. The windows can fog up
more quickly. Therefore, deactivate the cooling
with air-dehumidification function only briefly. For vehicles with a combustion engine, the
"Cooling with air dehumidification" function is
available when the engine is running. For hybrid
vehicles, the "Cooling with air dehumidification"
function is also available via the electric refrig-
erant compressor when the engine is not run-
ning. The air inside the vehicle is cooled and
dehumidified according to the temperature
selected.
Condensation may drip from the underside of
the vehicle when it is in cooling mode. This is
normal and not a sign that there is a malfunc-
tion.
Switching on/off
XTo activate: press theÁrocker switch up
or down.
The indicator lamp above the rocker switch
lights up.
or
XActivate the "Cooling with air dehumidifica-
tion" function via the multimedia system (see
the separate operating instructions).
XTo deactivate: press theÁrocker switch
up or down.
The indicator lamp above the rocker switch
goes out.
or
XDeactivate the "Cooling with air dehumidifi-
cation" function via the multimedia system
(see the separate operating instructions).
146Operating the climate control systems
Climate control

Problems with the "Cooling with air dehumidification" function
ProblemPossible causes/consequences andMSolutions
The indicator lamp in the
Ábutton flashes
three times or remains
off. Cooling with air
dehumidification can
also no longer be activa-
ted using the multimedia
system (see the sepa-
rate operating instruc-
tions).Cooling with air dehumidification has been deactivated due to a mal-
function.
XVisit a qualified specialist workshop.
Setting climate control to automatic
General notes
In automatic mode, the set temperature is main-
tained automatically at a constant level. The
system automatically regulates the temperature
of the dispensed air, the airflow and the air dis-
tribution.
The "Cooling with air dehumidification" function
is activated automatically in automatic mode.
Controlling front climate control auto-
matically using the front control panel
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XSet the desired temperature using the w
rocker switch on the front control unit.
or
XSet the desired temperature using the multi-
media system (see the separate operating
instructions).
XTo activate: press rocker switch Ãup or
down.
The indicator lamp in the Ãrocker switch
lights up.
XTo switch to manual operation: press the
K rocker switch up or down.
or
XSet the airflow using the multimedia system
(see the separate operating instructions).
or
XSet the airflow using the multimedia system
(see the separate operating instructions).
The indicator lamp in the Ãrocker switch
goes out. In automatic mode, if you adjust the airflow or
air distribution manually, the indicator lamp on
the
à rocker switch goes out. The function
which has not been changed manually, however, continues to be controlled automatically. When
the manually set function switches back to auto-
matic mode, the indicator lamp on the Ã
rocker switch lights up again.
Controlling rear-compartment climate
control automatically using the front
control panel
Observe the notes on controlling the rear-com-
partment climate control using the front control
panel (
Ypage 145).
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XPress the tor! rocker switch up or
down.
The climate control menu opens.
XSelect "Rear adjustment" in the air-condition-
ing setting bar (see the separate operating
instructions).
You can control the rear-compartment cli-
mate control using the front control panel or
the multimedia system.
XSet the desired temperature using the w
rocker switch on the front control unit.
or
XSet the desired temperature using the multi-
media system (see the separate operating
instructions).
Operating the climate control systems147
Climate control

Problems with the rear window defroster
ProblemPossible causes/consequences andMSolutions
The rear window
defroster has deactiva-
ted prematurely or can-
not be activated.The battery has not been sufficiently charged.
XSwitch off any consumers that are not required, e.g. reading lamps,
interior lighting or the seat heating.
When the battery is sufficiently charged, the rear window defroster
can be activated again.
Switching air-recirculation mode
on/off
General notes
You can also temporarily deactivate the flow of
fresh air manually if unpleasant odors are enter-
ing the vehicle from outside. The air already
inside the vehicle will then be recirculated.
If you switch on air-recirculation mode, the win-
dows can fog up more quickly, in particular at
low temperatures. Only use air-recirculation
mode briefly to prevent the windows from fog-
ging up.
Activating/deactivating
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XTo activate: press thegrocker switch up
or down.
The indicator lamp in the grocker switch
lights up.
Air-recirculation mode switches on automati-
cally:
Rat high outside temperatures
Rat high levels of pollution
Rin a tunnel
The indicator lamp in the grocker switch is
not lit when automatic air-recirculation mode is
activated. Outside air is added after about
30 minutes.
XTo deactivate: press thegrocker switch
up or down.
The indicator lamp in the grocker switch
goes out. Air-recirculation mode deactivates automati-
cally:
Rafter approximately five minutes at outside
temperatures below approximately 41 ‡
(5 †)
Rafter approximately five minutes if cooling
with air dehumidification is deactivated
Rafter approximately 30 minutes at outside
temperatures above approximately 41 ‡
(5 †) if the "Cooling with air dehumidifica-
tion" function is activated
Switching the residual heat on or off
General notes
Vehicles with rear-compartment climate
control: once the engine is switched off, it is
possible to make use of the residual heat of the
engine to continue heating or ventilating the
rear and front compartment of the vehicle for
approximately 15 minutes. If the "Residual heat"
function is set for only the front or only the rear compartment, it is possible to continue heating
or ventilating for approximately 30 minutes.
Vehicles without rear-compartment climate
control: once the engine is switched off, it is
possible to make use of the residual heat of the
engine to continue heating or ventilating the
front compartment of the vehicle for approx-
imately 30 minutes.
The heating or ventilation time depends on the
temperature that has been set.
152Operating the climate control systems
Climate control

XTo activate pre-entry climate control via
SmartKey:unlock the vehicle with the Smart-
Key or KEYLESS-GO.
The climate control functions are activated
for up to 5 minutes for pre-heating and pre-
cooling.
To deactivate "Pre-entry climate control via SmartKey": "Pre-entry climate control via
SmartKey" switches off automatically when the
engine is started.
The following functions remain active after the
engine is started:
RSeat heating (heating)
RSeat ventilation (ventilation)
RArmrest heating
RPerfume atomizer
RIonization
An activated "Pre-entry climate control via
SmartKey" function can be deactivated using
the rocker switch (
Ypage 158).
156Operating the climate control systems
Climate control

these will be activated together with the "Pre-
entry climate control at departure time".
Activating the perfume atomizer or ionization
(see separate operating instructions).
Setting the departure time
You can set the departure time using the on-
board computer or via the My Mercedes Electric
– Vehicle Homepage. The activation of the "Pre-
entry climate control at departure time" func-
tion can be linked to this departure time. Your
vehicle will then be cooled or heated until the
desired temperature is reached in time for the
set departure time. "Pre-entry climate control at departure time" will be activated a maximum of
55 minutes before departure. If the departure is
delayed, the vehicle will be heated or cooled for
another five minutes.
XTo set the departure time: set the departure
time using the on-board computer
(
Ypage 272). Set the departure time via the
My Mercedes Electric – Vehicle Homepage
(
Ypage 189).
XTo activate or deactivate "Pre-entry cli-
mate control at departure time": activate
or deactivate "Pre-entry climate control at
departure time" via the multimedia system
(see the separate operating instructions).
Activate or deactivate "Pre-entry climate con-
trol at departure time" via the My Mercedes
Electric – Vehicle Homepage (
Ypage 189).
When activating the "Pre-entry climate control
at departure time" function: you can sele ct
w

hether only the driver's area or the whole vehi-
cle interior should be heated or cooled.
The "Pre-entry climate control at departure
time" function switches off automatically when
the vehicle is started. The following functions
remain active:
RSeat heating
RSeat ventilation
RArmrest heating
RSteering wheel heating
RPerfume atomizer
RIonization
Switching off "Pre-entry climate control at
departure time": the activated "Pre-entry cli-
mate control at departure time" can be switched
off using the rocker switch (
Ypage 158).
Activating or deactivating "Immediate
pre-entry climate control" using the
rocker switch
You can activate "Immediate pre-entry climate
control" even if the vehicle interior is already at
the desired temperature. This means that the
vehicle interior continues to be cooled or
heated, e.g. if the journey is interrupted for up to 50 minutes, and the interior temperature is kept
constant.
XTo activate or deactivate "Immediate pre-
entry climate control": press rocker
switch :up or down.
The blue or red indicator lamp on the rocker
switch lights up or goes out.
The colors of the indicator lamps on rocker
switch :have the following meanings:
Rblue: cooling activated
Rred: heating activated
Ryellow: departure time is preselected
Setting the air vents
Important safety notes
GWARNING
Very hot or very cold air can flow from the air
vents. This could result in burns or frostbite in
the immediate vicinity of the air vents. There
is a risk of injury.
Make sure that all vehicle occupants always
maintain a sufficient distance to the air out-
lets. If necessary, redirect the airflow to
another area of the vehicle interior.
158Setting the air vents
Climate control