hood open MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

High-voltage batteryBattery care ................................... 182
Charging (charging station) ............ 186
Charging (mains socket) ................1 83
Charging (wallbox) ......................... 185
Charging cable warming ................ 182
Cruise range .................................. 182
Energy consumption ......................1 82
General notes .................................. 43
Method of operation ......................1 81
Outside temperatures .................... 182
Overvoltage protection .................. 182
Problems with the charging proc-
ess ................................................. 187
Terms of use .................................. 182
Vehicle fire ....................................... 43
Hill start assist .................................. 165
HOLD function
Activating ....................................... 209
Activation conditions ..................... 209
Deactivating ................................... 209
Display message ............................ 303
Function/notes .............................2 08
General notes ................................ 208
Hood
Closing ...........................................3 53
Display message ............................ 310
Important safety notes .................. 352
Opening ......................................... 352
Horn ...................................................... 32
HUD
see Head-up display
Hybrid drive system
Automatic switch off ........................ 42
Danger of electric shock .................. 42
Display message ............................ 297
General notes .................................. 42
High-voltage battery ........................ 43
Important safety notes .................... 42
Manual switch off ............................ 42
Opening the hood ............................ 43
Warning lamp ................................. 315
Hybrid vehicles
Important safety notes .................... 42
Hydroplaning ..................................... 196I
Ignition lock
see Key positions
Immobilizer .......................................... 78
Indicator and warning lamps
COLLISION PREVENTION ASSIST
PLUS .............................................. 322
Indicator lamps
see Warning and indicator lamps
Indicators
see Turn signals
Instrument cluster
Overview .......................................... 33
Warning and indicator lamps ........... 34
Instrument cluster lighting .............. 256
Interior lighting
Control ...........................................1 35
Emergency lighting ........................ 135
Overview ........................................ 134
Reading lamp ................................. 134
J
Jack
Using ............................................. 406
Jump starting (engine) ......................376
K
Key positions
SmartKey ....................................... 162
Start/Stop button .......................... 162
KEYLESS-GO
Convenience closing feature ............ 96
Deactivation ..................................... 80
Locking ............................................ 80
Start function ................................... 81
Unlocking ......................................... 80
Kickdown
Driving tips ....................................1 73
Knee bag .............................................. 52
L
Lamps
see Warning and indicator lamps
Lane Keeping Assist
see Active Lane Keeping Assist
Index11

Cockpit
FunctionPage
:Steering wheel paddle shift-
ers174
;Combination switch131
=Horn
?Instrument cluster33
ADIRECT SELECT lever170
BOverhead control panel39
CControl panel for:
ÜLowering the rear seat
head restraints116
u Extending/retracting
the rear roller sunblind334
PASSENGER AIR BAG indica-
tor lamp46
Adjusting the brightness of
the instrument lighting and
the multimedia system dis-
play
DIgnition lock162
Start/Stop button162
FunctionPage
EClimate control systems140
FAdjusts the steering wheel120
Steering wheel heating120
GCruise control lever197
HElectric parking brake190
IDiagnostics connection28
JOpening the hood352
KLight switch130
LControl panel for:
Activating Steering Assist
and Stop&Go Pilot207
Switching on Active Lane
Keeping Assist237
Deactivating PARKTRONIC214
Switching on the 360° cam-
era224
Activating Night View Assist230
Switching on the head-up
display259
32Cockpit
At a glance

Deactivate the hybrid system manually if:
Rthe6 restraint system warning lamp in the
instrument cluster lights up after an accident
Rthe vehicle is badly damaged, e.g. after an
accident, and the restraint system compo-
nents were not activated
Rthe vehicle is badly damaged and has to be
towed or transported
XIf possible, move the vehicle out of the
danger zone: shift the automatic transmis-
sion into position N.
XRelease the electric parking brake.
XRoll the vehicle to a safe place and park it
safely.
Get assistance from others if necessary.
iThe vehicle is locked automatically when
the ignition is switched on and the wheels are
turning. There is therefore a risk of being
locked out if the vehicle is being pushed or
tested on a dynamometer.
XSwitch the ignition off.
XShift the automatic transmission to park posi-
tion P(Ypage 170).
Depress the electric parking brake
(
Ypage 190).
Secure the vehicle against rolling away
(
Ypage 406).
XTo use the high-voltage switch-off device:
open the trunk lid.
XLift the trunk floor upwards (Ypage 329).
XRemove the right-hand paneling in the trunk.
XPress release clip :in the direction of the
arrow and pull it out.
XPull the high voltage switch-off device ;
apart until it engages in the stop position.
If the hybrid drive system has been deactivated
due to reasons mentioned above, have it checked at a qualified specialist workshop
before reactivation.
High-voltage battery
GWARNING
In the event of a vehicle fire, the internal pres- sure of the high-voltage battery can exceed a
critical value. In this case flammable gas
escapes through a ventilation valve on the
underbody. The gas can ignite. There is a risk
of injury.
Leave the danger zone immediately. Secure
the danger area at a suitable distance, whilst
observing legal requirements.
GWARNING
If the housing of the high-voltage battery has
been damaged, electrolyte and gases may
leak out. These are poisonous and caustic.
There is a risk of injury.
Avoid contact with skin, eyes or clothing.
Immediately rinse electrolyte splashes off
with water and seek medical attention
straight away.
!Exhaustive discharge caused by the vehicle
standing idle for lengthy periods can damage
the high-voltage battery.
Hybrid vehicles: if the vehicle is idle for
lengthy periods, run it for a few minutes once every six weeks to charge up the high-voltage
battery. During the charging process, switch
off all electrical consumers, e.g. the auto-
matic climate control or the seat heating.
PLUG-IN HYBRID vehicles: make sure that
the high-voltage battery is connected to a
charging station during long periods when the
vehicle is standing idle.
PLUG-IN HYBRID vehicles: charging the high-
voltage battery (
Ypage 180).
Engine compartment
Before opening the hood:
XApply the electric parking brake.
XShift the automatic transmission to park posi-
tion P.
XSwitch the ignition off.
Hybrid vehicles43
Safety
Z

Protection against theft
Immobilizer
The immobilizer prevents your vehicle from
being started without the correct SmartKey.
XTo activate with the SmartKey:remove the
SmartKey from the ignition lock.
XTo activate with KEYLESS-GO: switch the
ignition off and open the driver's door.
XTo deactivate: switch on the ignition.
When leaving the vehicle, always take the
SmartKey with you and lock the vehicle. Anyone
can start the engine if a valid SmartKey has been
left inside the vehicle.
iThe immobilizer is always deactivated when
you start the engine.
In the event that the engine cannot be started
(yet the vehicle's battery is charged), the sys-
tem is not operational. Contact an authorized
Mercedes-Benz Center or call
1-800-FOR-MERCedes (in the USA) or
1-800-387-0100 (in Canada).
ATA (anti-theft alarm system)
XTo arm: lock the vehicle with the SmartKey or
KEYLESS-GO.
Indicator lamp :flashes. The alarm system
is armed after approximately 10 seconds.
XTo disarm: unlock the vehicle with the Smart-
Key or KEYLESS-GO.
or
XInsert the SmartKey into the ignition lock.
A visual and audible alarm is triggered if the
alarm system is armed and you open:
Ra door
Rthe vehicle with the mechanical key
Rthe trunk lid
Rthe hood
XTo turn the alarm off with the SmartKey:
press the %or& button on the Smart-
Key.
The alarm is switched off.
or
XRemove the Start/Stop button from the igni-
tion lock.
XInsert the SmartKey into the ignition lock.
The alarm is switched off.
XTo stop the alarm using KEYLESS-GO:
grasp the outside door handle. The SmartKey
must be outside the vehicle.
The alarm is switched off.
or
XPress the Start/Stop button on the dash-
board. The SmartKey must be inside the vehi-
cle.
The alarm is switched off.
The alarm is not switched off, even if you close
the open door that triggered it, for example.
iIf the alarm continues for more than
30 seconds, the mbrace emergency call sys-
tem automatically notifies the Customer
Assistance Center. This is done either by text message or data connection.
The emergency call system sends a message
or establishes a data connection provided
that:
Ryou have subscribed to the mbrace service.
Rthe mbrace service has been activated
properly.
Rthe necessary mobile phone network is
available.
78Protection against theft
Safety

For this reason, you should always switch off
the windshield wipers in dry weather.
1$Windshield wiper off
2ÄIntermittent wipe, low (rain sensor set
to low sensitivity)
3Å Intermittent wipe, high (rain sensor
set to high sensitivity)
4° Continuous wipe, slow
5¯Continuous wipe, fast
BíSingle wipe/î to wipe the wind-
shield using washer fluid
XSwitch on the power supply with the Start/
Stop button or the SmartKey (Ypage 162).
XTurn the combination switch to the corre-
sponding position.
In the ÄorÅ position, the appropriate
wiping frequency is set automatically according
to the intensity of the rain. In the Åposition,
the rain sensor is more sensitive than in
the Ä position, causing the windshield wip-
ers to wipe more frequently.
Vehicles with MAGIC VISION CONTROL: the
washer fluid is fed through the wiper blades and
when wiping with washer fluid îthe washer
fluid is emitted directly from the blades.
Vehicles with MAGIC VISION CONTROL: if you
push and hold the combination switch beyond
the point of resistance in the direction of arrow
B, the manual wash program is activated. If you briefly push and hold the combination switch
beyond the point of resistance in the direction of
arrow B, the automatic wash program is acti-
vated.
If the wiper blades are worn, the windshield will
no longer be wiped properly. This could prevent
you from observing the traffic conditions.
Replacing the wiper blades
Important safety notes
GWARNING
If the windshield wipers begin to move while
you are changing the wiper blades, you could be trapped by the wiper arm. There is a risk of
injury.
Always switch off the windshield wipers and
ignition before changing the wiper blades.
!To avoid damaging the wiper blades, make
sure that you touch only the wiper arm of the
wiper.
!Never open the hood if a windshield wiper
arm has been folded away from the wind-
shield.
Hold the windshield wiper arm firmly when
you change the wiper blade. If you release the
windshield wiper arm without a wiper blade
and it falls onto the windshield, the windshield
may be damaged by the force of the impact.
Mercedes-Benz recommends that you have
the wiper blades changed at a qualified spe-
cialist workshop.
!Always position the windshield wiper arms
vertically before folding them away from the
windshield. By doing so, you will avoid dam-
age to the hood.
Replacing the wiper blades (standard
windshield wipers)
Moving the wiper arms to a vertical posi-
tion
On vehicles without KEYLESS-GO:
XTurn the SmartKey to position 0in the ignition
lock (Ypage 162).
XSet the windshield wiper to the °position.
XTurn the SmartKey to position 1in the ignition
lock (Ypage 162).
XAs soon as the wiper arms are vertical to the
hood, turn the SmartKey to position 0in the
ignition lock (
Ypage 162).
XRemove the SmartKey.
XFold the wiper arms away from the windshield
until you feel them snap into place.
136Windshield wipers
Lights and windshield wipers

In order to ensure the direct flow of fresh air
through the air vents into the vehicle interior,
please observe the following notes:
Rkeep the air inlet between the windshield and
the hood free of blockages, such as ice, snow
or leaves.
Rnever cover the air vents or air intake grilles in
the vehicle interior.
Setting the center air vents
:Fixed center air vent
;Center air vent, right
=Center vent control, right
?Center vent control, left
ACenter air vent, left
XTo open/close: press control=or?.
The control pops out.
XTurn control =or? counter-clockwise or
clockwise.
XTo adjust the air direction: hold rear air
vent ;orA by the middle fin and move up or
down or to the left or right.
Setting the side air vents
:Side window defroster vent
;Side air vent
=Control for left side air vent
XTo open/close: press control=.
The control pops out.
XTurn control =counter-clockwise or clock-
wise.
XTo adjust the air direction: hold side air
vent ;by the middle fin and move it up or
down or to the left or right.
Setting the glove box air vent
!
Close the air vent when heating the vehicle.
At high outside temperatures, open the air
vent and activate the "cooling with air dehu-
midification" function. Otherwise, tempera-
ture-sensitive items stored in the glove box
could be damaged.
When the climate control system is activated,
the glove box can be ventilated, for instance to
cool its contents. The level of airflow depends on
the airflow and air distribution settings.
:Air vent control
;Air vent
Setting the air vents159
Climate control
Z

previously selected climate control setting is
activated. In this way you can cool or heat the
interior of the vehicle before starting the jour-
ney.
Only start the engine via your smartphone if it is
safe to start and run the engine where your vehi-
cle is parked.
Observe the legal stipulations in the area where
your vehicle is parked. Engine start via smart-
phone may be limited to certain countries or
regions.
You can execute a maximum of two consecutive
starting attempts via your smartphone. If you
insert the SmartKey into the ignition lock, you
can carry out two more starting attempts.
Once you have started the engine, you can
switch the engine off via your smartphone at any
time.
You can only start the engine via your smart-
phone if:
Rthe SmartKey is in the ignition lock
Rpark positionPis selected
Rthe accelerator pedal is not depressed
Rthe anti-theft alarm system is not activated
Rthe panic alarm is not activated
Rthe hazard warning lamps are switched off
Rthe hood is closed.
Rthe doors are closed and locked
Rthe windows and sliding sunroof are closed
Also make sure that:
Rthe fuel tank is sufficiently filled
Rthe starter battery is sufficiently charged
GWARNING
Limbs could be crushed or trapped if the
engine is started unintentionally during ser-
vice or maintenance work. There is a risk of
injury.
Always secure the engine against uninten-
tional starting before carrying out mainte-
nance or repair work.
Make sure that the engine cannot be started via
your smartphone before carrying out mainte-
nance or repairs. You can prevent an engine
start via your smartphone, for example, if you:
Rswitch on the hazard warning lamps
Rdo not lock the doors
Ropen the hood
Pulling away
General notes
GWARNING
If the engine speed is above the idling speed
and you engage transmission position Dor R,
the vehicle could pull away suddenly. There is
a risk of an accident.
When engaging transmission position Dor R,
always firmly depress the brake pedal and do not simultaneously accelerate.
Depress the accelerator carefully when pulling
away.
The vehicle locks centrally once you have pulled
away. The locking knobs in the doors drop down.
You can open the doors from the inside at any
time.
You can also deactivate the automatic locking
feature (
Ypage 87).
It is only possible to shift the transmission from
position Pto the desired position if you depress
the brake pedal. Only then is the parking lock
released.
If you do not depress the brake pedal, the
DIRECT SELECT lever can still be moved but the
parking lock remains engaged.
iUpshifts take place at higher engine speeds
after a cold start. This helps the catalytic con-
verter to reach its operating temperature
more quickly.
Information on the automatic release of the
electric parking brake (
Ypage 191).
Hill start assist
Hill start assist helps you when pulling away for-
wards or in reverse on an uphill gradient. It holds
the vehicle for a short time after you have
removed your foot from the brake pedal. This
gives you enough time to move your foot from
the brake pedal to the accelerator pedal and to
depress it before the vehicle begins to roll.
GWARNING
After a short time, hill start assist will no lon-
ger brake your vehicle and it could roll away.
There is a risk of an accident and injury.
Driving165
Driving and parking
Z

Outside temperature display
You should pay special attention to road condi-
tions when temperatures are around freezing
point.
Bear in mind that the outside temperature dis-
play indicates the temperature measured and
does not record the road temperature.
The outside temperature display is in the multi-function display (
Ypage 258).
There is a short delay before a change in outside
temperature is shown in the multifunction dis-
play.
Coolant temperature display
GWARNING
Opening the hood when the engine is over-
heated or when there is a fire in the engine
compartment could expose you to hot gases
or other service products. There is a risk of
injury.
Let an overheated engine cool down before
opening the hood. If there is a fire in the
engine compartment, keep the hood closed
and contact the fire department.
!A display message is shown if the coolant
temperature is too high.
If the coolant temperature is above 257 ‡
(125 †) do not drive any further. The engine
will otherwise be damaged.
All vehicles except PLUG‑ IN HYBRID vehicles:
the coolant temperature gauge is in the lower
area of the tachometer (
Ypage 33).
PLUG-IN HYBRID vehicles: the multifunction dis-
play shows the coolant temperature in the
Coolant
submenu (Ypage 269).
Under normal operating conditions and with the
specified coolant level, the coolant temperature
may rise to 255 ‡ (124 †).
Operating the on-board computer
:Multifunction display
;Right control panel
=Left control panel
XTo activate the on-board computer: turn
the SmartKey to position 1in the ignition lock.
You can control the multifunction display and
the settings in the on-board computer using the
buttons on the multifunction steering wheel.
Left control panel
òROpens the menu list
9
:Press briefly:
RScrolls in lists
RSelects a menu or function
RIn the RadioorMediamenu:
opens the track or station list and
selects a station, an audio track or
a video scene
RIn the Telephonemenu: switches
to the phone book and selects a
name or a telephone number
9
:Press and hold:
RScrolls quickly through all lists
RIn the RadioorMediamenu:
selects a station, audio track or
video scene using rapid scrolling
RIn the Telephonemenu: starts
rapid scrolling if the phone book is
open
Displays and operation257
On-board computer and displays
Z

Engine
Display messagesPossible causes/consequences andMSolutions
+
CheckCoolantLevelSee Operator's Man‐ual
The coolant level is too low.
!Avoid making long journeys with too little coolant in the engine
cooling system. The engine will otherwise be damaged.
XAdd coolant, observing the warning notes before doing so
(Ypage 356).
If you have to add coolant frequently:
XContact a qualified specialist workshop and have the engine cooling
system checked.
?The fan motor is faulty.
XAt coolant temperatures below 257 ‡(125 †), drive to the nearest
qualified specialist workshop.
XAvoid heavy loads on the engine as you do so, e.g. driving in moun-
tainous terrain and stop-start traffic.
?
Coolant Too HotStop Vehicle TurnEngine Off
The coolant is too hot.
A warning tone also sounds.
GWARNING
Do not drive when your engine is overheated. This can cause some
fluids which may have leaked into the engine compartment to catch
fire.
Steam from the overheated engine can also cause serious burns which
can occur just by opening the hood.
There is a risk of injury.
XPull over and stop the vehicle safely and switch off the engine, pay- ing attention to road and traffic conditions.
XSecure the vehicle against rolling away (Ypage 189).
XWait until the engine has cooled down.
XMake sure that the air supply to the engine radiator is not blocked,e.g. by snow, slush or ice.
XDo not start the engine again until the display message goes out and
the coolant temperature is below 257 ‡ (125 †). Otherwise, the
engine could be damaged.
XPay attention to the coolant temperature display.
If the temperature increases again:
XVisit a qualified specialist workshop immediately.
Under normal operating conditions and with the specified coolant
level, the coolant temperature may rise to 255 ‡ (124 †).
294Display messages
On-board computer and displays

Display messagesPossible causes/consequences andMSolutions
MThe hoodis open . Awarning tone also sounds.
GWARNIN G
The open hoo dmay bloc kyour vie wwhen th evehicl eis in motion .
There is aris kof an accident.
XPull ove rand stop th evehicl esafely as soo nas possible, payin g
attention to roa dand traffic conditions.
XSecur eth evehicl eagainst rollin gaway (Ypage 189).
XCloseth ehood.
CAt least on edoor is open . Awarning tone also sounds.
XClos eall th edoors.
To vie wthe ext .mirror,adjustfront-passengersea tor remove thehea drestraint .
The front-passenger seat is in th echauffeur mod eposition and th e
head restrain tis folded down .
GWARNING
If th efront-passenger seat is th echauffeur mod eposition and th e
head restrain tis folded down ,th evie wof th efront-passenger exterio r
mirror can be impaired.
There is aris kof an accident.
XRemove th ehead restrain ton th efront-passenger seat
(Ypage 113).
or
XMov eth efront-passenger seat bac kint oth enormal position
(Ypage 111).
Front-PassengerSea tCannotBeUsedVisit Workshop
RThe front-passenger seat canno tbe moved from th echauffeur
mod eposition int oth enormal position .There is amalfunction .
RThe frontpassenger head restrain tis folded down and can no longer
be folded up. There is amalfunction .
GWARNING
If head restraints are no tadjusted correctly, they canno tprovid epro -
tection as intended.
There is an increased ris kof injury in th ehead and neck area ,e.g. in
th eevent of an acciden tor when braking .
XDo notuse th efront-passenger seat .
XVisitaqualified specialist workshop immediately.
n
Before oper. front-pass. sea tfro mrear,deactiv.over‐ridefeature.
You hav eattempte dto adjust th efront-passenger seat from th erear
compartmen twhile th eoverride feature is activated.
XDeactivat eth eoverride feature for th erear side windows
(Ypage 67).
XAdjus tth efront-passenger seat from th erear (Ypage 108).
310Display messages
On-board computer and displays