open gas tank MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

F
Features............................................ .330
Filling capacities (Technical data) ... 427
Flat tire
Changing a wheel/mounting the
spare wheel ................................... 405
MOExtended tires .......................... 368
Preparing the vehicle ..................... 367
TIREFIT kit ...................................... 369
Floormats ...........................................3 50
Folding table ...................................... 328
Frequencies
Mobile phone ................................. 425
Two-way radio ................................ 425
Front-passenger seat
Adjusting from the driver's seat ..... 108
Adjusting from the rear compart-
ment .............................................. 108
Fuel
Additives ........................................ 429
Consumption statistics .................. 262
Displaying the current consump-
tion ................................................ 261
Displaying the range ......................2 61
Driving tips ....................................1 92
Fuel gauge ....................................... 33
Grade (gasoline) ............................ 428
Important safety notes .................. 428
Problem (malfunction) ................... 180
Refueling ........................................ 177
Tank content/reserve fuel ............. 428
Fuel level
Calling up the range (on-board
computer) ...................................... 261
Fuel tank
Capacity ........................................ 428
Problem (malfunction) ................... 180
Fuses
Allocation chart ..................... 381, 383
Before changing .............................3 82
Dashboard fuse box ....................... 382
Fuse box in the engine compart-
ment .............................................. 383
Fuse box in the front-passenger
footwell .......................................... 382
Fuse box in the trunk ..................... 383
Important safety notes .................. 381
G
Garage door opener
Clearing the memory ..................... 350
General notes ................................ 347
Important safety notes .................. 348
Opening/closing the garage door .. 350
Problems when programming ........3 49
Programming (button in the rear-
view mirror) ................................... 348
Synchronizing the rolling code ....... 349
Gasoline ............................................. 428
Gear indicator (on-board com-
puter, Mercedes-AMG vehicles) ....... 275
Genuine parts ...................................... 24
Glove box ...........................................3 26
H
Handbrake
see Parking brake
HANDS-FREE ACCESS .......................... 91
Hazard warning lamps ......................132
Head restraints
Adjusting ....................................... 114
Adjusting (manually) ......................1 15
Adjusting (rear) .............................. 116
EASY ADJUST luxury head
restraint ......................................... 115
Luxury ............................................ 115
Supplementary cushion ................. 116
Head-up display
Adjusting the brightness ................ 273
Displays and operating .................. 259
Function/notes .............................2 59
Important safety notes .................. 259
Selecting displays .......................... 273
Setting the position ....................... 273
Headlamps
Fogging up ..................................... 134
see Automatic headlamp mode
Heating
see Climate control
High beam flasher .............................1 32
High-beam headlamps
Adaptive Highbeam Assist PLUS .... 133
Display message ............................ 292
Switching on/off ........................... 132
10Index

and that it is not swallowed. Do not inhale fuelvapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
RWash away fuel from skin immediately
using soap and water.
RIf fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance with-
out delay.
RIf fuel is swallowed, seek medical assis-
tance without delay. Do not induce vomit-
ing.
RImmediately change out of clothing which
has come into contact with fuel.
GWARNING
Electrostatic buildup can create sparks and
ignite fuel vapors. There is a risk of fire and
explosion.
Always touch the vehicle body before opening
the fuel filler flap or touching the fuel pump
nozzle. Any existing electrostatic buildup is
thereby discharged.
Do not get into the vehicle again during the refu-
eling process. Otherwise, electrostatic charge
could build up again.
!Do not use diesel to refuel vehicles with a
gasoline engine. Do not switch on the ignition
if you accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel system. Even small amounts of the wrong fuel could
result in damage to the fuel system and the
engine. Notify a qualified specialist workshop
and have the fuel tank and fuel lines drained
completely.
!Overfilling the fuel tank could damage the
fuel system.
!Take care not to spill any fuel on painted
surfaces. You could otherwise damage the
paintwork.
!Use a filter when refueling from a fuel can.
Otherwise, the fuel lines and/or injection sys-
tem could be blocked by particles from the
fuel can. If you overfill the fuel tank, fuel could spray out
when the fuel pump nozzle is removed.
For further information on fuel and fuel quality
(
Ypage 428).
Refueling
General information
Pay attention to the important safety notes
(Ypage 177).
PLUG-IN HYBRID vehicles: pressure in the fuel
tank must be released before refueling.
Except PLUG-IN HYBRID vehicles: if you
unlock/lock the vehicle from the outside, the
fuel filler flap also unlocks/locks.
The position of the fuel filler cap is displayed in
the instrument cluster 8. The arrow next to
the filling pump indicates the side of the vehicle.
Preparing to refuel
XSwitch off the engine.
XOpen the driver's door.
The on-board electronics now have status 0.
This is the same as the SmartKey having been
removed.
or, if the SmartKey is inserted in the ignition
lock:
XRemove the SmartKey from the ignition lock.
Opening the fuel filler flap (except
PLUG-IN HYBRID vehicles)
:To open the fuel filler flap
;To insert the fuel filler cap
=Tire pressure table
?Fuel type to be used
178Refueling
Driving and parking

Problems with fuel and the fuel tank
ProblemPossible causes/consequences andMSolutions
Fuel is leaking from the
vehicle.GWARNING
The fuel line or the fuel tank is faulty.
Risk of explosion or fire.
XApply the electric parking brake.
XSwitch off the engine.
XMake sure that the ignition is switched off (Ypage 162).
or
XWhen using the SmartKey, turn the SmartKey to position 0in the
ignition lock and remove it (Ypage 162).
XDo not restart the engine under any circumstances.
XConsult a qualified specialist workshop.
The fuel filler flap cannot
be opened.The fuel filler flap is not unlocked.
XUnlock the vehicle (Ypage 79).
XPLUG-IN HYBRID Vehicles: depressurize the fuel tank
(Ypage 178).
The SmartKey battery is discharged or nearly discharged.
XUnlock the vehicle using the mechanical key (Ypage 81).
The fuel filler flap is unlocked, but the opening mechanism is jammed.
XConsult a qualified specialist workshop.
Charging the high-voltage battery
(PLUG-IN HYBRID vehicles)
Important safety notes
GDANGER
The vehicle's high-voltage electrical system is under high voltage. If you modify components
in the vehicle's high-voltage electrical system
or touch damaged components, you may be
electrocuted. The components in the vehi-
cle's high-voltage electrical system may be
damaged in an accident, although the damage
is not visible. There is a risk of fatal injury.
Following an accident, do not touch any high-
voltage components and never modify the
vehicle's high-voltage electrical system. Have
the vehicle towed away after an accident and
the vehicle's high-voltage electrical system
checked by a qualified specialist workshop.
GWARNING
In the event of a vehicle fire, the internal pres- sure of the high-voltage battery can exceed a
critical value. In this case flammable gas
escapes through a ventilation valve on the
underbody. The gas can ignite. There is a risk
of injury.
Leave the danger zone immediately. Secure
the danger area at a suitable distance, whilst
observing legal requirements.
GDANGER
If you use incorrectly installed mains sockets or adapters, extension cables or similar to
connect the charging cable to a mains socket,
this could lead to fires or an electric shock.
There is a risk of fatal injury.
180Charging the high-voltage battery (PLUG-IN HYBRID vehicles)
Driving and parking

Other identifications, for example:
R0 W-30
R5 W-30
R5 W-40
Fuel
Important safety notes
GWARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and explo-
sion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before refueling.
GWARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
RWash away fuel from skin immediately
using soap and water.
RIf fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance with-
out delay.
RIf fuel is swallowed, seek medical assis-
tance without delay. Do not induce vomit-
ing.
RImmediately change out of clothing which
has come into contact with fuel.
Tank capacity
Missing values were not available at time of
going to print.
ModelTotal capacity
S 400 4MATIC
PLUG-IN HYBRID vehi-
cles16.6 US gal (63.0 l)
Allot her models21.1 US gal
(80.0 l)
ModelOf which
reserve
S 400 4MATIC
Mercedes‑AMG vehiclesApprox.
3.2 US gal (12.0 l)
Allot her modelsApprox.
2.1 US gal (8.0 l)
Gasoline
Fuel grade
!Do not use diesel to refuel vehicles with a
gasoline engine. Do not switch on the ignition
if you accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel system.
Even small amounts of the wrong fuel could
result in damage to the fuel system and the
engine. Notify a qualified specialist workshop
and have the fuel tank and fuel lines drained
completely.
!Only refuel using unleaded premium grade
gasoline with at least 91 AKI/95 RON.
iE10 fuel contains up to 10% bioethanol.
Your vehicle is E10-compatible. You can
refuel your vehicle using E10 fuel.
!Only use the fuel recommended. Operating
the vehicle with other fuels can lead to engine
failure.
!Do not use the following:
RE15 (gasoline with 15% ethanol)
RE85 (gasoline with 85% ethanol)
RE100 (100% ethanol)
RM15 (gasoline with 15% methanol)
428Service products and filling capacities
Technical data