tow MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

Index....................................................... 3
Introduction......................................... 24
At a glance........................................... 32
Safety................................................... 42
Opening and closing...........................79
Seats, steering wheel and mirrors ..104
Lights and windshield wipers ..........130
Climate control ................................. 140
Driving and parking..........................161
On-board computer and displays ....256
Stowage and features ......................325
Maintenance and care ......................352
Breakdown assistance .....................367
Wheels and tires ............................... 384
Technical data................................... 425
2Contents

Brake Assistsee BAS (Brake Assist System)
Brake fluid
Display message ............................ 283
Notes ............................................. 430
Brake force distribution
see EBD (electronic brake force
distribution)
Brake lamps
Display message ............................ 291
Brake pedal
Pedal resistance/pedal travel .......... 44
Brakes
ABS .................................................. 68
Adaptive Brake Assist ...................... 72
BAS .................................................. 69
BAS PLUS with Cross-Traffic
Assist ............................................... 69
Brake fluid (notes) ......................... 430
Display message ............................ 278
EBD .................................................. 75
High-performance brake system .... 196
Hill start assist ............................... 165
HOLD function ............................... 208
Important safety notes .................. 194
Maintenance .................................. 195
Parking brake ................................ 190
RBS warning lamp .......................... 315
Recuperative Brake System ............. 44
Riding tips ...................................... 194
Warning lamp ................................. 315
Breakdown
Where will I find...? ........................ 367
see Flat tire
see Towing away
Brightness control (instrument
cluster lighting) ................................... 35
Buttons on the steering wheel ......... 257
C
California
Important notice for retail cus-
tomers and lessees .......................... 25
Calling up a malfunction
see Display messages
Camera
see 360° camera see Rear view camera
Car
see Vehicle
Care
360° camera ................................. 363
Car wash ........................................ 359
Carpets .......................................... 366
Display ........................................... 364
Exhaust pipe .................................. 363
Exterior lights ................................ 362
Gear or selector lever .................... 365
General notes ................................ 359
Interior ........................................... 364
Matte finish ................................... 361
Night View Assist Plus ................... 364
Paint .............................................. 361
Plastic trim .................................... 364
Power washer ................................ 360
Rear view camera .......................... 363
Roof lining ...................................... 366
Seat belt ........................................ 366
Seat cover ..................................... 365
Sensors ......................................... 362
Steering wheel ............................... 365
Trim pieces .................................... 365
Washing by hand ........................... 360
Wheels ........................................... 361
Windows ........................................ 362
Wiper blades .................................. 362
Wooden trim .................................. 365
CD player (on-board computer) ........ 266
Center console
Overview .......................................... 37
Stowage space .............................. 326
Center console in the rear com-
partment
Stowage compartment .................. 327
Central locking
Locking/unlocking (SmartKey) ........ 79
Changing the media source ............. 265
Charging
see Charging the high-voltage bat-
tery (important safety notes)
Charging cable
Connecting .................................... 185
Controls ......................................... 183
Important safety notes .................. 183
Indicator lamp ................................ 184
Index5

ECO displayFunction/notes ............................ .193
On-board computer ....................... 262
ECO start/stop function
Automatic engine start .................. 167
Automatic engine switch-off .......... 166
Deactivating/activating ................. 167
General information ....................... 166
Important safety notes .................. 166
Introduction ................................... 166
Electronic Stability Program
see ESP
®(Electronic Stability Program)
Emergency
Automatic measures after an acci-
dent ................................................. 61
Emergency release
Driver's door ....................................8 7
Trunk ............................................... 94
Vehicle ............................................. 87
Emergency Tensioning Devices
Activation ......................................... 57
Emissions control
Service and warranty information ....2 5
Engine
Check Engine warning lamp .......... .320
Display message ............................ 294
ECO start/stop function ................ 166
Engine number ............................... 427
Irregular running ............................ 169
Jump-starting ................................. 376
Starting (important safety notes) ... 164
Starting problems .......................... 169
Starting the engine with the
SmartKey ....................................... 164
Starting via smartphone ................ 164
Starting with the Start/Stop but-
ton ................................................. 164
Switching off .................................. 190
Switching off with the Start/Stop
button ............................................ 190
Switching off with the vehicle key .. 190
Tow-starting (vehicle) ..................... 381
Engine electronics
Problem (malfunction) ................... 169
Engine oil
Adding ...........................................3 55
Additives ........................................ 430
Checking the oil leve l ..................... 353 C
hecking the oil level using the
dipstick .......................................... 353
Checking the oil level using the
on-board computer ........................ 355
Display message ............................ 296
Filling capacity ............................... 430
General notes ................................ 429
Notes about oil grades ................... 429
Notes on oil level/consumption .... 353
Temperature (on-board computer,
Mercedes-AMG vehicles) ...............2 75
Viscosity ........................................ 430
ESP
®(Electronic Stability Pro-
gram)
AMG menu (on-board computer) ... 276
Characteristics ................................. 73
Deactivating/activating ................. 269
Deactivating/activating (notes) ....... 74
Display message ............................ 278
Function/notes ................................ 73
General notes .................................. 73
Important safety information ........... 73
Trailer stabilization ........................... 74
Warning lamp ................................. 317
ETS/4ETS (Electronic Traction Sys-
tem) ...................................................... 73
Exhaust
see Exhaust pipe
Exhaust check ................................... 193
Exhaust pipe
Cleaning ......................................... 363
Exhaustive discharging (high-volt-
age battery) ....................................... 374
Exterior lighting
Cleaning ......................................... 362
see Lights
Exterior mirrors
Adjusting ....................................... 123
Dipping (automatic) ....................... 124
Folding in/out (automatically) ....... 124
Folding in/out (electrically) ........... 124
Out of position (troubleshooting) ... 124
Setting ........................................... 124
Storing settings (memory func-
tion) ............................................... 126
Storing the parking position .......... 125
Eyeglasses compartment ................. 326
Index9

Starting .......................................... 249
When the vehicle is stationary ....... 251
Power locks ......................................... 87
Power washers .................................. 360
Power windows
see Side windows
Pre-entry climate control (via
SmartKey)
Problems (malfunctions) ................ 157
Pre-entry climate control at depar-
ture time
General notes ................................ 157
Pre-entry climate control at time of
departure
Setting departure time ................... 158
Pre-entry climate control via key
General notes ................................ 155
PRE-SAFE
®(anticipatory occupant
protection)
Display message ............................ 284
Operation ......................................... 59
PRE-SAFE
®Brake
Activating/deactivating ................. 271
Display message ............................ 284
Function/notes ................................ 75
Important safety notes .................... 76
Warning lamp ................................. 322
PRE-SAFE
®PLUS (anticipatory
occupant protection PLUS)
Display message ............................ 284
Operation ......................................... 60
Program selector button .................. 173
Protection against theft
ATA (Anti-Theft Alarm system) ......... 78
Immobilizer ...................................... 78
Protection of the environment
General notes .................................. 24
Pulling away
Automatic transmission ................. 165
General notes ................................ 165
Hill start assist ............................... 165
Q
QR codeMercedes-Benz Guide App ................. 1
Rescue card ..................................... 29
Qualified specialist workshop ........... 28
R
Radio
Selecting a station ......................... 265
Radio-wave reception/transmis-
sion in the vehicle
Declaration of conformity ................ 28
Rain closing feature
Panorama sliding sunroof ................ 99
RBS (Recuperative Brake System)
Warning lamp ................................. 315
Reading lamp ..................................... 134
Rear compartment
Activating/deactivating climate
control ........................................... 145
Setting the air distribution ............. 149
Setting the air vents ...................... 160
Setting the airflow ......................... 150
Setting the temperature ................ 148
Stowage compartment .................. 327
Rear lamps
see Lights
Rear seats
Adjusting ....................................... 107
Adjusting a rear reclining seat ....... 107
Overview .......................................... 41
Setting the reclined position .......... 107
Rear view camera
Cleaning instructions ..................... 363
Displays in the COMAND display ... 221
Function/notes ............................. 220
Rear window blind ............................ 334
Rear window defroster
Problem (malfunction) ................... 152
Switching on/off ........................... 151
Rear-view mirror
Anti-glare (manual) ........................ 123
Dipping (automatic) ....................... 124
Recuperative Brake System
Driving safety systems ..................... 44
Important safety notes .................... 44
Refrigerant (air-conditioning sys-
tem)
Important safety notes .................. 432
Refueling
Fuel gauge ....................................... 33
Important safety notes .................. 177
16Index

Switching on/off ........................... 131
Start/Stop button
General notes ................................ 162
Key positions ................................. 163
Removing ....................................... 163
Starting the engine ........................ 164
Start/stop function
see ECO start/stop function
Starting (engine) ................................ 164
STEER CONTROL .................................. 77
Steering
Display message ............................ 311
Warning lamps ............................... 324
Steering Assist
see DISTRONIC PLUS
Steering Assist and Stop&Go Pilot
(DISTRONIC PLUS)
Display message ............................ 305
Steering assistant STEER CON-
TROL
see STEER CONTROL
Steering wheel
Adjusting (electrically) ................... 120
Button overview ............................... 35
Buttons (on-board computer) ......... 257
Cleaning ......................................... 365
EASY ENTRY/EXIT feature ............. 122
Important safety notes .................. 120
Paddle shifters ............................... 174
Steering wheel heating .................. 120
Storing settings (memory func-
tion) ............................................... 126
Steering wheel heating
Problem (malfunction) ................... 122
Switching on/off ........................... 120
Steering wheel paddle shifters ........ 174
Stop&Go Pilot
see DISTRONIC PLUS
Stowage areas ................................... 325
Stowage compartments
Armrest (under) ............................. 327
Center console .............................. 326
Center console in rear compart-
ment .............................................. 327
Cup holders ................................... 330
Door ............................................... 327
Eyeglasses compartment ............... 326
Glove box ....................................... 326 Important safety information ......... 325
Rear ............................................... 327
Rear seat backrest ......................... 328
Stowage net ................................... 329
see Stowage areas
Stowage net ....................................... 329
Stowage space
Folding table .................................. 328
Parcel net retainers ....................... 329
Securing a load .............................. 329
Stowage well beneath the trunk
floor .................................................... 329
Summer tires
In w

inter ........................................ 386
Sun visor ............................................ 333
Suspension mode
Active Body Control ABC ............... 210
Suspension setting
AIRMATIC ...................................... 212
Suspension settings
SETUP (on-board computer) .......... 276
Switching air-recirculation mode
on/off ................................................. 152
T
Tachometer ........................................ 256
Tail lamps
Display message ............................ 292
see Lights
Tank content
Fuel gauge ....................................... 33
Technical data
Capacities ...................................... 427
Information .................................... 425
Tires/wheels ................................. 410
Vehicle data ................................... 433
Telephone
Accepting a call (multifunction
steering wheel) .............................. 267
Display message ............................ 311
Introduction ................................... 267
Menu (on-board computer) ............ 267
Number from the phone book ........ 268
Redialing ........................................ 268
Rejecting/ending a call ................. 268
Temperature
Coolant .......................................... 257
Index19

Tire bead (definition) ...................... 404
Tire pressure (definition) ................ 404
Tire pressures (recommended) ...... 403
Tire size (data) ............................... 410
Tire size designation, load-bearing
capacity, speed rating .................... 400
Tire tread ....................................... 385
Tire tread (definition) ..................... 404
Total load limit (definition) ............. 405
Traction ......................................... 399
Traction (definition) ....................... 405
Tread wear ..................................... 399
Uniform Tire Quality Grading
Standards ...................................... 398
Uniform Tire Quality Grading
Standards (definition) .................... 403
Wear indicator (definition) ............. 405
Wheel and tire combination ........... 412
Wheel rim (definition) .................... 403
see Flat tire
Top Tether ............................................ 64
Tow-starting
Emergency engine starting ............ 381
Important safety notes .................. 379
Towing a trailer
ESP
®(Electronic Stability Pro-
gram) ............................................... 74
Towing away
Important safety guidelines ........... 379
Installing the towing eye ................ 380
Notes for 4MATIC vehicles ............ 381
Removing the towing eye ............... 380
Transporting the vehicle ................ 381
With both axles on the ground ....... 380
Towing eye ......................................... 367
Traffic Sign Assist
Activating ....................................... 229
Display message ............................ 303
Function/notes ............................. 229
Important safety notes .................. 229
Instrument cluster display ............. 230
Switching on/off ........................... 270
Transfer case ..................................... 177
Transmission
see Automatic transmission
Transporting the vehicle .................. 381Trim pieces (cleaning instruc-
tions)
.................................................. 365
Trip computer (on-board com-
puter) .................................................. 262
Trip odometer
Calling up ....................................... 261
Resetti ng (
on-board computer) ...... 263
Trunk
Emergency release .......................... 93
Important safety notes .................... 88
Locking separately ........................... 93
Opening/closing (automatically
from inside) ...................................... 92
Opening/closing (automatically
from outside) ................................... 90
Opening/closing (from outside,
HANDS-FREE ACCESS) .................... 91
Opening/closing (manually from
outside) ............................................ 89
Power closing .................................. 87
Trunk lid
Display message ............................ 309
Obstacle recognition ........................ 89
Opening dimensions ...................... 433
Opening/closing .............................. 88
Trunk load (maximum) ...................... 433
Turn signals
Display message ............................ 291
Switching on/off ........................... 131
Two-way radio
Frequencies ................................... 425
Installation ..................................... 425
Transmission output (maximum) .... 425
Windshield (infrared reflective) ...... 351
Type identification plate
see Vehicle identification plate
U
UnlockingEmergency unlocking ....................... 87
From inside the vehicle (central
unlocking button) ............................. 86
Upshift indicator (on-board com-
puter, Mercedes-AMG vehicles) ....... 275
Index21

V
Vanity mirror (in the sun visor)........ 333
Vehicle
Correct use ...................................... 29
Data acquisition ............................... 29
Display message ............................ 308
Equipment ....................................... 25
Individual settings .......................... 269
Limited Warranty ............................. 29
Loading .......................................... 394
Locking (in an emergency) ............... 88
Locking (SmartKey) .......................... 79
Lowering ........................................ 409
Maintenance .................................... 26
Operating safety .............................. 27
Parking .......................................... 189
Parking for a long period ................ 192
Pulling away ................................... 165
Raising ........................................... 406
Reporting problems ......................... 29
Securing from rolling away ............ 406
Towing away .................................. 379
Transporting .................................. 381
Unlocking (in an emergency) ........... 87
Unlocking (SmartKey) ...................... 79
Vehicle data ................................... 433
Vehicle dimensions ........................... 433
Vehicle emergency locking ................ 88
Vehicle identification number
see VIN
Vehicle identification plate .............. 426
Vehicle level
Active Body Control ABC ............... 210
AIRMATIC ...................................... 212
Display message ............................ 300
Vehicle tool kit .................................. 367
Video
Operating the DVD ......................... 267
VIN
Type plate ...................................... 426
W
WarningStickers ........................................... 42
Warning and indicator lamps
ABS ................................................ 316 Brakes ........................................... 315
Check Engine ................................. 320
Coolant .......................................... 320
Distance warning ........................... 322
ESP
®.............................................. 317
ESP®OFF ....................................... 319
Fuel tank ........................................ 320
General notes ................................ 313
Hybrid drive system ....................... 315
Overview .......................................... 34
Parking brake ................................ 319
PASSENGER AIR BAG ...................... 46
RBS (Recuperative Brake Sys-
tem) ............................................... 315
Reserve fuel ................................... 320
Restraint system ............................ 319
Seat belt ........................................ 313
Steering ......................................... 324
Tire pressure monitor .................... 323
Warranty .............................................. 25
Washer fluid
Display message ............................ 311
Wheel and tire combinations
Tires ............................................... 412
Wheel bolt tightening torque ........... 409
Wheel chock ...................................... 406
Wheels
Changing a wheel .......................... 405
Checking ........................................ 385
Cleaning ......................................... 361
General notes ................................ 410
Important safety notes .................. 384
Information on driving .................... 384
Interchanging/changing ................ 405
Mounting a new wheel ................... 409
Mounting a wheel .......................... 406
Removing a wheel .......................... 408
Snow chains .................................. 386
Storing ........................................... 405
Tightening torque ........................... 409
Wheel size/tire size ....................... 410
Window curtain air bag
Display message ............................ 288
Operation ......................................... 53
Windows
see Side windows
22Index

One Mercedes Drive
Montvale, NJ 07645-0350
In Canada
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9
Operating safety
Important safety notes
GWARNING
If you do not have the prescribed service/
maintenance work or any required repairs
carried out, this can result in malfunctions or system failures. There is a risk of an accident.
Always have the prescribed service/mainte-
nance work as well as any required repairs
carried out at a qualified specialist workshop.
GWARNING
Flammable material such as leaves, grass or
twigs may ignite if they come into contact with
hot parts of the exhaust system. There is a risk of fire.
When driving off road or on unpaved roads,
check the vehicle's underside regularly. In
particular, remove parts of plants or other
flammable materials which have become
trapped. In the case of damage, contact a
qualified specialist workshop.
GWARNING
Modifications to electronic components, their software as well as wiring can impair their
function and/or the function of other net-
worked components. In particular, systems
relevant to safety could also be affected. As a
result, these may no longer function as inten-
ded and/or jeopardize the operating safety of
the vehicle. There is an increased risk of an
accident and injury.
Never tamper with the wiring as well as elec-
tronic components or their software. You
should have all work to electrical and elec-
tronic equipment carried out at a qualified
specialist workshop.
!There is a risk of damage to the vehicle if:
Rthe vehicle becomes stuck, e.g. on a high
curb or an unpaved road
Ryou drive too fast over an obstacle, e.g. a
curb or a hole in the road
Ra heavy object strikes the undercarriage or
parts of the chassis
In situations like this, the body, the undercar-
riage, chassis parts, wheels or tires could be
damaged without the damage being visible.
Components damaged in this way can unex-
pectedly fail or, in the case of an accident, no
longer withstand the strain they are designed to.
If the underbody paneling is damaged, com-
bustible materials such as leaves, grass or
twigs can gather between the underbody and
the underbody paneling. If these materials
come in contact with hot parts of the exhaust
system, they can catch fire.
In such situations, have the vehicle checked
and repaired immediately at a qualified spe-
cialist workshop. If on continuing your jour-
ney you notice that driving safety is impaired,
pull over and stop the vehicle immediately,
paying attention to road and traffic condi-
tions. In such cases, consult a qualified spe-
cialist workshop.
Hybrid vehicles have a combustion engine and
an electric motor. The voltage supply for oper-
ating the vehicle electrically is provided by the
vehicle's high-voltage electrical system.
GDANGER
The vehicle's high-voltage electrical system is under high voltage. If you modify components
in the vehicle's high-voltage electrical system
or touch damaged components, you may be
electrocuted. The components in the vehi-
cle's high-voltage electrical system may be
damaged in an accident, although the damage
is not visible. There is a risk of fatal injury.
Following an accident, do not touch any high-
voltage components and never modify the
vehicle's high-voltage electrical system. Have
the vehicle towed away after an accident and
Introduction27
Z

the vehicle's high-voltage electrical system
checked by a qualified specialist workshop.
The components of the vehicle's high-voltage
electrical system are marked with yellow warn-
ing stickers. The cables of the vehicle's high-
voltage electrical system are orange in color.
Vehicles with an electric motor generate much
less driving noise than vehicles with internal
combustion engines. As a result, your vehicle
may not be heard by other road users in certain
situations. This can happen, for example, when
you are parking and your vehicle is not seen by
other road users. This requires you to adopt a
particularly anticipatory driving style, as it is
necessary to allow for the possibility that other
road users may behave erratically.
Declarations of conformity
Vehicle components which receive
and/or transmit radio waves
USA: "The wireless devices of this vehicle com-
ply with Part 15 of the FCC Rules. Operation is
subject to the two following two conditions: 1)
These devices may not cause harmful interfer-
ence, and 2) These devices must accept any
interference received, including interference
that may cause undesired operation. Changes
or modifications not expressly approved by the
party responsible for compliance could void the
user’s authority to operate the equipment."
Canada: "The wireless devices of this vehicle
comply with Industry Canada license-exempt
RSS standard(s). Operation is subject to the fol-
lowing two conditions: (1) These devices may
not cause interference, and (2) These devices
must accept any interference, including inter-
ference that may cause undesired operation of
the device."
Diagnostics connection
The diagnostics connection is only intended for
the connection of diagnostic equipment at a
qualified specialist workshop.
GWARNING
If you connect equipment to the diagnostics
connection in the vehicle, it may affect the
operation of the vehicle systems. As a result,
the operating safety of the vehicle could be
affected. There is a risk of an accident.
Do not connect any equipment to a diagnos-
tics connection in the vehicle.
GWARNING
Objects in the driver's footwell can restrict the pedal travel or obstruct a depressed pedal.
The operating and road safety of the vehicle is
jeopardized. There is a risk of an accident.
Make sure that all objects in the vehicle are
stowed correctly, and that they cannot enter
the driver's footwell. Install the floormats
securely and as specified in order to ensure
sufficient clearance for the pedals. Do not use
loose floormats and do not place floormats on
top of one another.
!If the engine is switched off and equipment
on the diagnostics connection is used, the
starter battery may discharge.
Connecting equipment to the diagnostics con-
nection can lead to emissions monitoring infor-
mation being reset, for example. This may lead
to the vehicle failing to meet the requirements of
the next emissions test during the main inspec-
tion.
Qualified specialist workshop
An authorized Mercedes-Benz Center is a quali-
fied specialist workshop. It has the necessary
specialist knowledge, tools and qualifications to
correctly carry out the work required on your
vehicle. This is especially the case for work rel-
evant to safety.
Observe the notes in the Maintenance Booklet.
Always have the following work carried out at an
authorized Mercedes-Benz Center:
Rwork relevant to safety
Rservice and maintenance work
Rrepair work
Ralterations, installation work and modifica-
tions
Rwork on electronic components
Rwork on the hybrid drive system
28Introduction

Rear seats
iExample: vehicles with Rear Seat Entertain-
ment System
FunctionPage
:DVD player (see the separate
operating instructions)
;Cigarette lighter335
Socket336
FunctionPage
=Cup holder331
?Stowage compartment in the
rear seat armrest327
AStowage box in the seat
backrest328
Coolbox339
Rear seats41
At a glance