window MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

Publication details
Internet
Further information about Mercedes-Benz vehi-
cles and about Daimler AG can be found on the
following websites:
http://www.mbusa.com (USA only)
http://www.mercedes-benz.ca (Canada only)
Editorial office
©Daimler AG: not to be reprinted, translated or
otherwise reproduced, in whole or in part, with- out written permission from Daimler AG.
Vehicle manufacturer
Daimler AG
Mercedesstraße 137
70327 Stuttgart
Germany
Symbols
Registered trademarks:
RBluetooth®is a registered trademark of Blue-
tooth SIG Inc.
RDTS™ is a registered trademark of DTS, Inc.
RDolby®and MLP™ are registered trademarks
of DOLBY Laboratories.
RBabySmart™, ESP®and PRE-SAFE®are reg-
istered trademarks of Daimler AG.
RHomeLink®is a registered trademark of John-
son Controls.
RiPod®and iTunes®are registered trademarks
of Apple Inc.
RBurmester®is a registered trademark of
Burmester Audiosysteme GmbH.
RMicrosoft®and Windows media®are regis-
tered trademarks of Microsoft Corporation.
RSIRIUS®is a registered trademark of Sirius
XM Radio Inc.
RHD Radio™ is a registered trademark of iBiq-
uity Digital Corporation.
RGracenote®is a registered trademark of
Gracenote, Inc.
RZAGAT Survey®and related brands are regis-
tered trademarks of Zagat Survey, LLC.
In this Operator's Manual you will find the fol-
lowing symbols:
GWARNING
Warning notes make you aware of dangers
which could pose a threat to your health or
life, or to the health and life of others.
HEnvironmental note
Environmental notes provide you with infor-
mation on environmentally aware actions or
disposal.
!Notes on material damage alert you to dan-
gers that could lead to damage to your vehi-
cle.
iPractical tips or further information that
could be helpful to you.
X This symbol indicates an instruction
that must be followed.
X Several of these symbols in succession
indicate an instruction with several
steps. (Y
page)
This symbol tells you where you can find
more information about a topic.
YY This symbol indicates a warning or an
instruction that is continued on the next
page.
Dis‐
playThis text indicates a message on the
multifunction display/multimedia dis-
play.
As at 26.03.2015

1, 2, 3 ...
4ETS (Electronic Traction System)see ETS/4ETS (Electronic Trac-
tion System)
4MATIC (permanent four-wheel
drive) .................................................. 213
12 V socket
see Sockets
115 V socket ...................................... 337
360° camera
Cleaning ........................................ .363
Function/notes .............................2 24
A
ABS (Anti-lock Braking System)
Display message ............................ 278
Function/notes ................................ 68
Warning lamp ................................. 316
Accident
Automatic measures after an acci-
dent ................................................. 61
Activating/deactivating cooling
with air dehumidification ................. 146
Activating/deactivating Night
View Assist Plus
With spotlight function ................... 232
Active Blind Spot Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 234
Active Body Control (ABC)
Display message ............................ 300
Function/notes ............................. 210
Active Lane Keeping Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 237
Active multicontour seat .................. 117
Active Parking Assist
Detecting parking spaces .............. 217
Display message ............................ 302
Exiting a parking space .................. 219
Function/notes ............................. 216
Important safety notes .................. 216 Parking .......................................... 218
ADAPTIVE BRAKE ................................. 75
Adaptive Brake Assist
Function/notes ................................ 72
Adaptive Damping System (ADS) ..... 212
Adaptive Highbeam Assist Plus
Display message ............................ 293
Function/notes ............................. 133
Switching on/off ........................... 133
Additional speedometer ................... 274
Additives (engine oil) ........................ 430
Air bags
Belt bags .......................................... 48
Cushion air bags .............................. 53
Deployment ..................................... 57
Display message ............................ 289
Front air bag (driver, front
passenger) ....................................... 52
Important safety notes .................... 50
Introduction ..................................... 50
Knee bag .......................................... 52
Occupant Classification System
(OCS) ............................................... 53
PASSENGER AIR BAG i
ndicator
lamps ............................................... 46
Side impact air bag .......................... 52
Window curtain air bag .................... 53
Air vents
Glove box ....................................... 159
Important safety notes .................. 158
Rear ............................................... 160
Setting ........................................... 158
Setting the center air vents ........... 159
Setting the side air vents ............... 159
Air-conditioning system
see Climate control
AIRMATIC
Display message ............................ 299
Function/notes ............................. 212
Alarm
ATA (Anti-Theft Alarm system) ......... 78
Switching off (ATA) .......................... 78
Switching the function on/off
(ATA) ................................................ 78
Alarm system
see ATA (Anti-Theft Alarm system)
Anti-lock braking system
see ABS (Anti-lock Braking System)
Index3

Brake Assistsee BAS (Brake Assist System)
Brake fluid
Display message ............................ 283
Notes ............................................. 430
Brake force distribution
see EBD (electronic brake force
distribution)
Brake lamps
Display message ............................ 291
Brake pedal
Pedal resistance/pedal travel .......... 44
Brakes
ABS .................................................. 68
Adaptive Brake Assist ...................... 72
BAS .................................................. 69
BAS PLUS with Cross-Traffic
Assist ............................................... 69
Brake fluid (notes) ......................... 430
Display message ............................ 278
EBD .................................................. 75
High-performance brake system .... 196
Hill start assist ............................... 165
HOLD function ............................... 208
Important safety notes .................. 194
Maintenance .................................. 195
Parking brake ................................ 190
RBS warning lamp .......................... 315
Recuperative Brake System ............. 44
Riding tips ...................................... 194
Warning lamp ................................. 315
Breakdown
Where will I find...? ........................ 367
see Flat tire
see Towing away
Brightness control (instrument
cluster lighting) ................................... 35
Buttons on the steering wheel ......... 257
C
California
Important notice for retail cus-
tomers and lessees .......................... 25
Calling up a malfunction
see Display messages
Camera
see 360° camera see Rear view camera
Car
see Vehicle
Care
360° camera ................................. 363
Car wash ........................................ 359
Carpets .......................................... 366
Display ........................................... 364
Exhaust pipe .................................. 363
Exterior lights ................................ 362
Gear or selector lever .................... 365
General notes ................................ 359
Interior ........................................... 364
Matte finish ................................... 361
Night View Assist Plus ................... 364
Paint .............................................. 361
Plastic trim .................................... 364
Power washer ................................ 360
Rear view camera .......................... 363
Roof lining ...................................... 366
Seat belt ........................................ 366
Seat cover ..................................... 365
Sensors ......................................... 362
Steering wheel ............................... 365
Trim pieces .................................... 365
Washing by hand ........................... 360
Wheels ........................................... 361
Windows ........................................ 362
Wiper blades .................................. 362
Wooden trim .................................. 365
CD player (on-board computer) ........ 266
Center console
Overview .......................................... 37
Stowage space .............................. 326
Center console in the rear com-
partment
Stowage compartment .................. 327
Central locking
Locking/unlocking (SmartKey) ........ 79
Changing the media source ............. 265
Charging
see Charging the high-voltage bat-
tery (important safety notes)
Charging cable
Connecting .................................... 185
Controls ......................................... 183
Important safety notes .................. 183
Indicator lamp ................................ 184
Index5

Removing...................................... .185
Storing ...........................................1 83
Warming up ................................... 182
Charging the high-voltage battery
(important safety notes) ................... 180
Chauffeur mode
Display message ............................ 310
Fully reclined position .................... 114
General notes ................................ 111
Installing the head restraint ........... 113
Moving front-passenger seat into
the chauffeur position .................... 112
Moving the front-passenger seat
into the normal position ................. 113
Removing the head restraint .......... 113
Child
Restraint system .............................. 62
Child seat
Forward-facing restraint system ...... 66
LATCH-type (ISOFIX) child seat
anchors ............................................ 63
On the front-passenger seat ............ 65
Rearward-facing restraint system .... 66
Top Tether ....................................... 64
Child-proof locks
Important safety notes .................... 66
Rear doors ....................................... 67
Children
Special seat belt retractor ............... 62
Cigarette lighter ................................ 335
Cleaning
Mirror turn signal ........................... 362
Climate control
Automatic climate control ............. 141
Controlling automatically ............... 147
Cooling with air dehumidification .. 146
Defrosting the windows ................. 151
Defrosting the windshield .............. 151
ECO start/stop function ................ 145
General notes ................................ 140
Immediate pre-entry climate con-
trol ................................................. 158
Indicator lamp ................................ 147
Ionization ....................................... 155
Notes on using the automatic cli-
mate control .................................. 145
Overview of systems ...................... 140
Perfume atomizer .......................... 153 Pre-entry climate control at
departure time ............................... 157
Pre-entry climate control via
key ... 155
P

roblem with the rear window
defroster ........................................ 152
Problems with cooling with air
dehumidification ............................ 147
Rear control panel ......................... 141
Refrigerant ..................................... 432
Refrigerant filling capacity ............. 432
Setting the air distribution ............. 149
Setting the air vents ...................... 158
Setting the airflow ......................... 150
Setting the climate mode ............... 148
Setting the temperature ................ 148
Switching air-recirculation mode
on/off ............................................ 152
Switching on/off ........................... 145
Switching residual heat on/off ...... 152
Switching the rear window
defroster on/off ............................ 151
Switching the synchronization
function on and off ........................ 150
Climate control system
Climate control .............................. 145
Cockpit
Overview .......................................... 32
COLLISION PREVENTION ASSIST
PLUS
Activating/deactivating ................. 270
Display message ............................ 284
Operation/notes .............................. 71
COMAND display
Cleaning ......................................... 364
Combination switch .......................... 131
Consumption statistics (on-board
computer) .......................................... 262
Convenience closing feature .............. 96
Convenience opening feature ............ 95
Coolant (engine)
Checking the level ......................... 356
Display message ............................ 294
Displaying the temperature (on-
board computer) ............................ 269
Filling capacity ............................... 431
Important safety notes .................. 431
Temperature gauge ........................ 257
Warning lamp ................................. 320
6Index

Operation ......................................... 54
System self-test ...............................56
Occupant safety
Air bags ...........................................5 0
Automatic measures after an acci-
dent ................................................. 61
Children in the vehicle ..................... 61
Important safety notes .................... 45
Introduction to the restraint sys-
tem .................................................. 44
Occupant Classification System
(OCS) ............................................... 53
PASSENGER AIR BAG indicator
lamps ............................................... 46
Pets in the vehicle ........................... 67
PRE-SAFE
®(anticipatory occu-
pant protection) ............................... 59
PRE-SAFE
®PLUS (anticipatory
occupant protection PLUS) .............. 60
Restraint system warning lamp ........ 45
OCS
Conditions ....................................... 53
Faults ............................................... 57
Operation ......................................... 54
System self-test ............................... 56
Odometer ........................................... 261
Oil
see Engine oil
On-board computer
AMG menu ..................................... 275
Assistance graphic menu ............... 268
Assistance menu ........................... 269
Display messages .......................... 277
Displaying a service message ........ 358
DISTRONIC PLUS ........................... 204
Factory settings ............................. 275
Head-up display ............................. 259
HYBRID menu ................................ 272
Important safety notes .................. 256
Instrument cluster menu ............... 274
Lights menu ................................... 274
Media menu ................................... 265
Menu overview .............................. 261
Message memory .......................... 277
Navigation menu ............................ 263
Operation ....................................... 257
Radio menu ................................... 265 Service menu ................................. 269
Settings menu ............................... 269
Standard display ............................ 261
Telephone menu ............................ 267
Trip menu ...................................... 261
Video DVD operation ..................... 267
Online access to the vehicle
Data protection .............................. 188
Functions ....................................... 189
General informa tion ....................... 188
Inte

rnet .......................................... 189
Opening the fuel filler flap
(PLUG-IN HYBRID vehicles) ............ 179
Operating safety
Declaration of conformity ................ 28
Important safety notes .................... 27
Operating system
see On-board computer
Operator's Manual
Overview .......................................... 25
Vehicle equipment ........................... 25
Outside temperature display ........... 257
Overhead control panel ...................... 39
Override feature
Rear side windows ........................... 67
P
Paint code number ............................ 426
Paintwork (cleaning instructions) ... 361
Panic alarm .......................................... 44
Panorama roof with power tilt/
sliding panel
Important safety notes .................... 97
Opening/closing the roller sun-
blind ............................................... 100
Operating ......................................... 98
Operating the roller sunblinds for
the sliding sunroof ........................... 99
Problem (malfunction) ................... 103
Rain closing feature ......................... 99
Resetting ....................................... 102
Reversing feature ............................. 98
Parcel net hooks ............................... 329
Parking
Important safety notes .................. 189
Parking brake ................................ 190
14Index

Starting .......................................... 249
When the vehicle is stationary ....... 251
Power locks ......................................... 87
Power washers .................................. 360
Power windows
see Side windows
Pre-entry climate control (via
SmartKey)
Problems (malfunctions) ................ 157
Pre-entry climate control at depar-
ture time
General notes ................................ 157
Pre-entry climate control at time of
departure
Setting departure time ................... 158
Pre-entry climate control via key
General notes ................................ 155
PRE-SAFE
®(anticipatory occupant
protection)
Display message ............................ 284
Operation ......................................... 59
PRE-SAFE
®Brake
Activating/deactivating ................. 271
Display message ............................ 284
Function/notes ................................ 75
Important safety notes .................... 76
Warning lamp ................................. 322
PRE-SAFE
®PLUS (anticipatory
occupant protection PLUS)
Display message ............................ 284
Operation ......................................... 60
Program selector button .................. 173
Protection against theft
ATA (Anti-Theft Alarm system) ......... 78
Immobilizer ...................................... 78
Protection of the environment
General notes .................................. 24
Pulling away
Automatic transmission ................. 165
General notes ................................ 165
Hill start assist ............................... 165
Q
QR codeMercedes-Benz Guide App ................. 1
Rescue card ..................................... 29
Qualified specialist workshop ........... 28
R
Radio
Selecting a station ......................... 265
Radio-wave reception/transmis-
sion in the vehicle
Declaration of conformity ................ 28
Rain closing feature
Panorama sliding sunroof ................ 99
RBS (Recuperative Brake System)
Warning lamp ................................. 315
Reading lamp ..................................... 134
Rear compartment
Activating/deactivating climate
control ........................................... 145
Setting the air distribution ............. 149
Setting the air vents ...................... 160
Setting the airflow ......................... 150
Setting the temperature ................ 148
Stowage compartment .................. 327
Rear lamps
see Lights
Rear seats
Adjusting ....................................... 107
Adjusting a rear reclining seat ....... 107
Overview .......................................... 41
Setting the reclined position .......... 107
Rear view camera
Cleaning instructions ..................... 363
Displays in the COMAND display ... 221
Function/notes ............................. 220
Rear window blind ............................ 334
Rear window defroster
Problem (malfunction) ................... 152
Switching on/off ........................... 151
Rear-view mirror
Anti-glare (manual) ........................ 123
Dipping (automatic) ....................... 124
Recuperative Brake System
Driving safety systems ..................... 44
Important safety notes .................... 44
Refrigerant (air-conditioning sys-
tem)
Important safety notes .................. 432
Refueling
Fuel gauge ....................................... 33
Important safety notes .................. 177
16Index

Refuelingprocess (PLUG-IN
HYBRID vehicles) .......................... .178
see Fuel
Remote control
Garage door opener ....................... 347
Programming (garage door
opener) .......................................... 348
Replacing bulbs
General notes ................................ 135
Reporting safety defects .................... 29
Rescue card ......................................... 29
Reserve (fuel tank)
see Fuel
Reserve fuel
Display message ............................ 296
Warning lamp ................................. 320
Residual heat (climate control) ........ 152
Restraint system
Display message ............................ 287
Introduction ..................................... 44
Warning lamp ................................. 319
Warning lamp (function) ................... 45
Reversing feature
Panorama sliding sunroof ................ 98
Roller sunblinds ............................... 99
Side windows ................................... 94
Trunk lid ........................................... 89
Reversing lamps (display mes-
sage) ................................................... 292
ROAD SURFACE SCAN ....................... 211
Roadside Assistance (breakdown) .... 26
Roller sunblind
Panorama roof with power tilt/
sliding panel ..................................... 99
Rear side windows ......................... 333
Rear window .................................. 334
Roller sunblind of the panorama
roof with power tilt/sliding panel
Operating (front roller sunblind) .... 100
Operating (rear roller sunblind) ...... 100
Roof carrier ........................................ 330
Roof lining and carpets (cleaning
guidelines) ......................................... 366
Roof load (maximum) ........................ 433S
Safety
Children in the vehicle ..................... 61
Hybrid drive system ......................... 42
see Occupant safety
see Operating safety
Safety notes
Hybrid vehicles ................................ 42
Safety system
see Driving safety systems
SD memory card
Selecting ........................................ 266
Seat
Adjusting the front-passenger
seat from the driver's seat ............. 108
Multicontour seat in the rear com-
partment ........................................ 117
Seat belt buckle extender
Display message ............................ 285
Seat belt extender
Function/notes ................................ 49
Seat belts
Adjusting the driver's and front-
passenger seat belt ......................... 50
Adjusting the height ......................... 49
Cleaning ......................................... 366
Correct usage .................................. 48
Fastening ......................................... 49
Important safety guidelines ............. 47
Introduction ..................................... 46
Releasing ......................................... 50
Seat belt extender ........................... 49
Warning lamp ................................. 313
Warning lamp (function) ................... 50
Seating
Seating comfort package ............... 117
Seating comfort package ................. 117
Seats
Active multicontour seat ................ 117
Adjusting (electrically) ................... 106
Adjusting (rear compartment) ........ 107
Adjusting the 4-way lumbar sup-
port ................................................ 118
Adjusting the head restraint .......... 114
Calling up a stored setting (mem-
ory function) .................................. 127
Chauffeur mode ............................. 111
Index17

Cleaning the cover .........................365
Correct driver's seat position ........1 04
Display message ............................ 310
EASY-ENTRY/EXIT system ............. 122
Important safety notes .................. 105
Multicontour seat .......................... 117
Seat heating .................................. 118
Seat heating problem .................... 119
Seat ventilation .............................. 119
Seat ventilation problem ................ 120
Storing settings (memory func-
tion) ............................................... 126
Switching seat heating on/off ....... 118
Switching seat ventilation on/off .. 119
Section
Wheels and tires ............................ 384
Securing a load
see Securing cargo
Securing cargo .................................. 329
Selector lever
Cleaning ......................................... 365
see Automatic transmission
Sensors (cleaning instructions) ....... 362
Service menu (on-board com-
puter) ..................................................2 69
Service message
see ASSYST PLUS
Service products
Brake fluid ..................................... 430
Coolant (engine) ............................ 431
Engine oil ....................................... 429
Fuel ................................................ 428
Important safety notes .................. 427
Refrigerant (air-conditioning sys-
tem) ............................................... 432
Washer fluid ................................... 431
Setting the charge current (on-
board computer) ............................... 272
Setting the departure time (on-
board computer) ............................... 272
Settings
Factory (on-board computer) ......... 275
On-board computer ....................... 269
SETUP (on-board computer) ............. 276
Side impact air bag .............................5 2
Side marker lamp (display mes-
sage) ................................................... 292 Side windows
Cleaning ........................... .............. 362
Convenience closing feature ............ 96
Convenience opening feature ..........9 5
Importa

nt safety information ........... 94
Opening/closing .............................. 95
Problem (malfunction) .....................9 7
Resettin g........................................ .96
Reversin gfeature ............................ .94
Sliding sunroof
see Panorama roof with power
tilt/sliding panel
SmartKey
Changing the battery ....................... 82
Changing the programming .............8 1
Checking the battery ...................... .82
Convenience closing feature ............ 96
Convenience opening feature .......... 95
Display message ............................ 312
Door central locking/unlocking ...... .79
Important safety notes .................... 79
KEYLESS-GO start function .............. 81
Loss .................................................8 4
Mechanical key ................................ 81
Overview .......................................... 79
Positions (ignition lock) ................. 162
Problem (malfunction) ..................... 84
Starting the engine ........................ 164
Smartphone
Starting the engine ........................ 164
Snow chains ...................................... 386
Sockets
Center console .............................. 336
General notes ................................ 336
Rear compartment .........................3 37
Trunk ............................................. 337
Special seat be
lt retractor
.................. 62
Specialist workshop ............................ 28
Speed, controlling
see Cruise control
Speedometer
Activating/deactivating the addi-
tional speedometer ........................ 274
Digital ............................................ 263
In the Instrument cluster ................. 33
Selecting the display unit ...............2 74
Standing lamps
Display message ............................ 292
18Index

V
Vanity mirror (in the sun visor)........ 333
Vehicle
Correct use ...................................... 29
Data acquisition ............................... 29
Display message ............................ 308
Equipment ....................................... 25
Individual settings .......................... 269
Limited Warranty ............................. 29
Loading .......................................... 394
Locking (in an emergency) ............... 88
Locking (SmartKey) .......................... 79
Lowering ........................................ 409
Maintenance .................................... 26
Operating safety .............................. 27
Parking .......................................... 189
Parking for a long period ................ 192
Pulling away ................................... 165
Raising ........................................... 406
Reporting problems ......................... 29
Securing from rolling away ............ 406
Towing away .................................. 379
Transporting .................................. 381
Unlocking (in an emergency) ........... 87
Unlocking (SmartKey) ...................... 79
Vehicle data ................................... 433
Vehicle dimensions ........................... 433
Vehicle emergency locking ................ 88
Vehicle identification number
see VIN
Vehicle identification plate .............. 426
Vehicle level
Active Body Control ABC ............... 210
AIRMATIC ...................................... 212
Display message ............................ 300
Vehicle tool kit .................................. 367
Video
Operating the DVD ......................... 267
VIN
Type plate ...................................... 426
W
WarningStickers ........................................... 42
Warning and indicator lamps
ABS ................................................ 316 Brakes ........................................... 315
Check Engine ................................. 320
Coolant .......................................... 320
Distance warning ........................... 322
ESP
®.............................................. 317
ESP®OFF ....................................... 319
Fuel tank ........................................ 320
General notes ................................ 313
Hybrid drive system ....................... 315
Overview .......................................... 34
Parking brake ................................ 319
PASSENGER AIR BAG ...................... 46
RBS (Recuperative Brake Sys-
tem) ............................................... 315
Reserve fuel ................................... 320
Restraint system ............................ 319
Seat belt ........................................ 313
Steering ......................................... 324
Tire pressure monitor .................... 323
Warranty .............................................. 25
Washer fluid
Display message ............................ 311
Wheel and tire combinations
Tires ............................................... 412
Wheel bolt tightening torque ........... 409
Wheel chock ...................................... 406
Wheels
Changing a wheel .......................... 405
Checking ........................................ 385
Cleaning ......................................... 361
General notes ................................ 410
Important safety notes .................. 384
Information on driving .................... 384
Interchanging/changing ................ 405
Mounting a new wheel ................... 409
Mounting a wheel .......................... 406
Removing a wheel .......................... 408
Snow chains .................................. 386
Storing ........................................... 405
Tightening torque ........................... 409
Wheel size/tire size ....................... 410
Window curtain air bag
Display message ............................ 288
Operation ......................................... 53
Windows
see Side windows
22Index

Door controlpanel
FunctionPage
:s Seat ventilation119
;c Seat heatin g118
=w Adjust sth efront-
passenger seat from th edriv-
er' sseat
10 8
?r 45=
Stores settings for the seat,
exterior mirrors and steering
wheel
126
AAdjusts the seats electrically106
B7Zª\
Adjusts and folds the exterior
mirrors in/out electrically
123
CW Opens/closes the right
side window94
DW Opens/closes the rear
right side window94
FunctionPage
E6 Unlocks fuel filler flap179
FpOpens/closes the
trunk lid92
Gn Override feature for the
controls in the rear compart-
ment
67
HOpens the door86
I%&Unlocks/locks
the vehicle86
JW Opens/closes the rear
left side window94
KW Opens/closes the left
side window94
40Door control panel
At a glance