MERCEDES-BENZ S500 2002 W220 Owner's Manual

228 Catalytic converter
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Catalytic converter
Your Mercedes-Benz is equipped with monolithic type
catalytic converters, an important element in
conjunction with the oxygen sensors to achieve
substantial control of the pollutants in the exhaust
emissions. Keep your vehicle in proper operating
condition by following our recommended maintenance
instructions as outlined in your Service Booklet.
Caution!
To prevent damage to the catalytic converters, use only
premium unleaded gasoline in this vehicle.
Any noticeable irregularities in engine operation should
be repaired promptly. Otherwise, excessive unburned
fuel may reach the catalytic converter causing it to
overheat, which could start a fire.
Wa r n i n g !
As with any vehicle, do not idle, park or operate
this vehicle in areas where combustible materials
such as grass, hay or leaves can come into contact
with the hot exhaust system, as these materials
could be ignited and cause a vehicle fire.

229 Emission control
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Certain systems of the engine serve to keep the toxic
components of the exhaust gases within permissible
limits required by law.
These systems, of course, will function properly only
when maintained strictly according to factory
specifications. Any adjustments on the engine should,
therefore, be carried out only by qualified
Mercedes-Benz Center authorized technicians. Engine
adjustments should not be altered in any way. Moreover,
the specified service jobs must be carried out regularly
according to Mercedes-Benz servicing requirements.
For details refer to the Service Booklet.
Wa r n i n g !
Inhalation of exhaust gas is hazardous to your
health. All exhaust gas contains carbon monoxide,
and inhaling it can cause unconsciousness and
lead to death.Do not run the engine in confined areas (such as a
garage) which are not properly ventilated. If you
think that exhaust gas fumes are entering the
vehicle while driving, have the cause determined
and corrected immediately. If you must drive under
these conditions, drive only with at least one
window fully open.

230 Starter switch
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Starter switch
0The electronic key can be withdrawn in this position
only. The electronic key can only be removed with
the selector lever in position “P”. After removing the
electronic key or with the electronic key in starter
switch position 0 or 1, the selector lever is locked in
position “P”.1Most electrical consumers can be operated. For
detailed information see respective subjects.
2Driving position.
Gear selector lever is unlocked.
To move the selector lever out of position “P”, firmly
depress the service brake pedal.
3Starting position.
See page 235 for instructions on starting and stopping
the engine.
See page 42 for instructions on the simultaneous use of
the electronic key and the KEYLESS-GO-function.
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Wa r n i n g !
When leaving the vehicle always remove the
electronic key from the starter switch, take the
KEYLESS-GO-card (if so equipped) with you and
lock the vehicle. Do not leave children unattended
in the vehicle, or with access to an unlocked
vehicle. Unsupervised use of vehicle equipment
may cause serious personal injury.

231 Starter switch
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If the electronic key is left in the starter switch
position 0 for an extended period of time, it can no
longer be turned in the lock. In this case, remove
electronic key from starter switch and reinsert.
Caution!
To prevent accelerated battery discharge and a possible
dead battery, always remove the electronic key from the
starter switch. Do not leave the electronic key in starter
switch position 0.Notes:
A warning sounds when the driver’s door is opened
with the electronic key in starter switch position 1 or 0.
If the electronic key cannot be turned in the starter
switch, the vehicle battery may not be sufficiently
charged. See battery on page 357 or jump starting on
page 359.
With the engine at idle speed, the charging rate of the
alternator (output) is limited.
It is therefore recommended that you turn off
unnecessary electrical consumers while driving in stop-
and-go traffic. This precaution helps to avoid draining of
the battery.
Unnecessary strain on the battery and charging system
may be minimized by turning off the following power
consumers, for example:
Heated seats, rear window defroster. In addition, the
automatic climate air volume control should be set to
the lowest position.

232 Starter switch — KEYLESS-GO
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Start- / Stop button (vehicles with KEYLESS-GO)
Symbols on start-/stop button for Canada only:
See page 235 for instructions on starting and turning off
the engine.
See page 42 for instructions on the simultaneous use of
the electronic key and the KEYLESS-GO-function.Pressing the start- / stop button (1) on the gear selector
lever without depressing the brake pedal will
sequentially activate the starter switch positions 1 (on)
and 2 (operation) and 0 (off).
The engine can be started with the starter switch in any
position (on, operation or off), as long as the gear
selector lever is in position “P” or “N” and the brake
pedal depressed.
1
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Wa r n i n g !
When leaving the vehicle always take the electronic
key and the KEYLESS-GO-card with you, and lock
the vehicle. Do not leave children unattended in the
vehicle, or with access to an unlocked vehicle.
Unsupervised use of vehicle equipment may cause
serious personal injury.

233 Starter switch — KEYLESS-GO
Te ch n i c a l
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cluster displayPractical hints Car care Index “On” position
(starter switch position 1, see page 230).
Most electrical consumers can be operated. For detailed
information see respective subjects.
Operation / driving position
(starter switch position 2, see page 230).
All electrical consumers can be operated. Gear selector
is unlocked.
“Off” position
(electronic key removable from starter switch).
Most electrical consumers cannot be operated.
The selector lever is locked in position “P”.
Notes:
For improved recognition of the KEYLESS-GO-card the
doors should be closed when pressing the start- / stop
button.
The gear selector lever can only be moved with the
vehicle battery charged and connected, and the starter
switch in the Operation position. With the gear selector
lever in position “P”, the brake pedal must also be
depressed.Important!
For the KEYLESS-GO-system to function properly, the
operator should observe the following:
•If the KEYLESS-GO-card is positioned farther away
from the vehicle (e.g. inside clothing or a briefcase),
the vehicle cannot be locked (see page 38) or started
with the start-/stop button (see page 235).
•If the KEYLESS-GO-card is removed from the vehicle
while the engine is running, or by placing the card
in front of the center armrest (see page 198), the
message “CHIP-CARD – NOT RECOGNIZED!” will
appear repeatedly for approx. 2 seconds in the
multifunction display, see page 328.
If the message “CHIP - CARD – NOT RECOGNIZED”
is ignored for an extended of time (approx.
15 minutes), the engine could stop by itself during a
vehicle stop (e.g. traffic light). The vehicle can then
no longer be centrally locked or the engine
restarted. You must first find the card. Start the
engine again.

234 Starter switch — KEYLESS-GO
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•Do not forget, the engine can be started by anyone if
a KEYLESS-GO-card is left inside the vehicle.
•To be able to operate the vehicle in the case of a
malfunction in the KEYLESS-GO-system (e.g. strong
radio frequency disturbance), we recommend that
you carry the electronic key plus mechanical key
with you and keep them in a safe place so that they
are always handy. Never leave the electronic key in
the vehicle.
•To avoid radio transmission interference, never store
the KEYLESS-GO-card together with other electronic
items (e.g. cellular telephones, other KEYLESS-GO-
cards) or metallic objects (e.g. coins, metal foil).Notes:
With the engine at idle speed, the charging rate of the
alternator (output) is limited.
It is therefore recommended that you turn off
unnecessary electrical consumers while driving in stop-
and-go traffic. This precaution helps to avoid draining of
the battery.
Unnecessary strain on the battery and charging system
may be minimized by turning off the following power
consumers, for example:
Heated seats, rear window defroster. In addition, the
automatic climate air volume control should be set to
the lowest position.

235 Starting and turning off the engine
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cluster displayPractical hints Car care Index Starting and turning off the engine
Before starting
Ensure that parking brake is engaged and that selector
lever is in position “P” or “N”.
Important!
In areas where temperatures frequently drop below -4
°F
(-20
°C) we recommend that an engine block heater be
installed. Your authorized Mercedes-Benz Center will
advise you on this subject, see page 255.
Starting with the electronic key
Do not depress accelerator.
Turn electronic key in starter switch to position 2.
Briefly turn electronic key in starter switch clockwise to
the stop and release. The starter will engage until the
engine is running.
If engine will not run, and the starting procedure stops,
turn electronic key completely to the left and repeat
starting the engine.After several unsuccessful attempts, have the system
checked at the nearest authorized Mercedes-Benz
Center.
Important!
Due to the installed starter non-repeat feature, the
electronic key must be turned completely to the left
before attempting to start the engine again.
Note:
Too many unsuccessful starting attempts may discharge
the battery.
Turning off with the electronic key
Put the selector lever in position “P” and turn the
electronic key in the starter switch to position 0 to stop
the engine.
The electronic key can only be removed with the
selector lever in position “P”.

236 Starting and turning off the engine
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Starting with KEYLESS-GO
Note:
For improved recognition of the chip card the doors
should be closed when pressing the start-/stop button.
Depress brake pedal during the starting procedure.
Do not depress accelerator.
Briefly press start-/stop button on gear selector lever.
The starter will engage until the engine is running.
If engine will not run, and the starting procedure stops,
press start-/stop button on gear selector lever and repeat
starting the engine.
After several unsuccessful attempts, have the system
checked at the nearest authorized Mercedes-Benz
Center.Turning off with KEYLESS-GO
Stop the vehicle and put the selector lever in
position “P”.
Press start-/stop button on the selector lever until the
engine stops. With the driver’s door closed the starter
switch is set to the “On” position (starter switch
position 1). With the driver’s door opened the starter
switch is set to the “Off” position (starter switch
position 0, same as electronic key removed from starter
switch).
Note:
The engine can only be turned off with selector lever in
position “P”. If attempting to turn off the engine while
the selector lever is in any other position than “P” a
signal sounds and the message “SELECTOR LEVER
TO P” appears in the multifunction display as a
reminder to move the selector to position “P”.

237 Automatic transmission
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cluster displayPractical hints Car care Index Automatic transmissionThe automatic transmission selects individual gears
automatically, dependent upon
•Selector lever position
•Program mode selector
•Accelerator position
•Vehicle speed
The gear shifting process is continuously adapted,
dependent on the driving style, the driving situation
and the road characteristics.
Important!
When parking the vehicle or before working on the
vehicle with the engine running, firmly depress the
parking brake pedal and shift the selector lever into “P”.
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