Fuel MERCEDES-BENZ S500 2002 W220 Service Manual

376 Emergency engine shut-down
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Emergency engine shut-down
If the engine can no longer be stopped using the
electronic key or the start- / stop button (vehicles with
KEYLESS-GO), the engine can be turned off by
withdrawing two fuses.
For easy removal of fuses use the fuse extractor
(supplied with vehicle tool kit) to pull out the fuses
marked on the fuse chart as “ENGINE EMERGENCY
OFF”.
The fuse chart is also located in the vehicle tool kit,
seepage346.
For fuses see page 337.Fuel filler flap, manual release
Pull back the trim inside the trunk on the right-hand
side. Pull the release knob (arrow) and open the fuel
filler flap.
P80.20-0538-26

382 Cleaning and care of the vehicle
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Cleaning and care of the vehicle
In operation, your vehicle is subjected to varying
external influences which, if gone unchecked, can
attack the paintwork as well as the underbody and
cause lasting damage.
Such damage is caused not only by extreme and varying
climatic conditions, but also by air polution, road salt,
tar, gravel and stone chipping. Grease and oil, fuel,
coolant, brake fluid, bird droppings, insects, tree resins
etc. should be removed immediately to avoid paint
damage. Frequent washing reduces and/or eliminates
the aggressiveness and potency of the above adverse
influences.More frequent washings are necessary to deal with
unfavorable conditions; for example, near the ocean, in
industrial areas (smoke, exhaust emissions), or during
winter operation.
You should check your vehicle from time to time for
stone chipping or other damage. Any damage should be
repaired as soon as possible to prevent the start of
corrosion.
In doing so, do not neglect the underside of the vehicle.
A prerequisite for a thorough check is a washing of the
underbody followed by a thorough inspection. Damaged
areas need to be reundercoated.
Your vehicle has been treated at the factory with a wax-
base rustproofing in the body cavities which will last for
the lifetime of the vehicle. Post-production treatment is
neither necessary nor recommended by Mercedes-Benz
because of the possibility of incompatibility between
materials used in the production process and others
applied later.
We have selected car-care products and compiled
recommendations which are specially matched to our
vehicles and which always reflect the latest technology.
You can obtain Mercedes-Benz approved car-care
products at your authorized Mercedes-Benz Center.
Wa r n i n g !
Many cleaning products can be hazardous. Some
are poisonous, others are flammable. Always follow
the instructions on the particular container.
Always open your vehicle’s doors or windows when
cleaning the inside.Never use fluids or solvents that are not designed
for cleaning your vehicle.

391 Contents – Technical data
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Technical dataSpare parts service ........................392
Warranty coverage .........................392
Identification labels .......................393
Layout of poly-V-belt drive ............395
Technical data ................................396
Fuels, coolants, lubricants etc. -
capacities ...................................402Engine oils ...................................... 404
Engine oil additives ...................... 404
Air conditioner refrigerant .......... 404
Brake fluid ...................................... 404
Premium unleaded gasoline ........ 405
Fuel requirements ........................ 405
Gasoline additives ......................... 406
Coolants .......................................... 406
Consumer information ................. 408

402 Fuels, coolants, lubricants etc. - capacities
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Fuels, coolants, lubricants etc. - capacities
Vehicle components and their respective lubricants must match. Therefore use only brands tested and recommended
by us. Please refer to the Factory Approved Service Products pamphlet, or inquire at your Mercedes-Benz Center.
Model Capacity Fuels, coolants, lubricants etc.
Engine with oil filter S 430, S 500
S 55 AMG
S 6008.5 US qt (8.0 l)
8.0 US qt (7.5 l)
10.0 US qt (9.5 l)Recommended engine oils
Automatic
transmission9.6 US qt (9.1 l) Automatic transmission fluid
Rear axle 1.7 US qt (1.6 l) Hypoid gear oil SAE 85 W 90
Hydraulic system for
adaptive damping
system (ADS) or active
body control (ABC)approx. 5.3 US qt (5.0 l) MB Hydraulic fluid
Power steering approx. 1.1 US qt (1.0 l) MB Power steering fluid
Front wheel hubs approx. 2.1 oz (60 g) each High temperature roller bearing grease
Brake system 0.7 US qt (0.7 l) MB Brake fluid (DOT 4+)
Cooling system S 430, S 500
S 55 AMG
S 600approx. 12.1 US qt (11.5 l)
approx. 12.1 US qt (11.5 l)
approx. 12.7 US qt (12.0 l)MB Anticorrosion / antifreeze

403 Fuels, coolants, lubricants etc. - capacities
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including a reserve of23.2 US gal (88.0 l)
2.9 US gal (11.0 l)Premium unleaded gasoline: Posted
Octane 91
(Avg. of 96 RON / 86 MON)
Air conditioner system R-134a refrigerant and special PAG
lubricant
Windshield washer
and headlamp
cleaning system7.1 US qt (6.7 l) MB Windshield washer concentrate
1
1 Use MB Windshield Washer Concentrate “S” and water for temperatures above freezing or MB Windshield Washer Concentrate “S” and
commercially available premixed windshield washer solvent / antifreeze for temperatures below freezing. Follow suggested mixing ratios, see
page 345.
Model Capacity Fuels, coolants, lubricants etc.

404 Fuels, coolants, lubricants etc. - capacities
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Engine oils
Engine oils are specifically tested for their suitability in
our engines. Therefore, use only engine oils
recommended by Mercedes-Benz. Information on
recommended brands is available in the Factory
Approved Service Product pamphlet, or at your
authorized Mercedes-Benz Center.
Please follow Service Booklet recommendations for
scheduled oil changes. Failure to do so could result in
engine damage not covered by the Mercedes-Benz
Limited Warranty.
Engine oil additives
Do not blend oil additives with engine oil. They may be
harmful to the engine operation.
Damage or malfunctions resulting from blending oil
additives are not covered by the Mercedes-Benz Limited
Warranty.Air conditioner refrigerant
R-134a (HFC) refrigerant and special PAG lubricating oil
is used in the air conditioner system.
Never use R-12 (CFC) or mineral-based lubricating oil,
otherwise damage to the system will occur.
Brake fluid
During vehicle operation, the boiling point of the brake
fluid is continuously reduced through the absorption of
moisture from the atmosphere. Under extremely hard
operating conditions, this moisture content can lead to
the formation of bubbles in the system thus reducing
the system’s efficiency.
The brake fluid must therefore be replaced every two
years, preferably in the spring.
It is recommended to use only brake fluid approved by
Mercedes-Benz. Your authorized Mercedes-Benz Center
will provide you with additional information.

405 Fuels, coolants, lubricants etc. - capacities
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Caution!
To maintain the engine’s durability and performance,
premium unleaded gasoline must be used. If premium
unleaded is not available and low octane fuel is used,
follow these precautions:
•have the fuel tank filled only partially with unleaded
regular and fill up with premium unleaded as soon
as possible,
•avoid full throttle driving and abrupt acceleration,
•do not exceed an engine speed of 3000 rpm, if the
vehicle is loaded with a light load such as two
persons and no luggage,
•do not exceed
2/3 of maximum accelerator pedal
position, if the vehicle is fully loaded or operating in
mountainous terrain.Fuel requirements
Use only Premium unleaded meeting ASTM
standard D 439:
The octane number (posted at the pump) must be
91 min. It is an average of both the Research (R) octane
number and the Motor (M) octane number: (R+M) / 2).
This is also known as ANTI-KNOCK INDEX.
Unleaded gasoline containing oxygenates such as
Ethanol, IPA, IBA and TBA can be used provided the
ratio of any one of these oxygenates to gasoline does not
exceed 10%, MTBE not to exceed 15%.
The ratio of Methanol to gasoline must not exceed 3%
plus additional cosolvents.
Using mixtures of Ethanol and Methanol is not allowed.
Gasohol, which contains 10% Ethanol and 90% unleaded
gasoline, can be used.
These blends must also meet all other fuel requirements
such as resistance to spark knock, boiling range, vapor
pressure etc..

406 Fuels, coolants, lubricants etc. - capacities
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Gasoline additives
A major concern among engine manufacturers is carbon
build up caused by gasoline. Mercedes-Benz
recommends the use of only quality gasoline containing
additives that prevent the build up of carbon deposits.
After an extended period of using fuels without such
additives, carbon deposits can build up especially on the
intake valves and in the combustion area, leading to
engine performance problems such as:
•warm-up hesitation,
•unstable idle,
•knocking / pinging,
•misfire,
•power loss.
Do not blend other specific fuel additives with fuel.
They only result in unnecessary cost, and may be
harmful to the engine operation.
Damage or malfunctions resulting from poor fuel
quality or from blending specific fuel additives are not
covered by the Mercedes-Benz Limited Warranty.Coolants
The engine coolant is a mixture of water and
anticorrosion / antifreeze, which provides:
•corrosion protection,
•freeze protection,
•boiling protection (by increasing the boiling point).
The cooling system was filled at the factory with a
coolant providing freeze protection to approximately
-22
°F (-30
°C) and corrosion protection.
If the antifreeze mixture is effective to -22
°F (-30
°C), the
boiling point of the coolant in the pressurized cooling
system is reached at approximately 266
°F (130
°C).
The coolant solution must be used year round to provide
the necessary corrosion protection and increase in the
boil-over protection. You should have it replaced every
3years.
To provide the important corrosion protection, the
solution must be at least 45% anticorrosion / antifreeze
(equals a freeze protection to approx. - 22
°F [- 30
°C]). If
you use a solution that is more than 55% anticorrosion /
antifreeze (freeze protection to approx. - 49
°F [- 45
°C]),

407 Fuels, coolants, lubricants etc. - capacities
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heat transfer capability of the solution. Therefore, do not
use more than this amount of anticorrosion / antifreeze.
If the coolant level is low, water and MB anticorrosion /
antifreeze should be used to bring it up to the proper
level (have cooling system checked for signs of leakage).
The water in the cooling system must meet minimum
requirements, which are usually satisfied by normal
drinking water. If your are not sure about the water
quality, consult your authorized Mercedes-Benz Center.
Anticorrosion / antifreeze
Your vehicle contains a number of aluminium parts. The
use of aluminium components in motor vehicle engines
necessitates that anticorrosion / antifreeze coolant used
in such engines be specifically formulated to protect the
aluminium parts. (Failure to use such anticorrosion /
antifreeze coolant will result in a significantly
shortened service life.)
Therefore the following product is strongly
recommended for use in your vehicle: Mercedes-Benz
anticorrosion / antifreeze agent.Before the start of the winter season (or once a year in
the hot southern regions), you should have the
anticorrosion / antifreeze concentration checked. The
coolant is also regularly checked each time you bring
your vehicle to your authorized Mercedes-Benz Center
for service.
Anticorrosion / antifreeze quantity
Model Approx. freeze protection
– 35
°F
(– 37°C)– 49
°F
(– 45°C)
S 430, S 500,
S 55 AMG6.1 US qt
(5.75 l)6.7 US qt
(6.3 l)
S 600 6.3 US qt
(6.0 l)7. 0 U S q t
(6.6 l)

411 Index
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cluster displayPractical hints Car careIndex Economy mode ...........................................................176
Front center console
storage compartment ventilation ...................... 178
MAXCOOL .......................................................... 170, 181
Rear window defroster ............................................. 183
Residual engine heat utilization (REST) ................176
Special settings ......................................................... 172
Switching on and off ................................................ 177
Automatic climate control, rear
Air volume, manual .................................................. 181
Basic setting .............................................................. 181
Automatic maximum cooling ....................................... 170
Rear passenger compartment climate control ..... 181
Automatic transmission ...............................................237
Emergency operation ...............................................245
Fluid level ...................................................................343
Program mode selector switch ............................... 244
Selector lever position ..............................................240
BBabySmart
TM airbag deactivation system ..................... 88
Self-test ......................................................................... 88
BAS (Brake assist system) ............................................ 277
Battery .............................................................................357Battery recycling ...................................................... 358
BATTERY / ALTERNATOR -
malfunction and warning messages ...................... 311
Block heater ................................................................... 255
BRAKE ASSIST -
malfunction and warning messages ...................... 312
Brake assist system (BAS) ........................................... 277
Brake fluid .................................. 248, 299, 304, 402, 404
BRAKE FLUID -
malfunction and warning messages ...................... 313
Brake pad wear ............................................................... 313
BRAKE PAD WEAR -
malfunction and warning messages ...................... 313
Brake warning lamp ..................................................... 304
Brake fluid low ......................................................... 304
Brakes .......................................... 246, 248, 277, 278, 280
Bulbs
See Replacing bulbs ................................................. 364
CCapacities
Fuels, coolants, lubricants etc. .............................. 402
Card, KEYLESS-GO ..........................................................28
Catalytic converter ........................................................ 228
Center console .................................................................. 24