octane MERCEDES-BENZ S65AMG 2010 W221 Owner's Manual

ESC OFF ........................................ 495
Fog lamps ...................................... 300
Front passenger front air bag
off ............................................ 46, 498
Fuel tank reserve ........................... 496
High-beam headlamps .............32, 301
Instrument cluster .........................489
Low-beam headlamps ....................299
Low tire pressure/TPMS
malfunction telltale ........................497
Seat belt telltale ................32, 52, 493
SRS .......................................... 40, 494
Turn signals ..................................... 32
Lane Keeping Assist .......................... 362
Messages in the multifunction
display ........................................... 462
Switching on or off ......................... 233
Language settings ............................... 94
LATCH-type child seat anchors (ISOFIX) see Children in the vehicle
License plate lamps
Messages in the multifunction
display ........................................... 486
Light alloy wheels, cleaning ............. 445
Lighters see Cigarette lighters
Lighting .............................................. 298
Daytime running lamp mode ..........299
Exterior .......................................... 298
Interior ........................................... 304
Limp-home mode .............................. 325
Load index (tires) ...................... 426, 431
Loading see Vehicle loading
Locking the vehicle
KEYLESS-GO .................................. 275
Manually ........................................ 500
SmartKey ....................................... 274
Loss of
Key ................................................ 277
Service and Warranty Information
booklet .......................................... 524
Low-beam headlamps ....................... 299
Exterior lamp switch ......................298
Switching on .................................. 299
Lubricants .......................................... 537M
Maintenance ........................................ 22
Maintenance Call, automatic (Tele
Aid) ..................................................... 395
Maintenance System
Service indicator display ................439
Service indicator message .............439
Service term exceeded ..................439
Manual headlamp mode (Low-
beam headlamps) .............................. 299
Manual shift program ....................... 324
Maximum engine speed see Vehicle specification
Maximum loaded vehicle weight ..... 431
Maximum load rating (tires) ............. 431
Maximum permissible tire
inflation pressure .............................. 431
Mechanical key see Key, Mechanical
Media interface ................................. 200
Memory function ............................... 297
Menus see Control system menus
Minispare wheel
see Spare wheel
Mirrors ............................................... 294
Auto-dimming rear view mirrors ....295
Exterior rear view mirror parking
position .......................................... 295
Exterior rear view mirrors ..............295
Front vanity mirrors .......................386
Interior rear view mirror .................294
Memory function ........................... 297
Power-folding exterior rear view
mirrors ........................................... 296
Rear vanity mirrors ........................386
MON (Motor Octane Number) .......... 541
Motor Octane Number see MON
MP3 .................................................... 176
Multicontour seats, front ................. 218
Multicontour seats, rear ................... 293
Multifunction display ........................ 222
Symbol messages ..........................466
Text messages ............................... 454
Vehicle status messages ...............45212Index221_AKB; 6; 20, en-USd2ugruen,Version: 2.11.8.12009-09-24T13:28:17+02:00 - Seite 12

PRE-SAFE®
............................................ 54
Messages in the multifunction
display ........................................... 454
PRE-SAFE ®
Brake ................................. 69
Activating/deactivating .................232
Messages in the multifunction
display ........................................... 454
Problems
While driving .................................. 314
With vehicle ..................................... 24
With wipers .................................... 306
Product information ............................ 21
Production options weight ............... 431
Program mode selector switch
Automatic shift program ................322
Manual shift program ..................... 324
Proximity key
see Key, SmartKey
PSI (air pressure unit) ....................... 431
R
RACETIMER ........................................ 228
Radar sensors
Messages in the multifunction
display ........................................... 461
Switching on or off ......................... 236
Radio .................................................. 165
HD Radio™ .................................... 167
Satellite radio ................................ 170
Selecting stations ..........................226
Radio transmitters ............................ 438
Rain sensor see Intermittent wiping
Rear axle oil ....................................... 538
Rear door ashtray see Ashtrays
Rear doors
Child safety locks ............................ 61
Rear door window
Override switch ................................ 61
Sunshades ..................................... 308
Rear fog lamp
see Fog lamps
Rear Seat Entertainment System .... 189
AUX sockets .................................. 187
CD/DVD drive ............................... 180
Headphone ...................................... 82
Remote control ................................ 81
Rear seat head restraints
see Head restraints
Rear view camera .............................. 354
Cleaning the camera lens ..............444
Rear window defroster ..................... 372
Recommended tire inflation
pressure ..................................... 411, 431
Refrigerant, air conditioning ............ 540
Refueling ............................................ 402
Regular checks .................................. 403
Reminder, Seat belt see Seat belts, Telltale
Remote control
see Key, SmartKey
Remote control (Rear Seat
Entertainment System) ....................... 81
Replacing batteries ........................502
Remote control (SPLITVIEW) .............. 81
Replacing batteries ........................502
Remote door lock (Tele Aid) ............. 394
Remote door unlock (Tele Aid) ......... 394
Replacing
Key ................................................ 278
Replacing bulbs ................................. 504
Reporting safety defects .................... 24
Research Octane Number see RON
Reserve fuel
Messages in the multifunction
display ........................................... 484
Reset tool (NECK-PRO active front
head restraints) ................................. 501
Restraint systems see Occupant safety
Retaining hook .................................. 381
Rims ........................................... 431, 532
Roadside Assistance ................... 22, 391
Roller sunblinds ................................. 375
RON (Research Octane Number) ..... 541
Roof rack ............................................ 380
Rubber parts, cleaning ...................... 446Index15221_AKB; 6; 20, en-USd2ugruen,Version: 2.11.8.12009-09-24T13:28:17+02:00 - Seite 15

contacting you in a timely manner should the
need arise.
If you sell your Mercedes, please leave all
literature with the vehicle to make it available
to the next operator.
If you bought this vehicle used, be sure to
send in the “Notice of Purchase of Used Car”
found in the Service and Warranty
Information Booklet, or call the Mercedes-
Benz Customer Assistance Center (in the
USA) at 1-800-FOR-MERCedes
(1-800-367-6372), or Customer Service (in
Canada) at 1-800-387-0100.
Operating your vehicle outside the
USA or Canada
If you plan to operate your vehicle in foreign
countries, please be aware that:
R Service facilities or replacement parts may
not be readily available.
R Unleaded gasoline for vehicles with
catalytic converters may not be available;
the use of leaded fuels will damage the
catalysts.
R Gasoline may have a considerably lower
octane rating, and improper fuel can cause
engine damage.
Certain Mercedes-Benz models are available
for delivery in Europe under our European
Delivery Program. For details, consult an
authorized Mercedes-Benz Center or write to:
In the USA:
Mercedes-Benz USA, LLC
European Delivery Department
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada:
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9
Operating safetyGWarning!
Work improperly carried out on electronic
components and associated software could
cause them to cease functioning. Because the
vehicle’s electronic components are
interconnected, any modifications made may
produce an undesired effect on other
systems. Electronic malfunctions could
seriously impair the operating safety of your
vehicle.
Contact an authorized Mercedes-Benz Center
for repairs or modifications to electronic
components.
Other improper work or modifications on the
vehicle could also have a negative impact on
the operating safety of the vehicle.
Some safety systems only function while the
engine is running. You should therefore never
turn off the engine while driving.
GWarning!
Heavy blows against the vehicle underbody or
tires/wheels may cause serious damage and
impair the operating safety of your vehicle.
Such blows can be caused, for example, by
running over an obstacle, road debris or a
pothole. If you feel a sudden significant
vibration or ride disturbance, or you suspect
that damage to your vehicle as occurred:
R turn on your hazard warning flashers
R slow down carefully
R drive with caution to an area which is a safe
distance from the road
Inspect the vehicle underbody and tires/
wheels for possible damage. If the vehicle
appears unsafe, have it towed to the nearest
authorized Mercedes-Benz Center or other
qualified maintenance or repair facility for
further inspection or repairs.
Introduction23221_AKB; 6; 20, en-USd2ugruen,Version: 2.11.8.12009-09-24T13:28:17+02:00 - Seite 23Z

Mercedes-Benz Center to have the fuel
system drained completely.
! To prevent damage to the catalytic
converters, only use premium unleaded
gasoline in this vehicle.
Any noticeable irregularities in engine
operation should be repaired promptly.
Otherwise, excessive unburned fuel may
reach the catalytic converter, causing it to
overheat and potentially start a fire.
i Only use premium unleaded gasoline with
a minimum Posted Octane Rating of 91
(average of 96 RON/86 MON).
Information on gasoline quality can
normally be found on the fuel pump. Please
contact gas station personnel in case
labels on the pump cannot be found.
For more information on gasoline, see
“Premium unleaded gasoline”
(Y page 541), see “Fuel requirements”
(Y page 541), or contact an authorized
Mercedes-Benz Center, or visit
www.mbusa.com (USA only).
Locking/unlocking the vehicle with the
SmartKey or KEYLESS-GO automatically
locks/unlocks the fuel filler flap.
iIn case the central locking system does
not release the fuel filler flap, or the
opening mechanism is clamping, contact
Roadside Assistance or an authorized
Mercedes-Benz Center.
The fuel filler flap is located on the right-hand
side of the vehicle towards the rear.
XTurn off the engine.
iLeaving the engine running and the fuel
filler cap open can cause the yellow engine
malfunction indicator lamp ; to
illuminate.
For more information, see also “Practical
hints” (Y page 496).
XRemove the SmartKey from the starter
switch.
KEYLESS-GO: Open the driver’s door. This
puts the starter switch in position 0, same
as with the SmartKey removed from the
starter switch. The driver’s door then can
be closed again.
XOpening: Press fuel filler flap : at the
point indicated by the arrow.
XTurn fuel filler cap ; counterclockwise.XTake off fuel filler cap ;.XPlace fuel filler cap ; in direction of arrow
into holder =.
XFully insert filler nozzle unit and refuel.XOnly fill your tank until the filler nozzle unit
cuts out – do not top off or overfill.
XClosing: Turn fuel filler cap ; clockwise
until it audibly engages.
iClose the fuel filler flap before locking the
vehicle. Otherwise the flap locking pin will
prevent closing the fuel filler flap.
XClose fuel filler flap :.
Check regularly and before a long trip
For information on quantities and
requirements of operating agents, see “Fuels,
coolants, lubricants, etc.” (Y page 537).
Check the following:
REngine oil level (Y page 405)
RTire inflation pressure (Y page 413)
RCoolant level (Y page 408)
RVehicle lighting (Y page 504)
At the gas station403Operation221_AKB; 6; 20, en-USd2ugruen,Version: 2.11.8.12009-09-24T13:28:17+02:00 - Seite 403Z

Vehicle specification S 450 4MATIC
(221.084)
The quoted data apply only to the standard
vehicle. Contact an authorized Mercedes-
Benz Center for the corresponding data of all
special bodies and special equipment.
i The S 450 4MATIC is available in Canada
only.Engine S 450 4MATICEngine, type273Mode of operation4-stroke engine,
gasoline injectionNo. of cylinders8Bore3.66 in (92.90 mm)Stroke3.39 in (86.00 mm)Total piston
displacement284.6 cu in
(4 663 cm 3
)Compression
ratio10.5:1Output acc. to
SAE J 1349 46335 hp/6
000 rpm
(250 kW/6 000 rpm)Maximum torque
acc. to SAE J 1349339 lb-ft/
2 700 - 5 000 rpm
(460 Nm/
2 700 - 5 000 rpm)Maximum engine
speed6 500 rpmFiring order1-5-4-2-6-3-7-8Poly-V-belt2 404 mmElectrical system S 450 4MATICAlternator14 V/180 AStarter motor12 V/1.7 kWElectrical system S 450 4MATICBattery12 V/95 AhSpark plugs, typeNGK PLKR 6ABosch Y 7 MPP33Spark plugs,
electrode gap0.031 in (0.8 mm)Spark plugs,
tightening torque15 - 18 lb-ft
(20 - 25 Nm)Main dimensions S 450 4MATICOverall vehicle
length200.1 in (5 100 mm)Overall vehicle
width 4783.5 in (2
120 mm)Overall vehicle
height58.2 in (1 479 mm)Wheelbase119.5 in (3 035 mm)Track, front63.0 in (1 600 mm)Track, rear63.2 in (1 606 mm)Turning circle38.7 ft (11.8 m)Weights S 450 4MATICRoof loadmax. 220 lb (100 kg)Trunk loadmax. 220 lb (100 kg)
Vehicle specification S 550 (221.171)
The quoted data apply only to the standard
vehicle. Contact an authorized Mercedes-
Benz Center for the corresponding data of all
special bodies and special equipment.
i The S 550 is available in the USA only.
46
Premium fuel required. Performance may vary with fuel octane rating.
47 Exterior rear view mirrors folded out.Vehicle specification S 550 (221.171)527Technical data221_AKB; 6; 20, en-USd2ugruen,Version: 2.11.8.12009-09-24T13:28:17+02:00 - Seite 527Z

Engine S 550Engine, type273Mode of operation4-stroke engine,
gasoline injectionNo. of cylinders8Bore3.86 in (98.00 mm)Stroke3.56 in (90.50 mm)Total piston
displacement333.3 cu in
(5 461 cm 3
)Compression
ratio10.7:1Output acc. to
SAE J 1349 48382 hp/6
000 rpm
(285 kW/6 000 rpm)Maximum torque
acc. to SAE J 1349391 lb-ft/3 000 rpm
( 530 Nm/3 000 rpm)Maximum engine
speed6 500 rpmFiring order1-5-4-2-6-3-7-8Poly-V-belt2 404 mmElectrical system S 550Alternator14 V/180 AStarter motor12 V/1.7 kWBattery12 V/95 AhSpark plugs, typeNGK PLKR 6ABosch Y 7 MPP33Spark plugs,
electrode gap0.031 in (0.8 mm)Spark plugs,
tightening torque15 - 18 lb-ft
(20 - 25 Nm)Main dimensions S 550Overall vehicle
length206.7 in (5 250 mm)Overall vehicle
width 4983.5 in (2
120 mm)Overall vehicle
height58.2 in (1 479 mm)Wheelbase124.6 in (3 165 mm)Track, front63.0 in (1 600 mm)Track, rear63.2 in (1 606 mm)Turning circle40.0 ft (12.2 m)Weights S 550Roof loadmax. 220 lb (100 kg)Trunk loadmax. 220 lb (100 kg)
Vehicle specification S 550 4MATIC
(221.186)
The quoted data apply only to the standard
vehicle. Contact an authorized Mercedes-
Benz Center for the corresponding data of all
special bodies and special equipment.
Engine S 550 4MATICEngine, type273Mode of operation4-stroke engine,
gasoline injectionNo. of cylinders8Bore3.86 in (98.00 mm)Stroke3.56 in (90.50 mm)Total piston
displacement333.3 cu in
(5 461 cm 3
)48 Premium fuel required. Performance may vary with fuel octane rating.
49 Exterior rear view mirrors folded out.528Vehicle specification S 550 4MATIC (221.186)Technical data
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Engine S 550 4MATICCompression
ratio10.5:1Output acc. to
SAE J 1349 50382 hp/6
000 rpm
(285 kW/6 000 rpm)Maximum torque
acc. to SAE J 1349391 lb-ft/
2 800 - 4 800 rpm
(530 Nm/
2 800 - 4 800 rpm)Maximum engine
speed6 500 rpmFiring order1-5-4-2-6-3-7-8Poly-V-belt2 404 mmElectrical system S 550 4MATICAlternator14 V/180 AStarter motor12 V/1.7 kWBattery12 V/95 AhSpark plugs, typeNGK PLKR 6ABosch Y 7 MPP33Spark plugs,
electrode gap0.031 in (0.8 mm)Spark plugs,
tightening torque15 - 18 lb-ft
(20 - 25 Nm)Main dimensions S 550 4MATICOverall vehicle
length206.7 in (5 250 mm)Overall vehicle
width 5183.5 in (2
120 mm)Overall vehicle
height58.2 in (1 479 mm)Main dimensions S 550 4MATICWheelbase124.6 in (3 165 mm)Track, front63.0 in (1 600 mm)Track, rear63.2 in (1 606 mm)Turning circle40.0 ft (12.2 m)Weights S 550 4MATICRoof loadmax. 220 lb (100 kg)Trunk loadmax. 220 lb (100 kg)
Vehicle specification S 600 (221.176)
The quoted data apply only to the standard
vehicle. Contact an authorized Mercedes-
Benz Center for the corresponding data of all
special bodies and special equipment.
Engine S 600Engine, type275Mode of operation4-stroke engine,
gasoline injectionNo. of cylinders12Bore3.23 in (82.00 mm)Stroke3.43 in (87.00 mm)Total piston
displacement336.4 cu in
(5 513 cm 3
)Compression
ratio9.0:1Output acc. to
SAE J 1349 52510 hp/5
000 rpm
(380 kW/5 000 rpm)50
Premium fuel required. Performance may vary with fuel octane rating.
51 Exterior rear view mirrors folded out.
52 Premium fuel required. Performance may vary with fuel octane rating.Vehicle specification S 600 (221.176)529Technical data221_AKB; 6; 20, en-USd2ugruen,Version: 2.11.8.12009-09-24T13:28:17+02:00 - Seite 529Z

Engine S 600Maximum torque
acc. to SAE J 1349612 lb-ft/
1 800 - 3 500 rpm
(830 Nm/
1 800 - 3 500 rpm)Maximum engine
speed5 950 rpmFiring order1-12-5-8-3-10-
6-7-2-11-4-9Poly-V-belt2 370 mmElectrical system S 600Alternator14 V/220 AStarter motor12 V/2.0 kWBattery12 V/95 AhSpark plugs, typeNGK IFR 6Q-GSpark plugs,
electrode gap0.028 in (0.7 mm)Spark plugs,
tightening torque15 - 22 lb-ft
(20 - 30 Nm)Main dimensions S 600Overall vehicle
length206.7 in (5 250 mm)Overall vehicle
width 5383.5 in (2
120 mm)Overall vehicle
height58.2 in (1 479 mm)Wheelbase124.6 in (3 165 mm)Track, front63.0 in (1 600 mm)Track, rear63.2 in (1 606 mm)Turning circle40.0 ft (12.2 m)Weights S 600Roof loadmax. 220 lb (100 kg)Trunk loadmax. 220 lb (100 kg)
Vehicle specification S 63 AMG
(221.177)
The quoted data apply only to the standard
vehicle. Contact an authorized Mercedes-
Benz Center for the corresponding data of all
special bodies and special equipment.
Engine S 63 AMGEngine, type156Mode of operation4-stroke engine,
gasoline injectionNo. of cylinders8Bore4.02 in (102.20 mm)Stroke3.72 in (94.60 mm)Total piston
displacement378.8 cu in
(6 208 cm 3
)Compression
ratio11.3:1Output acc. to
SAE J 1349 54518 hp/6
800 rpm
(386 kW/6 800 rpm)Maximum torque
acc. to SAE J 1349465 lb-ft/5 200 rpm
( 630 Nm/5 200 rpm)Maximum engine
speed7 200 rpmFiring order1-5-4-2-6-3-7-8Poly-V-belt2 360 mm53
Exterior rear view mirrors folded out.
54 Premium fuel required. Performance may vary with fuel octane rating.530Vehicle specification S 63 AMG (221.177)Technical data
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Electrical system S 63 AMGAlternator14 V/220 AStarter motor12 V/2.1 kWBattery12 V/95 AhSpark plugs, typeNGK ILZKAR 7A10Spark plugs,
electrode gap0.039 in (1.0 mm)Spark plugs,
tightening torque15 - 18 lb-ft
(20 - 25 Nm)Main dimensions S 63 AMGOverall vehicle
length207.1 in (5 261 mm)Overall vehicle
width 5583.5 in (2
120 mm)Overall vehicle
height58.7 in (1 490 mm)Wheelbase124.6 in (3 165 mm)Track, front63.0 in (1 600 mm)Track, rear63.2 in (1 606 mm)Turning circle40.0 ft (12.2 m)Weights S 63 AMGRoof loadmax. 220 lb (100 kg)Trunk loadmax. 220 lb (100 kg)
Vehicle specification S 65 AMG
(221.179)
The quoted data apply only to the standard
vehicle. Contact an authorized Mercedes-
Benz Center for the corresponding data of all
special bodies and special equipment.
Engine S 65 AMGEngine, type275Mode of operation4-stroke engine,
gasoline injectionNo. of cylinders12Bore3.25 in (82.60 mm)Stroke3.66 in (93.00 mm)Total piston
displacement364.9 cu in
(5 980 cm 3
)Compression
ratio9.0:1Output acc. to
SAE J 1349 56603 hp/
4 800 - 5 100 rpm
(450 kW/
4 800 - 5 100 rpm)Maximum torque
acc. to SAE J 1349738 lb-ft/
2 000 - 4 000 rpm
(1 000 Nm/
2 000 - 4 000 rpm)Maximum engine
speed5 950 rpmFiring order1-12-5-8-3-10-
6-7-2-11-4-9Poly-V-belt2 370 mmElectrical system S 65 AMGAlternator14 V/220 AStarter motor12 V/1.7 kWBattery12 V/95 AhSpark plugs, typeNGK IFR 6Q-G55
Exterior rear view mirrors folded out.
56 Premium fuel required. Performance may vary with fuel octane rating.Vehicle specification S 65 AMG (221.179)531Technical data221_AKB; 6; 20, en-USd2ugruen,Version: 2.11.8.12009-09-24T13:28:17+02:00 - Seite 531Z

ModelCapacityFuels, coolants,
lubricants, etc.Cooling
system,
vehicles with
rear climate
controlS 450 4MATIC 69approx. 17.1 US qt (16.2 l)S 55070
S 550 4MATICapprox. 13.8 US qt (13.1 l)S 600
S 65 AMGapprox. 15.9 US qt (15.0 l)S 63 AMGapprox. 11.8 US qt (11.2 l)Low
temperature
cooling systemS 600approx. 2.8 US qt (2.6 l)S 65 AMGapprox. 3.3 US qt (3.1 l)Fuel tankAll models23.8 US gal (90.0 l)Premium unleaded
gasoline (Minimum
Posted Octane 91
[Avg. of
96 RON/86 MON])Fuel tank
reserveS 450 4MATIC 69
S 550 70
S 550 4MATIC
S 600approx. 2.9 US gal (11.0 l)S 63 AMG
S 65 AMGapprox. 3.7 US gal (14.0 l)Air
conditioning
systemAll models—R134a refrigerant
and special
PAG lubricant oil
(never R 12)Washer system
and headlamp
cleaning
systemAll models6.9 US qt (6.5 l)MB Windshield
Washer
Concentrate 73
( Y page 544)
Washer fluid mixing
ratio ( Y page 544)Approved engine oils
Engine oils are specifically tested for their
suitability in our engines and durability for our
service intervals. Therefore, only use
approved engine oils and oil filters required
for vehicles with the Maintenance System.For a listing of approved engine oils and oil
filters, contact an authorized Mercedes-Benz
Center or visit www.mbusa.com (USA only).
! Using engine oils and oil filters of a
specification other than those expressly69 Canada only.
70 USA only.
73 Mixed with water or commercially available premixed washer solvent/antifreeze.Fuels, coolants, lubricants, etc.539Technical data221_AKB; 6; 20, en-USd2ugruen,Version: 2.11.8.12009-09-24T13:28:17+02:00 - Seite 539Z