MERCEDES-BENZ S-CLASS SALOON 2022 Owners Manual

If
yo u or other people come into contact with
fuel, obser vethefo llowing: #
Immediate lyrinse fuel o. your skin with
soap and water. #
If fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical at tention
immedia tely. #
Ifyo u swallow fuel, seek medical atten-
tion immediatel y.Do not induce vomit-
ing. #
Change immediately out of clo thing that
has come into contact with fuel. &
W
WARNING
ARNING Risk of /re and explosion due
to electrostatic charge
Electrostatic charge can ignite fuel vapour. #
Before you open the fuel /ller cap or
ta ke hold of the pump nozzle, touch the
me tallic vehicle body. #
Toavo id creating ano ther electrostatic
ch arge , do not get into theve hicle again
during there fuelling process. *
N
NOOTE
TE Dama gecaused bythe wrong fuel Ve
hicles with a petrol engine:
Even small amounts of the wrong fuel could
re sult in damage tothe fuel system, the
engine and the emission control system. #
Only refuel using unleaded, sulphur-free
spar k-ignition engine fuel that conforms
to European EN 228, or an equivalent
speci/cation.
Fu el of this speci/cation may contain up to
10% ethanol. Your vehicle is suitable for use
with E10 fuel.
Ne verre fuel wi thone of thefo llowing fuels:
R Diesel
R Regular petrol with an octane number
lo we rth an 91 RON R
Petrol with more than 10% ethanol byvol-
ume, e.g. E15, E20, E85, E100
R Petrol with more than 3% me thanol byvol-
ume, e.g. M15, M30
R Petrol with additives containing me tal
If yo u ha veacciden tally refuelled wi th the
wrong fuel: #
Do not switch on theve hicle. #
Consult a quali/ed specialist workshop. *
N NOOTE
TE Do not use diesel torefuel vehicles
with a petrol engine If
yo u ha veacciden tally refuelled wi th the
wrong fuel:
R Do not switch on theve hicle. Otherwise
fuel can enter the engine.
Even small amounts of the wrong fuel
could result in damage tothe fuel system
and the engine. The repair costs are high. #
Consult a quali/ed specialist workshop. 218 218
Driving and parking

#
Have the fuel tank and fuel lines drained
comple tely. *
N
NO
OTE
TE Damage tothe fuel system due to
ove r/lling the fuel tank #
Only /ll the fuel tank until the pump noz-
zle switches o..
If to o much fuel has been added due, for
ex ample, toafa ulty /lling pump: #
Do not switch on theve hicle. #
Consult a quali/ed specialist workshop. *
N
NOOTE
TE Fuel may spr ayout when you
re mo vethe fuel pump nozzle #
Only /ll the fuel tank until the pump noz-
zle switches o.. R
R
eq
eq uir
uir ements:
ements:
R The vehicle is unloc ked. %
Do not getinto theve hicle again during the
re fuelling process. Othe rwise, electrostatic
ch arge could build up again.
Obser vethe no tes on operating 0uids and fuel.
The recommended octane number foryo ur vehi-
cle can be found on the information label in the
fuel /ller 0ap. 1
Fuel /ller 0ap
2 Brac ketfo r fuel /ller cap
3 Tyre pressure table
4 QR code forre scue card
5 Fuel type #
Press on the back area of fuel /ller 0ap 1. #
Turn the fuel /ller cap anti-clockwise and
re mo veit. Driving and parking
219
219

#
Insert fuel /ller cap from abo veinto brac ket
2 . #
Comple tely insert the pump nozzle into the
ta nk /ller nec k,hook in place and refuel. #
Only /ll the fuel tank until the pump nozzle
switches o.. #
Replace the cap on the /ller neck and turn
clockwise until it engages audibl y.#
Close fuel /ller 0ap 1.P
P
ar
ar king
king P
P
ar
ar king t
king t he v
he vehicle
ehicle &
W
WARNING
ARNING Risk of accident and injury
caused byan insu1ciently secured vehi-
cle rolling away
If th eve hicle is not securely par ked su1-
cient ly,it can rollawa y in an uncontrolled way
eve n at a slight downhill gradient. #
On uphill or downhill gradients, turn the
front wheels so that theve hicle rolls
to wa rdsth eke rb if it starts moving. #
apply the parking brake. #
Switch the transmission toposition j. &
W
WARNING
ARNING Risk of /re caused byhot
ex haust system parts
Flammable materials such as lea ves, grass or
twigs may ignite. #
Park theve hicle so that no 0ammable
material can come into contact with hot
ve hicle components. #
In particular, do not park on dry grass-
land or har vested grain /elds. &
W WARNING
ARNING Risk of accident and injury due
to leaving children unattended in theve hi-
cle
If ch ildren are leT unattended in theve hicle,
th ey could, in particular:
R open doors, thereby endangering other
persons or road users.
R get out and be struck byoncoming tra1c. R
operate vehicle equipment and become
trapped, forex ample.
In addition, thech ildren could also set the
ve hicle in motion by,fo rex ample:
R releasing the parking brake.
R changing the transmission position.
R starting theve hicle. #
Never lea vechildren unattended in the
ve hicle. #
When leaving theve hicle, alw aysta ke the
ke y with you and lock theve hicle. #
Keep theve hicle key out of there ach of
ch ildren. *
N
NOOTE
TE Damage totheve hicle due toitro ll-
ing away #
Always secure theve hicle against rolling
awa y. 220
220
Driving and parking

*
N
NO
OTE
TE Damage due totheve hicle lo wering V
V
ehicles wit
ehicles wit h AIRMA
h AIRMATIC or E-A
TIC or E-A CTIVE BOD
CTIVE BOD Y
Y
C
C ONTR
ONTR OL:
OL:The vehicle can lo wer because of
te mp erature di.erences or longer non-opera-
tional times. This can cause damage toparts
of the body. #
When stopping theve hicle and when
driving o., make sure that there are no
obstacles such as curbs under or in the
immediate vicinity of the body. #
Bring theve hicle toa standstill bypressing the
brake pedal. #
Ongradients, turn the front wheels so that the
ve hicle will rollto wa rdsth eke rb if it starts
moving. #
Apply the electric parking brake. #
Engage transmission position jin a station-
ary vehicle with the brake pedal applied
(/ page 214). #
Switch o. theve hicle bypressing the1 but-
to n. #
Release the service brake slo wly. #
Get out of theve hicle and lock it.
% When you park theve hicle, you can still oper-
ate the side windo wsand the panoramic slid-
ing sunroof for appr oximately four minutes if
th e driver's door is closed. Gar
Gar
ag
age door opener
e door opener Pr
Pr
ogr
ogr amming butt
amming butt ons f
ons for t
or the g
he g ar
arag
ag e door opener
e door opener &
D
DAN
AN GER
GER Risk of fatal injuries caused by
ex haust gases
Combustion engines emit poisonous exhaust
ga ses such as carbon monoxide. Inhaling
th ese exhaust gases is hazardous tohealth
and leads topoisoning. Driving and parking
221
221

#
Never lea vetheve hicle or, if present, the
stationa ryheater running in an enclosed
space without su1cient ventilation. &
W
WARNI NG
ARNI NGRisk of injury bybecoming
trapped when opening and closing a
ga rage door
When you operate or prog ram a garage door
with an integ ratedga rage door opener, per-
sons can become trapped or struck bythe
ga rage door if they stand wi thin its range of
mo vement. #
Always make sure that nobody is within
th era nge of thega rage door's mo ve-
ment. Before prog
ramming thega rage door opener, park
th eve hicle outside thega rage . Make sure that the
ve hicle is switched on but not star ted.
R R eq
eq uir
uir ements:
ements:
R The vehicle has been par ked outside the
gar age or outside thera nge of mo vement of
th e door. R
The vehicle is switched on.
R The vehicle has not been star ted.
% The garage door opener function is alw ays
av ailable when theve hicle is switched on. #
Press and hold but ton1, 2or3 that you
wish toprog ram.
Indicator lamp 40ashes yello w. %
It can take up to20 seconds before the indi-
cator lamp 0ashes yello w. #
Release the pr eviously pressed button.
Indicator lamp 4continues to0ash yello w. #
Point remo tecont rol5 from a distance of
1 cm to8 cm towa rds button 1,2or3. #
Press and hold button 6ofremo tecont rol
5 until one of thefo llowing signals appears:
R Indicator lamp 4lights up green continu-
ousl y.Prog ramming is comple te.
R Indicator lamp 40ashes green. Prog ram-
ming was successful. Additionall y,syn-
ch ronisation of thero lling code with the
door system must be car ried out. #
If indicator lamp 4does not light up or 0ash
gr een: repeat the procedure. #
Release all of the buttons.
% The remo tecont rolfo rth e door drive is not
included in the scope of delivery of thega rage
door opener. 222
222
Driving and parking

Sync
Sync
hr
hronising tonising t he r
he rolling code
olling code
R
R eq
eq uir
uir ements:
ements:
R The door system uses a rolling code.
R The vehicle must be within range of thega rage
door or door drive.
R The vehicle as well as persons and objects are
located outside thera nge of mo vement of the
door. #
Press the prog ramming button on the door
drive unit.
Initiate the next step within appr oximately
30 seconds. #
Press pr eviously prog rammed button 1,2
or 3 repeatedly until the door closes.
When the door closes, prog ramming is com-
ple ted.
% Please also read the operating inst ructions for
th e door drive.
T T r
roubleshoo
oubleshoo ting when pr
ting when progr ogramming t
amming t he r
he remo te
emo te
contr
contr ol
ol #
Check if the transmitter frequency of remo te
cont rol5 is suppor ted. #
Replace the batteries in remo tecont rol5. #
Hold remo tecont rol5 atvarious angles from
a distance of 1 cm to8 cm front of the inside
re arview mir ror.Yo u should test every position
fo r at least 25 seconds before trying ano ther
position. #
Hold remo tecont rol5 atthe same angles at
va rious distances in front of the inside rear
view mir ror.Yo u should test every position for
at least 25 seconds before trying ano ther
position. #
Onremo tecont rolsth at transmit only for a
limited period, press button 6onremo te
cont rol5 again before transmission ends. #
Angle the aerial line of thega rage door opener
unit towa rdsth ere mo tecont rol.
% It is possible that older garage doors cannot
be operated using there mo tecont rol in the
inside rearview mir roreve n aTer you ha ve
successfully per form ed the measures descri-
bed abo ve. If this is the case, contact the
HomeLink ®
Hotline. %
Support and additional information on pro-
gramming:
R Onthe HomeLink ®
Hotline on (0) 08000
466 354 65 or +49 (0) 6838 907-277
R Onthe Internet at https://
www.homelink.com
Opening or closing t Opening or closing t he g
he gar
arag
ag e door
e door
R
R eq
eq uir
uir ements:
ements:
R The cor responding button is prog rammed to
operate the door. #
Press and hold buttons 1,2or3 until the
door opens or closes. #
If indicator lamp 40ashes yellow aTer
appr oximately 20 seconds: press and hold the
pr ev iously pressed button again until the door
opens or closes.
Clear
Clear ing t
ing the g
he gar
arag
ag e door opener memory
e door opener memory #
Press and hold buttons 1and 3.
Indicator lamp 4lights up yello w. #
If indicator lamp 40ashes green: release
buttons 1and 3.
The entire memory has been dele ted. Driving and parking
223
223

Electr
Electr
ic par
ic parking br
king br ake
ake F
F
unction of t
unction of t he electr
he electric par
ic parking br
king br ak
ake (appl
e (appl ying
ying
aut
aut omaticall
omaticall y)
y) &
W
WARNING
ARNING Risk of accident and injury due
to leaving children unattended in theve hi-
cle
If ch ildren are leT unattended in theve hicle,
th ey could, in particular:
R open doors, thereby endangering other
persons or road users.
R get out and be struck byoncoming tra1c.
R operate vehicle equipment and become
trapped, forex ample.
In addition, thech ildren could also set the
ve hicle in motion by,fo rex ample:
R releasing the parking brake.
R changing the transmission position.
R starting theve hicle. #
Never lea vechildren unattended in the
ve hicle. #
When leaving theve hicle, alw aysta ke the
ke y with you and lock theve hicle. #
Keep theve hicle key out of there ach of
ch ildren. The electr
The electr
ic par
ic parking br
king br ak
ake is applied if t
e is applied if t he tr
he trans-
ans-
mission is in position
mission is in position j
jand one of t
and one of t he f
he follo
ollowing
wing
conditions is
conditions is ful/lled:
ful/lled:
R The vehicle is switched o..
R The seat belt tongue is not inse rted in the seat
belt buckle of the driver's seat and the driver's
door is opened.
% Toprev ent application: pull the handle of the
electric parking brake (/ page 225).
In t
In t he f
he f ollo
ollowing situations, t
wing situations, t he electr
he electric par
ic parking
king
br
br ak
ak e is also applied:
e is also applied:
R The HOLD function is keeping theve hicle sta-
tionar y.
R Active Parking Assist is keeping theve hicle
stationar y.
R Active Distance Assist DISTRONIC is bringing
th eve hicle toa standstill. R
In addition, one of t
In addition, one of t he f
he follo
ollowing conditions
wing conditions
mus
mus t be
t be ful/lled:
ful/lled:
- The vehicle is switched o..
- The seat belt tongue is not inse rted in the
seat belt buckle of the driver's seat and
th e driver's door is opened.
- There is a system malfunction.
- The po wer supply is insu1cient.
- The vehicle is stationary for a lengt hy
period.
When the electric parking brake is applied, the
re d! indicator lamp lights up in the driver's
displa y.
% The electric parking brake is not automatically
applied if theve hicle is switched o. bythe
ECO start/s top function.
F F unction of t
unction of t he electr
he electric par
ic parking br
king br ak
ake (r
e (r eleasing
eleasing
aut
aut omaticall
omaticall y)
y)
The electr
The electr ic par
ic parking br
king br ak
ake is r
e is r eleased when t
eleased when t he
he
f
f ollo
ollo wing conditions ar
wing conditions ar e
eful/lled:
ful/lled:
R The driver's door is closed.
R The vehicle has been star ted. 224
224
Driving and parking

R
The transmission is in position hork and
yo u depress the accelerator pedal or you shiT
from transmission position jtoh ork
when on le velgr ound.
R Ifth e transmission is in position k,the boot
lid must be closed.
R The seat belt tongue is inse rted into the seat
belt buckle of the driver's seat.
If th e seat belt tongue is not inse rted into the
seat belt buckle of the driver's seat, one of the
fo llowing conditions must be ful/lled:
- You shiT from transmission position j.
or
- You ha veprev iously driven at speeds
gre ater than 3 km/h.
When the electric parking brake is released, the
re d! indicator lamp in the driver's display
goes out. Appl
Appl
ying/r
ying/r eleasing t
eleasing t he electr
he electric par
ic parking br
king br ake
ake
manually
manually
Appl Appl ying
ying #
Push handle 1.
The red indicator lamp lights up in the driver's
display !. %
The electric parking brake is only securely
applied if there d! indicator lamp is lit
continuousl y.
R R eleasing
eleasing #
Switch on theve hicle. #
Pull handle 1.
The red! indicator lamp in the driver's
display goes out.
Emerg
Emerg ency br
ency br aking
aking #
Press and hold handle 1.
As long as theve hicle is in motion, the
Release parking brake message is displayed
and there d! indicator lamp 0ashes.
When theve hicle has been braked toa stand-
still, the electric parking brake is applied. The
re d! indicator lamp lights up in the driv-
er's displa y. Inf
Inf
or
ormation on collision det
mation on collision det ection on a park
ection on a parked
ed
v
v ehicle
ehicle If a collision is de
tected when theto w- awa y pro-
te ction is primed on a loc kedve hicle, you will Driving and parking
225
225

re
ceive a noti/cation in the multimedia system
when you switch theve hicle on.
Yo u will receive information about thefo llowing
points:
R The area of theve hicle that may ha vebeen
damaged.
R The forc e of the impact.
The following situation can lead toinadver tent
activation:
R The par kedve hicle is mo ved, forex ample, in a
two-s tore yga rage.
% Deactivate tow- awa y protection in order to
pr ev ent inadver tent activation. If you deacti-
va te to w-awa y protection, collision de tection
will also be deactivated.
Yo u can permanently deactivate collision
de tection via the multimedia system
(/ page 226). Syst Syst
em limits
em limits
De tection may be restric ted in thefo llowing situa-
tions:
R theve hicle is damaged without impact, for
ex ample, if an outside mir ror is torn o. or the
paint is damaged byakey
R an impact occurs at low speed
R the electric parking brake is not applied Se
Se
tting collision det
tting collision det ection on a park
ection on a parked v
ed vehicle
ehicle Multimedia system:
4 © 5
Settings 5
Vehicle
5 Open/close 5
Vehicle protection #
Activate or deactivate the function via Colli-
sion notification.
% A maximum of thre e incidents can be regis-
te re d. Up to15 pho tos are take nfo rev ery
incident. In theev ent of ano ther incident, the
pho tos of the /rst incident will be overwritten
if th ey have not been dele ted already. A
A
ctiv
ctiv ating or deactiv
ating or deactiv ating t
ating the collision phot
he collision phot os
os
function
function
No tepossible legal restrictions in some count ries
re ga rding automatic recording of theve hicle sur-
ro undings. #
Activate or deactivate Take photos.
T T r
ransf
ansf err
erring t
ing t he collision phot
he collision phot os wit
os with t
h the
he
Mer
Mer cedes me App
cedes me App #
Select Upload to Mercedes me . #
Select Upload automatically . #
Scan thege nerated QR code on the central
display with the Mercedes me App.
The encryp ted collision pho tos will then be
uploaded toMercedes me.
% Any device that can scan QR codes can be
used toview the collision pho tos in the
Mercedes me App.
Cop
Cop ying t
ying t he collision phot
he collision phot os t
os to a USB
o a USB 0ash
0ashdr
drive
ive #
Connect a USB 0ash drive . #
Select Manage collision photos .226
226
Driving and parking

#
Select Copy (USB) .
All collision ph otos are copied tothe USB
0ash drive.
% Toensure secure operation, only use with
FA T32 or exFA Tfo rm atted USB storage devi-
ces.
Dele
Dele ting collision phot
ting collision phot os
os #
Select Manage collision photos. #
Select Delete.
All collision pho tos will be dele ted. N
No
ot
tes on par
es on par king up t
king up the v
he vehicle
ehicle If
yo u lea vetheve hicle par ked up for longer than
six weeks, it may su.er damage thro ugh disuse.
The 12 V battery may also be impaired or dam-
aged byheavy discharging.
% Further information can be obtained at a
qu ali/ed specialist workshop. S S
t
tandb
andb y mode (e
y mode (e xt
xtension of t
ension of t he st
he start
arter batt
er batt er
ery's
y's
per
per iod out of use)
iod out of use) S
S
t
tandb
andb y mode function
y mode function
% This function is not available for all models.
If standby mode is activated, energy loss will be
minimised during extended periods of non-opera-
tion.
St andby mode is characterised bythefo llowing:
R The star ter battery is preser ved.
R The maximum non-operational time appears in
the driver's displa y.
R The connection toonline services is inter rup-
te d.
If th efo llowing conditions are ful/lled, standby
mode can be activated or deactivated using the
multimedia system:
R The vehicle is switched on.
R The vehicle has not been star ted.
Exceeding theve hicle's displ ayed non-operational
time may cause incon venience; i.e. it cannot be
guaranteed that the star ter battery will reliably
start theve hicle. Char
gethe star ter battery in thefo llowing situa-
tions:
R The vehicle's non-ope rational time must be
ex tended.
R The star ter battery charge leve l is insu1cient
fo r standby mode.
% Standby mode is automatically deactivated
when theve hicle is switched on.
A A ctiv
ctiv ating/deactiv
ating/deactiv ating st
ating standb
andby mode (par
y mode (par king up
king up
t
t he v
he v ehicle)
ehicle)
R
R eq
eq uir
uir ements:
ements:
R The vehicle has been switched on but not star-
te d.
Multimedia system: 4 © 5
Settings 5
Vehicle
5 Opening/closing #
Activate or deactivate Standby mode. Driving and parking
227
227