MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Guide

Correct use
If you remove any warning stickers, you or oth-
ers could fail to recognize certain dangers.
Leave warning stickers in position.
Observe the following information when driving
your vehicle:
Rthe safety notes in this manual
Rthe vehicle technical data
Rtraffic rules and regulations
Rlaws and safety standards pertaining to motor
vehicles
Problems with your vehicle
If you should experience a problem with your
vehicle, particularly one that you believe may
affect its safe operation, we urge you to contact
an authorized Mercedes-Benz Center immedi-
ately to have the problem diagnosed and recti-
fied. If the problem is not resolved to your sat-
isfaction, please discuss the problem again with
a Mercedes-Benz Center or contact us at one of
the following addresses.
In the USA
Customer Assistance Center
Mercedes-Benz USA, LLC
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada
Customer Relations Department
Mercedes-Benz Canada, Inc.
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9
Reporting safety defects
USA only:
The following text is published as required of
manufacturers under Title 49, Code of U.S. Fed-
eral Regulations, Part 575 pursuant to the
"National Traffic and Motor Vehicle Safety Act of 1966".
If you believe that your vehicle has a defect
which could cause a crash or could cause injury
or death, you should immediately inform the
National Highway Traffic Safety Administration
(NHTSA) in addition to notifying Mercedes-Benz
USA, LLC. If NHTSA receives similar complaints, it may
open an investigation, and if it finds that a safety
defect exists in a group of vehicles, it may order
a recall and remedy campaign. However, NHTSA
cannot become involved in individual problems
between you, your dealer, or Mercedes-Benz
USA, LLC.
To contact NHTSA, you may call the Vehicle
Safety Hotline toll-free at
1-888-327-4236(TTY: 1-800-424-9153
);go to
http://www.safercar.gov ; or write to: Admin-
istrator, NHTSA, 400 Seventh Street, SW.,
Washington, DC 20590.
You can also obtain other information about
motor vehicle safety from
http://www.safercar.gov
Limited Warranty
!
Follow the instructions in this manual about
the proper operation of your vehicle as well as
about possible vehicle damage. Damage to
your vehicle that arises from culpable contra-
ventions against these instructions is not cov-
ered either by the Mercedes-Benz Limited
Warranty or by the New or Used-Vehicle War-
ranty.
QR codes for the rescue card
The QR codes are secured in the fuel filler flap
and on the opposite side on the B-pillar. In the
event of an accident, rescue services can use
the QR code to quickly find the appropriate res-
cue card for your vehicle. The current rescue
card contains the most important information
about your vehicle in a compact form, e.g. the
routing of the electric cables.
You can find more information under http://
portal.aftersales.i.daimler.com/public/
content/asportal/en/communication/
informationen_fuer/QRCode.html.
Data stored in the vehicle
Data storage
A wide range of electronic components in your
vehicle contain data memories.
Introduction29
Z

These data memories temporarily or perma-
nently store technical information about:
Rvehicle's operating state
Rincidents
Rmalfunctions
In general, this technical information docu-
ments the state of a component, a module, a
system or the surroundings.
These include, for example:
Roperating conditions of system components,
e.g. fluid levels
Rthe vehicle's status messages and those of its
individual components, e.g. number of wheel
revolutions/speed, deceleration in move-
ment, lateral acceleration, accelerator pedal
position
Rmalfunctions and defects in important system
components, e.g. lights, brakes
Rvehicle reactions and operating conditions in
special driving situations, e.g. air bag deploy-
ment, intervention of stability control sys-
tems
Rambient conditions, e.g. outside temperature
This data is of an exclusively technical nature
and can be used to:
Rassist in recognizing and rectifying malfunc-
tions and defects
Ranalyze vehicle functions, e.g. after an acci-
dent
Roptimize vehicle function
The data cannot be used to trace the vehicle's
movements.
When your vehicle is serviced, technical infor-
mation can be read from the event data memory
and malfunction data memory.
Services include, for example:
Rrepair services
Rservice processes
Rwarranties
Rquality assurance
The vehicle is read out by employees of the ser-
vice network (including the manufacturer) using
special diagnostic testers. More detailed infor-
mation is obtained from it, if required.
After a malfunction has been rectified, the infor-
mation is deleted from the malfunction memory or is continually overwritten.
When operating the vehicle, situations are con-
ceivable in which this technical data, in connec- tion with other information (if necessary, under
consultation with an authorized expert), could
be traced to a person.
Examples include:
Raccident reports
Rdamage to the vehicle
Rwitness statements
Further additional functions that have been con-
tractually agreed upon with the customer allow
certain vehicle data to be conveyed by the vehi-
cle as well. The additional functions include, for
example, vehicle location in case of an emer-
gency.
COMAND/mbrace
If the vehicle is equipped with COMAND or
mbrace, additional data about the vehicle's
operation, the use of the vehicle in certain sit-
uations, and the location of the vehicle may be
compiled through COMAND or the mbrace sys-
tem.
For additional information please refer to the
COMAND User Manual or the Digital Operator's
Manual and/or the mbrace Terms and Condi-
tions.
Event data recorders
This vehicle is equipped with an event data
recorder (EDR). This vehicle is equipped with an
event data recorder (EDR). The main purpose of
an EDR is to record, in certain crash or near
crash-like situations, such as an air bag deploy-
ment or hitting a road obstacle, data that will
assist in understanding how a vehicle's systems
performed. The EDR is designed to record data
related to vehicle dynamics and safety systems for a short period of time, typically 30 seconds
or less.
The EDR in this vehicle is designed to record
such data as:
RHow various systems in your vehicle were
operating
RWhether or not the driver and passenger
safety belts were buckled/fastened
RHow far (if at all) the driver was depressing theaccelerator and/or brake pedal and
RHow fast the vehicle was traveling.
30Introduction

These data can help provide a better under-
standing of the circumstances in which acci-
dents and injuries occur. NOTE: EDR data are
recorded by your vehicle only if a non-trivial
crash situation occurs; no data is recorded by
the EDR under normal driving conditions and no
personal data (e.g. name, gender, age and acci-dent location) are recorded. However, other par-
ties, such as law enforcement could combine
EDR data with the type of personally identifyingdata routinely acquired during a crash investi-
gation.
Access to the vehicle and/or the EDR is needed
to read data that is recorded by the EDR, and
special equipment is required. In addition to the vehicle manufacturer, other parties that have
the special equipment, such as law enforce-
ment, can read the information by accessing the
vehicle or the EDR.
EDR data may be used in civil and criminal mat-
ters as a tool in accident reconstruction, acci-
dent claims and vehicle safety. Since the Crash
Data Retrieval CDR tool that is used to extract
data from the EDR is commercially available,
Mercedes-Benz USA, LLC ("MBUSA") expressly
disclaims any and all liability arising from the
extraction of this information by unauthorized
Mercedes-Benz personnel.
MBUSA will not share EDR data with others
without the consent of the vehicle owners or, if
the vehicle is leased, without the consent of the
lessee. Exceptions to this representation
include responses to subpoenas by law enforce-
ment; by federal, state or local government; in
connection with or arising out of litigation involv-ing MBUSA or its subsidiaries and affiliates; or,
as required by law.
Warning: The EDR is a component of the
Restraint System Module. Tampering with, alter-
ing, modifying or removing the EDR component
may result in a malfunction of the Restraint Sys-
tem Module and other systems.
State laws or regulations regarding EDRs that
conflict with federal regulation are pre-empted.
This means that in the event of such conflict, the federal regulation governs. As of February 2013,
13 states have enacted laws relating to EDRs.Information on copyright
General information
Information on license for free and open-source
software used in your vehicle and its electronic
components is available on the following web-
site:
http://www.mercedes-benz.com/opensource
Introduction31
Z

Cockpit
FunctionPage
:Steering wheel paddle shift-
ers174
;Combination switch131
=Horn
?Instrument cluster33
ADIRECT SELECT lever170
BOverhead control panel39
CControl panel for:
ÜLowering the rear seat
head restraints116
u Extending/retracting
the rear roller sunblind334
PASSENGER AIR BAG indica-
tor lamp46
Adjusting the brightness of
the instrument lighting and
the multimedia system dis-
play
DIgnition lock162
Start/Stop button162
FunctionPage
EClimate control systems140
FAdjusts the steering wheel120
Steering wheel heating120
GCruise control lever197
HElectric parking brake190
IDiagnostics connection28
JOpening the hood352
KLight switch130
LControl panel for:
Activating Steering Assist
and Stop&Go Pilot207
Switching on Active Lane
Keeping Assist237
Deactivating PARKTRONIC214
Switching on the 360° cam-
era224
Activating Night View Assist230
Switching on the head-up
display259
32Cockpit
At a glance

Instrument cluster
Displays
FunctionPage
:Speedometer
;Multifunction display258
=Tachometer256
?Coolan ttemperature25 7
FunctionPag e
AFuelgauge
Fue lfiller flap location indi-
cator 8: thefuel filler cap
is on th eright-hand side .
iInformation on displayin gth eoutside tem-
peratur ein th emultifunction display can be
foun dunder "Outside temperature display"
(
Ypage 257).
iInformation on additional displays for PLUG-
IN HYBRID vehicles can be foun din th e
"PLUG-I NHYBRID operation "section
(
Ypage 242).
Instrument cluster33
At a glance

Warning and indicator lamps
FunctionPage
:!ABS316
;åESP®OFF317
÷ESP®317
=#Turn signal, left131
?LLow-beam headlamps131
AKHigh-beam headlamps132
BTParking lamps, license
plate and instrument cluster
lighting
131
C! Turn signal, right131
D·Distance warning322
E!Electric parking brake
(yellow)319
FunctionPage
FElectric parking brake (red)319
F USA only
!Canada only
G;Engine diagnostics320
HÐ Power steering324
IBrakes (red)315
$USA only
JCanada only
JéRBS (Recuperative
Brake System)315
Kü Seat belts313
L6Restraint system45
MhTire pressure monitor323
iInformation on additional indicator and
warning lamps for PLUG-IN vehicles can be
found in the "PLUG-IN HYBRID operation"
section (
Ypage 242).
34Instrument cluster
At a glance

Multifunction steering wheel
FunctionPage
:Multifunction display258
;Sets the brightness of the
instrument cluster and the
multimedia system display
256
=Multimedia system display
?DVD changer or single DVD
drive
AMultimedia system control-
ler and buttons
B~
Rejects or ends a call267
Exits the telephone book/
redial memory
6
Makes or accepts a call
Switches to the redial mem-
ory
WX
Adjusts the volume
8
Mute
ó
Switches on the Voice Con-
trol System
FunctionPage
Cò
Opens the menu list
9:
Selects a menu or submenu
or scrolls through lists257
a
Confirms a selection257
Hides display messages277
%
Back257
ñ
Switches off the Voice Con-
trol System
Multifunction steering wheel35
At a glance

iIn vehicles with multimedia system
COMAND you can find further information:
Ron the multimedia system in the Digital
Operator's Manual
Ron the DVD changer or single DVD drive in
the Digital Operator's Manual
Ron the Voice Control System in the sepa-
rate operating instructions
36Multifunction steering wheel
At a glance

Center console
FunctionPage
:Switches multimedia system
on/off (see the separate
operating instructions)
;Adjusts the volume/mute
(see the separate operating
instructions)
=èECO start/stop func-
tion167
ÉSets the vehicle level
(vehicles with PLUG-IN
HYBRID operation)210, 212
?Touchpad (see the separate
operating instructions)
Telephone keypad (see the
separate operating instruc-
tions)
AÉ Sets the vehicle level210
Selects the operating mode
(vehicles with PLUG-IN
HYBRID operation)
243
BAdjusts the suspension set-
tings210,
212
FunctionPage
CÛ Selects the drive pro-
gram/program selector but-
ton
173
Ñ Selects the drive pro-
gram/program selector but-
ton (Mercedes-AMG vehi-
cles)
173
Selects automatic drive pro-
grams E, S and E+ (vehicles
with PLUG-IN HYBRID opera-
tion)
250
DBack button (see the sepa-
rate operating instructions)
ESeat adjustment button (see
the separate operating
instructions)
FNavigation button (see the
separate operating instruc-
tions)
GRadio button (see the sepa-
rate operating instructions)
H£ Hazard warning lamps132
IMedia button (see the sepa-
rate operating instructions)
JTelephone, address book and
Internet button (see separate
operating instructions)
Center console37
At a glance

FunctionPage
KVehicle and system settings
button (see separate operat-
ing instructions)
FunctionPage
LMultimedia system control-
ler (see the separate operat-
ing instructions)
iInformation on the ECO start/stop function
for vehicles with PLUG_IN HYBRID operation
can be found in the "PLUG_IN HYBRID oper-
ation" section (
Ypage 252).
38Center console
At a glance