MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

RM30 (gasoline with 30% methanol)
RM85 (gasoline with 85% methanol)
RM100 (100% methanol)
RGasoline with metalliferous additives
RDiesel
Do not mix such fuels with the fuel recom-
mended for your vehicle.
!To ensure the longevity and full perform-
ance of the engine, only premium-grade
unleaded gasoline must be used.
If standard unleaded gasoline is unavailable
and you have to refuel with unleaded gasoline
of a lower grade, observe the following pre-
cautions:
ROnly fill the fuel tank to half full with regular
unleaded gasoline and fill the rest with pre-
mium-grade unleaded gasoline as soon as
possible.
RDo not drive at the maximum speed.
RAvoid sudden acceleration and engine
speeds over 3,000 rpm.
You will usually find information about the fuel
grade on the pump. If you cannot find the label
on the pump, ask the staff for assistance.
iFor further information, consult a qualified
specialist workshop or visit
http://www.mbusa.com (USA only).
As a temporary measure, if the recommended
fuel is not available, you may also use regular
unleaded gasoline with an octane rating of
87 AKI/91 RON. This may reduce engine per-
formance and increase fuel consumption. Avoid
driving at full throttle and sudden acceleration.
Never refuel using fuel with a lower AKI.
Information on refueling .
Additives
!Operating the engine with fuel additives
added later can lead to engine failure. Do not
mix fuel additives with fuel. This does not
include additives for the removal and preven-
tion of residue buildup. gasoline must only be
mixed with additives recommended by
Mercedes-Benz. Comply with the instructions
for use on the product label. More information
about recommended additives can be
obtained from any authorized Mercedes-Benz
Center.
Mercedes-Benz recommends that you use bran- ded fuels that have additives. The quality of the fuel available in some coun-
tries may not be sufficient. Residue could build
up in the injection system as a result. In such
cases, and in consultation with an authorized
Mercedes-Benz Center, the gasoline may be
mixed with the cleaning additive recommended
by Mercedes-Benz. You must observe the notes
and mixing ratios specified on the container.
Engine oil
General notes
!Never use engine oil or an oil filter of a spec-
ification other than is necessary to fulfill the
prescribed service intervals. Do not change
the engine oil or oil filter in order to achieve
longer replacement intervals than those pre-
scribed. You could otherwise cause engine
damage or damage to the exhaust gas after-
treatment.
Follow the instructions in the service interval
display regarding the oil change. Otherwise,
you may damage the engine and the exhaust
gas aftertreatment.
When handling engine oil, observe the important
safety notes on service products (
Ypage 427).
The engine oils are matched to the performance
of Mercedes-Benz engines and service intervals.
You should therefore only use engine oils and oil
filters that are approved for vehicles with main- tenance systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz Center.
Or visit the website
http://bevo.mercedes-benz.com.
The table shows which engine oils have been
approved for your vehicle.
Service products and filling capacities429
Technical data
Z

ModelMB-Freigabe orMB-Approval
All models229.5
Use only SAE 0W-40 or SAE 5W-40 engine oils
for Mercedes-AMG vehicles.
iMB approval is indicated on the oil contain-
ers.
Filling capacities
The following values refer to an oil change
including the oil filter.
Missing values were not available at time of
going to print.
ModelCapacity
S 400 4MATIC
S 550 e6.9 US qt (6.5 l)
S 600
Mercedes‑May-
bach S 600
Mercedes‑AMG
S 6511.1 US qt (10.5 l)
Mercedes‑AMG
S 63 4MATIC9.0 US qt (8.5l)
Allot her models8.5 US qt (8.0 l)
Additives
!Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity
Viscosity describes the flow characteristics of a
fluid. If an engine oil has a high viscosity, this
means that it is thick; a low viscosity means that it is thin.
Select an engine oil with an SAE classification
(viscosity) suitable for the prevailing outside
temperatures. The table shows you which SAE
classifications are to be used. The low-temper-
ature characteristics of engine oils can deterio-
rate significantly, e.g. as a result of aging, soot
and fuel deposits. It is therefore strongly rec-
ommended that you carry out regular oil
changes using an approved engine oil with the
appropriate SAE classification.
Brake fluid
GWARNING
The brake fluid constantly absorbs moisture
from the air. This lowers the boiling point of
the brake fluid. If the boiling point of the brake
fluid is too low, vapor pockets may form in the
brake system when the brakes are applied
hard. This would impair braking efficiency.
There is a risk of an accident.
You should have the brake fluid renewed at
the specified intervals.
Comply with the important safety notes for ser-
vice products when handling brake fluid
(
Ypage 427).
The brake fluid change intervals can be found in
the Maintenance Booklet.
Only use brake fluid approved by Mercedes-
Benz according to MB-Freigabe or MB-Approval
331.0.
Information about approved brake fluid can be
obtained at any qualified specialist workshop or on the Internet at
http://bevo.mercedes-benz.co m.
iHave the brake fluid regularly replaced at a
qualified specialist workshop and the replace-
ment confirmed in the Maintenance Booklet.
430Service products and filling capacities
Technical data

Coolant
Important safety notes
GWARNING
If antifreeze comes into contact with hot com- ponents in the engine compartment, it may
ignite. There is a risk of fire and injury.
Let the engine cool down before you add anti-
freeze. Make sure that antifreeze is not spilled
next to the filler neck. Thoroughly clean the
antifreeze from components before starting
the engine.
!Only add coolant that has been premixed
with the desired antifreeze protection. You
could otherwise damage the engine.
Further information on coolants can be found
in the Mercedes-Benz Specifications for Ser-
vice Products, MB BeVo 310.1, e.g. on the
Internet at http://bevo.mercedes-benz.com.
Or contact a qualified specialist workshop.
!Always use a suitable coolant mixture, even
in countries where high temperatures prevail.
Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
iHave the coolant regularly replaced at a
qualified specialist workshop and the replace-
ment confirmed in the Maintenance Booklet.
The coolant is a mixture of water and anti-
freeze/corrosion inhibitor. It performs the fol-
lowing tasks:
Rcorrosion protection
Rantifreeze protection
Rraising the boiling point
If th e c
oolant has antifreeze protection down to
-35 ‡ (-37 †), the boiling point of the coolant
during operation is approximately 266 ‡
(130 †).
The antifreeze concentrate/corrosion inhibitor
concentration in the engine cooling system
should:
Rbe at least 50%. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 †).
Rnot exceed 55% (antifreeze protection down
to -49 ‡ [-45 †]). Otherwise, heat will not be dissipated as effectively. Mercedes-Benz recommends an antifreeze/
corrosion inhibitor concentrate in accordance
with
MB Specifications for Service Products 310.
1.
iWhen the vehicle is first delivered, it is filled
with a coolant mixture that ensures adequate
antifreeze and corrosion protection.
iThe coolant is checked with every mainte-
nance interval at a qualified specialist work-
shop.
Filling capacities
Missing values were not available at time of
going to print.
ModelCapacity
S 400 4MATIC
S 550 e13.3 US qt (12.6 l)
S 600
Mercedes‑May-
bach S 60015.7 US qt (14.9l)
Mercedes‑AMG
S 63 4MATIC8.5 US qt (8.0l)
Mercedes‑AMG
S 6511.3 US qt (10.7 l)
Allot her models12.8 US qt (12.1 l)
Windshield washer system
Important safety notes
GWARNING
Windshield washer concentrate could ignite if it comes into contact with hot engine compo-
nents or the exhaust system. There is a risk of
fire and injury.
Make sure that no windshield washer con-
centrate is spilled next to the filler neck.
!Do not add distilled or de-ionized water to
the washer fluid container. Otherwise, the
level sensor may be damaged.
!Only MB SummerFit and MB WinterFit
washer fluid should be mixed together. The
Service products and filling capacities431
Technical data
Z

spray nozzles may otherwise become
blocked.
At temperatures above freezing:
XFill the washer fluid reservoir with a mixture of
water and windshield washer fluid, e.g. MB
SummerFit.
Add 1 part MB SummerFit to 100 parts water.
At temperatures below freezing:
XFill the washer fluid reservoir with a mixture of
water and washer fluid, e.g. MB WinterFit.
For the correct mixing ratio refer to the infor-
mation on the antifreeze reservoir.
iAdd windshield washer fluid, e.g. MB Sum-
merFit or MB WinterFit, to the washer fluid all
year round.
Climate control system refrigerant
Important safety notes
The climate control system of your vehicle is fil-
led with refrigerant R‑134a.
The instruction label regarding the refrigerant
type used can be found on the radiator cross
member.
!Only the refrigerant R‑134a and the PAG oil
approved by Mercedes-Benz may be used.
The approved PAG oil may not be mixed with
any other PAG oil that is not approved for
R-134a refrigerant. Otherwise, the climate
control system may be damaged.
Service work, such as topping up refrigerant or
replacing components, may only be carried out
by a qualified specialist workshop. All applicable
regulations, as well as SAE standard J639, must
be adhered to.
Always have work on the climate control system
carried out at a qualified specialist workshop.
Refrigerant instruction label
Example: refrigerant instruction label
:
Warning symbol
;Refrigerant filling capacity
=Applicable SAE standards
?PAG oil part number
AType of refrigerant
Warning symbols :indicate:
Rpossible dangers
Rhaving service work carried out at a qualified
specialist workshop
Filling capacities
ModelRefrigerant
S 550 e
Mercedes‑AMG vehicles25.0 ± 0.4 oz
(710 ± 10 g)
ModelPAG oil
S 550 e
Mercedes‑AMG vehicles4.3 oz
(120 g)
Vehicles without rear-com-
partment air-conditioning
systemCapacity
Refrigerant23.3 ± 0.4 oz (660 ± 10 g)
PAG oil3.9 oz
(110 g)
432Service products and filling capacities
Technical data

Vehicles with rear-com-
partment air-conditioning
systemCapacity
Refrigerant27.1 ± 0.4 oz(770 ± 10 g)
PAG oil4.2 oz
(120 g)
Vehicle data
General notes
Please note that for the specified vehicle data:
Rthe heights specified may vary as a result of:
-tires
-load
-condition of the suspension
-optional equipment
Roptional equipment reduces the maximum
payload.
Dimensions and weights
Trunk lid opening dimensions (example:
Mercedes‑Maybach)
Missing values were not available at time of
going to print.
Model:Opening height
S 400 4MATIC
S 550 4MATIC
S 55071.0 in
(1803 mm)
Model:Opening height
Mercedes ‑AMG
vehicles71.2 in
(1808 mm)
All other models71.1 in
(1806 mm)
S-Class with a short wheelbase
All models
Vehicle length201.4 in (5116 mm)
Vehicle width
including exterior
mirrors83.9 in (2130 mm)
Vehicle height59.0 in (1499 mm)
Wheelbase119.5 in (3035 mm)
Turning radius39.0 ft (11.90 m)
Maximum roof load220 lb (100 kg)
Maximum trunk
load220 lb (100 kg)
S-Class with a long wheelbase
Missing values were not available at time of
going to print.
S 400 4MATIC
Vehicle length
Vehicle height
Vehicle width
including exterior
mirrors
Wheelbase
Turning radius
Maximum roof load
Maximum trunk
load
Vehicle data433
Technical data
Z

Mercedes‑AMG
vehicles
Vehicle length208.1 in (5287 mm)
Vehicle height59.0 in (1499 mm)
Vehicle width
including exterior
mirrors83.9 in (2130 mm)
Wheelbase124.6 in (3165 mm)
Turning circle,
Mercedes-AMG S 63
4MATIC41.0 ft (12.50m)
Turning circle,
Mercedes‑AMG S 6540.4 ft (12.30 m)
Maximum roof load220 lb (100 kg)
Maximum trunk
load220 lb (100 kg)
All other models
Vehicle length206.5 in (5246 mm)
Vehicle width
including exterior
mirrors83.9 in (2130 mm)
Wheelbase124.6 in (3165 mm)
Turning radius40.4 ft (12.30m)
Maximum roof load220 lb (100 kg)
Maximum trunk
load220 lb (100 kg)
ModelVehicle height
S 55058.8 in (1494 mm)
S 550 4MATIC
S 550 e
S 60058.9 in (1497 mm)
High-voltage battery
(S 550 e)
ModelLithium-ion
Energy content
High-voltage battery
(S 550 e)
Nominal capacity
Range in electric-only
mode (according to NEDC)
Charging time at 16 A
(using a charging station
or wallbox)
Charging time at 8 A(using
a mains socket)
Mercedes‑Maybach
All models
Vehicle length214.7 in (5453 mm)
Vehicle height59.0 in (1498 mm)
Vehicle width
including exterior
mirrors83.9 in (2130 mm)
Wheelbase132.5 in (3365 mm)
Turning radius42.3 ft (12.90 m)
Maximum trunk
load220 lb (100 kg)
434Vehicle data
Technical data

435

436