MERCEDES-BENZ S-CLASS SEDAN & MAYBACH 2019 Hybrid Owner's Manual

É22258481104ËÍ
2225 848110
Order no.P222 0200 13Partno. 222 5848 11 0
Editio nA2019 S-Class
Plug-in
hybrid Supplemen t
Mer ced es-Benz

Publication
details
Int erne t
Fu rther information aboutMercedes-Ben zvehi‐
cles andabout Daimler AGcan befound onthe
fo llo wing websit es:
htt p:// www .mbusa. com(USAonly)
htt p:// www .mercedes- benz.ca(Canada only)
Edit orial office
© Daim lerAG:Notto be repr int ed, translat edor
ot her wise repr oduced, inwhole orinpar t,wit h‐
out written per mission from Daimler AG.
Ve hicl em anuf actur er
Daiml erAG
Mer cedess trasse 137
7032 7Stuttgar t
Ge rmany Sym
bols
In this Oper ator's Manual, youw illfind thef ol‐
lo wing symbol s: &
DANG ER Dan gerd ue tonoto bserving
th ew arning notic es
Wa rning notic es draw your att entio nt oh az‐
ar ds that ma yendang eryour healt horlife, or
th eh ealt horlifeo fother s. #
Please observethew arning notic es in
th is manual. +
ENV
IRONM ENTALNOTEEnvironme ntal
da ma gedue tofailur etoo bser veenvi‐
ro nment alno tes En
vironme ntal no tesi nclude information on
en vironment allyresponsible behaviororenvi‐
ro nment ally responsible disposal. #
Obser veenvironmen taln otes. *
NO
TEDama getoproper tydue tofailur e
to obser venoteso nm ater ial damag e No
teso nm ater ial damag einfor my ouof
ri sk sw hichm aylead toyour vehicle being
damag ed. #
Obser venoteso nm ater ial damag e. %
Useful instructions orfur ther information
th at coul dbehelpf ulto you.
X In
stru ction
(007B page)Fu
rther information onatopic
Display Inf
ormation inthem ultifunc tiondis‐
pla y/multimedia display
+ Highestmenu leve l,whic hist ob e
select edinthem ultimedia system
* Corresponding submenus, whichare
to be select edinthem ultimedia sys‐
te m
*M arks ac aus e
Asat25 .09.20 17

We
lcome tothewo rld of Mer cedes -Ben z
Bef oreyo ufirs tdr ive of f,re ad this Oper ator's
Manual carefull yand famili arize yourself with
yo ur vehicle. Foryo ur ow nsa fety and along er
ve hicle life, follo wtheins truction sand warning
no tic es inthis Opera tor's Manua l.Disr egarding
th em maylead todamag eto theve hicle orper‐
sonal injury.
Ve hicle damag ere sulting from thedisr egardof
th eins truction sis no tco veredby theMer cedes-
Benz LimitedWarrant y.
The equipment ormodel designation ofyour
ve hicle mayva ry acc ordin gto :
R Model
R Order
R National version
R Availabilit y
Mer cedes-Ben zre ser vesth eright tointroduce
ch ang esinthefo llo wing areas:
R Des ign
R Equipmen t
R Tech nica lfe atur es The
equipme ntinyour vehicle mayth er efor edif‐
fe rfr om that sho wninthedescr iption sand illus‐
tr ations.
The follo wing areint egr alpar tsof theve hicle:
R Digit alOper ator's Manual
R Print ed Oper ator's Manual
R Maint enance Booklet
R Eq<0058004C00530050004800510057001000470048005300480051004700480051
0057> supplements
Ke ep these documen tsintheve hicle atall
times. Ifyo usell theve hicle, alwayspass allof
th edocumen tson tothene wow ner .
Mer cedes-Be nzUS A,LLC
Mer cedes-Benz Canada,Inc.
A Daimle rCom pany
2225848110
2225848 110

Gene
ralno tes... ......... ................................... 4
Oper ator&#39;s Manual .......................................... 4
Pr otect ing theen vironmen t... ......... ................4
Oper ating safety.............................................4
Qua lified speci alistwo rkshop .........................5
Cor rect useof theve hicle ...............................5
Limit edWarrant y............................................ 5
No teson plug-in hybrid oper ation ...................6
Swi tching offth ehy brid system manually ...... 7 Occupant
safety.... ....................................... 9
Re stra int system .............................. ............... 9 Climat
econtr ol......... .................................. 10
Ov ervie wof thecon trol panel forau to‐
matic climatecontr ol<0011001100110011001100110011001100110011001100110011001100110011
0011001100110011001100110011001100110011001100110011> .......10
Pr e-ent ryclimat econtr olvia Smar tKey ......... 11
Pr e-ent ryclimat econtr olat time of
dep artur e<0011001100110011001100110011001100110011001100110011001100110011
0011001100110011001100110011001100110011001100110011> <0011001100110011001100110011001100110011001100110011001100110011
001100110011001100110011001100110011>12
Ac tivati ng/d eactiv ating immed iate pre-
ent ryclimat econtr ol<0011001100110011001100110011001100110011001100110011001100110011
0011001100110011001100110011001100110011001100110011> .......13 Oper
ating modes ........................................ 15
Fu nctio nsoftheoper ating modes ................1 5
Swi tching operating mod e........... .................17 Multimedia
system .................................... 18
Con figur ing settings forplu g-in hybrid
ve hicles ........................................................ 18
Fu nctio nsoftheener gyflow displa y.............1 9
Sho wing theener gyflow displa y...... .............1 9 Disp
lays and oper ation ..............................20
No teson theIns trument Displayand on-
boar dcom puter.............................. .............. 20
DY NA MIC SELE CTswitc h... ............... ........... 20
Hap ticacceler ator pedal function................. 22
Fu nctio nof thepo we rdisp lay of the
electr icmo tor..... .............................. ............23
Fu nctio nof thepo we rme ter..... ................... 23
Displa yingthepo we rme ter..... .....................2 3
Fu nctio nof thero ute-based operatin g-
mod est ra tegy ................................. .............2 3
Ac tivati ng route-based operatin g-mod e
st ra tegy (ROS) ..............................................2 4 Cha
rging thehigh -voltag ebat tery ............ 25
No teson high-v oltagebatt ery... ...................2 5
Chec kingth ech arge leve lof thehigh-
vo ltag ebatt ery.............................................2 5
Fu nctio nof theindicat orlam pon the
ve hicle socket........... ....................................25
No teson chargin gth ehigh-v oltagebat‐
te ry atthemains socket(mo de2)........... .....26
Ov ervie wof thech argin gcable control
pane l,ve rsion 1............................................ 27
Se tting themaximum permissible charg‐
ing current forch argin gat amain s
soc ket........... ................................................29
No teson chargin gth ehigh-v oltagebat‐
te ry atawa llbo x(mode 3)............................ 30
No teson chargin gth ehigh-v oltagebat‐
te ry atach argin gst atio n(mod e3) .............. 30
St artin gth ech argin gpr oce ss.......................3 1
Endi ngthech argin gpr oce ss........................ 33 Dr
iving andparking ................................... 34
Dr iving ............. .............................................34
Re fuel ing...... ................................................ 35 2
Contents

Br
eak down assista nc e<0011001100110011001100110011001100110011001100110011001100110011
001100110011001100110011001100110011001100110011001100110011> 37
TIREFIT kitstor ag elocation .......................... 37
St artin gassis tance <0011001100110011001100110011001100110011001100110011001100110011
001100110011001100110011001100110011> ..............37
Pe rm itted towing methods ............................3 7 Te
ch nical data............................................ 39
Ve hicle identif ication plate,VIN and
engine number overview .................. .............3 9
Oper ating fluids .... .......................... .............. 40
Ve hicle data... ......... ...................................... 41 Disp
laymes sagesand warning/indi‐
cat orlam ps...... .......................................... 43
Displa ymessag es............................ .............4 3
Wa rning and indic ator lam ps.........................5 1 Inde
x........................................................... 53 Con
tents 3

Oper
ator&#39;s Manua l
This Supplement prov ides informatio non allthe
im por tant func tions ofyour hybrid vehicle that
ar eeit her notdesc ribed ordifferfr om the
descr iption sin theve hicle Operator&#39;s Manual.
This information supplements orreplaces the
cor responding sectionsintheve hicle Operator&#39;s
Manual. Under nocircums tances does theSup‐
plement replace theOper ator&#39;s Manual.
This Supplement describesallmodels, and
st andar dand optio nal equipme ntforyo ur vehi‐
cle, asavailable atthetime ofgoing topress.
Countr y-specif icdif fere nces arepo ssi ble. Bea r
in mind that your vehicle mayno tfe atur eall
fun ction sdesc ribed here.This isalso thecase
fo rsy stems andfunc tionsre leva nt tosaf ety.
Ther efor e, theeq uipment onyour vehicle may
dif ferfr om that inthedescr iption sand illustra‐
tion s.
The original purchase contract documen tation
fo ryo ur vehicle contains alis tof all ofthesy s‐
te ms inyour vehicle. Should
youha ve anyqu estion scon cerning
eq uipment andoper ation, please consult an
aut hor ized Mercedes- BenzCenter.
The Oper ator&#39;s Manual, theSupplement andthe
Maint enance Bookletar eim por tant docum ents
and should be kept intheve hicle. Pr
otecting theen vir onmen t
+ ENV
IRONM ENTALNOTEEnvironme ntal
po lluti on cau sed byirre sponsible dis‐
posal ofthehigh-v oltagebatt ery A
high-v oltagebatt erycon tains mat erials
whic har ehar mful totheen vironmen t. #
Dispose ofdef ective high-v oltagebat‐
te ries ataqu alif ied spec ialistwo rk‐
shop. Oper
ating safety
Hyb rid ve hicles have acom bustioneng ineand
an elec tric mo tor.The ener gysupply foroper at‐ ing
theve hicle electr icallyis prov ided bythe
high-v oltageon-boar delectr icalsystem. &
DANG ER Risk offata linj uryby touc hin g
damag edhigh -volt ageco mp onent s
The vehicle&#39;s high-voltageon-boar delectr ical
sy stem isunder highvoltag e. Ifyo umod ify
co mp onent partsintheve hicle&#39;s high-volt‐
ag eon-boar delectr icalsystem ortouc hdam‐
ag ed comp onent parts,youma ybe elec tro‐
cut ed.
The comp onent partsintheve hicle&#39;s high-
vo ltag eon- boar delect rical system maybe
damag edinan acciden t,alt hough thedam‐
ag eis no tvisible. #
Afteran accide nt,donotto uc han y
high -volt ageco mp onent sand never
modify theve hicle&#39;s high-voltageon-
boar delectr icalsystem. #
Afteran accide nt,have theve hicle
tr anspor tedaw ay. #
Have thehigh-v oltageon- boar delectr i‐
cal system checkedat aqu alif ied spe‐
cialis two rkshop. 4
Gener alno tes

The
com ponent sof thehigh-v oltageon- boar d
electr icalsystem aremar kedwit hye llo wwa rn‐
ing sticke rs.The cablesof thehigh-v oltageon-
boar delectr icalsystem areor ang e.
Ve hicles withan electr icmo torge ner atemu ch
less drivin gnois eth an vehicles withint ernal
combus tionengines. Asare sult, your vehicle
ma yno tbe hear dby other road user sin cer tain
situat ions.This canhappen ,fo rex am ple, when
yo uar epar kingand your vehicle isno tseen by
ot her road user s.This requ ires youto adop ta
par ticular lyant icip ator ydr ivin gst yle, as itis
neces saryto allo wforth epossibility that other
ro ad user sma ybeha veunpredic tably. Qualif
iedspecialis two rkshop
Alw aysha ve thefo llo wing workcar ried out on
yo ur vehicle ataqu alif ied spec ialistwo rkshop:
R Workreleva nt tosaf ety
R Service andmaintena nce work
R Repair work
R Modif ications aswellas installation sand
con versions R
Workon electr oniccomponent s
R Workon thehy brid system Cor
rect use oftheve hicl e
If yo ure mo veanywa rning sticke rs,yo uor other s
could failto recogni zecer tain dang ers. Lea ve
wa rning sticke rs inposit ion.
When usingtheve hicle, observethefo llo wing
inf ormatio n:
R thesaf etyno tesin this manual
R tech nica lda ta forth eve hicle
R traf fic ru les and regulations
R laws and safetyst andar dsper tainin gto
mo torve hicles Limit
edWa rranty
* NO
TEDama getotheve hicle arising
fr om violation ofthese oper ating instruc‐
tion s. Damag
eto theve hicle canarise from viola‐
tion ofthese oper ating instruction s.
This damag eis no tco veredeit her bythe
Mer cedes-Ben zim plied warrant yor by the
Ne w‑ orUsed- Vehicle Warrant y. #
Followtheins truction sin these oper at‐
ing instruction son proper operation of
yo ur vehicle aswellas on possible vehi‐
cle damag e. Gener
alno tes 5

No
teson plug-in hybrid oper ation &
WARNIN GRisk ofchemical burnsand
poisonin gfrom damag edhigh-v oltage
batt ery
If th ehousing ofthehigh-v oltagebatt eryhas
been damag ed,electr olyt eand gases may
leak out. #
Avoid cont actwithth eskin ,ey es or
clo thing. #
Imm ediat elyrinse electr olytesplashes
of fwit hwa terand seek medica latt en‐
tion stra ight away. &
DANG ER Risk ofexplosion from exces‐
siv eint ernal press ureof thehigh-v oltage
batt ery
In theev ent ofave hicle fire ,th eint ernal
pr essur eof thehigh-v oltagebatt erycould
exc eed acr itical value. Inthis case, flamma‐
ble gasescapes thro ugh ableed valve in the
ve hicle&#39;s underbody .
The gascan ignit e. #
Lea vethedang erzon eimmediat ely. #
Secu rethedang erzon eat asuit able
dis tance, whilst obser vinglegalrequ ire‐
men ts. The
hybrid system combin esacombus tion
engine withan electr icmo tor.
Charact eristic swhen theve hicle isat ast and‐
st ill:
R thecombus tionengine isge ner ally switc hed
of f.
R engine idlingonlyoccur sin cer tain ins tan‐
ces.
Ch aract eristics when star tin gth eve hicle:
R ifth ehigh-v oltagebatt eryis suf ficie ntly
ch arge d, theve hicle canbestar tedwit hth e
electr icdrive wit hout thecombus tionengine
(noiseless star t).
R ifth ehigh-v oltagebatt eryis no tsuf ficie ntly
ch arge dor theoper ating temp eratur eof the
comb ustion enginehasno tbee nre ac hed,
th eve hicle canstar twit hth ecombus tion
engine. Char
acteristics withmoder atepo we routpu t
re qu iremen ts:
R thecombus tionengine isswitc hedoffas
of tenas possi ble du ring thejour ney.
R theve hicle canbeacceler ated electr icallyup
to speeds ofappr oximat ely87 mph
(1 40 km/ h).
Char acteristic swit hhigh powe routpu tre qu ire‐
men ts:
R theelectr icmo torsupp orts thecombus tion
engine (boostef fect), e.g. whenpu lling away
or acceler ating.
R thehigh-v oltagebatt eryis disc harging.
Char acteristics when releasing theaccelera tor
pedal during thejour ney:
R theelectr icmo toris oper ated asaalt ernat or
when inoverru nmod eand during braki ng.
R thehigh-v oltagebatt eryis ch argin g.
No teson electr icdriving:
R vehicles withhy brid systems gener atesigni fi‐
cantly less nois eth an vehicles withcombus‐
tion engines. 6
Gener alno tes

R
when drivin gin elec tric mode theve hicle
ma yno tbe hear dby other road user sdue to
th esignif icantlyless noisege ner ated .
R dependi ng on theve hicle&#39;s equipment and
national legislation,theve hicle maybe
eq uipped withAc ous ticVehicle Indication.
Inf ormation onAcous ticVehicle Indication:
R Acous ticVehicle Indication gener ates acer‐
ta in sound ataspeed between 0and 19mp h
(30 km/ h).
R this helps other road user s,par ticular ly
pe destrians and bikerider s,to hear your
ve hicle better .
R abo vethis speed, natural vehicle noise issuf‐
fi cie ntforth eve hicle tobe hear din good
time byother road user s.
R thesound canalso behear din theve hicle
int erior .
R thevo lume depen dson theengine speed,
th espeed andtheacceler ator pedal position .
R Acous ticVehicle Indication switchesoffat a
speed ofover 19 mp h(30 km/h) because
th enatura lve hicle noise issuf ficie nt. Sw
itchin gof fthe hybrid system manua lly &
DANG ER Risk offata linj uryby touc hin g
damag edhigh -volt ageco mp onent s
The vehicle&#39;s high-voltageon-boar delectr ical
sy stem isunder highvoltag e. Ifyo umod ify
co mp onent partsintheve hicle&#39;s high-volt‐
ag eon-boar delectr icalsystem ortouc hdam‐
ag ed comp onent parts,youma ybe elec tro‐
cut ed.
The comp onent partsintheve hicle&#39;s high-
vo ltag eon- boar delect rical system maybe
damag edinan acciden t,alt hough thedam‐
ag eis no tvisible. #
Afteran accide nt,donotto uc han y
high -volt ageco mp onent sand never
modify theve hicle&#39;s high-voltageon-
boar delectr icalsystem. #
Afteran accide nt,have theve hicle
tr anspor tedaw ay. #
Have thehigh-v oltageon- boar delectr i‐
cal system checkedat aqu alif ied spe‐
cialis two rkshop. Onl
ydeactiv ateth ehy brid system manually in
th efo llo wing situat ions:
R The 0075 restra int system warning lam p
light sup intheins trument cluster,e.g. afte r
an acc iden t.
R The vehicle isbadly damag ed,e.g. afte ran
accide nt,and there stra int system com po‐
nen tswe renotacti vated. Gener
alno tes 7

Using
thehigh -voltag ediscon nectdevice #
Swit chtheignition off. #
Switc hth etra nsmiss iontoposition 005D. #
Appl yth eelectr icpar king brak e. #
Secur eth eve hicle agains tro lling away (see
th eve hicle Operator&#39;s Manual). #
Open thetrunk lid. #
Liftth etrunk floor upw ards. #
Remo vetheright-h andtrim inthetrunk . #
Press release clip1inthedir ect ion ofthe
ar row and pullitout . #
Pull high-volt agedisc onnec tde vic e2 inthe
dir ect ion ofthear row untilit en gage s.
The hybrid system isdiscon nected.
All workon thehy brid system (including afte r
switc hingoffmanually) mayonl ybe car ried out
by aqu alif ied spec ialistwo rkshop. 8
Gener alno tes