heating MERCEDES-BENZ M-Class 2013 W166 Owner's Guide

utilize any of the added maximum rear axle
load when towing a trailer, the vehicle/trailer
combination may not exceed a maximum
speed of 60 mph (100 km/h) for reasons
concerning the operating permit .This also
applies in countries in which the permissible
maximum speed for vehicle/trailer
combinations is above 60 mph (100 km/h).
When towing a trailer, your vehicle's handling
characteristics will be different in comparison
with when driving without atrailer.
On long and steep downhill gradients, you
must select shift range 1,2or 3in good time.
i This also applies if you have activated
cruise control or DISTRONIC PLUS.
This will use the braking effect of the engine,
so that less braking will be required to
maintai nthe speed, This relieves the load on
the brake system and prevents the brakes
from overheating and wearing too quickly. If
you need additional braking, depress the
brake pedal repeatedly rather than
continuously.
Driving tips If the trailer swings from side to side:
X
Do not accelerate.
X Do not counter-steer.
X Brake if necessary.
R Maintain a greater distance from the
vehicle in front than when driving without a
trailer.
R Avoid braking abruptly. If possible, brake
gently at first to allow the trailer to run on.
Then, increase the braking force rapidly.
R The values given for gradient-climbing
capabilities from a standstill refer to sea
level. When driving in mountainous areas,
note that the power output of the engine
and, consequently, the vehicle's gradient-
climbing capability, decreases with
increasing altitude. Installing the ball coupling
G
WARNING
If the ball coupling is not installed and secured
correctly it can become detached while the
vehicle is in motion and fall onto the road.
There is a risk of accident and injury.
Always install and secure the ball coupling as
described. Before every journey, ensure that
the ball coupling is secured with the bolt and
the corresponding spring cotter. G
WARNING
If the ball coupling is not installed correctly or
not secured with the bolt provided and the
corresponding spring cotter, the trailer may
come loose. There is a risk of an accident.
Always install and secure the ball coupling as
described. Before every journey, ensure that
the ball coupling is secured with the bolt and
the corresponding spring cotter. G
WARNING
If the ball coupling is not installed and secured
correctly the trailer may come loose. There is
a risk of an accident.
Install and secure the ball coupling as
described in the ball coupling installation
instructions. Make sure that the ball coupling
is installed and secured correctly before every
journey. Cover cap Towing
atrailer
255Driving an d parking Z

The bottles are not secured or prevented from
tipping over. Therefore, do not place any open
drink containers in the stowage
compartments.
Cup holder in the front-compartment
center console
0002
Cup holder
0003 Cover
X To open: slide cover 0003to its foremost
position.
X To close: pull cover 0003back as far as it will
go.
You can remove the cup holder's rubber mat
for cleaning. Clean with clear, lukewarm
water only.
Temperature-controlled cup holder in
the front-compartment center console 0002
Cup holder
0003 Residual heat indicator lamp
001F Switch The temperature-controlled cup holder can
be used to keep cold drink
scool and warm
drinks warm.
X Turn the SmartKey to position 2in the
ignition lock.
X To switch on the cooling function: press
and hold button 001Funtil the blue indicator
lamp on the button lights up.
X To switch on the heating function: press
and hold button 001Funtil the red indicator
lamp on the button lights up.
X To switch off the function: press and hold
button 001Funtil the indicator lamp on the
button goes out.
When the heating function is used, the metal
insert of the cup holder is heated. Once a
certain temperature is reached, residual heat
indicator lamp 0003lights up. This means that
the metal insert of the cup holder is hot. For
this reason, you must not reach into the cup
holder metal insert.
Do not use hard or sharp objects to clean the
cup holder. Use only a soft cloth to clean it.
Cup holder in the rear seat armrest !
Do not sit on or support your body weight
on the rear seat armrest when it is folded
down, as you could otherwise damage it. X
Fold down the rear seat armrest.
Cup holder 0002is located in the rear seat
armrest. 344
FeaturesStowage and features

The roller sunblind can be hooked back into
place should it pop out from the top of the
guide rail.
X Tilt pull-out profile 0002as illustrated.
X Slip guide bush 0003into open area of guide
rail 001F.
X Straighten up pull-out profile 0002again. Ashtray
Front ashtray !
The holder under the ashtray is not heat
resistant .Before placing lit cigarettes in the
ashtray, make sure that the ashtray is
properly engaged. Otherwise, the holder
could be damaged. X
To open: slide cover 0002to its foremost
position.
X Fold cover 001Fof the insert upwards.
X To remove the insert: push insert001Fto
the left 001E.
Insert 001Fslides out slightly to the right. X
Lift insert 001Fup0003 and out.
X To re-install the insert: place insert001F
into the holder and press it down on the
right until it engages.
X To close: pull cover 0002back as far as it will
go.
Rear-compartment ashtray !
Close the ashtray when it is not in use and
before you fold the rear seats forward. You
can otherwise damage the ashtray. X
To open: briefly press cover 0003at the top.
The ashtray opens.
X To remove the insert: push into recess
001F from the right.
Ashtray insert 0002slides out slightly to the
right.
X Lift insert 0002up and out.
X To re-install the insert: place insert0002
into the holder and press down on the right
until it engages.
Vehicles without a Rear Seat Entertainment
System have an ashtray in the center console
in the rear compartment. Cigarette lighter
G
WARNING
You can burn yourself if you touch the hot
heating element or the socket of the cigarette
lighter. 346
FeaturesStowage and features

In addition, flammable materials can ignite if:
R
the hot cigarette lighter falls
R a child holds the hot cigarette lighter to
objects, for example
There is a risk of fire and injury.
Always hold the cigarette lighter by the knob.
Always make sure that the cigarette lighter is
out of reach of children. Never leave children
unsupervised in the vehicle.
! The cigarette lighter in the center console
in the front compartment is not intended
for operating the tire inflation compressor. Youra
ttention must always be focused on the
traffic conditions. Only use the cigarette
lighter when road and traffi cconditions
permit.
X Turn the SmartKey to position 2in the
ignition lock (Y page 157).
X To open: slide cover 0002to its foremost
position.
X Press in cigarette lighter 0003.
Cigarette lighter 0003will pop out
automatically when the heating element is
red-hot.
X To close: pull cover 0002back as far as it will
go. 12
Vsockets
General notes X
Turn the SmartKey to position 1in the
ignitio nlock (Y page 157).
With the exception of the socket in the front
center console, all socket scan be used for
accessories with a maximum curren tdraw of
240 W (20 A). The socket in the front center
console can be used for accessories with a
maximum current draw of 180 W (15 A).
Accessories include such items as lamps or
chargers for mobile phones.
If you use the sockets for long periods when
the engine is switched off, the battery may
discharge.
i An emergency cut-out ensures that the
on-board voltage does not drop too low.If
the on-board voltage is too low, the power
to the sockets is automatically cut. This
ensures tha tthere is sufficient power to
start the engine.
Socket in the front-compartment center
console !
The socket is not suitable for operating
the tire inflation compressor. X
To open: slide cover 0002to its foremost
position.
X Lift up the cover of socket 0003.
X To close: pull cover 0002back as far as it will
go. Features
347Stowage and features Z

should drive for a few minutes after
cleaning. Braking heats the brake discs and
the brake pads/linings, thus drying them.
The vehicle can then be parked.
Regular care of your vehicle is a condition for
retaining the quality in the long term.
Use care products and cleaning agents
recommended and approved by Mercedes-
Benz. Washing the vehicle and cleaning the
paintwork
Automatic car wash G
WARNING
Braking efficiency is reduced after washing
the vehicle. There is a risk of an accident.
After the vehicle has been washed, brake
carefully while paying attention to the traffic
conditions until full braking power is restored.
! If DISTRONIC PLUS or the HOLD function
is activated, the vehicle brakes
automatically in certain situations. To
prevent damage to the vehicle, deactivate
DISTRONIC PLUS and the HOLD function in
the following or other similars ituations:
R when towing the vehicle
R in the car wash
! Neve rclean your vehicle in a Touchless
Automatic Car Wash as these use special
cleaning agents. These cleaning agents can
damage the paintwork or plastic parts.
! Make sure that:
R the side windows and the sliding sunroof
are fully closed.
R the ventilation/heating is switched off
(the OFF button has been pressed).
R the windshield wiper switch is in position
0.
Otherwise, the vehicle might be damaged.
! In car washes with a towing mechanism,
make sure that the automatic transmission is in transmission position
N, otherwise the
vehicle could be damaged.
R Vehicles with a SmartKey:
Do not remove the SmartKey from the
ignition lock. Do not open the driver's
door or front-passenger door when the
engine is switched off .Otherwise, the
automatic transmission selects park
position Pautomatically and locks the
wheels .You can prevent this by shifting
the automatic transmission to N
beforehand.
R Vehicles with KEYLESS-GO:
Do not open the driver's door or front-
passenger door when the engine is
switched off. Otherwise, the automatic
transmission selects park position P
automatically and locks the wheels.
Observe the following to make sure that the
automatic transmission stays in position N:
X Make sure the vehicle is stationary and the
ignition is switched off.
X Turn the SmartKey to position
2(Y page 157) in the ignition lock.
Use the SmartKey instead of the Start/
Stop button on vehicles with KEYLESS-GO.
X Depress and hold the brake pedal.
X Shift the automatic transmission to
position N.
X Release the brake pedal.
X Release the electric parking brake.
X Switch off the ignition and leave the
SmartKey in the ignition lock.
You can wash the vehicle in an automatic car
wash from the very start.
If the vehicle is very dirty, pre-wash it before
cleaning it in an automatic car wash.
After using an automatic car wash, wipe off
wax from the windshield and the wiper
blades. This will prevent smears and reduce
wiping noises caused by residue on the
windshield. 370
CareMaintenance and care

Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g.
MB 229.5). They have not necessarily been
approved by Mercedes-Benz. Fuel
Important safety notes G
WARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and
explosion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before
refueling. G
WARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come
into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
R Wash away fuel from skin immediately
using soap and water.
R If fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance
without delay.
R If fuel is swallowed, seek medical
assistance without delay.Don ot induce
vomiting.
R Immediately change out of clothing which
has come into contact with fuel. Tank capacity Model Total
capacity All models
24.6 US gal
(93.0 l) Model Of which
reserve All models
Approx.
3.2 US gal (12.0 l) ML 63 AMG
Approx.
3.7 US gal (14.0 l) Gasoline
Fuel grade
!
Do not use diesel to refuel vehicles with a
gasoline engine. Do not switch on the
ignition if you accidentally refuel with the
wrong fuel. Otherwise, the fuel will enter
the fuel system. Even small amounts of the
wrong fuel could result in damage to the
fuel system and the engine. The repair
costs are high. Notify aqualified specialist
workshop and have the fuel tan kand fuel
lines drained completely.
! You should only refuel with unleaded
premium-grade gasoline as thi savoids
damaging the catalytic converter.
If engine running problems are apparent,
have the cause checked immediately and
repaired .Excess unburned fuel can
otherwise enter the catalytic converter,
leading to overheating and possibly
causing a fire.
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline may be used. Service products and filling capacities
445Technical data Z

with the instructions for use on the product
label.
Do not mix other fuel additives with fuel. This
causes unnecessary costs and could damage
the engine.
Diesel Fuel grade
G
WARNING
If you mix diesel fuel with gasoline, the flash
poin tis lower than that of pure diesel fuel.
When the engine is running, exhaust system
components could overheat without being
noticed. There is a risk of fire.
Never refuel with gasoline. Never mix gasoline
with diesel fuel.
! Only use commercially available vehicular
ULTRA-LOW SULFUR DIESEL FUEL (ULSD,
15 ppm maximum sulfur content) that
meets the ASTM D975 standard. If you do
not refuel with ULSD, you may damage the
BlueTEC exhaust gas aftertreatment
system of the vehicle.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not mix diesel fuel with
gasoline, kerosene or paraffin. This may
otherwise result in damage to the fuel
system and engine.
You will usually find information aboutt he fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or on the
Internet at http://www.mbusa.com (USA
only).
Information on refueling (Y page 174).
Bio-diesel -FAME (fatt yacid methyl ester)
Mercedes-Ben zUSA approves the use of bio-
diesel B5 for all BlueTEC diesel engines. The
concentration of bio-diesel in the ULSD may
not exceed 5% by volume. Pure bio-diesel and diesel fuel with a higher
percentage of bio-diesel, such as B20, can
damage the engine and the fuel system. For
this reason, they are not approved.
For more information, consult the gas station
staff. The bio-diesel B5 label on the gasoline
pump mus
tclearly state that the standard for
ULS Dhas been fulfilled. If the label is not
clear, do no trefuel the vehicle.
Do not refuel your vehicle with fuels unless
they have been approved by Mercedes-Benz.
Information on refueling (Y page 174).
Low outside temperatures
i Diesel fuel with improved cold flow
properties is available during the winter
months. Further information about fuel
properties can be obtained from oil
companies, e.g. at gas stations.
Flow improver
To improve the low-temperature resistance of
diesel fuel, a flow improver can be attached.
The effectiveness of a flow improver is not
guaranteed for every fuel.
Only use flow improvers tested and approved
by Mercedes-Benz. Durin guse, please
observe the information on operation.
Correct dosage and sufficient mixing are
decisive in improving low-temperature
resistance with the flow improver.
Overdosage can potentially even decrease
low-temperature resistance and must
therefore be avoided.F ollow the
manufacturer's guidelines on dosage.
Mix the additive into the diesel in good time,
before the flow characteristics of the diesel
become insufficient. Otherwise, malfunctions
can arise through heating the fuel system,
e.g. through parking in a heated garage.
More information about recommended flow
improvers can be obtained from any qualified
specialist workshop. Service products and filling capacities
447Technical data Z

Flexible Fuel vehicles
Important safety notes
G
WARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and
explosion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before
refueling. G
WARNING
Fuel is poisonous and hazardous to health.
There is a ris kofinjury.
You must make sure tha tfuel does no tcome
into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
R Wash away fuel from skin immediately
using soap and water.
R If fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance
without delay.
R If fuel is swallowed, seek medical
assistance without delay. Do not induce
vomiting.
R Immediately change out of clothing which
has come into contact with fuel.
Flexible Fuel vehicles can be refueled with the
following fuel types:
R premium-grade unleaded gasoline
R E85 fuel
R a mixture of E85 fuel and premium-grade
unleaded gasoline
i Flexible Fuel vehicles can be recognized
by the Ethanol up to E85 sticker on the
inside of the fuel filler flap. Fuel consumption
The energy content of E85 fuel is less than
that of the same amount of premium-grade
gasoline. The amount of fuel consumed when
operating the vehicle with E85 fuel is
therefore higher than with premium-grade
gasoline.
Maintenance
Informy
our authorized Mercedes-Benz
Center that you are operating or have
operated the vehicle with E85 fuel.
Low outside temperatures
If the outside temperature is below 32 ‡
(0 †) the starting procedure can take
noticeably longer when operating with E85
fuel.
E85 fuel is not suitable for use at outside
temperatures under -4 ‡ (-20 †). DEF
Important safety notes Comply with the important safety notes for
service products when handling DEF
(Y
page 444).
DEFi s a water-soluble fluid for the exhaust
gas aftertreatmentofd iesel engines.Itis:
R not poisonous
R colorless and odorless
R not flammable
When you open the DEF container, small
amounts of ammonia vapor may be released.
Ammonia vapors have a pungent odor and are
particularly irritating to the skin, to mucous
membranes and to the eyes. You may
experience a burning sensation in your eyes,
nose and throat. Coughing and watering of
the eyes are possible.
Do not inhale ammonia vapors. Fill the DEF
tank only in well-ventilated areas. 448
Service products and filling capacitiesTechnical data

Low outside temperatures
DEF freezes at a temperature of
approximately 12
‡(-11 †). The vehicl eis
delivered from the factory equipped with a
DEFp reheating system. Winter operation can
thus be guaranteed even at temperatures
below 12 ‡ (-11 †).
Additives !
Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity !
Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system
Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the BlueTEC exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
Filling capacities Model Total capacity
ML 350 BlueTEC 4MAT
IC
7.3 US gal
(27.5 l) Engine oil
General notes !
Never use engine oil or an oil filter of a
specificatio nothe rthan is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
intervals than those prescribed. You could
otherwise cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
Comply with the important safety notes for
service products when handling engine oil
(Y page 444).
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz
Center. Or visit the website
http://bevo.mercedes-benz.com.
The table shows which engine oils have been
approved for your vehicle. Model Engine
model MB
Approval ML 350
BlueEFFICIENCY
ML 350 4MATIC
BlueEFFICIENCY
276 229.5
ML 550 4MATIC
BlueEFFICIENCY
278 229.5
ML 63 AMG
157 229.5
ML 350 BlueTEC
4MATIC
642 228.51,
229.31,
229.51 Service products and fillingc
apacities
449Technical data Z

Coolant
Important safety notes G
WARNING
If antifreeze comes into contact with hot
components in the engine compartment, it
may ignite. There is a risk of fire and injury.
Let the engine cool down before you add
antifreeze. Make sure that antifreeze is not
spilled next to the fille rneck. Thoroughly
clean the antifreeze from components before
starting the engine.
! Only add coolant that has been premixed
with the desired antifreeze protection .You
could otherwise damage the engine.
Further information on coolants can be
found in the Mercedes-Benz Specifications
for Service Products, MB Specifications for
Service Products 310.1, e.g. on the
Internet at
http://bevo.mercedes-benz.com. Or
contact a qualified specialist workshop.
! Always use a suitable coolant mixture,
even in countries where high temperatures
prevail.
Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
Comply with the important safety precautions
for service products when handling coolant
(Y page 444).
The coolant is a mixture of water and
antifreeze/corrosion inhibitor. It performs
the following tasks:
R corrosion protection
R antifreeze protection
R raising the boiling point
If the coolant has antifreeze protection down
to -35 ‡ (-37 †), the boiling point of the
coolant during operation is approximately
266 ‡ (130 †). The antifreeze/corrosion inhibitor
concentration in the engine cooling system
should:
R
be at least 50%. This will protec tthe engine
cooling system against freezing down to
approximately -35 ‡ (-37 †).
R not exceed 55% (antifreeze protection
down to -49 ‡ [-45 †]). Otherwise, heat
will not be dissipated as effectively.
If the vehicle has lost coolant, add equal
amounts of water and antifreeze/corrosion
inhibitor.
Mercedes-Benz recommends an antifreeze/
corrosion inhibitor concentrate in
accordance with MB Specifications for
Service Products 310.1.
The coolant is checked with every
maintenance interval at a qualified specialist
workshop.
i When the vehicle is first delivered, it is
filled with a coolant mixture that ensures
adequate antifreeze and corrosion
protection.
Filling capacities Model Capacity
ML 350
BlueEFFICIENCY
ML 350 4MATIC
BlueEFFICIENCY
Approx. 11.1 US qt
(10.5 l) ML 550 4MATIC
BlueEFFICIENCY
Approx. 13.6 US qt
(12.9 l) ML 63 AMG
Approx. 12.4 US qt
(11.7 l) ML 350 BlueTEC 4
MATIC
Approx. 12.2 US qt
(11.5 l) i
Use MB 325.0 or MB 326.0 corrosion
inhibitor/antifreeze. Service products and filling capacities
451Technical data Z