check engine MERCEDES-BENZ S-Class 2012 W221 Owner's Guide

use a sponge and cold water to clean it. DEF
residues crystallize after time and
contaminate the affected surfaces.
! DEF is not a fuel additive and must not be
added to the fuel tank. If DEF is added to
the fuel tank, this can lead to engine
damage.
i If you are adding between maintenance
intervals, add approximately 1 gallon (3.8 l)
of DEF to the DEF tank. One gallon (3.8 l)
of DEF is approximately 2 DEF refill bottles.
Then, have the DEF supply checked and
filled completely if necessary. For this
purpose, Mercedes-Benz recommends a
qualified specialist workshop.
Further information on DEF ( Y page 527).
The filler neck for DEF is located under the
"Minispare" emergency spare wheel in the
trunk floor.XSwitch off the ignition.XOpen the trunk.XLift up the trunk floor ( Y page 436).XTurn the "Minispare" emergency spare
wheel fastening in the direction of the
arrow and remove it.XRemove the "Minispare" emergency spare
wheel.XTurn DEF cap : counter-clockwise and
remove it.XTurn DEF filler cap ; counter-clockwise
and open it.
Filler cap ; is secured with a plastic strap.XUnscrew the covering cap from DEF refill
bottle =.XPlace DEF refill bottle = on the filler neck
as shown and screw on clockwise hand-
tight.
! Only screw on the DEF refill bottle hand-
tight. It could otherwise be damaged.
322RefuelingDriving and parking

XPress DEF refill bottle = down.
The DEF tank is filled. This may take up to
one minute.
i If the DEF refill bottle is no longer pressed
down, the filling process stops and the
partially emptied bottle can be removed.
XRelease DEF refill bottle =.XTurn DEF refill bottle = counter-clockwise
and remove it.XPlace DEF filler cap ; on the filler neck and
turn it clockwise.XInsert DEF cap : as shown and turn it
clockwise as far as it will go.XPlace the "Minispare" emergency spare
wheel in the emergency spare wheel well
above the DEF tank.XInsert the "Minispare" emergency spare
wheel fastening and tighten clockwise.XFold the trunk floor down.XClose the trunk lid.XDrive at a speed above 10 mph (16 km/h).
The Check Additive See Operator's
Manual message goes out after
approximately one minute.
i If the Check Additive See
Operator's Manual message remains
shown in the multifunction display, add an
additional bottle of DEF.
i Then, have the DEF supply checked at a
qualified specialist workshop and
completely refilled if necessary.
Parking
Important safety notes
GWARNING
Do not park this vehicle in areas where
combustible materials can come into contact
with the hot exhaust system. Combustible
materials, such as grass, hay or leaves could
be ignited by the hot exhaust system and
cause a vehicle fire. Do not park the vehicle
on dry grassland or harvested grain fields.
Unintended vehicle movement can cause
serious personal injury or damage to the
vehicle or the vehicle drivetrain. To reduce
such risks, always do the following before
turning off the engine and leaving the vehicle:
R keep your right foot on the brake pedal.
R engage the electric parking brake.
R shift the automatic transmission into park
position P.
R slowly release the brake pedal.
R when parked on an incline, always turn the
front wheels towards the road curb.
R turn the SmartKey in the ignition lock to
position 0 and remove the SmartKey from
the ignition lock, or press the KEYLESS-GO
Start/Stop button.
R take the SmartKey with you and lock the
vehicle when leaving.
Switching off the engine
Important safety notes
GWARNING
Do not turn off the engine before the vehicle
has come to a complete stop. With the engine
not running, there is no power assistance for
the brake and steering systems. In this case,
it is important to keep in mind that a
considerably higher degree of effort is
necessary to brake and steer the vehicle.
Parking323Driving and parkingZ

Steering and braking requires significantly
more effort and you could lose control of the
vehicle and cause an accident as a result.
Do not turn off the engine while the vehicle is
in motion.
Exhaust checkGWARNING
Inhalation of exhaust gas is hazardous to your
health. All exhaust gas contains carbon
monoxide (CO), and inhaling it can cause
unconsciousness and possible death.
Do not run the engine in confined areas (such
as a garage) which are not properly ventilated.
If you think that exhaust gas fumes are
entering the vehicle while driving, have the
cause determined and corrected
immediately. If you must drive under these
conditions, drive only with at least one
window fully open at all times.
Certain engine systems are designed to keep
the level of poisonous components in exhaust
fumes within legal limits.
These systems only work at peak efficiency
when they are maintained exactly in
accordance with the manufacturer's
specifications. For this reason, all work on the
engine must be carried out only by qualified
and authorized Mercedes-Benz technicians.
The engine settings must not be changed in
any circumstances. Furthermore, all specific
service work must be carried out at regular
intervals and in accordance with the
Mercedes-Benz service requirements. Details
can be found in the Service Booklet.
Brakes
Important safety notes
GWARNING
On slippery road surfaces, never downshift in
order to obtain braking action. This could
result in drive wheel slip and reduced vehicle
control. Your vehicle's ABS will not prevent
this type of loss of control.GWARNING
Make sure that you do not endanger other
road users when you apply the brakes.
Downhill gradients
! On long and steep gradients, you must
reduce the load on the brakes by shifting
early to a lower gear. This allows you to take
advantage of the engine braking effect and
helps avoid overheating and excessive
wear of the brakes.
When you take advantage of the engine
braking effect, a drive wheel may not turn
for some time, e.g. on a slippery road
surface. This could cause damage to the
drive train. This type of damage is not
covered by the Mercedes-Benz warranty.
Heavy and light loads
GWARNING
Depressing the brake pedal constantly results
in excessive and premature wear to the brake
pads.
It may also cause the brakes to overheat,
seriously impairing their effectiveness. It may
then not be possible to stop the vehicle in
sufficient time to avoid an accident.
If the brakes have been subjected to a heavy
load, do not stop the vehicle immediately, but
drive on for a short while. This allows the
airflow to cool the brakes more quickly.
Wet roads
GWARNING
After driving in heavy rain for some time
without applying the brakes or through water
deep enough to wet brake components, the
first braking action may be somewhat
reduced. You have to depress the brake pedal
Driving tips327Driving and parkingZ

more firmly. Maintain a safe distance from
vehicles in front.
After driving on a wet road or having the
vehicle washed, brake firmly while paying
attention to the traffic conditions. This will
warm up the brake discs, thereby drying them
more quickly and protecting them against
corrosion.
Limited braking performance on salt
treated roadsGWARNING
The layer of salt on the brake discs and the
brake pads/linings may cause a delay in the
braking effect, resulting in a significantly
longer braking distance, which could lead to
an accident.
To avoid this danger, you should:
R occasionally brake carefully, without
putting other road users at risk, when you
are driving on salted roads. This helps to
remove any salt that may have started to
build up on the brake discs and the brake
pads/linings.
R maintain a greater distance to the vehicle
ahead and drive with particular care.
R carefully apply the brakes at the end of a
trip and immediately after commencing a
new trip, so that salt residues are removed
from the brake discs.
Servicing the brakes
! If the red brake warning lamp lights up in
the instrument cluster and you hear a
warning tone while the engine is running,
the brake fluid level may be too low.
Observe additional warning messages in
the multifunction display.
The brake fluid level may be too low due to
brake pad wear or leaking brake lines.
Have the brake system checked
immediately. This work should be carried
out at an authorized Mercedes-Benz
Center.
All checks and maintenance work on the
brake system must be carried out at a
qualified specialist workshop. This work
should be carried out at an authorized
Mercedes-Benz Center.
Have the brake pads replaced and the brake
fluid renewed at a qualified specialist
workshop, e.g. an authorized Mercedes-Benz
Center.GWARNING
If brake pads or brake fluid other than those
recommended are used, the braking
properties of the vehicle can be degraded to
an extent that safe braking is substantially
impaired. This could result in an accident.
! Vehicles with 4MATIC: function or
performance tests may only be carried out
on a 2-axle dynamometer. If you are
planning to have the vehicle tested on such
a dynamometer, contact an authorized
Mercedes-Benz Center to obtain further
information first. Otherwise, you could
damage the drive train or the brake system.
! Vehicles with 4MATIC: as the ESP®
system operates automatically, the engine
and the ignition must be switched off
(SmartKey in position 0 or 1 in the ignition
lock or Start/Stop button in position 0 or
1 ) when the electric parking brake is being
tested on a brake dynamometer.
Braking maneuvers triggered automatically
by ESP ®
may seriously damage the brake
system.
! Vehicles with 4MATIC: as the ESP®
system operates automatically, the engine
and the ignition system must be switched
off (SmartKey in position 0 or 1 in the
ignition lock or Start/Stop button in
position 0 or 1) when:
R testing the electric parking brake on a
brake dynamometer.
R you intend to have the vehicle towed with
one of the axles raised.
328Driving tipsDriving and parking

Braking maneuvers triggered automatically
by ESP ®
may seriously damage the brake
system.
If your brake system is subject only to
moderate loads, you should test the
functionality of your brakes at regular
intervals by pressing firmly on the brake pedal
at high speeds. This improves the grip of the
brake pads.GWARNING
Make sure that you do not endanger other
road users when you apply the brakes.
You can find a description of Brake Assist
(BAS) on ( Y page 70) or of BAS PLUS on
( Y page 70).
High-performance brake system for
AMG vehicles
The high-performance brake system is
installed only on the S 63 AMG and S 65 AMG.
GWARNING
New vehicle brake pads and discs, and
replacement brake pads and discs may take
several hundred miles of driving until they
provide optimum braking efficiency. Until that
time, you may need to use increased brake
pedal pressure while braking. Please be aware
of this and adjust your driving and braking
accordingly during this break-in period.
Excessive high-demand braking will cause
correspondingly high brake wear. Please be
attentive to the brake warning lamp in the
instrument cluster and brake condition
messages in the multifunction display.
Especially for high performance driving, it is
important to maintain and have the brake
system checked regularly.
The high-performance brake system is
designed for heavy loads. This may lead to
noise when braking. This will depend on:
R speed
R braking force
R environmental conditions, such as
temperature and humidity
The wear of individual components of the
brake system, such as the brake pads/linings
or brake discs, depends on the individual
driving style and operating conditions.
For this reason, it is impossible to state a
mileage that will be valid under all
circumstances. An aggressive driving style
will lead to high wear. You can obtain further
information about this from your authorized
Mercedes-Benz Center.
Driving on wet roads
Hydroplaning
If water has accumulated to a certain depth
on the road surface, there is a danger of
hydroplaning occurring, even if:
R you drive at low speeds.
R the tires have adequate tread depth.
For this reason, in the event of heavy rain or
in conditions in which hydroplaning can occur
you must drive in the following manner:
R reduce your speed
R avoid ruts
R brake carefully
Driving on flooded roads
! Do not drive through flooded areas.
Check the depth of any water before driving
through it. Drive slowly through standing
water. Otherwise, water may enter the
vehicle interior or the engine compartment.
This can damage the electronic
components in the engine or the automatic
transmission. Water can also be drawn in
Driving tips329Driving and parkingZ

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible. Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Please read the information on qualified
specialist workshops ( Y page 31).
Important safety notes
You will find an illustration of the instrument
cluster in the "At a glance" section
( Y page 35).
GWARNING
A driver's attention to the road and traffic
conditions must always be his/her primary
focus when driving.
For your safety and the safety of others,
selecting features through the multifunction
steering wheel should only be done by the
driver when traffic and road conditions permit
it to be done safely.
Bear in mind that at a speed of just 30 mph
(approximately 50 km/h ), your vehicle is
covering a distance of 44 feet (approximately
14 m) every second.
GWARNING
No messages will be displayed if either the
instrument cluster or the multifunction
display is inoperative.
As a result, you will not be able to see
information about your driving conditions,
such as
R speed
R outside temperature
R warning/indicator lamps
Rmalfunction/warning messages
R failure of any systems
Driving characteristics may be impaired.
If you must continue to drive, do so with added
caution. Contact an authorized Mercedes-
Benz Center as soon as possible.GWARNING
HYBRID vehicles: It is imperative that you read
the HYBRID Supplemental Operating
Instructions included in your vehicle literature
portfolio. You may otherwise not receive all
necessary safety information and warning for
the operation of your vehicle.
GWARNING
Malfunction and warning messages are only
indicated for certain systems and are
intentionally not very detailed. The
malfunction and warning messages are
simply a reminder with respect to the
operation of certain systems. They do not
replace the owner's and/or driver's
responsibility to maintain the vehicle's
operating safety. Have all required
maintenance and safety checks performed on
the vehicle. Bring the vehicle to an authorized
Mercedes-Benz Center to address the
malfunction and warning messages.
Displays and operation
Coolant temperature display
GWARNING
Driving when your engine is overheated can
cause some fluids which may have leaked into
the engine compartment to catch fire. You
could be seriously burned.
Steam from an overheated engine can cause
serious burns which can occur just by opening
the engine hood. Stay away from the engine
if you see or hear steam coming from it.
Stop the vehicle in a safe location away from
other traffic. Turn off the engine, get out of the
372Displays and operationOn-board computer and displays

XPress a.
The current selection is displayed.XTo activate/deactivate: press a
again.
When ATTENTION ASSIST ( Y page 356) is
activated, the À symbol appears in the
multifunction display when the ignition is on.
Activating/deactivating Blind Spot
Assist
You can use the Blind Spot Assist
function to activate or deactivate Blind Spot
Assist ( Y page 360) or Active Blind Spot
Assist ( Y page 364).
XPress = or ; on the steering wheel
to select the DriveAssist menu.XPress 9 or : to select Blind Spot
Assist .XPress a.
The current selection is displayed.XTo activate/deactivate: press a
again.
Activating/deactivating Lane Keeping
Assist
You can use the Lane Keeping Assist
function to activate/deactivate Lane Keeping
Assist ( Y page 362) or Active Lane Keeping
Assist ( Y page 367).
XPress the = or ; button on the
steering wheel to select the DriveAssist
menu.XPress the 9 or : button to select
Lane Keeping Assist .XPress a.
The current selection is displayed.XTo activate/deactivate: press a
again.
If Lane Keeping Assist or Active Lane keeping
Assist is activated, the multifunction display
shows the à symbol when the ignition is
switched on.
Service menu
In the Service menu you can:
R call up display messages ( Y page 388)
R check the tire pressure electronically
( Y page 497)
R call up the service due date ( Y page 462)
R check the oil level ( Y page 457)
Settings menu
Introduction
The Settings menu can be used for:
R switching the daytime running lamps on/
off
R switching Adaptive Highbeam Assist on/
off
R showing or hiding the additional
speedometer
R selecting the units for speed and distance
R switching the belt adjustment on/off
R activating/deactivating the radar sensor
system
Switching the daytime running lamps
on/off
This function is not available in Canada.
If you have activated the Daytime Running
Light function and the light switch is in the
$ or c position, the daytime running
lamps are switched on automatically when
the engine is running.
In the dark, the following also light up:
R the parking lamps
R the tail lamps
R the license plate lamp
R the side marker lamps
If you turn the light switch to a different
position, the corresponding lights are
switched on. If you switch off the daytime
running lamps at night, make sure that the
light switch is set to L or c .
The factory setting is On.
Menus and submenus385On-board computer and displaysZ

Display messagesPossible causes/consequences and M Solutions$ (USA
only) J (Canada
only)
Service See Oper.
ManualThere is a malfunction in the system. The brake system continues
to operate normally.XDrive on carefully.XVisit a qualified specialist workshop.$ (USA
only) J (Canada
only)
Check Brake Fluid
LevelGRisk of accident
There is not enough brake fluid in the brake fluid reservoir.
Additionally, the red $ (USA only)/ J (Canada only)
warning lamp lights up in the instrument cluster and a warning
tone sounds.
XPull over and stop the vehicle safely as soon as possible, paying
attention to road and traffic conditions. Do not continue driving
under any circumstances.XEngage the electric parking brake.XConsult a qualified specialist workshop.XDo not add brake fluid. This will not rectify the malfunction.GWARNING
Driving with the message Check Brake Fluid Level displayed can result in an accident. Have
your brake system checked immediately.
Do not add brake fluid before checking the brake system. Overfilling the brake fluid reservoir can
result in spilling brake fluid on hot engine parts and the brake fluid catching fire. You can be
seriously burned.
Display messagesPossible causes/consequences and M SolutionsG
Tele Aid
InoperativeUSA only: one or more of the main functions in the mbrace system
are malfunctioning.
Canada only: one or more of the main functions of the TELEAID
system are malfunctioning.XUSA only: have the mbrace system checked at a qualified
specialist workshop.XCanada only: have the TELEAID system checked at a qualified
specialist workshop.PRE-SAFE
Inoperative See
Oper. ManualGRisk of injury
Important functions of PRE-SAFE ®
have failed. All other occupant
safety systems, e.g. air bags, remain available.
XVisit a qualified specialist workshop immediately.396Display messagesOn-board computer and displays

Display messagesPossible causes/consequences and M Solutionsb
Please Switch Off
LightsThe lights are still switched on when you leave the vehicle. A
warning tone also sounds.XTurn the light switch to $ or c .
or
XIf the rear fog lamp is switched on: press the light switch in to
the stop.Adaptive High-beam
Assist inoperativeAdaptive Highbeam Assist is defective.XVisit a qualified specialist workshop.
Engine
Display messagesPossible causes/consequences and M Solutions+
Check Coolant
Level See Oper.
ManualThe coolant level is too low.XAdd coolant, observing the warning notes when doing so
( Y page 460).XIf coolant needs to be added more often than usual, have the
engine coolant system checked at a qualified specialist
workshop.GWARNING
Do not spill antifreeze on hot engine parts. Antifreeze contains ethylene glycol which may burn
if it comes into contact with hot engine parts. You could be seriously burned.
! The coolant level is too low. Avoid making long journeys with too little coolant in the cooling
system. The engine will otherwise be damaged.
The display messages and the corresponding symbol that indicate that the coolant level is
too low must not be ignored.
404Display messagesOn-board computer and displays

Display messagesPossible causes/consequences and M Solutions?
Coolant Low Stop
Vehicle Turn
Engine OffThe coolant is too hot.XPull over and stop the vehicle safely and switch off the engine,
paying attention to road and traffic conditions.XMake sure that the air supply to the engine radiator is not
blocked, e.g. by snow, slush or ice.XWait until the display message disappears before restarting the
engine. Otherwise, there is a risk of engine damage.XPay attention to the coolant temperature display.XIf the temperature increases again, visit a qualified specialist
workshop immediately.The poly-V-belt may have torn.XPull over and stop the vehicle safely and switch off the engine,
paying attention to road and traffic conditions.XOpen the hood.XCheck whether the poly-V-belt is torn.
If the poly-V-belt is torn:
! Do not continue driving. The engine could otherwise overheat.
XConsult a qualified specialist workshop.
If the poly-V-belt is not damaged:
XWait until the display message disappears before restarting the
engine. Otherwise, there is a risk of engine damage.XPay attention to the coolant temperature display.XVisit a qualified specialist workshop.GWARNING
Driving when your engine is overheated can cause some fluids which may have leaked into the
engine compartment to catch fire. You could be seriously burned.
Steam from an overheated engine can cause serious burns which can occur just by opening the
engine hood. Stay away from the engine if you see or hear steam coming from it.
Stop the vehicle in a safe location away from other traffic. Turn off the engine, get out of the
vehicle and do not stand near the vehicle until the engine has cooled down.
! If the coolant temperature exceeds 248 ‡(120 †) do not continue driving. The engine will
otherwise be damaged.
Display messages405On-board computer and displaysZ