MERCEDES-BENZ S-Class 2012 W221 Owner's Manual

Setting the side air ventsXTo open/close: turn thumbwheel = up or
down.
i Side window defroster vent : is never
completely shut, even if side air vent ; is
shut.
Setting the glove box air vent
When automatic climate control is activated,
the glove box can be ventilated, for instance
to cool its contents. The level of airflow
depends on the airflow and air distribution
settings.
! Close the air vent when heating the
vehicle.
At high outside temperatures, open the air
vent and activate the "cooling with air
dehumidification" function. Otherwise,
temperature-sensitive items stored in the
glove box could be damaged.
XTo open: turn thumbwheel : counter-
clockwise from position 3 to position 2.XTo close: turn thumbwheel : clockwise
from position 2 to position 3.
Setting the rear-compartment air
vents
Setting the center vents in the rear
compartment
:Rear-compartment air vent, left;Rear-compartment air vent, right=Rear-compartment air vent thumbwheel,
right?Rear control panel for automatic climate
controlARear-compartment air vent thumbwheel,
leftXTo open/close: turn thumbwheel = or
A to the right or left.
i
In vehicles without rear-compartment air-
conditioning system: close the rear-
compartment air vents when heating mode
is activated, as no warm air flows through
the rear vents in the basic heating setting.
Setting the air vents299Climate controlZ

Setting the B-pillar air vents:B-pillar air vent;Thumbwheel for B-pillar air ventXTo open/close: turn thumbwheel ; to the
left or right.300Setting the air ventsClimate control

Useful information ............................302
Breaking-in notes .............................. 302
Driving ............................................... 302
Automatic transmission ...................310
Refueling ............................................ 317
Parking ............................................... 323
Driving tips ........................................ 326
Driving systems ................................ 330301Driving and parking

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible. Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Please read the information on qualified
specialist workshops ( Y page 31).
Breaking-in notes
The first 1000 miles (1500 km)
The more you look after the engine when it is
new, the more satisfied you will be with its
performance in the future.
R Drive at varying vehicle speeds and engine
speeds for the first 1000 miles (1500 km)
for this reason.
R Avoid overstraining the vehicle during this
period, e.g. driving at full throttle.
R Change gear in good time, at the latest
when the tachometer needle is 2
/ 3 of the
way to the red area in the tachometer
display.
R Do not manually shift to a lower gear to
brake the vehicle.
R If possible, do not depress the accelerator
pedal past the point of resistance
(kickdown).
R Only select shift ranges 3, 2 or 1 when
driving slowly, e.g. in mountainous terrain.
R If possible, drive in drive program E (in AMG
vehicles in drive program C) for the first
1000 miles (1500 km).
After 1000 miles (1500 km), you can increase
the engine speed gradually and bring the
vehicle up to full speed.
Additional breaking-in notes for AMG
vehicles:
R do not drive faster than 85 mph
(140 km/h) in the first 1000 miles
(1500 km).
R only allow the engine to reach a maximum
engine speed of 4500 rpm briefly.
R change gear in good time.
i You should also observe these notes on
running in if the engine or parts of the drive
train on your vehicle have been replaced.
i Always observe the respective speed
restrictions.
Driving
Important safety notes
GWARNING
Make sure absolutely no objects are
obstructing the pedals' range of movement.
Keep the driver's footwell clear of all
obstacles. If there are any floormats or
carpets in the footwell, make sure the pedals
still have sufficient clearance.
During sudden driving or braking maneuvers
the objects could get caught between the
pedals. You could then no longer brake or
accelerate. This could lead to accidents and
injury.
GWARNING
On slippery road surfaces, never downshift in
order to obtain braking action. This could
result in drive wheel slip and reduced vehicle
control. Your vehicle's ABS will not prevent
this type of loss of control.
GWARNING
It is dangerous to shift the automatic
transmission out of parking position P or
neutral position N if the engine speed is
higher than idle speed. If your foot is not firmly
on the brake pedal, the vehicle could
accelerate quickly forward or in reverse. You
302DrivingDriving and parking

could lose control of the vehicle and hit
someone or something. Only shift into gear
when the engine is idling normally and when
your right foot is firmly on the brake pedal.GWARNING
HYBRID vehicles: It is imperative that you read
the HYBRID Supplemental Operating
Instructions included in your vehicle literature
portfolio. You may otherwise not receive all
necessary safety information and warning for
the operation of your vehicle.
! Warm up the engine quickly. Do not use
the engine's full performance until it has
reached operating temperature.
Only shift the automatic transmission to
the desired drive position when the vehicle
is stationary.
Where possible, avoid spinning the drive
wheels when pulling away on slippery
roads. You could otherwise damage the
drive train.
! S 63 AMG: at low engine oil temperatures
below 68 ‡ (+20 † ), the maximum engine
speed is restricted in order to protect the
engine. To protect the engine and maintain
smooth engine operation, avoid driving at
full throttle when the engine is cold.
SmartKey positions
SmartKeygTo remove the SmartKey1Power supply for some consumers, such
as the windshield wipers2Ignition (power supply for all consumers)
and drive position3To start the engine
i The SmartKey can be turned in the
ignition lock even if it is not the correct
SmartKey for the vehicle. The ignition is not
switched on. The engine cannot be started.
KEYLESS-GO
General information
Vehicles with KEYLESS-GO are equipped with
a SmartKey featuring an integrated KEYLESS-
GO function and a detachable Start/Stop
button.
The Start/Stop button must be inserted into
the ignition lock and the SmartKey must be in
the vehicle.
Pressing the Start/Stop button several times
in succession corresponds to the different
SmartKey positions in the ignition lock. This
is only the case if you are not depressing the
brake pedal.
If you depress the brake pedal and press the
Start/Stop button, the engine starts
immediately.
The Start/Stop button can be removed from
the ignition lock. Then, you can insert the
SmartKey into the ignition lock.
Driving303Driving and parkingZ

iYou do not have to remove the Start/Stop
button from the ignition lock when you
leave the vehicle. However, you should
always take the SmartKey with you when
leaving the vehicle. The vehicle can be
started with the Start/Stop button and the
electrical equipment can be operated while
the SmartKey is in the vehicle.:Start/Stop button;Ignition lockXInsert Start/Stop button : into ignition
lock ;.
i
When you insert Start/Stop button :
into ignition lock ;, the system requires a
detection time of approximately two
seconds before you can use Start/Stop
button :.
Start/Stop button
=USA only?Canada onlyXPosition 0: if Start/Stop button : has not
yet been pressed, this corresponds to the
SmartKey being removed from the ignition.XPosition 1: press Start/Stop button :.
You can now activate the windshield
wipers, for example.
i If you then open the driver's door when in
this position, the power supply is
deactivated.
XPosition 2 (ignition): press Start/Stop
button : twice.
i
If you press Start/Stop button : once
when in this position and the driver's door
is open, the power supply is deactivated
again.
As soon as the ignition is switched on, all the
indicator lamps in the instrument cluster light
up. If an indicator lamp does not go out after
the engine is started or if it lights up while the
vehicle is in motion, see ( Y page 422).
Starting the engine
Important safety notes
GWARNING
Inhalation of exhaust gas is hazardous to your
health. All exhaust gas contains carbon
monoxide (CO), and inhaling it can cause
unconsciousness and possible death.
Do not run the engine in confined areas (such
as a garage) which are not properly ventilated.
If you think that exhaust gas fumes are
entering the vehicle while driving, have the
cause determined and corrected
immediately. If you must drive under these
conditions, drive only with at least one
window fully open at all times.
! Do not depress the accelerator pedal
when starting the engine.
i Vehicles with a gasoline engine: the
catalytic converter is preheated for up to
304DrivingDriving and parking

30 seconds after a cold start. The sound of
the engine may change during this time.
Automatic transmissionXShift the transmission to position P.
The transmission position display in the
multifunction display shows P.
i
You can also start the engine when the
transmission is in position N.
Starting procedure with the SmartKey
i To start the engine using the SmartKey
instead of KEYLESS-GO, pull the Start/
Stop button out of the ignition lock.
XTo start a gasoline engine: turn the
SmartKey to position 3 in the ignition lock
( Y page 303) and release it as soon as the
engine is running.XTo start a diesel engine: turn the
SmartKey to position 2 in the ignition lock
( Y page 303).
The % preglow indicator lamp in the
instrument cluster lights up.XWhen the % preglow indicator lamp
goes out, turn the SmartKey to position 3
( Y page 303) and release it as soon as the
engine is running.
i You can start the engine without preglow
if the engine is warm.
Using KEYLESS-GO to start the engine
GWARNING
As long as the SmartKey is in your vehicle, the
vehicle can be started. Therefore, never leave
children unattended in the vehicle, as they
could otherwise accidentally start the engine.
When leaving the vehicle, always take the
SmartKey with you and lock the vehicle. Do
not leave children unattended in the vehicle,
or with access to an unlocked vehicle. A
child's unsupervised access to a vehicle could
result in an accident and/or serious personal
injury.
i The Start/Stop button can be used to
start the vehicle manually without inserting
the SmartKey into the ignition lock. The
Start/Stop button must be inserted into
the ignition lock and the SmartKey must be
in the vehicle. This mode for starting the
engine operates independently of the ECO
start/stop automatic engine start function.XDepress the brake pedal and keep it
depressed.XTo start a gasoline engine: press the
Start/Stop button ( Y page 303) once.
The engine starts.XTo start a diesel engine: press the Start/
Stop button ( Y page 303) once.
Preglow is activated and the engine starts.
i If the engine is warm, the preglow time is
shortened.
Pulling away
Automatic transmission
GWARNING
It is dangerous to shift the automatic
transmission out of parking position P or
neutral position N if the engine speed is
higher than idle speed. If your foot is not firmly
on the brake pedal, the vehicle could
accelerate quickly forward or in reverse. You
could lose control of the vehicle and hit
someone or something. Only shift into gear
when the engine is idling normally and when
your right foot is firmly on the brake pedal.
i It is only possible to shift the transmission
from position P to the desired position if
you depress the brake pedal. Only then is
the parking lock released. If you do not
depress the brake pedal, you can move the
DIRECT SELECT lever but the parking lock
remains engaged.
XDepress the brake pedal and keep it
depressed.XShift the transmission to position D or R.Driving305Driving and parkingZ

XRelease the brake pedal.XCarefully depress the accelerator pedal.
The electric parking brake ( Y page 324) is
automatically released.
The red F (USA only) or ! (Canada
only) indicator lamp in the instrument
cluster goes out.
i The vehicle locks centrally once you have
pulled away. The locking knobs in the doors
drop down.
You can open the doors from the inside at
any time.
You can also deactivate the automatic
locking feature ( Y page 264).
i Upshifts take place at higher engine
speeds after a cold start. This helps the
catalytic converter to reach its operating
temperature more quickly.
Hill start assist
Hill start assist helps you when pulling away
forwards or in reverse on an uphill gradient.
It holds the vehicle for a short time after you
have removed your foot from the brake pedal.
This gives you enough time to move your foot
from the brake pedal to the accelerator pedal
and depress it before the vehicle begins to
roll.
GWARNING
Never leave the vehicle when it is held by hill
start assist. After approximately one second,
hill start assist will no longer brake your
vehicle and it could roll away.
XTake your foot off the brake pedal.
i Once you have taken your foot off the
brake pedal, the vehicle is held for around
one second.
XPull away.
Hill start assist will not function if:
R you are pulling away on a level road or a
downhill gradient.
R the transmission is in position N.
R
the electric parking brake is applied.
R ESP ®
is malfunctioning.
ECO start/stop function
General information
The ECO start/stop function is only available
for the S 63 AMG.
The ECO start/stop function is only available
in drive program C.
The ECO start/stop function switches the
engine off automatically when the vehicle
stops moving.
The engine starts automatically when the
driver wants to pull away again. The ECO
start/stop function thereby helps you to
reduce the fuel consumption and emissions
of your vehicle.
The ECO start/stop function is activated each
time the engine is switched on. If all the
requirements are fulfilled for automatic
engine switch-off ( Y page 307), the green
¤ ECO symbol is shown in the
multifunction display and Stop/Start
active appears. If not all of the requirements
are fulfilled, the ¤ ECO symbol is shown
in yellow and Stop/Start inactive
appears.
If the ECO start/stop function is deactivated
( Y page 307), the ¤ symbol is not shown.
GWARNING
If the engine is switched off and the ECO
symbol is shown in green in the multifunction
display, the engine has been switched off
automatically. All of the vehicle's systems
remain active. If you open the door, unfasten
your seat belt or remove your foot from the
brake pedal, the engine will automatically
start. The vehicle may begin moving. You
could suffer serious or even fatal injury or
cause an accident resulting in injury or death.
Never leave the vehicle while the ECO symbol
in the multifunction display is shown in green
306DrivingDriving and parking

or yellow. Always secure the vehicle against
rolling away before leaving it.
! Always switch the ignition off and take the
key with you when leaving the vehicle.
Automatic engine switch-off
The ECO start/stop function switches the
engine off automatically if the vehicle is
braked to a standstill and the brake remains
depressed with the transmission in position
D or N.
i You can still activate the HOLD function
when the vehicle is stationary, even if the
engine has been switched off
automatically. It is then not necessary to
continue applying the brakes during the
automatic stop phase. When you depress
the accelerator pedal, the engine starts
automatically and the braking effect of the
HOLD function is deactivated. Depress the
accelerator pedal carefully, as the engine
must be started first.
The engine is only switched off if:
R the outside temperature is within the range
which is suitable for the system.
R the engine is at normal operating
temperature.
R the set temperature for the vehicle interior
has been reached.
R the battery is sufficiently charged.
R the system detects that the windshield is
not fogged up when the air-conditioning
system is switched on.
R the hood is closed.
R no engine-relevant diagnostics are active.
R the driver's door is closed and the seat belt
is fastened.
Automatic engine start
The engine is started automatically if you:
R release the brake pedal when HOLD is not
activated and the transmission is in
position D or N
R shift the transmission to position R
R depress the accelerator pedal
R switch off the ECO start/stop function or
switch to drive program S or M
R unfasten your seat belt or open the driver's
door
The engine is also started automatically if:
R the vehicle starts to roll.
R the brake system requires this.
R the system detects moisture on the
windshield when the air-conditioning
system is switched on.
R the temperature in the vehicle interior
deviates from the set range.
R the charge level of the battery is too low.
Deactivating/activating the ECO start/
stop function
General information
You can deactivate and activate the ECO
start/stop function using COMAND
( Y page 261).
i You can also use the programmable
button ( Y page 120) to activate and
deactivate the ECO start/stop function if
you have assigned this function to the
button.
Deactivating
XDeactivate the ECO start/stop function
using COMAND ( Y page 261):
The ¤ ECO symbol goes out and the
Stop/Start deactivated display
message is shown in the multifunction
display.
i If drive program S or M has been selected,
the ECO start/stop function is always
deactivated.
Driving307Driving and parkingZ

ActivatingXActivate the ECO start/stop function using
COMAND ( Y page 261).
The ¤ ECO symbol and the Stop/
Start active display message are shown
in the multifunction display.
If not all conditions for automatic engine
switch-off are fulfilled ( Y page 307), the
Stop/Start inactive message appears.
i
If you activate the ECO start/stop
function in drive program S or M, drive
program C is selected automatically.
308DrivingDriving and parking