filter MERCEDES-BENZ S-Class 2012 W221 Owner's Manual

1, 2, 3 ...
115 V socket ...................................... 442
12 V socket see Sockets
4ETS
see ETS/4ETS (Electronic
Traction System)
4MATIC (permanent four-wheel
drive) .................................................. 346
4MATIC off-road system ................... 346
A
ABC see Active Body Control (ABC)
ABS (Anti-lock Braking System)
Display message ............................ 389
Function/notes ................................ 69
Important safety notes ....................69
Warning lamp ................................. 423
Activating/deactivating cooling
with air dehumidification ................. 293
Active Blind Spot Assist Activating/deactivating (on-
board computer) ............................ 385
Function/information ....................364
Active Body Control (ABC)
Display message ............................ 410
Function/notes ............................. 345
Active Driving Assistance package . 363
Active Lane Keeping Assist Activating/deactivating (on-
board computer) ............................ 385
Display message ............................ 411
Function/information ....................367
Active Light System
Display message ............................ 403
Active multicontour seat .......... 108, 272
Active service system PLUS see ASSYST PLUS service interval
display
ADAPTIVE BRAKE ................................. 73
Adaptive Damping System (ADS) ..... 344
Adaptive Highbeam Assist
Display message ............................ 404
Function/notes ............................. 280
Switching on/off (on-board
computer) ...................................... 386
Additional speedometer ................... 386
Additives (engine oil) ........................ 528
Address Entering (example) .........................153
see Address book
Address book
Calling up ....................................... 205
Connecting a call ........................... 208
Creating an entry ........................... 206
Deleting an entry ........................... 207
Entering characters .......................132
Entry as a home address ...............178
Importing contacts ........................204
Introduction ................................... 203
Starting route guidance .................208
Voice tag ....................................... 208
Air bags
Display message ............................ 399
Front air bag (driver, front
passenger) ....................................... 48
Important safety notes ....................46
PASSENGER AIRBAG OFF
indicator lamp .................................. 50
Safety guidelines ............................. 45
Side impact air bag ..........................48
Window curtain air bag ....................49
Air-conditioning system
see Climate control
Air distribution
Setting ........................................... 295
Setting (COMAND) .........................266
Air filter (display message) .............. 408
Airflow Setting ........................................... 295
Setting (COMAND) .........................266
AIRMATIC
Display message ............................ 409
Function/notes ............................. 343
Air pressure
see Tire pressure
Air vents
Glove box ....................................... 299
Important safety notes ..................2984Index

Exterior lightingsee Exterior lighting
Exterior mirror parking position
Adjusting (COMAND) .....................262
Exterior mirrors
Adjusting ....................................... 111
Dipping (automatic) .......................112
Folding in/out (automatically) .......112
Folding in/out (electrically) ...........112
Out of position (troubleshooting) ...112
Storing settings (memory
function) ........................................ 113
Storing the parking position ..........113
Eyeglasses compartment ................. 433
F
Factory setting (reset function) ....... 150
Fader, setting .................................... 135
Fast forward Audio mode (CD, DVD, MP3) .........225
Rear Seat Entertainment System ...255
Video DVD ..................................... 242
Fast rewind
Audio mode (CD, DVD, MP3) .........225
Rear Seat Entertainment System ...255
Video DVD ..................................... 242
Favorites (COMAND) ......................... 120
Filler cap see Fuel filler flap
First-aid kit ......................................... 472
Flat tire Changing a wheel/mounting the
spare wheel ................................... 473
MOExtended run-flat system .........477
Preparing the vehicle .....................473
Raising the vehicle .........................474
Floormat ............................................. 453
Freeway information ......................... 187
Front fog lamps ................................. 278
Display message ............................ 402
Switching on/off ........................... 278
Front-passenger seat
Adjusting from the driver's seat ..... 105
Adjusting from the rear
compartment ................................. 105
Front windshield
see Windshield
Fuel
Additives ........................................ 526
Displaying the current
consumption .................................. 376
Displaying the range ......................376
Driving tips .................................... 326
Fuel gauge ....................................... 35
Important safety notes ..................525
Premium-grade unleaded gasoline . 525
Problem (malfunction) ...................320
Refueling ........................................ 317
Specifications ................................ 525
Tank content/reserve fuel .............524
Fuel filler flap, opening/closing ....... 319
Fuel filter (display message) ............ 408
Fuel level Calling up the range (on-board
computer) ...................................... 376
Fuel tank
Capacity ........................................ 524
Problem (malfunction) ...................320
Function buttons (COMAND) ............ 119
Fuses Allocation chart ............................. 486
Before changing ............................. 486
Dashboard fuse box .......................486
Engine emergency stop .................487
Fuse box in the engine
compartment ................................. 487
Fuse box in the rear compartment . 486
Important safety notes ..................485
G
Garage door opener Clearing the memory .....................453
Notes ............................................. 450
Opening/closing the garage door ..453
Programming (button in the rear-
view mirror) ................................... 451
Gasoline ............................................. 318
Gear indicator (on-board
computer) .......................................... 379
Gear or selector lever (cleaning
guidelines) ......................................... 468
Genuine Mercedes-Benz parts ......... 520
Glove box ........................................... 432
GPS reception .................................... 151
12Index

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible. Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Please read the information on qualified
specialist workshops ( Y page 31).
Overview of climate control systems
Important safety notes
GWARNING
Severe conditions (e.g. strong air pollution)
may require replacement of the filter before
its scheduled replacement interval. A clogged
filter will reduce the air volume to the interior
and the windows could fog up, impairing
visibility and endangering you and others.
Have a blocked filter replaced at a Mercedes-
Benz Center as soon as possible.
GWARNING
Follow the recommended settings for heating
and cooling given on the following pages.
Otherwise, the windows could fog up,
impairing visibility and endangering you and
others.
The automatic climate control controls the
temperature and the humidity in the vehicle
interior and filters undesirable substances
from the air.
The automatic climate control is only
operational when the engine is running 16
.
Optimum operation is only achieved if you
drive with the side windows and sliding
sunroof/panorama roof with power tilt/
sliding panel closed.
You can also set some automatic climate
control functions via COMAND (Y page 265).
i Ventilate the vehicle for a brief period
during warm weather, e.g. using the
convenience opening feature ( Y page 93).
This will speed up the cooling process and
the desired vehicle interior temperature
will be reached more quickly.
i The integrated filter can filter out most
particles of dust and completely filters out
pollen. A clogged filter reduces the amount
of air supplied to the vehicle interior. For
this reason, you should always observe the
interval for replacing the filter, which is
specified in the Service Booklet. As it
depends on environmental conditions, e.g.
heavy air pollution, the interval may be
shorter than stated in the Service Booklet.
i It is possible that the blower may be
activated automatically 40 minutes after
the SmartKey is removed. The vehicle is
then ventilated for 30 minutes to dry the
air-conditioning system.16 The residual heat function can only be activated/deactivated if the ignition is switched off.290Overview of climate control systemsClimate control

GWARNING
Overfilling of the fuel tank may create
pressure in the system which could cause a
gas discharge. This could cause the gasoline
to spray back out when removing the fuel
pump nozzle, which could cause personal
injury.
GWARNING
Hybrid vehicles: be sure to read the "HYBRID"
supplement. Otherwise, you could fail to
recognize dangers.
GWARNING
Do not fill diesel tanks with gasoline. Do not
mix diesel fuel with gasoline. Otherwise the
fuel system and engine could be damaged. In
addition, the vehicle could catch fire.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not use diesel to refuel
vehicles with a gasoline engine. Even a
small quantity of the wrong fuel will
damage the fuel system and engine.
! Do not switch on the ignition if you
accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel lines.
Notify a qualified specialist workshop and
have the fuel tank and fuel lines drained
completely.
Gasoline
Fuel grade
! You should only refuel with unleaded
premium-grade gasoline as this avoids
damaging the catalytic converter.
If engine running problems are apparent,
have the cause checked immediately and
repaired. Excess unburned fuel can
otherwise enter the catalytic converter,
leading to overheating and possibly
causing a fire.
! Use a filter when refueling from a fuel can.
Otherwise, the fuel lines and/or injection
system could be blocked by particles from
the fuel can.
i Only refuel with premium-grade unleaded
gasoline with a specified minimum octane
number of 91 (average value of 96 RON/
86 MON).
You will usually find information about the
fuel grade on the pump. If you cannot find
the label on the pump, ask the staff for
assistance.
You can find more information under "Fuel"
( Y page 525), or by contacting an
authorized Mercedes-Benz Service Center
or visiting http://www.mbusa.com (USA
only).
Diesel
Fuel grade
! Only refuel with ULTRA-LOW SULFUR
DIESEL FUEL (ULSD, 15 ppm SULFUR
MAXIMUM). Using other diesel fuels could
result in increased wear and damage to the
engine and/or exhaust system.
Never refuel with marine diesel or heating
oil.
Do not mix these fuels with diesel fuels and
do not use any special additives, as this
may result in damage.
! Use a filter when adding fuel from a fuel
can. Otherwise, the fuel lines and/or the
fuel injection system could be blocked by
particles from the fuel can.
i Usually, you will find information about
the fuel grade on the pump. If you cannot
find the label on the gasoline pump, ask the
gas station staff.
You can find more information under “Fuel”
( Y page 525), or by contacting an
authorized Mercedes-Benz Service Center
or visiting http://www.mbusa.com (USA
only).
318RefuelingDriving and parking

conditions. Additionally, the driver must
provide the steering, braking and other driving
inputs necessary to remain in control of the
vehicle.
High-frequency sources such as toll stations,
speed measuring systems etc. can cause the
DISTRONIC PLUS system to temporarily
cease functioning.GWARNING
The DISTRONIC PLUS cannot take road and
traffic conditions into account. Only use the
DISTRONIC PLUS if the road, weather and
traffic conditions make it advisable to travel
at a constant speed.
GWARNING
Use of the DISTRONIC PLUS can be
dangerous on slippery roads. Rapid changes
in tire traction can result in wheel spin and
loss of control.
The DISTRONIC PLUS does not function in
adverse sight and distance conditions. Do not
use the DISTRONIC PLUS during conditions of
fog, heavy rain, snow or sleet.
GWARNING
The DISTRONIC PLUS cannot take weather
conditions into account. Switch off the
DISTRONIC PLUS or do not switch it on if:
R roads are slippery or covered with snow or
ice. The wheels could lose traction while
braking or accelerating, and the vehicle
could skid.
R the DISTRONIC PLUS system sensor covers
are dirty or visibility is diminished due to
snow, rain or fog, for example. The distance
control system functionality could be
impaired.
Always pay attention to surrounding traffic
conditions even while the DISTRONIC PLUS is
switched on. Otherwise, you may not be able
to recognize dangerous situations until it is
too late. This could cause an accident in which
you and/or others could be injured.
GWARNING
The "Resume" function should only be
operated if the driver is fully aware of the
previously set speed and wishes to resume
this particular preset speed.
GWARNING
Your undivided attention to street and traffic
conditions is necessary at all times whether
DISTRONIC PLUS is active or not.
The use of DISTRONIC PLUS can be
dangerous on winding roads or in heavy traffic
because conditions do not allow safe driving
at a constant speed.
DISTRONIC PLUS does not react to stationary
objects on the road (for example, a vehicle
stopped in traffic or an abandoned vehicle).
DISTRONIC PLUS likewise does not react to
oncoming vehicles.
Deactivate DISTRONIC PLUS:
R when changing to the right lane, if the
vehicles in the left lane are driving slower
R when driving into a filter lane or an
expressway exit
R in complex driving situations, for example
in construction sites on an expressway
In these situations DISTRONIC PLUS will
maintain the set speed if it is not deactivated.
DISTRONIC PLUS is intended only for
maintaining a set speed and a set distance
from the objects moving in front of the
vehicle.
GWARNING
An intermittent warning sounds and the
distance warning lamp · in the instrument
cluster is illuminated if the DISTRONIC PLUS
system calculates that the distance to the
vehicle ahead and your vehicle's current
speed indicate that the DISTRONIC PLUS will
not be capable of slowing the vehicle
sufficiently to maintain the preset following
distance, which creates a danger of a
collision.
334Driving systemsDriving and parking

Display messagesPossible causes/consequences and M Solutions¸·
Replace Air FilterVehicles with a diesel engine: the engine air filter is dirty and must
be replaced.XVisit a qualified specialist workshop.!
Check Fuel FilterVehicles with a diesel engine: there is water in the fuel filter. The
water must be drained off.XVisit a qualified specialist workshop.Ø
Check Additive See
Oper. ManualThe DEF tank is empty.XHave the DEF tank filled as soon as possible at a qualified
specialist workshop ( Y page 321).Ø
Remaining Starts:
16The DEF level has fallen to a minimum.XHave the DEF tank filled immediately at a qualified specialist
workshop. ( Y page 321)
Driving systems
Display messagesPossible causes/consequences and M SolutionsÀ
Attention Assist:
Pause!Based on specific criteria, ATTENTION ASSIST 21
has determined
that the driver is tired or paying less attention. A warning tone also
sounds.XIf necessary, take a break.
During long journeys, take regular breaks in good time so you get
enough rest.
À
Attention Assist
InoperativeATTENTION ASSIST 21
has failed.XVisit a qualified specialist workshop.Á
Night View Assist
InoperativeNight View Assist Plus is defective.XVisit a qualified specialist workshop.21 Not available on hybrid vehicles.408Display messagesOn-board computer and displays

Reduce Oil Level message appears, the
engine oil level is too high.XHave excess oil siphoned off.
! Do not add too much oil. Adding too much
oil can result in damage to the engine or the
catalytic converter. Have excess oil
siphoned off.
If the For Engine Oil Level Ignition
Must be On message appears:
XTurn the SmartKey to position 2 in the
ignition lock.
If the Need More Time to Check Engine
Oil Level message appears:
XIf the engine is at normal operating
temperature: repeat the measurement
after about five minutes.
If the engine is not at normal operating
temperature (e.g. if the engine was only
started briefly): repeat the measurement
after about 30 minutes.
If the Engine Oil Level Not When
Engine On message appears:
XSwitch off the engine.XIf the engine is at normal operating
temperature: wait about five minutes
before carrying out the measurement.
If the engine is not at normal operating
temperature, e.g. if the engine was only
started briefly: wait about 30 minutes
before carrying out the measurement.
i If you wish to cancel the measurement,
press the % button on the multifunction
steering wheel.
Adding engine oil
GWARNING
If engine oil comes into contact with hot
engine parts, it may ignite and you could burn
yourself. Do not spill any engine oil on hot
engine parts.
HEnvironmental note
When adding oil, take care not to spill any. If
oil enters the soil or waterways, it is harmful
to the environment.
! Use only engine oils and oil filters that
have been approved for vehicles equipped
with a service system. A list of the engine
oils and oil filters tested and approved in
accordance with the Mercedes-Benz
Specifications for Service Products can be
called up by visiting http://
www.mbusa.com (USA only). More
information about tested and approved
engine oils and oil filters is available from
any authorized Mercedes-Benz Center.
Damage to the engine or exhaust system is
caused by the following:
R using engine oils and oil filters which
have not been specifically approved for
the service system.
R replacing the engine oil or oil filter after
the replacement interval required by the
service system has elapsed
R using engine oil additives.
! Do not add too much oil. If the oil level is
above the "max" mark on the dipstick, too
much oil has been added. This can lead to
damage to the engine or the catalytic
converter. Have excess oil siphoned off.
Example: engine oil cap
Engine compartment459Maintenance and careZ

CapacitiesModelCapacityFuel, coolant,
lubricants, etc.Engine oil and
filterS 550 34
S 550 4MATIC 34
S 63 AMG9.0 US qt (8.5 l)Approved engine
oilsS 600
S 65 AMG9.5 US qt (9.0 l)S 350 BlueTEC
4MATIC8.5 US qt (8.0 l)Cooling systemS 550 34
S 550 4MATIC 34Approximately 14.5 US qt
(13.7 l)MB 325.0 or
MB 326.0
anticorrosion/
antifreezeS 600Approximately 15.3 US qt
(14.5 l)S 63 AMGApproximately 12.2 US qt
(11.5 l)S 65 AMGApproximately 14.7 US qt
(13.9 l)S 350 BlueTEC
4MATICApproximately 12.0 US qt
(11.4 l)Tank capacityS 550 34
S 550 4MATIC 34
S 350 BlueTEC
4MATIC21.9 US gal (83.0 l)Gasoline engines:
premium-grade
unleaded gasoline
(at least 91 octane,
average value
between 96 RON/
86 MON)
Diesel engines:
ULTRA-LOW
SULFUR HIGHWAY
DIESEL FUEL (ULSD,
maximum sulfur
content 15 ppm)S 600
S 63 AMG
S 65 AMG23.8 US gal (90.0 l)ReserveAll models except
AMG vehicles2.9 US gal (11.0 l)AMG vehicles3.7 US gal (14.0 l)34 BlueEFFICIENCY.524Service products and capacitiesTechnical data

! Do not refuel with low-grade fuel and do
not use fuel additives that are not tested
and approved for Mercedes-Benz vehicles.
Damage to or malfunctions of the fuel
system may otherwise occur.
DEF
Important safety notes
i For BlueTEC vehicles only.
DEF is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
! Rinse surfaces that have come into
contact with DEF immediately with water or
remove DEF using a damp cloth and cold
water. If the DEF has already crystallized,
use a sponge and cold water to clean it. DEF
residues crystallize after time and
contaminate the affected surfaces.
High outside temperatures
If DEF heats up to over 122 ‡ (50 †) for
extended periods, e.g. as a result of direct
sunlight on the DEF reservoir, DEF can
decompose. Ammonia vapors develop as a
result.
GWARNING
When opening the filler cap of the DEF tank
ammonia gas vapors may escape. Refill DEF
in a well ventilated area only. Ammonia gas
vapors have a pungent odor and are
particularly irritating for your skin, mucous
membranes, and eyes. Inhaling ammonia gas
vapors will cause burning eyes, nose, and
throat, as well as coughing and watering eyes.
Low outside temperatures
DEF freezes at a temperature of
approximately 12 ‡ (–11 †). The vehicle is
equipped with a DEF preheating system when
it leaves the factory. Winter operation is
therefore also guaranteed at temperatures
below 12 ‡ (–11 †).
Additives
! Only use DEF in accordance with ISO
22241. Do not use additives with DEF and
do not dilute DEF with water. This may
destroy the BlueTEC exhaust gas
aftertreatment system.
Purity
Assuring the purity of DEF is particularly
important with respect to avoiding
malfunctions in the exhaust gas
aftertreatment system.
If DEF is pumped out of the DEF tank, e.g.
during repair work, it must not be returned to
the tank. The purity of the fluid can no longer
be guaranteed.
! Impurities in DEF (e.g. due to other
service products, cleaning agents or dust)
lead to:
R increased emission values
R damage to the catalytic converter
R engine damage
R malfunctions in the BlueTEC exhaust gas
aftertreatment system
Engine oil
Please bear the following in mind
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz Center
or go to the Internet site
http://www.mbusa.com (USA only).
! Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
Service products and capacities527Technical dataZ