key MERCEDES-BENZ S CLASS 2016 Repair Manual

On vehicles with KEYLESS-GO: X
Switch off the engine. X
Remove your foot from the brake pedal. X
Set the windshield wipers to position

Useful information
i This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
i Read the information on qualified specialist
workshops ( Y
page 28).
Overview of climate control systems
General notes Observe the settings recommended on the fol-
lowing pages. The windows could otherwise fog
up.
To prevent the windows from fogging up: R
switch off climate control only briefly R
switch on air-recirculation mode only briefly R
switch on the cooling with air dehumidifica-
tion function R
switch on the defrost windshield function
briefly, if required
Climate control regulates the temperature and
air humidity in the vehicle interior. The air filter
cleans the air, thus improving the interior cli-
mate.
For vehicles with a combustion engine, the
"Cooling with air dehumidification" function is
only available when the engine is running. For
hybrid vehicles, the "Cooling with air dehumidi-
fication" function is also available via the elec-
tric refrigerant compressor when the engine is
not running. Optimum climate control is only
achieved with the side windows and roof closed.
If you start the engine using your smartphone,
the last selected climate control setting is reac-
tivated ( Y
page 164).
The residual heat function can only be activated
or deactivated with the ignition switched off
( Y
page 152).
i Ventilate the vehicle for a brief period during
warm weather, e.g. using the convenience
opening feature ( Y
page 95). This will speed
up the cooling process and the desired inte- rior temperature will be reached more
quickly.
i The integrated filter filters out most parti-
cles of dust and soot and completely filters
out pollen. It also reduces gaseous pollutants
and odors. A clogged filter reduces the
amount of air supplied to the vehicle interior.
For this reason, you should always observe
the interval for replacing the filter, which is
specified in the Maintenance Booklet. As it
depends on environmental conditions, e.g.
heavy air pollution, the interval may be
shorter than stated in the Maintenance Book-
let.
i It is possible that the blower may be activa-
t ed automatically 60 minutes after the Smart-
Key has been removed depending on various
factors, e.g. the outside temperature. The
vehicle is then ventilated for 30 minutes to dry
the climate control system.140
Overview of climate control systems
Climate control

X
Turn the SmartKey to position 2 in the ignition
lock ( Y
page 162).X
To activate: press the

Problems with the "Cooling with air dehumidification" function Problem
Possible causes/consequences and P Solutions
The indicator lamp in the
V button flashes
three times or remains
off. Cooling with air
dehumidification can
also no longer be activa-
ted using the multimedia
system (see the sepa-
rate operating instruc-
tions). Cooling with air dehumidification has been deactivated due to a mal-
function. X
Visit a qualified specialist workshop.
Setting climate control to automatic
General notes In automatic mode, the set temperature is main-
tained automatically at a constant level. The
system automatically regulates the temperature
of the dispensed air, the airflow and the air dis-
tribution.
The "Cooling with air dehumidification" function
is activated automatically in automatic mode.
Controlling front climate control auto-
matically using the front control panel X
Turn the SmartKey to position 2 in the ignition
lock ( Y
page 162).X
Set the desired temperature using the

You can set the temperature separately for the
following areas on vehicles without rear-com-
partment climate control: R
front footwells, left and right R
driver and front passenger area
You can set the temperature separately for the
following areas on vehicles with rear-compart-
ment climate control: R
front footwells, left and right R
driver and front passenger area R
rear compartment, left and right
Setting the temperature in the front
compartment using the front control
panel X
Turn the SmartKey to position 2 in the ignition
lock ( Y
page 162).X
To increase or reduce: press the

Defrosting th e windshieldYou can use this function to defrost th e wind-
shield or to clear a fogge d up windshield or fron t
sid e windows on th e inside.
Switc h of f th e "Windshield defrosting" function
as soo n as th e windshield is clear again .X
Tur n th e SmartKey to position 2 in th e ignition
loc k ( Y
page 162).X
To switch on: press th e d rocker switch
on th e fron t contro l uni t up or down .
The indicator lamp in th e d rocker switch
lights up.
The climat e contro l syste m switches to th e
followin g functions:R
hig h airflowR
hig h temperatureR
air distribution to th e windshield and fron t
sid e windowsR
air-recirculation mode of fR
windshield heatin g onR
coolin g wit h air dehumidificationX
To deactivate : press th e d rocker switch
up or down .
The indicator lamp in th e d rocker switch
goe s out . The previously selecte d setting s are
restored . Air-recirculation mode remain s
deactivated.
or X
Press th e X rocker switch up or down .
or X
Use th e

Problems with the rear window defroster Problem
Possible causes/consequences and P Solutions
The rear window
defroster has deactiva-
ted prematurely or can-
not be activated. The battery has not been sufficiently charged. X
Switch off any consumers that are not required, e.g. reading lamps,
interior lighting or the seat heating.
When the battery is sufficiently charged, the rear window defroster
can be activated again.
Switching air-recirculation mode
on/off
General notes You can also temporarily deactivate the flow of
fresh air manually if unpleasant odors are enter-
ing the vehicle from outside. The air already
inside the vehicle will then be recirculated.
If you switch on air-recirculation mode, the win-
dows can fog up more quickly, in particular at
low temperatures. Only use air-recirculation
mode briefly to prevent the windows from fog-
ging up.
Activating/deactivating X
Turn the SmartKey to position 2 in the ignition
lock ( Y
page 162).X
To activate: press the r rocker switch up
or down.
The indicator lamp in the r rocker switch
lights up.
Air-recirculation mode switches on automati-
cally: R
at high outside temperatures R
at high levels of pollution R
in a tunnel
The indicator lamp in the r rocker switch is
not lit when automatic air-recirculation mode is
activated. Outside air is added after about
30 minutes. X
To deactivate: press the r rocker switch
up or down.
The indicator lamp in the r rocker switch
goes out. Air-recirculation mode deactivates automati-
cally: R
after approximately five minutes at outside
temperatures below approximately 41 ‡
(5 †) R
after approximately five minutes if cooling
with air dehumidification is deactivated R
after approximately 30 minutes at outside
temperatures above approximately 41 ‡
(5 †) if the "Cooling with air dehumidifica-
tion" function is activated
Switching the residual heat on or off
General notes Vehicles with rear-compartment climate
control: once the engine is switched off, it is
possible to make use of the residual heat of the
engine to continue heating or ventilating the
rear and front compartment of the vehicle for
approximately 15 minutes. If the "Residual heat"
function is set for only the front or only the rear
compartment, it is possible to continue heating
or ventilating for approximately 30 minutes.
Vehicles without rear-compartment climate
control: once the engine is switched off, it is
possible to make use of the residual heat of the
engine to continue heating or ventilating the
front compartment of the vehicle for approx-
imately 30 minutes.
The heating or ventilation time depends on the
temperature that has been set.152
Operating the climate control systems
Climate control

Front control panel X
Turn th e SmartKey to position 0 in th e ignition
loc k or remove it ( Y
page 162).X
To activate: press th e ! or V rocke r
switch up or down .
The indicator lamp in th e ! or V rocke r
switch lights up.
The blowe r will run at a low spee d regardless of
th e airflow setting .
If you activat e th e residual heat function at high
temperatures , only th e ventilation will be acti-
vated. The blowe r run s at medium speed.X
To deactivate: press th e ! or V
rocke r switch up or down .
The indicator lamp in th e ! or V rocke r
switch goes out .
Rear control panel X
Turn th e SmartKey to position 0 in th e ignition
loc k or remove it ( Y
page 162).
The RES T display appear s on th e rear com-
partmen t display.X
To activate: press rocke r switch t up or
down ( Y
page 141).
The indicator lamp in rocke r switch t lights
up. X
To deactivate: press rocke r switch t up or
down ( Y
page 141).
The indicator lamp in rocke r switch t goes
out . RES T goes out on th e rear compartmen t
display.
i If you do no t activat e th e residual heat func-
tion , RES T goes out automatically after fiv e
minute s on th e rear compartmen t display.
Residual heat is deactivated automatically: R
after approximately 30 minute si f the residual
heat function is activated in the front or rear
compartment R
after approximately 15 minutes if the residual
heat function is activated in the front and rear
compartments R
when the ignition is switched on R
if the battery voltage drops Perfume atomizer
Operating the perfume atomizer
G WARNING
If children open the vial, they could drink the
perfume or it could come into contact with
their eyes. There is a risk of injury. Do not
leave children unsupervised in the vehicle.
If the perfume liquid has been drunk, consult
a doctor. If perfume comes into contact with
your eyes or skin, rinse the eyes with clean
water. If you continue to experience difficul-
ties, consult a doctor.
H Environmental note
Full vials must not be dis-
posed of with household
waste. They must be collec-
ted separately and recycled
to protect the environment.
Dispose of full vials in an
environmentally responsible
manner and take them to a
harmful substance collec-
tion point.
C
Vial lid
D
Vial
The perfume atomizer helps to improve driving
comfort.
Via the multimedia system you can: R
switch the perfume atomizer on or off R
regulate the perfume intensity (see the sepa-
rate operating instructions)Operating the climate control systems 153
Climate control Z

Problems with the perfume atomizer Problem
Possible causes/consequences and P Solutions
The vehicle interior is not
perfumed although the
perfume atomizer is acti-
vated. The perfume vial has not been pushed into the holder as far as it will
go. X
Slide the perfume vial into the holder as far as it will go.
The perfume vial is not filled sufficiently. X
Pre-filled vials: dispose of the empty vial.X
Use a new pre-filled vial. X
Refillable vials: fill the perfume vial with a maximum of 0.5 fl. oz.
(15 ml) of the same perfume.
The perfume atomizer is faulty. X
Have the perfume atomizer checked at a qualified specialist work-
shop.
Ionization You can use the "Ionization" function to purify
the air in the vehicle interior and attain an
improved interior climate.
The ionization of the interior air is odorless and
cannot be perceived directly in the vehicle inte-
rior.
You can switch ionization on or off using the
multimedia system (see the separate operating
instructions).
Ionization can only be switched on if the front
climate control system is activated. The side air
vent on the driver's side must be open.
Pre-entry climate control via Smart-
Key
General notes The "Pre-entry climate control via SmartKey"
function is only available in PLUG-IN HYBRID
vehicles.
Before getting in, the driver's seat area or the
whole interior can be briefly warmed or ventila-
ted in advance with the air from the air vents
being pre-cooled.
The high-voltage battery must be sufficiently
charged before "Pre-entry climate control via
SmartKey" can be activated. When the vehicle is pre-cooled, the following
functions are activated if required: R
Climate control system R
Blower R
Seat ventilation
When the vehicle is pre-heated, the following
functions are activated if required: R
Climate control system R
Blower R
Seat heating R
Steering wheel heating R
Exterior mirror heating R
Rear window defroster
If you have activated the following functions
using the multimedia system, they are activated
together with the "Pre-entry climate control via
SmartKey" function: R
Armrest heating R
Perfume atomizer R
Ionization
Activating the perfume atomizer or ionization
(see separate operating instructions).
Activating or deactivating "Pre-entry
climate control via SmartKey"
Before "Pre-entry climate control via SmartKey"
can be activated, you must activate the function
via the multimedia system (see separate oper-
ating instructions).Operating the climate control systems 155
Climate control Z

X
To activate pre-entry climate control via
SmartKey: unlock the vehicle with the Smart-
Key or KEYLESS-GO.
The climate control functions are activated
for up to 5 minutes for pre-heating and pre-
cooling.
To deactivate "Pre-entry climate control via
SmartKey": "Pre-entry climate control via
SmartKey" switches off automatically when the
engine is started.
The following functions remain active after the
engine is started: R
Seat heating (heating) R
Seat ventilation (ventilation) R
Armrest heating R
Perfume atomizer R
Ionization
An activated "Pre-entry climate control via
SmartKey" function can be deactivated using
the rocker switch ( Y
page 158).156
Operating the climate control systems
Climate control