fuel MERCEDES-BENZ S-CLASS SEDAN 2012 Service Manual

changes by 18 ‡ (10 †), the tire pressure
changes by approximately 10 kPa (0.1 bar/
1.5 psi). Take this into account when
checking the pressure of warm tires and only
correct the tire pressure if it is too low for the
current operating conditions. If you check the
tire pressure when the tires are warm, the
resulting value will be higher than if the tires
were cold. This is normal. Do not reduce the
tire pressure to the value specified for cold
tires. The tire pressure would otherwise be
too low.
Observe the recommended tire pressures for
cold tires:
R on the Tire and Loading Information placard
on the B-pillar on the driver's side
R in the tire pressure table on the inside of
the fuel filler flap
R printed in yellow on the rim of the
emergency/collapsible spare wheel
(depending on vehicle equipment)
Underinflated or overinflated tires
Underinflation
GWARNING
Tires with pressure that is too low can
overheat and burst as a consequence. In
addition, they also suffer from excessive and/
or irregular wear, which can severely impair
the braking properties and the driving
characteristics. There is a risk of an accident.
Avoid tire pressures that are too low in all the
tires, including the spare wheel.
Underinflated tires may:
R wear quickly and unevenly
R have an adverse effect on fuel consumption
R overheat, leading to tire defects
R have an adverse effect on handling
characteristics
OverinflationGWARNING
Tires with excessively high pressure can burst
because they are damaged more easily by
road debris, potholes etc. In addition, they
also suffer from irregular wear, which can
severely impair the braking properties and the
driving characteristics. There is a risk of an
accident.
Avoid tire pressures that are too high in all the
tires, including the spare wheel.
Overinflated tires may:
R have an adverse effect on handling
characteristics
R wear quickly and unevenly
R be more susceptible to damage
R have an adverse effect on ride comfort
R increase the braking distance
Maximum tire pressures
Never exceed the maximum permissible tire
inflation pressure. Always observe the
recommended tire pressure for your vehicle
when adjusting the tire pressure
( Y page 495).
:Example: maximum permissible tire
pressure
i The actual values for tires are vehicle-
specific and may deviate from the values in
the illustration.
498Tire pressureWheels and tires

Checking the tire pressures
Important safety notes
Observe the "Tire pressure information"
section ( Y page 495).
Information on air pressure for the tires on
your vehicle can be found:
R on the vehicle's Tire and Loading
Information placard on the B-pillar
R on the tire pressure label on the fuel filler
flap
R in the "Tire pressure information" section
Checking tire pressures manually
To determine and set the correct tire
pressure, proceed as follows:
XRemove the valve cap of the tire that is to
be checked.XPress the tire pressure gauge securely onto
the valve.XRead the tire pressure and compare it with
the recommended value on the Tire and
Loading Information placard on the
B-pillar on the driver's side of your vehicle.XIf necessary, increase the tire pressure to
the recommended value ( Y page 495).XIf the tire pressure is too high, release air
by pressing down the metal pin in the valve
using the tip of a pen, for example. Then
check the tire pressure again using the tire
pressure gauge.XScrew the valve cap onto the valve.XRepeat these steps for the other tires.
Tire pressure monitor
Important safety notes
It is the driver's responsibility to set the tire
pressure to that recommended for cold tires
which is suitable for the operating situation
( Y page 495). Note that the correct tire
pressure for the current operating situation
must first be taught-in to the tire pressure
monitor. If there is a substantial loss of
pressure, the warning threshold for the
warning message is aligned to the reference
values taught-in. Restart the tire pressure
monitor after adjusting the pressure of the
cold tires ( Y page 501). The current
pressures are saved as new reference values.
As a result, a warning message will appear if
the tire pressure drops significantly.
The tire pressure monitor does not warn you
of an incorrectly set tire pressure. Observe
the notes on the recommended tire pressure
( Y page 495).
The tire pressure monitor is not able to warn
you of a sudden loss of pressure, e.g. if the
tire is penetrated by a foreign object. In the
event of a sudden loss of pressure, bring the
vehicle to a halt by braking carefully. Avoid
abrupt steering maneuvers.
If a tire pressure monitor system is installed,
the vehicle's wheels have sensors that
monitor the tire pressures in all four tires. The
tire pressure monitor warns you if the
pressure drops in one or more of the tires. The
tire pressure monitor only functions if the
correct sensors are installed to all wheels.
The tire pressure monitor has a yellow
warning lamp in the instrument cluster for
indicating pressure loss/malfunctions (USA)
or pressure loss (Canada). Whether the
warning lamp flashes or lights up indicates
whether a tire pressure is too low or the tire
pressure monitoring system is
malfunctioning:
R if the warning lamp is lit continuously, the
tire pressure on one or more tires is
significantly too low. The tire pressure
monitor is not malfunctioning.
R USA only: if the warning lamp flashes for
around a minute and then remains lit
constantly, the tire pressure monitor is
malfunctioning.GWARNING
Each tire, including the spare (if provided),
should be checked at least once a month
when cold and inflated to the pressure
Tire pressure499Wheels and tiresZ

recommended by the vehicle manufacturer
on the Tire and Loading Information placard
on the driver's door B-pillar or the tire
pressure label on the inside of the fuel filler
flap. If your vehicle has tires of a different size
than the size indicated on the Tire and Loading
Information placard or the tire pressure label,
you should determine the proper tire pressure
for those tires.
As an added safety feature, your vehicle has
been equipped with a tire pressure monitoring
system (TPMS) that illuminates a low tire
pressure telltale when one or more of your
tires are significantly underinflated.
Accordingly, when the low tire pressure
telltale illuminates, you should stop and check
your tires as soon as possible, and inflate
them to the proper pressure. Driving on a
significantly underinflated tire causes the tire
to overheat and can lead to tire failure.
Underinflation also reduces fuel efficiency
and tire tread life, and may affect the vehicle's
handling and stopping ability.
Please note that the TPMS is not a substitute
for proper tire maintenance, and it is the
driver's responsibility to maintain correct tire
pressure, even if underinflation has not
reached the level to trigger illumination of the
TPMS low tire pressure telltale.
USA only:
Your vehicle has also been equipped with a
TPMS malfunction indicator to indicate if the
system is not operating properly. The TPMS
malfunction indicator is combined with the
low tire pressure telltale. When the system
detects a malfunction, the warning lamp will
flash for approximately a minute and then
remain continuously illuminated. This
sequence will be repeated every time the
vehicle is started as long as the malfunction
exists.
When the malfunction indicator is illuminated,
the system may not be able to detect or signal
low tire pressure as intended. TPMS
malfunctions may occur for a variety of
reasons, including the installation ofincompatible replacement or alternate tires
or wheels on the vehicle that prevent the
TPMS from functioning properly. Always
check the TPMS malfunction telltale after
replacing one or more tires or wheels on your
vehicle to ensure that the replacement or
alternate tires and wheels allow the TPMS to
continue to function properly.
i USA only:
If the tire pressure monitor is
malfunctioning, it may take more than ten
minutes for the tire pressure warning lamp
to inform you of the malfunction by flashing
for approximately one minute and then
remaining lit.
When the malfunction has been rectified,
the tire pressure warning lamp goes out
after a few minutes of driving.
Information on tire pressures is displayed in
the multifunction display. After a few minutes
of driving, the current tire pressure of each
tire is shown in the multifunction display.
i The tire pressure values indicated by the
on-board computer may differ from those
measured at a gas station with a pressure
gauge. The tire pressures shown by the on-
board computer refer to those measured at
sea level. At high altitudes, the tire pressure
values indicated by a pressure gauge are
higher than those shown by the on-board
computer. In this case, do not reduce the
tire pressures.
i The operation of the tire pressure monitor
can be affected by interference from radio
transmitting equipment (e.g. radio
headphones, two-way radios) that may be
being operated in or near the vehicle.
i USA only:
This device complies with part 15 of the
FCC Rules. Operation is subject to the
following two conditions:
1. This device may not cause harmful
interference, and500Tire pressureWheels and tires

you can also define reference values
manually as described here.
Restart the tire pressure monitor after you
have set the tire pressure to the value
recommended for the desired driving
situation ( Y page 495). Only correct tire
pressures on cold tires. Comply with the
recommended tire pressures on the Tire and
Loading Information placard the B-pillar on
the driver's side. Additional tire pressure
values for driving at high speeds or with heavy
loads can be found in the tire pressure table
on the inside of the fuel filler flap.XMake sure that the tire pressure is correct
on all four wheels.XMake sure that the SmartKey is in position
2 in the ignition lock.XPress the = or ; button on the
steering wheel to select the Service
menu.XPress the 9 or : button to select
Tire Pressure .XPress the a button.
The multifunction display shows the
current tire pressure of the individual tires
or the Tire Pressures Displayed
After Driving A Few Minutes
message.XPress the : button.
The Use Current Pressures as New
Reference Values message appears in
the multifunction display.
If you wish to confirm the restart:
XPress the a button.
The Tire Pressure Monitor
Restarted message appears in the
multifunction display.
After driving for a few minutes, the system
checks whether the current tire pressures
are within the specified range. The new tire
pressures are then accepted as reference
values and monitored.If you wish to cancel the restart:XPress the % button.
The tire pressure values stored at the last
restart will continue to be monitored.
Loading the vehicle
Instruction labels for tires and loads
GWARNING
Overloaded tires can overheat, causing a
blowout. Overloaded tires can also impair the
steering and driving characteristics and lead
to brake failure. There is a risk of accident.
Observe the load rating of the tires. The load
rating must be at least half of the GAWR of
your vehicle. Never overload the tires by
exceeding the maximum load.
Two instruction labels on your vehicle show
the maximum possible load.
(1)The Tire and Loading Information placard
is on the B-pillar on the driver's side. The
Tire and Loading Information placard
shows the maximum permissible number
of occupants and the maximum
permissible vehicle load. It also contains
details of the tire sizes and
corresponding pressures for tires
installed at the factory.(2)The vehicle identification plate is on the
B-pillar on the driver's side. The vehicle
identification plate informs you of the
gross vehicle weight rating. It is made up
of the vehicle weight, all vehicle
occupants, the fuel and the cargo. You
can also find information about the
maximum gross axle weight rating on the
front and rear axle.
The maximum gross axle weight rating is
the maximum weight that can be carried
by one axle (front or rear axle). Never
exceed the maximum load or the
maximum gross axle weight rating for the
front or rear axle.502Loading the vehicleWheels and tires

GAWR (Gross Axle Weight Rating)
The GAWR is the maximum permissible axle
load. The actual load on an axle must never
exceed the gross axle weight rating. The
gross axle weight rating can be found on the
vehicle identification plate on the B-pillar on
the driver's side.
Speed rating
The speed rating is part of the tire
identification. It specifies the speed range for
which the tire is approved.
GVW (Gross Vehicle Weight)
The gross vehicle weight includes the weight
of the vehicle including fuel, tools, the spare
wheel, accessories installed, occupants,
luggage and the drawbar noseweight, if
applicable. The gross vehicle weight must not
exceed the gross vehicle weight rating GVWR
as specified on the vehicle identification plate
on the B-pillar on the driver's side.
GVWR (Gross Vehicle Weight Rating)
The GVWR is the maximum permissible gross
weight of a fully loaded vehicle (the weight of
the vehicle including all accessories,
occupants, fuel, luggage and the drawbar
noseweight, if applicable). The gross vehicle
weight rating is specified on the vehicle
identification plate on the B-pillar on the
driver's side.
Maximum loaded vehicle weight
The maximum weight is the sum of the curb
weight of the vehicle, the weight of the
accessories, the total load limit and the
weight of the optional equipment installed at
the factory.
Kilopascal (kPa)
Metric unit for tire pressure. 6.9 kPa
corresponds to 1 psi. Another unit for tire
pressure is bar. There are 100 kilopascals
(kPa) to 1 bar.
Load index
In addition to the load-bearing index, the load
index may also be imprinted on the sidewall
of the tire. This specifies the load-bearing
capacity more precisely.
Curb weight
The weight of a vehicle with standard
equipment including the maximum capacity
of fuel, oil and coolant. It also includes the air-
conditioning system and optional equipment
if these are installed in the vehicle, but does
not include passengers or luggage.
Maximum load rating
The maximum load rating in kilograms or
pounds is the maximum weight for which a
tire is approved.
Maximum permissible tire pressure
Maximum permissible tire pressure for one
tire.
Maximum load on one tire
Maximum load on one tire. This is calculated
by dividing the maximum axle load of one axle
by two.
PSI (pounds per square inch)
A standard unit of measure for tire pressure.
Definition of terms for tires and loading513Wheels and tiresZ

Mercedes-Benz specifically for your
vehicle.
These tires have been specially adapted for
use with the control systems, such as ABS
or ESP ®
, and are marked as follows:
R MO = Mercedes-Benz Original
R MOE = Mercedes-Benz Original Extended
(tires featuring run-flat characteristics)
R MO1 = Mercedes-Benz Original (only
certain AMG tires)
Mercedes-Benz Original Extended tires
may only be used on wheels that have been
specifically approved by Mercedes-Benz.
Only use tires, wheels or accessories
tested and approved by Mercedes-Benz.
Certain characteristics, e.g. handling,
vehicle noise emissions or fuel
consumption, may otherwise be adversely
affected. In addition, when driving with a
load, tire dimension variations could cause
the tires to come into contact with the
bodywork and axle components. This could
result in damage to the tires or the vehicle.
Mercedes-Benz accepts no liability for
damage resulting from the use of tires,
wheels or accessories other than those
tested and approved.
Information on tires, wheels and approved
combinations can be obtained from any
qualified specialist workshop.
i The recommended pressures for various
operating conditions can be found:
R on the Tire and Loading Information
placard with the recommended tire
pressures on the B-pillar on the driver's
side
R in the tire pressure table on the inside of
the fuel filler flap
Observe the notes on recommended tire
pressures under various operating
conditions ( Y page 495).
Check tire pressures regularly, and only
when the tires are cold. Comply with themaintenance recommendations of the tire
manufacturer in the vehicle document
wallet.
i Notes on the vehicle equipment – always
equip the vehicle:
R with tires of the same size on a given axle
(left/right)
R with the same type of tires at a given time
(summer tires, winter tires, MOExtended
tires)
i On the following pages, you can find
information on approved wheel rims and
tire sizes for equipping your vehicle with
winter tires. Winter tires are not available
ex factory as standard equipment or
optional extras.
If you would like to equip your vehicle with
approved winter tires, you may also, in
certain circumstances, require rims of the
appropriate size. The sizes of the approved
winter tires may deviate from those of the
original tires. This is dependent on the
model and the equipment installed at the
factory.
The tires and wheel rims, as well as further
information, can be obtained at a qualified
specialist workshop.
i Overview of abbreviations used in the
following tire tables:
R BA: both axles
R FA: front axle
R RA: rear axle
In the following table, the wheel/tire
combinations are allocated to the vehicle
models through variants, e.g. V1, V2 etc.:V1S 550 27V2S 350 BlueTEC 4MATIC, S 550
4MATIC 27V3S 600V4AMG vehicles27
BlueEFFICIENCY516Wheel and tire combinationsWheels and tires

iThe data shown on the identification plate
is example data. This data is different for
every vehicle and can deviate from the data
shown here. You can find the data
applicable to your vehicle on the vehicle's
identification plate.
Vehicle identification number (VIN)
The vehicle identification number (VIN) can
be found in the following locations:
R on the vehicle identification plate
( Y page 523)
R at the lower edge of the windshield
( Y page 524)
In addition to being stamped on the vehicle
identification plate, the vehicle identification
number (VIN) is also stamped onto the vehicle
body. It is under the trim behind the rear seat
armrest.
XFold down the rear seat armrest.XOpen the trim.
You will see vehicle identification number
(VIN) :.Engine number:Emission control information plate,
including the certification of both federal
and Californian emissions standards;Engine number (stamped into the
crankcase)=VIN (on the lower edge of the windshield)
Service products and filling
capacities
Important safety notes
GWARNING
Comply with all valid regulations with respect
to handling, storing and disposing of service
fluids. Otherwise, you could endanger
persons or the environment.
Keep service fluids out of the reach of
children.
For health reasons, you should prevent
service fluids from coming into direct contact
with your skin or clothing.
If a service fluid is swallowed, contact a
physician immediately.
Service products include the following:
R fuels (e.g. gasoline, diesel)
R additives for exhaust gas aftertreatment,
e.g. DEF
R lubricants (e.g. engine oil, transmission oil)
R coolant
R brake fluid
524Service products and filling capacitiesTechnical data

Rwindshield washer fluid
R climate control system refrigerant
Vehicle components and their service
products must match. Therefore only use
products tested and approved by Mercedes-
Benz.
Information about tested and approved
products can be obtained from an authorized
Mercedes-Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved
by Mercedes-Benz by the following
inscription on the containers:
R MB-Freigabe (e.g. MB-Freigabe 229.51)
R MB Approval (e.g. MB Approval 229.51)
Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g.
MB 229.5). They have not necessarily been
approved by Mercedes-Benz.
Fuel
Important safety notes
GWARNING
Gasoline and diesel fuels are highly flammable
and poisonous. They burn violently and can
cause serious injury.
Never allow sparks, flames or smoking
materials near gasoline or diesel fuel!
Turn off the engine before refueling.
Whenever you are around gasoline or diesel
fuel, avoid inhaling fumes and any skin or
clothing contact. Extinguish all smoking
materials.
Direct skin contact with fuels and the
inhalation of fuel vapors are damaging your
health.
Tank capacityTotal capacity
S 550 31
S 550 4MATIC 31
S 350 BlueTEC 4MATIC21.9 US gal (83.0 l)S 600
AMG vehicles23.8 US gal (90.0 l)Of which reserveApprox.
2.9 US gal (11.0 l)Of which reserve fuel,
AMG vehiclesApprox.
3.7 US gal (14.0 l)
Gasoline
Fuel grade
! Do not use diesel to refuel vehicles with a
gasoline engine. Even small amounts of the
wrong fuel result in damage to the fuel
system and engine.
! You should only refuel with unleaded
premium-grade gasoline as this avoids
damaging the catalytic converter.
If engine running problems are apparent,
have the cause checked immediately and
repaired. Excess unburned fuel can
otherwise enter the catalytic converter,
leading to overheating and possibly
causing a fire.
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline may be used.
If there is no premium-grade unleaded
gasoline available and regular unleaded
gasoline must be used, please observe the
following precautions:
R only fill the fuel tank to half full with
regular unleaded gasoline and fill the rest
31 BlueEFFICIENCYService products and filling capacities525Technical dataZ

with premium-grade unleaded gasoline
as soon as possible.
R do not drive at the maximum speed.
R avoid sudden acceleration.
R if the vehicle is carrying a light load, e.g.
two passengers without luggage, do not
allow the engine to rev above 3000 rpm.
R if the vehicle is fully loaded or is being
operated in mountainous terrain, do not
depress the accelerator pedal further
than Ô of the pedal travel.
Only refuel with premium-grade unleaded
gasoline with a minimum octane number of
91.
Reformulated Gasoline (RFG) and/or
unleaded gasoline with additives can be used.
However, the concentration of additives in
the fuel must be less than 10%, e.g.
R Ethanol
R TAME
R ETBE
R IPA
R TBA
For MTBE, the concentration should not
exceed 15%.
The concentration of methanol in gasoline
including other additives must not exceed
3%.
Using mixtures of methanol and ethanol is not
permitted. Gasohol, a mixture of 10% ethanol
and 90% unleaded gasoline, can be used.
All of these mix fuels must fulfill the fuel
requirements, e.g.:
R knock resistance
R boiling point
R vapor pressure
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult an
authorized Mercedes-Benz Center or visit
http://www.mbusa.com (USA only).Information on refueling ( Y page 321).
Additives
! Do not refuel with low-grade fuel and do
not use fuel additives that are not tested
and approved for Mercedes-Benz vehicles.
Damage to or malfunctions of the fuel
system may otherwise occur.
One of the main problems of poor fuel quality
is the forming of deposits that are created
during the gasoline combustion process.
Mercedes-Benz recommends that you use
branded fuels that have additives.
If you use fuels without these additives over
a longer period of time, carbon deposits may
build up. These deposits form at the inlet
valves and in the combustion chamber in
particular.
This could lead to engine problems, e.g.:
R longer engine warm-up phase
R uneven idle
R engine noise
R misfiring
R loss of power
Carbon deposits may form if the availability
of gasoline with relevant additives is
insufficient (in certain regions). In this case,
Mercedes-Benz recommends additives
approved for use in Mercedes-Benz vehicles;
see http://bevo.mercedes-benz.com.
For a list of approved products, consult an
authorized Mercedes-Benz Center. Comply
with the instructions for use on the product
label.
Do not mix other fuel additives with fuel. This
causes unnecessary costs and could damage
the engine.
Diesel
Fuel grade
GWARNING
Do not use gasoline to refuel vehicles with a
diesel engine. Never mix diesel with gasoline.
This causes damage to the fuel system and
526Service products and filling capacitiesTechnical data

engine and could result in the vehicle catching
fire.
! Only use commercially available vehicular
ULTRA-LOW SULFUR DIESEL FUEL (ULSD,
15 ppm maximum sulfur content) that
meets the ASTM D975 standard. If you do
not refuel with ULSD, you may damage the
BlueTEC exhaust gas aftertreatment
system of the vehicle.
! Do not use gasoline to refuel vehicles with
a diesel engine. Do not mix diesel fuel with
gasoline, kerosene or paraffin. This may
otherwise result in damage to the fuel
system and engine.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or on the
Internet at http://www.mbusa.com (USA
only).
Information on refueling ( Y page 321).
Bio-diesel - FAME (fatty acid methyl ester)
Mercedes-Benz USA approves the use of bio-
diesel B5 for all BlueTEC diesel engines. The
concentration of bio-diesel in the ULSD may
not exceed 5 % by volume.
Pure biodiesel and diesel fuel with a higher
percentage of biodiesel, such as B20, can
damage the engine and the fuel system. For
this reason, they are not approved.
For more information, consult the gas station
staff. The bio-diesel B5 label on the gasoline
pump must clearly state that the standard for
ULSD has been fulfilled. If the label is not
clear, do not refuel the vehicle.
Do not refuel your vehicle with fuels unless
they have been approved by Mercedes-Benz.
Information on refueling ( Y page 321).Low outside temperatures
i Diesel fuel with improved cold flow
properties is available during the winter
months. Further information about fuel
properties can be obtained from oil
companies, e.g. at gas stations.
Flow improver
To improve the low-temperature resistance of
diesel fuel, a flow improver can be attached.
The effectiveness of a flow improver is not
guaranteed for every fuel.
Only use flow improvers tested and approved
by Mercedes-Benz. During use, please
observe the information on operation.
Correct dosage and sufficient mixing are
decisive in improving low-temperature
resistance with the flow improver.
Overdosage can potentially even decrease
low-temperature resistance and must
therefore be avoided. Follow the
manufacturer's guidelines on dosage.
Mix the additive into the diesel in good time,
before the flow characteristics of the diesel
become insufficient. Otherwise, malfunctions
can arise through heating the fuel system,
e.g. through parking in a heated garage.
More information about recommended flow
improvers can be obtained from any qualified
specialist workshop.
DEF
Please bear the following in mind
DEF is a non-flammable, non-toxic, colorless,
odorless and water-soluble fluid.
High outside temperatures
GWARNING
If you open the DEF tank cap, small amounts
of ammonia vapor may be released. This
depends in particular upon the age of the DEF.
Service products and filling capacities527Technical dataZ