MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

Important safety notes
GWARNING
When driving in emergenc ymode, th edriving
characteristics deteriorate, e.g. when corner-
ing ,accelerating quickly and when braking .
Ther eis aris kof an accident.
Do no texceed th estate dmaximum speed.
Avoid abrup tsteering and driving maneuvers,
and driving ove robstacles (curbs, potholes,
off-road). This applie sin particular to aladen
vehicle.
Stop driving in emergenc ymod eif:
Ryou hear bangin gnoises .
Rthevehicl estart sto shake.
Ryou see smoke and smell rubber.
RES P®is intervening constantly.
Rthere are tears in th esidewalls of th etire.
Afte rdriving in emergenc ymode, have th e
whee lrim schecke dat aqualified specialist
workshop wit hregard to their further use. The
defective tire must be replace din every case.
TIREFIT kit
Important safety notes
TIREFI Tis atire sealant.
You can use TIREFI Tto seal punctures of up to
0.16 in (4 mm), particularl ythose in th etire
tread. You can use TIREFI Tat outside tempera-
tures down to Ò4 ‡ (Ò20†).
GWARNING
In th efollowin gsituations, th etire sealant is
unable to provid esufficien tbreakdown assis-
tance ,as it is unable to seal th etire properly:
Rthere are cut sor punctures in th etire larger
than those mentioned above.
Rth ewhee lrim is damaged.
Ryou hav edriven at ver ylow tire pressures or
on aflat tire.
There is aris kof an accident.
Do no tdrive th evehicle. Contac t aqualified
specialist workshop .
GWARNING
The tire sealant is harmful and causes irrita-
tion .It mus tno tcome into contact wit hyour
skin ,eyes or clothin gor be swallowed .Do no t
inhale TIREFI Tfumes. Kee ptire sealant away
from children .There is aris kof injury.
If you come into contact wit hth etire sealant ,
observ eth efollowing:
RRinse off th etire sealant from your skin
immediately wit hwater.
RIf th etire sealant comes into contact wit h
your eyes ,immediately rinse them thor-
oughly wit hclean water.
RIf tire sealant is swallowed ,immediately
rinse your mout hout thoroughl yand drink
plenty of water. Do no tinduc evomiting,
and see kmedica lattention immediately.
RImmediately chang eout of clothin gwhic h
has come into contact wit htire sealant .
RIf an allergic reaction occurs, see kmedica l
attention immediately.
!Do no toperate th etire inflation compressor
for longer than eigh tminute sat atime without
a break. It may otherwise overheat.
The tire inflation compressor can be operate d
again once it has cooled down .
Comply wit hth emanufacturer’s safet yinstruc -
tion son th esticker on th etire inflation com-
pressor.
Using the TIREFIT kit
XDo no tremove any foreign objects whic hhav e
penetrated th etire, e.g. screw sor nails.
XRemove th etire sealant bottle, th eaccompa-
nying TIREFI Tsticker and th etire inflation
Flat tire36 9
Breakdown assis tance
Z

compressor from the stowage well under-
neath the trunk floor (Ypage 367).
XAffix part:of the TIREFIT sticker to the
instrument cluster within the driver's field of
vision.
XAffix part ;of the TIREFIT sticker near the
valve on the wheel with the defective tire.
XPull connector ?with the cable and hose A
out of the tire inflation compressor housing.
XScrew hose Aonto flange Bof tire sealant
bottle :.
XPlace tire sealant bottle :head downwards
into recess ;of the tire inflation compres-
sor.
XRemove the cap from valve Con the faulty
tire.
XScrew filler hose Donto valve C.
XInsert connector ?into a 12 V socket
(Ypage 336) in your vehicle.
XTurn the SmartKey to position 1in the ignition
lock (Ypage 162).
XPress on and off switch =on the tire inflation
compressor to I.
The tire inflation compressor is switched on.
The tire is inflated. First, tire sealant is pumped into the tire. The
pressure can briefly rise to approximately
500 kPa (5 bar/73 psi).
Do not switch off the tire inflation com-
pressor during this phase.
XLet the tire inflation compressor run for a
maximum of five minutes. The tire should then
have attained a pressure of at least 180 kPa
(1.8 bar/26 psi).
If a pressure of 180 kPa (1.8 bar/26 psi) has
been attained after five minutes, see "Tire pres-
sure reached" (
Ypage 371).
If a tire pressure of 180 kPa (1.8 bar/26 psi) has
not been attained after five minutes, see "Tire
pressure not reached" (
Ypage 370).
If tire sealant has escaped, clean it off affected
areas as quickly as possible. Use plain water if
possible.
If your clothes are soiled with tire sealant, have
them cleaned with perchloroethylene at a dry
cleaner as soon as possible.
Tire pressure not reached
If a pressure of 180 kPa (1.8 bar/26 psi) has not
been attained after five minutes:
XSwitch off the tire inflation compressor.
XUnscrew the filler hose from the valve of the
faulty tire.
Note that tire sealant may escape when you
unscrew the filler hose.
XVery slowly drive forwards or reverse approx- imately 30 ft (10 m).
XPump up the tire again.
After a maximum of five minutes the tire pres-sure must be at least 180 kPa (1.8 bar/
26 psi).
GWARNING
If the required tire pressure is not reached
after the specified time, the tire is too badly
damaged. The tire sealant cannot repair the
tire in this instance. Damaged tires and a tire
pressure that is too low can significantly
impair the vehicle's braking and driving char-
acteristics. There is a risk of accident.
Do not continue driving. Contact a qualified
specialist workshop.
370Flat tire
Breakdown assistance

Tire pressure reached
GWARNING
A tire temporarily sealed with tire sealant
impairs the driving characteristics and is not
suitable for higher speeds. There is a risk of
accident.
You should therefore adapt your driving style
accordingly and drive carefully. Do not exceed the specified maximum speed with a tire that
has been repaired using tire sealant.
The maximum permissible speed for a tire
sealed with tire sealant is 50 mph (80 km/h).
The upper part of the TIREFIT sticker must be
affixed to the instrument cluster in the driver's
field of vision.
!Residue from the tire sealant may come out
of the filler hose after use. This could cause
stains.
Therefore, place the filler hose in the plastic
bag which contained the TIREFIT kit.
HEnvironmental note
Have the used tire sealant bottle disposed of
professionally, e.g. at a qualified specialist
workshop.
If a tire pressure of 180 kPa (1.8 bar/26 psi) has
been attained after five minutes:
XSwitch off the tire inflation compressor.
XUnscrew the filler hose from the valve of the
faulty tire.
XStow the tire sealant bottle and the tire infla-
tion compressor.
XPull away immediately.
XStop after driving for approximately ten
minutes and check the tire pressure with the
tire inflation compressor.
The tire pressure must now be at least
130 kPa (1.3 bar/19 psi).
GWARNING
If the required tire pressure is not reached
after driving for a short period, the tire is too
badly damaged. The tire sealant cannot repair
the tire in this instance. Damaged tires and a
tire pressure that is too low can significantly
impair the vehicle's braking and driving char-
acteristics. There is a risk of accident.
Do not continue driving. Contact a qualified
specialist workshop.
iIn cases such as the one mentioned above,
contact an authorized Mercedes-Benz Cen-
ter. Or call 1-800-FOR-MERCedes (in the
USA) or 1-800-387-0100 (in Canada).
XCorrect the tire pressure if it is still at least
130 kPa (1.3 bar/19 psi). See the Tire and
Loading Information placard on the driver's
side B-pillar or the tire pressure table in the
fuel filler flap for values.
XTo increase the tire pressure: switch on the
tire inflation compressor.
XTo reduce the tire pressure: depress pres-
sure release button Enext to pressure gauge
F.
XWhen the tire pressure is correct, unscrew the
filler hose from the valve of the sealed tire.
XScrew the valve cap onto the tire valve of the
sealed tire.
XPull the tire sealant bottle out of the tire infla-
tion compressor.
The filler hose remains attached to the tire
sealant bottle.
XDrive to the nearest qualified specialist work-
shop and have the tire changed there.
XHave the tire sealant bottle replaced as soon
as possible at a qualified specialist workshop.
XHave the tire sealant bottle replaced every
four years at a qualified specialist workshop.
Flat tire371
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Battery (vehicle)
12 V battery – important safety notes
PLUG-IN HYBRID vehicles are equipped with a
12 V battery and a high-voltage battery. The fol-
lowing notes refer to the 12 V battery. Notes on
the high-voltage battery can be obtained in the
"High-voltage battery – important safety notes"
section (
Ypage 374).
Special tools and expert knowledge are required
when working on the battery, e.g. removal and
installation. You should therefore have all work
involving the battery carried out at a qualified
specialist workshop.
GWARNING
Work carried out incorrectly on the battery
can lead, for example, to a short circuit and
thus damage the vehicle electronics. This can
lead to function restrictions applying to
safety-relevant systems, e.g the lighting sys-
tem, the ABS (anti-lock braking system) or the
ESP
®(Electronic Stability Program). The oper-
ating safety of your vehicle may be restricted.
You could lose control of the vehicle, for
example:
Rwhen braking
Rin the event of abrupt steering maneuvers
and/or when the vehicle's speed is not
adapted to the road conditions
There is a risk of an accident.
In the event of a short circuit or a similar inci-
dent, contact a qualified specialist workshop
immediately. Do not drive any further. You
should have all work involving the battery car- ried out at a qualified specialist workshop.
For further information about ABS and ESP
®,
see (Ypage 68) and (Ypage 73).
All vehicles except Mercedes-AMG vehicles:
GWARNING
Electrostatic build-up can lead to the creation of sparks, which could ignite the highly explo-
sive gases of a battery. There is a risk of an
explosion.
Before handling the battery, touch the vehicle
body to remove any existing electrostatic
build-up.
The highly flammable gas mixture forms when
charging the battery as well as when jump-start-
ing.
Always make sure that neither you nor the bat-
tery is electrostatically charged. A build-up of
electrostatic charge can be caused, for exam-
ple:
Rby wearing clothing made from synthetic
fibers
Rdue to friction between clothing and seats
Rif you push or pull the battery across the car-
pet or other synthetic materials
Rif you wipe the battery with a cloth
GWARNING
During the charging process, a battery produ-
ces hydrogen gas. If a short circuit occurs or
sparks are created, the hydrogen gas can
ignite. There is a risk of an explosion.
RMake sure that the positive terminal of a
connected battery does not come into con- tact with vehicle parts.
RNever place metal objects or tools on a bat-
tery.
RIt is important that you observe the descri-
bed order of the battery terminals when
connecting and disconnecting a battery.
RWhen jump-starting, make sure that the
battery poles with identical polarity are
connected.
RIt is particularly important to observe the
described order when connecting and dis-
connecting the jumper cables.
RNever connect or disconnect the battery
terminals while the engine is running.
GWARNING
Battery acid is caustic. There is a risk of injury.
Avoid contact with skin, eyes or clothing. Do
not inhale any battery gases. Do not lean over
the battery. Keep children away from batter-
ies. Wash away battery acid immediately with
372Battery (vehicle)
Breakdo wn assis tance

plenty of clean water and seek medical atten-
tion.
All vehicles:
HEnvironmental note
Batteries contain dangerous
substances. It is against the
law to dispose of them with
the household rubbish. They
must be collected separately and recycled to protect the
environment.
Dispose of batteries in an
environmentally friendly
manner. Take discharged
batteries to a qualified spe-
cialist workshop or a special
collection point for used bat-
teries.
!Have the battery checked regularly at a
qualified specialist workshop.
Observe the service intervals in the Mainte-
nance Booklet or contact a qualified specialist
workshop for more information.
!Always have work on batteries carried out at
a qualified specialist workshop. Should it, in
exceptional circumstances, be absolutely
necessary to disconnect the 12-volt battery
yourself, observe the following:
Rsecure the vehicle to prevent it from rolling
away.
Rswitch off the ignition.
Ralways disconnect the negative terminal
clamp first, followed by the positive termi-
nal clamp.
After the battery has been disconnected, the
transmission is locked in position P.
After the work has been done, install the bat-
tery and replace the cover of the positive ter-
minal clamp firmly.
Comply with safety precautions and take pro-
tective measures when handling batteries.
Risk of explosion.
Fire, open flames and smoking are
prohibited when handling the bat-
tery. Avoid creating sparks.
Electrolyte or battery acid is corro-
sive. Avoid contact with skin, eyes or
clothing.
Wear suitable protective clothing,
especially gloves, apron and face-
guard.
Immediately rinse electrolyte or acid
splashes off with clean water. Con-
tact a physician if necessary.
Wear eye protection.
Keep children away.
Observe this Operator's Manual.
For safety reasons, Mercedes-Benz recom-
mends that you only use batteries which have
been tested and approved for your vehicle by
Mercedes-Benz. These batteries provide
increased impact protection to prevent vehicle
occupants from suffering acid burns should the
battery be damaged in the event of an accident.
In order for the battery to achieve the maximum
possible service life, it must always be suffi-
ciently charged.
Like other batteries, the vehicle battery may
discharge over time if you do not use the vehicle.
In this case, have the battery disconnected at a
qualified specialist workshop. You can also
charge the battery with a charger recommended
by Mercedes-Benz. Contact a qualified special-
ist workshop for further information.
Have the battery condition of charge checked
more frequently if you use the vehicle mainly for
short trips or if you leave it standing idle for a
lengthy period. Consult a qualified specialist
workshop if you wish to leave your vehicle
parked for a long period of time.
Battery (vehicle)373
Breakdown assistance
Z

Remove theSmartKey if you park th evehicl e
and do no trequire any electrical consumers.
The vehicl ewill then use ver ylittl eenergy, thus
conserving battery power .
PLUG-IN HYBRID vehicles: if thebattery
charge is sufficient, th ehigh-voltage battery can
also suppl yth e12 Vbattery. This only happens
if th econdition of charge of th e12 Vbattery
require sthis, e.g. after usin gelectrical consum-
ers for an extended period wit hth eengin e
switched off .As th eon-board voltag eis contin-
uously monitore dthis can also be performed
when th eengin eis switched off .The condition of
charge of th e12 Vbattery and th eon-board
voltag eare thereby kept stable for alonger
period.
High-voltage battery – important
safety notes
Only PLUG-I NHYBRID vehicles are equipped
wit h a high-voltage battery.
GDANGER
The vehicle's high-voltage electrical system is under high voltage. If you modify component s
in th evehicle's high-voltage electrical system
or touch damaged components, you may be
electrocuted. The component sin th evehi-
cle's high-voltage electrical system may be
damaged in an accident, althoug hth edamag e
is no tvisible. There is aris kof fatal injury.
Followin gan accident, do no ttouch any high -
voltag ecomponent sand never modify th e
vehicle's high-voltage electrical system. Hav e
th evehicl etowed away after an acciden tand
th evehicle's high-voltage electrical system
checke dby aqualified specialist workshop.
GWARNIN G
In th eevent of avehicl efire, th einternal pres-
sur eof th ehigh-voltage battery can exceed a
critical value .In this cas eflammabl egas
escapes throug h aventilation valv eon th e
underbody. The gas can ignite. There is aris k
of injury.
Leav eth edanger zone immediately. Secur e
th edanger area at asuitable distance, whils t
observing legal requirements .
GWARNING
If th ehousing of th ehigh-voltage battery has
been damaged, electrolyt eand gase smay
leak out .These are poisonous and caustic.
There is aris kof injury.
Avoid contact wit hskin, eyes or clothing .
Immediately rinse electrolyt esplashes off
wit hwater and seek medical attention
straight away.
!Exhaustive discharge caused by th evehicl e
standing idle for lengthy periods can damag e
th ehigh-voltage battery. If th evehicl eis idle
for lengthy periods leav eth ehigh-voltage bat -
tery connecte dto acharging station .
Consult an authorize dMercedes-Benz Cente rif
you wish to leav eyour vehicl eparked for alon g
period of time.
Charging the 12 V battery
Mercedes-AM Gvehicles:
!Only use battery chargers wit h amaximum
charging voltag eof 14.4 V.
All other vehicles:
GWARNIN G
During charging and jump-starting ,explosive
gase scan escape from th ebattery. There is a
ris kof an explosion .
Particularly avoi dfire, open flames, creating
sparks and smoking. Ensur ethere is sufficien t
ventilation while charging and jump-starting .
Do no tlean ove r abattery.
GWARNIN G
Battery acid is caustic. There is aris kof injury.
Avoid contact wit hskin, eyes or clothing .Do
no tinhale any battery gases. Do no tlean ove r
th ebattery. Kee pchildren away from batter-
ies. Wash away battery acid immediately wit h
plenty of clean water and seek medical atten -
tion .
GWARNIN G
A discharged battery can freez eat tempera-
tures belo wfreezing point. When jump-start -
374Battery (vehicle)
Breakdown assistance

ing the vehicle or charging the battery, gasescan escape from the battery. There is a risk of
an explosion.
Allow the frozen battery to thaw out before
charging it or jump-starting.
!Only use battery chargers with a maximum
charging voltage of 14.8 V.
All vehicles:
!Only charge the battery using the jump-
starting connection point.
The jump-starting connection point is in the
engine compartment (
Ypage 376).
XOpen the hood.
XConnect the battery charger to the positive
terminal and ground point in the same order
as when connecting the donor battery in the
jump-starting procedure (
Ypage 376).
Keep away from fire and open flames. Do not
lean over a battery. Never charge the battery if it
is still installed in the vehicle, unless you use a
battery charger which has been tested and
approved by Mercedes-Benz. A battery charger
unit specially adapted for Mercedes-Benz vehi-
cles and tested and approved by Mercedes-
Benz is available as an accessory. It permits the
charging of the battery in its installed position.
Contact an authorized Mercedes-Benz Center
for further information and availability. Read the
battery charger's operating instructions before
charging the battery.
All vehicles except Mercedes-AMG vehicles:
if the indicator/warning lamps in the instrument
cluster do not light up at low temperatures, it is
very likely that the discharged battery has fro-
zen. In this case you may neither jump-start the
vehicle nor charge the battery. The service life of
a thawed-out battery may be shorter. The start-
ing characteristics can be impaired, particularly
at low temperatures. Have the thawed- out bat
-
tery checked at a qualified specialist workshop.
Mercedes-AMG vehicles: at low temperatures,
do not charge a battery which has been removed
using a battery charger. Allow the battery to
warm up gently first, if necessary. Otherwise,
the service life can be shortened and the start-
ing characteristics impaired, especially at low
temperatures.
PLUG-IN HYBRID vehicles: if the battery
charge is sufficient, the high-voltage battery can
also supply the 12 V battery. This only happens if the condition of charge of the 12 V battery
requires this, e.g. after using electrical consum-
ers for an extended period with the engine
switched off. As the on-board voltage is contin-
uously monitored this can also be performed
when the engine is switched off. The condition of
charge of the 12 V battery and the on-board
voltage are thereby kept stable for a longer
period.
Battery (vehicle)375
Breakdown assistance
Z

Jump-starting
For the jump-starting procedure, use only the jump-starting connection point in the engine com-
partment, consisting of a positive terminal and a ground point.
All vehicles except Mercedes-AMG vehicles:
GWARNING
Battery acid is caustic. There is a risk of injury.
Avoid contact with skin, eyes or clothing. Do not inhale any battery gases. Do not lean over the
battery. Keep children away from batteries. Wash away battery acid immediately with plenty of
clean water and seek medical attention.
GWARNING
During charging and jump-starting, explosive gases can escape from the battery. There is a risk of an explosion.
Particularly avoid fire, open flames, creating sparks and smoking. Ensure there is sufficient ven-
tilation while charging and jump-starting. Do not lean over a battery.
GWARNING
During the charging process, a battery produces hydrogen gas. If a short circuit occurs or sparks
are created, the hydrogen gas can ignite. There is a risk of an explosion.
RMake sure that the positive terminal of a connected battery does not come into contact with
vehicle parts.
RNever place metal objects or tools on a battery.
RIt is important that you observe the described order of the battery terminals when connecting
and disconnecting a battery.
RWhen jump-starting, make sure that the battery poles with identical polarity are connected.
RIt is particularly important to observe the described order when connecting and disconnecting
the jumper cables.
RNever connect or disconnect the battery terminals while the engine is running.
GWARNING
A discharged battery can freeze at temperatures below freezing point. When jump-starting the
vehicle or charging the battery, gases can escape from the battery. There is a risk of an explosion. Allow the frozen battery to thaw out before charging it or jump-starting.
If, at low temperatures, the indicator lamps/warning lamps in the instrument cluster do not light up,
it is highly likely that the discharged battery has frozen. In this case, you may neither charge the
battery nor jump-start the vehicle. The service life of a thawed-out battery may be shorter. The
starting characteristics can be impaired, particularly at low temperatures. Have the thawed-out
battery checked at a qualified specialist workshop.
All vehicles:
!Avoid repeated and lengthy starting attempts. Otherwise, the catalytic converter could be
damaged by the non-combusted fuel.
376Jump-starting
Breakdown assistance

Do not start the vehicle using a rapid charging device. If your vehicle's battery is discharged, the
engine can be jump-started from another vehicle or from a second battery using jumper cables.
Observe the following points:
RThe battery is not accessible in all vehicles. If the other vehicle's battery is not accessible, jump-
start the vehicle using a second battery or a jump-starting device.
RYou may only jump-start the vehicle when the engine and exhaust system are cold.
RAll vehicles except Mercedes-AMG vehicles: do not start the engine if the battery is frozen. Let
the battery thaw first.
ROnly jump-start from batteries with a 12 V voltage rating.
ROnly use jumper cables which have a sufficient cross-section and insulated terminal clamps.
RIf the battery is fully discharged, leave the battery that is being used to jump-start connected for
a few minutes before attempting to start. This charges the battery slightly.
RMake sure that the two vehicles do not touch.
Make sure that:
Rthe jumper cables are not damaged.
Rwhen the jumper cables are connected to the battery, uninsulated sections of the terminal clamp
do not come into contact with other metal sections.
Rthe jumper cables cannot come into contact with parts which can move when the engine is
running, such as the V-belt pulley or the fan.
XSecure the vehicle by applying the electric parking brake.
XShift the transmission to position P.
XMake sure that the ignition is switched off. All indicator lamps in the instrument cluster must be
off. When using the SmartKey, turn the SmartKey to position 0in the ignition lock and remove it
(
Ypage 162).
XSwitch off all electrical consumers, e.g. rear window defroster, lighting, etc.
XOpen the hood.
Example: ground point cover
XTurn fasteners :one Õturn and remove.
XRemove the cover while pressing down on cap ;of the washer fluid reservoir.
Jump-starting377
Breakdown assistance
Z

Position numberDidentifies the charged battery of the other vehicle or an equivalent jump-starting
device.
XSlide cover Cof positive terminal =in the direction of the arrow.
XConnect positive terminal =on your vehicle to positive terminal ?of donor battery Dusing the
jumper cable. Always begin with positive terminal =on your own vehicle first.
XStart the engine of the donor vehicle and run it at idling speed.
XConnect negative terminal Aof donor battery Dto ground point Bof your vehicle using the
jumper cable, connecting the jumper cable to donor battery Dfirst.
XStart the engine.
XBefore disconnecting the jumper cables, let the engine run for several minutes.
XFirst, remove the jumper cables from ground point Band negative terminal A, then from pos-
itive clamp =and positive terminal ?. Begin each time at the contacts on your own vehicle first.
XAfter removing the jumper cables, close cover Cof positive terminal =.
XReplace the earth point cover. Make sure all mountings for the fasteners are positioned precisely
beneath the corresponding recesses in the cover.
XPress fasteners:into the mountings. Turn the fasteners by Õof a turn to engage.
XHave the battery checked at a qualified specialist workshop.
PLUG-IN HYBRID vehicles: if your vehicle has been jump-started, it may not be possible to use the
electric drive for approximately 30 minutes.
Jump-starting is not considered to be a normal operating condition.
iJumper cables and further information regarding jump-starting can be obtained at any qualified
specialist workshop.
378Jump-starting
Breakdown assistance