MERCEDES-BENZ S-Class SEDAN 2016 W222 Manual Online

Useful information
i
This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
iRead the information on qualified specialist
workshops (Ypage 28).
SmartKey
Important safety notes
GWARNING
If children are left unsupervised in the vehicle,
they could:
Ropen the doors, thus endangering other
people or road users.
Rget out and disrupt traffic.
Roperate the vehicle's equipment.
Additionally, children could set the vehicle in
motion if, for example, they:
Rrelease the parking brake.
Rshifting the automatic transmission out of
park position P
RStart the engine.
There is a risk of an accident and injury.
When leaving the vehicle, always take the
SmartKey with you and lock the vehicle. Never
leave children or animals unattended in the
vehicle. Always keep the SmartKey out of
reach of children.
GWARNING
If you attach heavy or large objects to the
SmartKey, the SmartKey could be uninten-
tionally turned in the ignition lock. This could
cause the engine to be switched off. There is a risk of an accident.
Do not attach any heavy or large objects to theSmartKey. Remove any bulky key rings before
inserting the SmartKey into the ignition lock.
!Keep the SmartKey away from strong mag-
netic fields. Otherwise, the remote control
function could be affected.
Strong magnetic fields can occur in the vicin-
ity of powerful electrical installations.
Do not keep the SmartKey:
Rwith electronic devices, e.g. a mobile phone
or another SmartKey.
Rwith metallic objects, e.g. coins or metal foil.
Rinside metallic objects, e.g. a metal case.
This can affect the functionality of the Smart-
Key.
Do not keep the SmartKey in the temperature-
controlled cup holder (
Ypage 332). On vehicles
with the KEYLESS-GO start function, do not
keep it on the parcel shelf or in the trunk. Oth-
erwise, the SmartKey may not be detected, e.g. when starting the engine using the Start/Stop
button.
A check which periodically establishes a radio
connection between the vehicle and the Smart-
Key determines whether a valid SmartKey is in
the vehicle. This occurs, for example:
Rwhen starting the engine
Rwhilst driving
Rwhen using HANDS-FREE ACCESS
Rwhen the external door handles are touched
Rduring convenience closing
SmartKey functions
:& To lock the vehicle
;FTo open/close the trunk lid
=%To unlock the vehicle
SmartKey79
Opening and closing
Z

XTo unlock centrally:press the%button.
If you do not open the vehicle within approx-
imately 40 seconds of unlocking:
Rthe vehicle is locked again.
Ranti-theft protection is reactivated.
XTo lock centrally: press the&button.
The SmartKey centrally locks and unlocks the
following components:
Rthe doors
Rthe trunk lid
Rthe fuel filler flap
The turn signals flash once when unlocking and
three times when locking.
You can also set an audible signal to confirm
that the vehicle has been locked. The audible
signal can be activated and deactivated via the
multimedia system; see the separate operating
instructions.
You will receive visual and acoustic locking con-
firmation if all components were able to be
locked.
When the locator lighting is activated via the
multimedia system, it lights up when it is dark
after the vehicle is unlocked with the SmartKey.
Information on activating and deactivating the
locator lighting can be found in the separate
operating instructions.
XTo open the trunk lid automatically from
outside the vehicle: press and hold theF
button until the trunk lid opens.
XTo open the trunk lid automatically from
outside the vehicle: if the SmartKey is loca-
ted in the immediate vicinity of the veh icle
,
press the Fbutton on the SmartKey.
When the trunk lid closes you can then
release the button.
KEYLESS-GO
General notes
Bear in mind that the engine can be started by
any of the vehicle occupants if there is a Smart-
Key in the vehicle (
Ypage 164).
Locking/unlocking centrally
You can start, lock or unlock the vehicle using
KEYLESS-GO. To do this, you only need carry the
SmartKey with you. You can combine the func- tions of KEYLESS-GO with those of a conven-
tional SmartKey. Unlock the vehicle by using
KEYLESS-GO, for instance, and lock it using the
&
button on the SmartKey.
The driver's door and the door at which the han-
dle is used, must both be closed. The SmartKey
must be outside the vehicle. When locking or
unlocking with KEYLESS-GO, the distance
between the SmartKey and the corresponding
door handle must not be greater than 3 ft (1 m).
A brief radio connection between the vehicle
and the SmartKey determines whether a valid
SmartKey is in, or in the direct vicinity of, the
vehicle. This occurs, for example:
Rwhen starting the engine
Rwhile driving
Rwhen using HANDS-FREE ACCESS
Rwhen the external door handles are touched
Rduring convenience closing
XTo unlock the vehicle: touch the inner sur-
face of the door handle.
XTo lock the vehicle: touch sensor surface :
or ;.
Make sure that you do not touch the inner
surface of the door handle.
XConvenience closing feature: touch
recessed sensor surface ;for an extended
period.
Further information on the convenience clos-
ing feature (
Ypage 96).
XTo unlock the trunk lid: pull the handle on
the trunk lid.
Deactivating and activating
If you do not intend to use a SmartKey for an
extended period of time, you can deactivate the
KEYLESS-GO function of the SmartKey. The
SmartKey will then use very little power, thereby
80SmartKey
Opening and closing

conserving battery power. For the purposes of
activation/deactivation, the vehicle must not be
nearby.
XTo deactivate:press the&button on the
SmartKey twice in rapid succession.
The battery check lamp (
Ypage 82) of the
SmartKey flashes twice briefly and lights up
once, then KEYLESS-GO is deactivated .
XTo activate: press any button on the Smart-
Key.
or
XInsert the SmartKey into the ignition lock.
KEYLESS-GO and all of its associated features
are available again.
KEYLESS-GO start function
General notes
Bear in mind that the engine can be started by
any of the vehicle occupants if there is a Smart-
Key in the vehicle (
Ypage 164).
Changing the settings of the locking
system
You can change the settings of the locking sys-
tem. This means that only the driver's door and
the fuel filler flap are unlocked when the vehicle
is unlocked. This is useful if you frequently travel
on your own.
XTo change the setting: press and hold down
the % and& buttons simultaneously
for approximately six seconds until the bat-
tery check lamp flashes twice (
Ypage 82).
If the setting of the locking system is changed
within the signal range of the vehicle, pressing
the & or% button:
Rlocks or
Runlocks the vehicle
The SmartKey now functions as follows:
XTo unlock: press the%button once.
XTo unlock centrally: press the%button
twice.
XTo lock: press the &button. The KEYLESS-GO function is changed as fol-
lows:
XTo unlock the driver's door:
touch the inner
surface of the door handle on the driver's
door.
XTo unlock centrally: touch the inner surface
of the door handle on the front-passenger
door or the rear door.
XTo lock centrally: touch the outer sensor
surface on one of the door handles.
XTo restore the factory settings: press and
hold the %and& buttons simultane-
ously for approximately six seconds until the
battery check lamp flashes twice
(
Ypage 82).
Mechanical key
General notes
If the vehicle can no longer be locked or
unlocked with the SmartKey or KEYLESS-GO,
use the mechanical key.
If you use the mechanical key to unlock and
open the driver's door, the anti-theft alarm sys-
tem will be triggered. Switch off the alarm
(
Ypage 78).
If you unlock the vehicle using the mechanical
key, the fuel filler flap will not be unlocked auto-
matically.
XTo unlock the fuel filler flap: insert the
SmartKey into the ignition lock.
Removing the mechanical key
XPush release catch :in the direction of the
arrow and at the same time remove mechan- ical key ;from the SmartKey.
SmartKey81
Opening and closing
Z

For further information about:
Runlocking the driver's door (Ypage 87)
Runlocking the trunk (Ypage 93)
Rlocking the vehicle (Ypage 88)
Inserting the mechanical key
XPush mechanical key;completely into the
SmartKey until it engages and release
catch :is back in its basic position.
SmartKey battery
Important safety notes
GWARNING
Batteries contain toxic and corrosive substan- ces. If batteries are swallowed, it can result in
severe health problems. There is a risk of fatalinjury.
Keep batteries out of the reach of children. If
a battery is swallowed, seek medical attention immediately.
HEnvironmental note
Batteries contain dangerous
substances. It is against the
law to dispose of them with
the household rubbish. They
must be collected separatelyand recycled to protect the
environment.
Dispose of batteries in an
environmentally friendly
manner. Take discharged
batteries to a qualified spe-
cialist workshop or a special
collection point for used bat-
teries.
The SmartKey batteries contain perchlorate
material, which may require special handling
and regard for the environment. National guide-
lines must be observed during disposal. In Cal-
ifornia, see www.dtsc.ca.gov/
HazardousWaste/Perchlorate/index.cfm .Mercedes-Benz recommends that you have the
batteries replaced at a qualified specialist work-
shop.
Checking the battery
XPress the
&or% button.
The battery is working properly if battery
check lamp :lights up briefly.
The battery is discharged if battery check
lamp :does not light up briefly.
XChange the battery (Ypage 82).
If the SmartKey battery is checked within the
signal reception range of the vehicle, pressing
the & or% button:
Rlocks or
Runlocks the vehicle
iYou can obtain a battery from any qualified
specialist workshop.
Replacing the battery
You require a CR 2025 3 V cell battery.
XTake the mechanical key out of the SmartKey
(Ypage 81).
XPress mechanical key ;into the SmartKey
opening in the direction of the arrow until bat-
82SmartKey
Opening and closing

tery compartment cover:opens. Do not
hold battery compartment cover :closed
while doing so.
XRemove battery compartment cover :.
XRepeatedly tap the SmartKey against your
palm until battery=falls out.
XInsert the new battery with the positive ter-
minal facing upwards. Use a lint-free cloth to
do so.
XMake sure that the surface of the battery is
free of lint, grease and other contaminants.
XInsert the front tabs of battery compartment
cover :into the housing first and then press
to close it.
XInsert mechanical key ;into the SmartKey
(Ypage 82).
XCheck the function of all SmartKey buttons on
the vehicle.
SmartKey83
Opening and closing
Z

Problems with the SmartKey
ProblemPossible causes/consequences andMSolutions
You can no longer lock or
unlock the vehicle using
the SmartKey.The SmartKey battery is discharged or nearly discharged.
XCheck the SmartKey battery (Ypage 82) and replace it if necessary
(Ypage 82).
If this does not work:
XUnlock (Ypage 87) or lock (Ypage 88) the vehicle using the
mechanical key.
There is interference from a powerful source of radio waves.
XUnlock (Ypage 87) or lock (Ypage 88) the vehicle using the
mechanical key.
The SmartKey is faulty.
XUnlock (Ypage 87) or lock (Ypage 88) the vehicle using the
mechanical key.
XHave the SmartKey checked at a qualified specialist workshop.
You can no longer lock or
unlock the vehicle using
KEYLESS-GO.KEYLESS-GO was deactivated.
XReactivate KEYLESS-GO (Ypage 80).
The SmartKey battery is discharged or nearly discharged.
XCheck the SmartKey battery (Ypage 82) and replace it if necessary
(Ypage 82).
If this does not work:
XUnlock (Ypage 87) or lock (Ypage 88) the vehicle using the
mechanical key.
There is interference from a powerful source of radio waves.
XUnlock (Ypage 87) or lock (Ypage 88) the vehicle using the
mechanical key.
KEYLESS-GO is malfunctioning.
XLock/unlock the vehicle using the remote control function of the
SmartKey.
XHave the vehicle and SmartKey checked at a qualified specialist
workshop.
If the vehicle can also not be locked/unlocked using the remote con-
trol function:
XLock (Ypage 87) or unlock (Ypage 88) the vehicle using the
mechanical key.
XHave the vehicle and SmartKey checked at a qualified specialist
workshop.
84SmartKey
Opening and closing

ProblemPossible causes/consequences andMSolutions
The engine cannot be
started using the Smart-
Key.The on-board voltage is too low.
XSwitch off non-essential consumers, e.g. seat heating or interior
lighting, and try to start the engine again.
If this does not work:
XCheck the starter battery and charge it if necessary (Ypage 374).
or
XJump-start the vehicle (Ypage 376).
or
XConsult a qualified specialist workshop.
The engine cannot be
started using the Start/
Stop button. The Smart-
Key is in the vehicle.The vehicle is locked.
XUnlock the vehicle and try to start the vehicle again.
The SmartKey battery is discharged or nearly discharged.
XCheck the SmartKey battery (Ypage 82) and replace it if necessary
(Ypage 82).
If this does not work:
XStart your vehicle with the SmartKey in the ignition lock.
There is interference from a powerful source of radio waves.
XStart your vehicle with the SmartKey in the ignition lock.
You have lost a Smart-
Key.XHave the SmartKey deactivated at a qualified specialist workshop.
XReport the loss immediately to the vehicle insurers.
XIf necessary, have the locks changed as well.
You have lost the
mechanical key.XReport the loss immediately to the vehicle insurers.
XIf necessary, have the locks changed as well.
Doors
Important safety notes
GWARNING
If children are left unsupervised in the vehicle,
they could:
Ropen the doors, thus endangering other
people or road users.
Rget out and disrupt traffic.
Roperate the vehicle's equipment.
Additionally, children could set the vehicle in
motion if, for example, they:
Rrelease the parking brake.
Rshifting the automatic transmission out of
park position P
RStart the engine.
There is a risk of an accident and injury.
When leaving the vehicle, always take the
SmartKey with you and lock the vehicle. Never
leave children or animals unattended in the
vehicle. Always keep the SmartKey out of
reach of children.
Doors85
Opening and closing
Z

Unlocking and opening doors from
the inside
You can open a door from inside the vehicle
even if it has been locked. You can only open the
rear doors from inside the vehicle if they are notsecured by the child-proof locks (
Ypage 67). If
the vehicle has been locked with the SmartKey
or with KEYLESS-GO, opening a door from the
inside will trigger the anti-theft alarm system.
Switch off the alarm (
Ypage 78).
XTo unlock and open a front door: pull door
handle ;.
If the door is locked, locking knob :pops up.
The door is unlocked and opens.
XTo unlock a rear door: pull door handle;.
Locking knob :pops up and the door
unlocks.
XTo open a rear door: pull door handle;
again.
The door opens.
Centrally locking and unlocking the
vehicle from the inside
You can centrally lock and unlock the vehicle
from the inside. The buttons are located on both
front doors.
XTo unlock: press button :.
XTo lock:press button ;.
If the front-passenger door is closed, the vehi-
cle locks.
If the driver's door is open, the door stays
unlocked.
Meanwhile, the fuel filler flap will not be locked
or unlocked.
You cannot unlock the vehicle centrally from the
inside if the vehicle has been locked with the
SmartKey or KEYLESS-GO.
The doors can be opened from the inside. You
can only open the rear doors from inside the
vehicle if they are not secured by the child-proof
locks (
Ypage 67).
If the vehicle has been locked with the SmartKey
or with KEYLESS-GO, opening a door from the
inside will trigger the anti-theft alarm system.
Switch off the alarm (
Ypage 78).
If a locked door is opened from the inside, the
previous unlock status of the vehicle will be
taken into consideration if:
Rthe vehicle was locked using the locking but-
ton for the central locking, or
Rif the vehicle was locked automatically
The vehicle will be fully unlocked if it had previ-
ously been fully unlocked. If only the driver's
door had been previously unlocked, only the
door which has been opened from the inside is
unlocked.
86Doors
Opening and closing

Automa tic locking featu re
XTo deactivate:press and hold butto n: for
approximately fiv eseconds until atone
sounds.
XTo activate: press and hold butto n; for
approximately fiv eseconds until atone
sounds.
If you press on eof th etwo buttons and do no t
hear atone ,th erelevan tsetting has already
been selected.
The vehicl eis locke dautomatically when th e
ignition is switched on and th ewheels are turn-
ing .
You could therefor ebe locke dout if:
Rth evehicl eis bein gpushed.
Rth evehicl eis bein gtowed.
Rth evehicl eis on aroller dynamometer.
You can also switch th eautomatic locking func-
tion on and off usin gth emultimedia system; see
th eseparat eoperating instructions.
Power closing
Powe rclosin gpulls th edoor sand trunk lid int o
their locks automatically eve nif they are only
partly closed.
XTo power close adoor :push th edoor int o
th eloc kup to th efirst deten tposition .
Powe rclosin gwill pull th edoor fully closed.
XTo power close th etrunk lid :lightl ypush
th etrunk lid closed.
The powe rclosin gfunction pulls th etrunk lid
closed.
Unlocking the driver's door(mechan-
ical key)
If th evehicl ecan no longer be locke dor
unlocke dwit hth eSmartKey or KEYLESS-GO ,
use th emechanical key.
XTak eth emechanical ke yout of th eSmartKey
(Ypage 81).
XInser tth emechanical ke yas far as it will go
int oopening :in th eprotective cap .
XPull and hold th edoor handle.
XPull th eprotective cap on th emechanical ke y
as straight as possibl eaway from th evehicl e
until it releases.
XReleas eth edoor handle.
XInser tth emechanical ke yint oth eloc kof th e
driver's door as far as it will go.
XTurn th emechanical ke ycounter-clockwise
as far as it will go to position 1.
The locking knob pops up and th edoor
unlocks .
XTurn themechanical ke ybac kand remove it .
XInsertth emechanical ke yint oth eSmartKey
(Ypage 82) .
XCarefully press th eprotective cap onto th e
loc kcylinder until it engage sand is seated
Doors87
Opening and closing
Z

firmly. Do not pull the door handle when doing
so.
If you use the mechanical key to unlock and
open the driver's door, the anti-theft alarm sys-
tem will be triggered. Switch off the alarm
(
Ypage 78).
Locking the vehicle (mechanical key)
If the vehicle can no longer be locked with the
SmartKey or KEYLESS-GO, use the mechanical
key.
XOpen the driver's door.
XClose the front-passenger door, the rear
doors and the trunk lid.
XPress the locking button (Ypage 86).
XCheck whether the locking knobs on the
front-passenger door and the rear doors are
still visible. Press down the locking knobs by
hand, if necessary.
XClose the driver's door.
XTake the mechanical key out of the SmartKey
(Ypage 81).
XInsert the mechanical key as far as it will go
into opening :in the protective cap.
XPull and hold the door handle.
XPull the protective cap on the mechanical key
as straight as possible away from the vehicle
until it releases.
XRelease the door handle.
XInsert the mechanical key into the lock of the
driver's door as far as it will go.
XTurn the mechanical key clockwise as far as it
will go to position 1.
The locking knob drops down and the driver's
door is locked.
XTurn the mechanical key back and remove it.
XMake sure that the doors and the trunk lid are locked.
XInsert the mechanical key into the SmartKey
(Ypage 82).
XCarefully press the protective cap onto the
lock cylinder until it engages and is seated
firmly. Do not pull the door handle when doing
so.
If you lock the vehicle as described above, the
fuel filler flap is not locked. The anti-theft alarm system is not armed.
Trunk
Important safety notes
GWARNING
Combustion engines emit poisonous exhaust
gases such as carbon monoxide. Exhaust
gases can enter the vehicle interior if the
trunk lid is open when the engine is running,
especially if the vehicle is in motion. There is a
risk of poisoning.
Always switch off the engine before opening
the trunk lid. Never drive with the trunk lid
open.
GWARNING
If objects, luggage or loads are not secured or
not secured sufficiently, they could slip, tip
88Trunk
Opening and closing