air conditioning MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

1, 2, 3 ...
4ETS (Electronic Traction System)see ETS/4ETS (Electronic Trac-
tion System)
4MATIC (permanent four-wheel
drive) .................................................. 213
12 V socket
see Sockets
115 V socket ...................................... 337
360° camera
Cleaning ........................................ .363
Function/notes .............................2 24
A
ABS (Anti-lock Braking System)
Display message ............................ 278
Function/notes ................................ 68
Warning lamp ................................. 316
Accident
Automatic measures after an acci-
dent ................................................. 61
Activating/deactivating cooling
with air dehumidification ................. 146
Activating/deactivating Night
View Assist Plus
With spotlight function ................... 232
Active Blind Spot Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 234
Active Body Control (ABC)
Display message ............................ 300
Function/notes ............................. 210
Active Lane Keeping Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 237
Active multicontour seat .................. 117
Active Parking Assist
Detecting parking spaces .............. 217
Display message ............................ 302
Exiting a parking space .................. 219
Function/notes ............................. 216
Important safety notes .................. 216 Parking .......................................... 218
ADAPTIVE BRAKE ................................. 75
Adaptive Brake Assist
Function/notes ................................ 72
Adaptive Damping System (ADS) ..... 212
Adaptive Highbeam Assist Plus
Display message ............................ 293
Function/notes ............................. 133
Switching on/off ........................... 133
Additional speedometer ................... 274
Additives (engine oil) ........................ 430
Air bags
Belt bags .......................................... 48
Cushion air bags .............................. 53
Deployment ..................................... 57
Display message ............................ 289
Front air bag (driver, front
passenger) ....................................... 52
Important safety notes .................... 50
Introduction ..................................... 50
Knee bag .......................................... 52
Occupant Classification System
(OCS) ............................................... 53
PASSENGER AIR BAG i
ndicator
lamps ............................................... 46
Side impact air bag .......................... 52
Window curtain air bag .................... 53
Air vents
Glove box ....................................... 159
Important safety notes .................. 158
Rear ............................................... 160
Setting ........................................... 158
Setting the center air vents ........... 159
Setting the side air vents ............... 159
Air-conditioning system
see Climate control
AIRMATIC
Display message ............................ 299
Function/notes ............................. 212
Alarm
ATA (Anti-Theft Alarm system) ......... 78
Switching off (ATA) .......................... 78
Switching the function on/off
(ATA) ................................................ 78
Alarm system
see ATA (Anti-Theft Alarm system)
Anti-lock braking system
see ABS (Anti-lock Braking System)
Index3

Starting .......................................... 249
When the vehicle is stationary ....... 251
Power locks ......................................... 87
Power washers .................................. 360
Power windows
see Side windows
Pre-entry climate control (via
SmartKey)
Problems (malfunctions) ................ 157
Pre-entry climate control at depar-
ture time
General notes ................................ 157
Pre-entry climate control at time of
departure
Setting departure time ................... 158
Pre-entry climate control via key
General notes ................................ 155
PRE-SAFE
®(anticipatory occupant
protection)
Display message ............................ 284
Operation ......................................... 59
PRE-SAFE
®Brake
Activating/deactivating ................. 271
Display message ............................ 284
Function/notes ................................ 75
Important safety notes .................... 76
Warning lamp ................................. 322
PRE-SAFE
®PLUS (anticipatory
occupant protection PLUS)
Display message ............................ 284
Operation ......................................... 60
Program selector button .................. 173
Protection against theft
ATA (Anti-Theft Alarm system) ......... 78
Immobilizer ...................................... 78
Protection of the environment
General notes .................................. 24
Pulling away
Automatic transmission ................. 165
General notes ................................ 165
Hill start assist ............................... 165
Q
QR codeMercedes-Benz Guide App ................. 1
Rescue card ..................................... 29
Qualified specialist workshop ........... 28
R
Radio
Selecting a station ......................... 265
Radio-wave reception/transmis-
sion in the vehicle
Declaration of conformity ................ 28
Rain closing feature
Panorama sliding sunroof ................ 99
RBS (Recuperative Brake System)
Warning lamp ................................. 315
Reading lamp ..................................... 134
Rear compartment
Activating/deactivating climate
control ........................................... 145
Setting the air distribution ............. 149
Setting the air vents ...................... 160
Setting the airflow ......................... 150
Setting the temperature ................ 148
Stowage compartment .................. 327
Rear lamps
see Lights
Rear seats
Adjusting ....................................... 107
Adjusting a rear reclining seat ....... 107
Overview .......................................... 41
Setting the reclined position .......... 107
Rear view camera
Cleaning instructions ..................... 363
Displays in the COMAND display ... 221
Function/notes ............................. 220
Rear window blind ............................ 334
Rear window defroster
Problem (malfunction) ................... 152
Switching on/off ........................... 151
Rear-view mirror
Anti-glare (manual) ........................ 123
Dipping (automatic) ....................... 124
Recuperative Brake System
Driving safety systems ..................... 44
Important safety notes .................... 44
Refrigerant (air-conditioning sys-
tem)
Important safety notes .................. 432
Refueling
Fuel gauge ....................................... 33
Important safety notes .................. 177
16Index

Cleaning the cover .........................365
Correct driver's seat position ........1 04
Display message ............................ 310
EASY-ENTRY/EXIT system ............. 122
Important safety notes .................. 105
Multicontour seat .......................... 117
Seat heating .................................. 118
Seat heating problem .................... 119
Seat ventilation .............................. 119
Seat ventilation problem ................ 120
Storing settings (memory func-
tion) ............................................... 126
Switching seat heating on/off ....... 118
Switching seat ventilation on/off .. 119
Section
Wheels and tires ............................ 384
Securing a load
see Securing cargo
Securing cargo .................................. 329
Selector lever
Cleaning ......................................... 365
see Automatic transmission
Sensors (cleaning instructions) ....... 362
Service menu (on-board com-
puter) ..................................................2 69
Service message
see ASSYST PLUS
Service products
Brake fluid ..................................... 430
Coolant (engine) ............................ 431
Engine oil ....................................... 429
Fuel ................................................ 428
Important safety notes .................. 427
Refrigerant (air-conditioning sys-
tem) ............................................... 432
Washer fluid ................................... 431
Setting the charge current (on-
board computer) ............................... 272
Setting the departure time (on-
board computer) ............................... 272
Settings
Factory (on-board computer) ......... 275
On-board computer ....................... 269
SETUP (on-board computer) ............. 276
Side impact air bag .............................5 2
Side marker lamp (display mes-
sage) ................................................... 292 Side windows
Cleaning ........................... .............. 362
Convenience closing feature ............ 96
Convenience opening feature ..........9 5
Importa

nt safety information ........... 94
Opening/closing .............................. 95
Problem (malfunction) .....................9 7
Resettin g........................................ .96
Reversin gfeature ............................ .94
Sliding sunroof
see Panorama roof with power
tilt/sliding panel
SmartKey
Changing the battery ....................... 82
Changing the programming .............8 1
Checking the battery ...................... .82
Convenience closing feature ............ 96
Convenience opening feature .......... 95
Display message ............................ 312
Door central locking/unlocking ...... .79
Important safety notes .................... 79
KEYLESS-GO start function .............. 81
Loss .................................................8 4
Mechanical key ................................ 81
Overview .......................................... 79
Positions (ignition lock) ................. 162
Problem (malfunction) ..................... 84
Starting the engine ........................ 164
Smartphone
Starting the engine ........................ 164
Snow chains ...................................... 386
Sockets
Center console .............................. 336
General notes ................................ 336
Rear compartment .........................3 37
Trunk ............................................. 337
Special seat be
lt retractor
.................. 62
Specialist workshop ............................ 28
Speed, controlling
see Cruise control
Speedometer
Activating/deactivating the addi-
tional speedometer ........................ 274
Digital ............................................ 263
In the Instrument cluster ................. 33
Selecting the display unit ...............2 74
Standing lamps
Display message ............................ 292
18Index

Notes on using automatic climate
control
Climate control system
Below, you can find a number of notes and rec-
ommendations to help you use climate control
optimally.
RActivate climate control using the Ã
rocker switch. The indicator lamp in the Ã
rocker switch lights up.
RSet the temperature to 72 ‡ (22 †).
ROnly use the "Windshield defrosting" function
briefly until the windshield is clear again.
ROnly use air-recirculation mode briefly, e.g. if
there are unpleasant outside odors or when in
a tunnel. The windows could otherwise fog up, since no fresh air is drawn into the vehicle in
air-recirculation mode.
RUse the residual heat function if you want to
heat or ventilate the vehicle interior when the
ignition is switched off. The residual heat
function can only be activated or deactivated
with the ignition switched off. The residual
heat function is switched off when the ignition
is switched on.
If you are controlling the rear-compartment cli-
mate control using the front control panel, note
the following:
RIf you set rear-compartment climate control
using the front control panel, the Ysym-
bol appears in the rear-compartment control
panel display.
RIf the rear-compartment climate control is set
using the front control panel, it cannot be set
at the same time using the rear control panel. After completing the settings for the rear-
compartment climate control using the front
control panel, wait five seconds. You will then
be able to control the rear climate control
using the rear control panel.
RAfter selecting the rear compartment set-
tings, the front climate control can be con-
trolled automatically again via the multimedia
system after five seconds.
Alternatively, you can select "Cancel rear
compartment" in the multimedia system air-
conditioning function bar.
ECO start/stop function
During automatic engine switch-off, the climate
control system only operates at a reduced capa-
city. If you require the full climate control output,
you can switch off the ECO start/stop function
by pressing the ECO button (
Ypage 167).
Operating the climate control sys-
tems
Activating/deactivating climate con-
trol
General notes
When the climate control is switched off, the air
supply and air circulation are also switched off.
The windows could fog up. Therefore, switch off
climate control only briefly
Switch on climate control primarily using the
à rocker switch (
Ypage 147).
Activating/deactivating front climate
control using the front control panel
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XTo activate: press thetor! rocker
switch up or down.
The climate control menu opens.
XActivate climate control via the air-condition-
ing setting bar in the multimedia system (see
the separate operating instructions).
XTo deactivate: press thetor!
rocker switch up or down.
The climate control menu opens.
XActivate climate control via the air-condition-
ing setting bar in the multimedia system (see
the separate operating instructions).
Activating/deactivating rear-compart-
ment climate control using the front
control panel
Observe the notes on controlling the rear-com-
partment climate control using the front control
panel (
Ypage 145).
Operating the climate control systems145
Climate control

XTurn the SmartKey to position2in the ignition
lock (Ypage 162).
XTo activate: press thetor! rocker
switch up or down.
The climate control menu opens.
XSelect "Rear adjustment" in the air-condition-
ing setting bar (see the separate operating
instructions).
You can control the rear-compartment cli-
mate control using the front control panel or
via the multimedia system.
XActivate rear-compartment climate control
via the air-conditioning setting bar.
XTo deactivate: press thetor!
rocker switch up or down.
The climate control menu opens.
XSelect "Rear adjustment" in the air-condition- ing setting bar (see the separate operating
instructions).
XDeactivate rear-compartment climate control
via the air-conditioning setting bar.
Activating/deactivating rear-compart-
ment climate control using the rear con-
trol panel
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XTo activate: press rocker switch Lup or
down (Ypage 141).
The indicator lamp in rocker switch Lgoes
out. All settings are displayed in full in the
rear-compartment display.
XTo deactivate: press rocker switch Lup or
down (Ypage 141).
The indicator lamp in rocker switch Llights
up. OFF is displayed in the rear-compartment
display.
Switching cooling with air dehumidi-
fication on/off
General notes
If you deactivate the "Cooling with air-dehumid-
ification" function, the air inside the vehicle will
not be cooled. The air inside the vehicle will also
not be dehumidified. The windows can fog up
more quickly. Therefore, deactivate the cooling
with air-dehumidification function only briefly. For vehicles with a combustion engine, the
"Cooling with air dehumidification" function is
available when the engine is running. For hybrid
vehicles, the "Cooling with air dehumidification"
function is also available via the electric refrig-
erant compressor when the engine is not run-
ning. The air inside the vehicle is cooled and
dehumidified according to the temperature
selected.
Condensation may drip from the underside of
the vehicle when it is in cooling mode. This is
normal and not a sign that there is a malfunc-
tion.
Switching on/off
XTo activate: press theÁrocker switch up
or down.
The indicator lamp above the rocker switch
lights up.
or
XActivate the "Cooling with air dehumidifica-
tion" function via the multimedia system (see
the separate operating instructions).
XTo deactivate: press theÁrocker switch
up or down.
The indicator lamp above the rocker switch
goes out.
or
XDeactivate the "Cooling with air dehumidifi-
cation" function via the multimedia system
(see the separate operating instructions).
146Operating the climate control systems
Climate control

XTo switch on:press theÃrocker switch
on the front control unit up or down.
or
XActivate automatic mode via the air-condi-
tioning setting bar in the multimedia system
(see the separate operating instructions).
The indicator lamp in the Ãrocker switch
lights up.
iSelect the temperature and automatic
mode immediately thereafter. Otherwise, you
will have to select "Rear adjustment" again
from the air-conditioning setting bar before
activating automatic mode.
XTo switch to manual operation: press the
tor !rocker switch up or down.
The climate control menu opens.
XSelect "Rear adjustment" in the air-condition-
ing setting bar (see the separate operating
instructions).
XUse the air-conditioning setting bar to deac-
tivate automatic mode.
or
XSet the air distribution using rocker switch I
or M on the rear control panel (Ypage 141).
or
XSet the airflow using rocker switch Kon the
rear control panel (Ypage 141).
The AUTO indicator on the rear display goes
out.
If you adjust the rear airflow or air distribution
manually using the multimedia system when in
automatic mode, the AUTOindicator on the rear
display goes out. The function which has not
been changed manually, however, continues to
be controll ed a
utomatically. When the manually
set function switches back to automatic mode,
the AUTO display reappears in the rear-com-
partment display.
Controlling rear climate control auto-
matically using the rear control panel
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XSet the desired temperature using rocker
switches Hand N(Ypage 141).
XTo activate: press rocker switch Jup or
down (Ypage 141).
The indicator lamp in rocker switch Jlights
up.
XTo deactivate: press rocker switch Jup or
down (Ypage 141).
The indicator lamp in rocker switch Jgoes
out.
If you adjust the airflow or air distribution man-
ually when in automatic mode, the AUTOdisplay
in the rear-compartment display goes out. The
function which has not been changed manually,
however, continues to be controlled automati-
cally. When the manually set function switches
back to automatic mode, the AUTOdisplay
reappears in the rear-compartment display.
Adjusting the climate mode settings
In automatic mode you can select the following
airflow settings for the driver's and front-
passenger areas:
FOCUS high airflow, slightly cooler setting
MEDIU Mmedium airflow, standard setting
DIFFUSEl ow airflow, slightly warmer and draft-
free setting
XTo set: set the climate mode using the mul-
timedia system (see the separate operating
instructions).
Setting the temperature
General notes
148Operating the climate control systems
Climate control

aDirects air through the defroster and
footwell vents
W Sets the air distribution to automatic
Setting the air distribution in the front/
rear compartments using the multime-
dia system
The air distribution for the left and right sides of
the front and rear compartment can be adjusted
using the multimedia system (see the separate
operating instructions).
Setting the air distribution in the rear
compartment using the rear control
panel
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XPress rocker switch IorM up or down
repeatedly (Ypage 141) until the desired air
distribution symbol is shown in the display.
Setting the airflow
General notes
You can select different airflow settings for the
driver's and front-passenger sides as well as for
the rear compartment (only vehicles with rear
compartment climate control).
Observe the notes on controlling the rear-com-
partment climate control using the front control
panel (
Ypage 145).
Setting the front-compartment airflow
using the front control panel
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XTo increase or reduce: press theK
rocker switch up or down.
or
XSet the airflow using the multimedia system
(see the separate operating instructions).
Setting the rear-compartment airflow
using the front control panel
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XPress the tor! rocker switch up or
down.
The climate control menu opens.
XSelect "Rear adjustment" in the air-condition-
ing setting bar (see the separate operating
instructions).
You can control the rear-compartment cli-
mate control using the front control panel or
via the multimedia system.
XTo increase or reduce: press theK
rocker switch up or down on the front control
panel.
or
XSet the airflow using the multimedia system
(see the separate operating instructions).
Setting the rear compartment airflow
using the rear control panel
XTurn the SmartKey to position 2in the ignition
lock (Ypage 162).
XTo increase or reduce: press rocker switch
K up or down (Ypage 141).
Activating or deactivating the syn-
chronization function
Climate control can be set centrally using the
synchronization function. The settings for tem-
perature, air distribution and airflow on the driv-
er's side are adopted for the front-passenger
side and the rear compartment (vehicles with
rear-compartment air conditioning).
XTo activate or deactivate: activate or deac-
tivate the synchronization function using the
multimedia system (see the separate operat-
ing instructions).
Vehicles with rear-compartment air condi-
tioning: the SYNCdisplay appears on the
rear-compartment display.
The synchronization function is deactivated:
Rif the settings for the front-passenger side are
changed
Rvehicles with rear-compartment air condition-
ing: the settings for the rear compartment are
changed
150Operating the climate control systems
Climate control

Therefore, quickly move your foot from the
brake pedal to the accelerator pedal. Never
leave the vehicle when it is held by hill start
assist.
Hill start assist is not active if:
Ryou are pulling away on a level road or on a
downhill gradient.
Rthe transmission is in position N.
Rthe electric parking brake is applied.
RESP®is malfunctioning.
ECO start/stop function (all vehicles
except PLUG‑IN HYBRID)
Introduction
This section describes the ECO start/stop func- tion for all vehicles except PLUG-IN HYBRID
vehicles. Information on the ECO start/stop
function on PLUG-IN HYBRID vehicles
(
Ypage 252).
The ECO start/stop function switches the
engine off automatically if the vehicle is stopped
under certain conditions.
The engine starts automatically when the driver
wants to pull away again. The ECO start/stop
function thereby helps you to reduce the fuel
consumption and emissions of your vehicle.
Important safety notes
GWARNING
If the engine is switched off automatically and
you exit the vehicle, the engine is restarted
automatically. The vehicle may begin moving.
There is a risk of accident and injury.
If you wish to exit the vehicle, always turn off
the ignition and secure the vehicle against
rolling away.
General notes
:ECO start/stop display
The ECO start/stop function is activated when-
ever you switch on the engine using the Smart-
Key or the Start/Stop button.
If the engine has been switched off automati-
cally by the ECO start/stop function, the è
ECO symbol is shown in the multifunction dis-
play.
The ECO start/stop function is only available in drive program E(drive program Con Mercedes-
AMG vehicles).
Automatic engine switch-off
If the vehicle is braked to a standstill in Dor N,
the ECO start/stop function switches off the
engine automatically.
The ECO start/stop function is operational
when:
Rthe indicator lamp in the ECO button is lit
green.
Rthe outside temperature is within the range
that is suitable for the system.
Rthe engine is at normal operating tempera-
ture.
Rthe set temperature for the vehicle interior
has been reached.
Rthe battery is sufficiently charged.
Rthe system detects that the windshield is not
fogged up when the air-conditioning system is
switched on.
Rthe hood is closed.
Rthe driver's door is closed and the driver's
seat belt is fastened.
All of the vehicle's systems remain active when
the engine is stopped automatically.
The HOLD function can be activated if the
engine has been switched off automatically. It is
166Driving
Driving and parking

then not necessary to continue applying the
brakes during the automatic stop phase. When
you depress the accelerator pedal, the engine
starts automatically and the braking effect of
the HOLD function is deactivated.
All vehicles (except Mercedes-AMG vehi-
cles):automatic engine switch-off can take
place a maximum of four times in a row (initial
stop, then three subsequent stops).
Mercedes-AMG vehicles: the number of con-
secutive automatic engine switch-offs is unlimi-
ted.
Automatic engine start
The engine starts automatically if:
Ryou switch off the ECO start/stop function by pressing the ECO button
Ryou switch to drive program Sor M
Rin transmission position Dor Nthe brake
pedal is released and the HOLD function is not
active
Ryou depress the accelerator pedal
Ryou engage reverse gear R
Ryou move the transmission out of position P
Ryou unfasten your seat belt or open the driv-
er's door
Rthe vehicle starts to roll
Rthe brake system requires this
Rthe temperature in the vehicle interior devi-
ates from the set range
Rthe system detects moisture on the wind-
shield when the air-conditioning system is
switched on
Rthe battery's condition of charge is too low
Shifting the transmission to position Pdoes not
start the engine.
Deactivating or activating the ECO
start/stop function
All vehicles (except Mercedes-AMG vehi-
cles)
XTo deactivate: press ECO button :.
Indicator lamp ;goes out.
XTo activate: press ECO button :.
Indicator lamp ;lights up.
If indicator lamp ;is off, the ECO start/stop
function has been deactivated manually or as
the result of a malfunction. The engine will then
not be switched off automatically when the vehi- cle stops.
If drive program Sor Mhas been selected, the
ECO start/stop function is always deactivated.
If you switch on the ECO start/stop function
while drive program Sis selected, the drive pro-
gram automatically switches to E.
Mercedes-AMG vehicles
XTo deactivate: in drive program C, press ECO
button :.
or
XSwitch to drive program Sor M(Ypage 173).
Indicator lamp ;goes out.
Driving167
Driving an d parking
Z

GVWR (Gross Vehicle Weight Rating)
The GVWR is the maximum permissible gross
weight of a fully loaded vehicle (the weight of thevehicle including all accessories, occupants,
fuel, luggage and the drawbar noseweight, if
applicable). The gross vehicle weight rating is
specified on the vehicle identification plate on
the B-pillar on the driver's side.
Maximum loaded vehicle weight
The maximum weight is the sum of:
Rthe curb weight of the vehicle
Rthe weight of the accessories
Rthe load limit
Rthe weight of the factory installed optional
equipment
Kilopascal (kPa)
Metric unit for tire pressure. 6.9 kPa corre-
sponds to 1 psi. Another unit for tire pressure is
bar. 100 kilopascals (kPa) are the equivalent of
1 bar.
Load index
In addition to the load-bearing index, the load
index may also be imprinted on the sidewall of
the tire. This specifies the load-bearing capacity
more precisely.
Curb weight
The weight of a vehicle with standard equipment
including the maximum capacity of fuel, oil and
coolant. It also includes the air-conditioning sys-
tem and optional equipment if these are instal-
led in the vehicle, but does not include passen-
gers or luggage.
Maximum load rating
The maximum tire load is the maximum permis-
sible weight in kilograms or lbs for which a tire is
approved.
Maximum permissible tire pressure
Maximum permissible tire pressure for one tire.
Maximum load on one tire
Maximum load on one tire. This is calculated bydividing the maximum axle load of one axle by
two.
PSI (pounds per square inch)
A standard unit of measure for tire pressure.
Aspect ratio
Relationship between tire height and tire width
in percent.
Tire pressure
This is pressure inside the tire applying an out-
ward force to each square inch of the tire's sur-
face. The tire pressure is specified in pou

nds per
square inch (psi), in kilopascal (kPa) or in bar.
The tire pressure should only be corrected when
the tires are cold.
Cold tire pressure
The tires are cold:
Rif the vehicle has been parked with the tires
out of direct sunlight for at least three hours
and
Rif the vehicle has not been driven further than
1 mile (1.6 km)
Tread
The part of the tire that comes into contact with
the road.
Bead
The tire bead ensures that the tire sits securely
on the wheel. There are several steel wires in the
bead to prevent the tire from coming loose from
the wheel rim.
Sidewall
The part of the tire between the tread and the
bead.
Weight of optional extras
The combined weight of those optional extras
that weigh more than the replaced standard
parts and more than 5 lbs (2.3 kg). These
optional extras, such as high-performance
brakes, level control, a roof rack or a high-per-
formance battery, are not included in the curb
weight and the weight of the accessories.
TIN (Tire Identification Number)
This is a unique identifier which can be used by
a tire manufacturer to identify tires, for example
for a product recall, and thus identify the pur-
chasers. The TIN is made up of the manufactur- er's identity code, tire size, tire type code and
the manufacturing date.
404All about wheels and tires
Wheels and tires