fuel type MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

V
Vanity mirror (in the sun visor)........ 333
Vehicle
Correct use ...................................... 29
Data acquisition ............................... 29
Display message ............................ 308
Equipment ....................................... 25
Individual settings .......................... 269
Limited Warranty ............................. 29
Loading .......................................... 394
Locking (in an emergency) ............... 88
Locking (SmartKey) .......................... 79
Lowering ........................................ 409
Maintenance .................................... 26
Operating safety .............................. 27
Parking .......................................... 189
Parking for a long period ................ 192
Pulling away ................................... 165
Raising ........................................... 406
Reporting problems ......................... 29
Securing from rolling away ............ 406
Towing away .................................. 379
Transporting .................................. 381
Unlocking (in an emergency) ........... 87
Unlocking (SmartKey) ...................... 79
Vehicle data ................................... 433
Vehicle dimensions ........................... 433
Vehicle emergency locking ................ 88
Vehicle identification number
see VIN
Vehicle identification plate .............. 426
Vehicle level
Active Body Control ABC ............... 210
AIRMATIC ...................................... 212
Display message ............................ 300
Vehicle tool kit .................................. 367
Video
Operating the DVD ......................... 267
VIN
Type plate ...................................... 426
W
WarningStickers ........................................... 42
Warning and indicator lamps
ABS ................................................ 316 Brakes ........................................... 315
Check Engine ................................. 320
Coolant .......................................... 320
Distance warning ........................... 322
ESP
®.............................................. 317
ESP®OFF ....................................... 319
Fuel tank ........................................ 320
General notes ................................ 313
Hybrid drive system ....................... 315
Overview .......................................... 34
Parking brake ................................ 319
PASSENGER AIR BAG ...................... 46
RBS (Recuperative Brake Sys-
tem) ............................................... 315
Reserve fuel ................................... 320
Restraint system ............................ 319
Seat belt ........................................ 313
Steering ......................................... 324
Tire pressure monitor .................... 323
Warranty .............................................. 25
Washer fluid
Display message ............................ 311
Wheel and tire combinations
Tires ............................................... 412
Wheel bolt tightening torque ........... 409
Wheel chock ...................................... 406
Wheels
Changing a wheel .......................... 405
Checking ........................................ 385
Cleaning ......................................... 361
General notes ................................ 410
Important safety notes .................. 384
Information on driving .................... 384
Interchanging/changing ................ 405
Mounting a new wheel ................... 409
Mounting a wheel .......................... 406
Removing a wheel .......................... 408
Snow chains .................................. 386
Storing ........................................... 405
Tightening torque ........................... 409
Wheel size/tire size ....................... 410
Window curtain air bag
Display message ............................ 288
Operation ......................................... 53
Windows
see Side windows
22Index

If the hazardous situation passes without result-
ing in an accident, the original settings are
restored.
Automatic measures after an acci-
dent
Immediately after an accident, the following
measures are implemented, depending on the
type and severity of the impact:
Rthe hazard warning lamps are activated
Rthe emergency lighting is activated
Rthe vehicle doors are unlocked
Rthe front side windows are lowered
Rthe electrically adjustable steering wheel is
raised
Rthe engine is switched off and the fuel supply
is cut off
Rvehicles with seat belt extenders: the seat-
belt buckles for the outer rear seats are illu-
minated and extend forwards
Rvehicles with mbrace: automatic emergency
call
Rvehicles with the hybrid drive system: the
hybrid system and the high-voltage electrical
system are deactivated
Children in the vehicle
Important safety notes
Accident statistics show that children secured
in the rear seats are safer than children secured
in the front-passenger seat. For this reason,
Mercedes-Benz strongly advises that you install
a child restraint system on a rear seat. Children
are generally better protected there.
If a child younger than twelve years old and
under 5 ft (1.50 m) in height is traveling in the
vehicle:
Ralways secure the child in a child restraint
system suitable for Mercedes-Benz vehicles.
The child restraint system must be appropri-
ate to the age, weight and size of the child
Rbe sure to observe the instructions and safety
notes in this section in addition to the child restraint system manufacturer's installation
instructions
Rbe sure to observe the instructions and safety
notes on the "Occupant classification system
(OCS)" (
Ypage 53)
GWARNING
If you leave children unsupervised in the vehi-
cle, they could set it in motion by, for example:
Rrelease the parking brake.
Rshift the automatic transmission out of the
parking position P.
Rstart the engine.
In addition, they may operate vehicle equip-
ment and become trapped. There is a risk of
an accident and injury.
When leaving the vehicle, always take the
SmartKey with you and lock the vehicle. Never
leave children unsupervised in the vehicle.
GWARNING
If persons, particularly children are subjected to prolonged exposure to extreme heat or
cold, there is a risk of injury, possibly even
fatal. Never leave children unattended in the
vehicle.
GWARNING
If the child restraint system is subjected to
direct sunlight, parts may get very hot. Chil-
dren may burn themselves on these parts,
particularly on the metal parts of the child
restraint system. There is a risk of injury.
If you leave the vehicle, taking the child with
you, always ensure that the child restraint
system is not exposed to direct sunlight. Pro- tect it with a blanket, for example. If the child
restraint system has been exposed to direct
sunlight, let it cool down before securing the
child in it. Never leave children unattended in
the vehicle.
Always ensure that all vehicle occupants have
their seat belts fastened correctly and are sitting
properly. Particular attention must be paid to
children.
Children in the vehicle61
Safety
Z

and that it is not swallowed. Do not inhale fuelvapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
RWash away fuel from skin immediately
using soap and water.
RIf fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance with-
out delay.
RIf fuel is swallowed, seek medical assis-
tance without delay. Do not induce vomit-
ing.
RImmediately change out of clothing which
has come into contact with fuel.
GWARNING
Electrostatic buildup can create sparks and
ignite fuel vapors. There is a risk of fire and
explosion.
Always touch the vehicle body before opening
the fuel filler flap or touching the fuel pump
nozzle. Any existing electrostatic buildup is
thereby discharged.
Do not get into the vehicle again during the refu-
eling process. Otherwise, electrostatic charge
could build up again.
!Do not use diesel to refuel vehicles with a
gasoline engine. Do not switch on the ignition
if you accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel system. Even small amounts of the wrong fuel could
result in damage to the fuel system and the
engine. Notify a qualified specialist workshop
and have the fuel tank and fuel lines drained
completely.
!Overfilling the fuel tank could damage the
fuel system.
!Take care not to spill any fuel on painted
surfaces. You could otherwise damage the
paintwork.
!Use a filter when refueling from a fuel can.
Otherwise, the fuel lines and/or injection sys-
tem could be blocked by particles from the
fuel can. If you overfill the fuel tank, fuel could spray out
when the fuel pump nozzle is removed.
For further information on fuel and fuel quality
(
Ypage 428).
Refueling
General information
Pay attention to the important safety notes
(Ypage 177).
PLUG-IN HYBRID vehicles: pressure in the fuel
tank must be released before refueling.
Except PLUG-IN HYBRID vehicles: if you
unlock/lock the vehicle from the outside, the
fuel filler flap also unlocks/locks.
The position of the fuel filler cap is displayed in
the instrument cluster 8. The arrow next to
the filling pump indicates the side of the vehicle.
Preparing to refuel
XSwitch off the engine.
XOpen the driver's door.
The on-board electronics now have status 0.
This is the same as the SmartKey having been
removed.
or, if the SmartKey is inserted in the ignition
lock:
XRemove the SmartKey from the ignition lock.
Opening the fuel filler flap (except
PLUG-IN HYBRID vehicles)
:To open the fuel filler flap
;To insert the fuel filler cap
=Tire pressure table
?Fuel type to be used
178Refueling
Driving and parking

XPress the fuel filler flap in the direction of
arrow:.
The fuel filler flap swings up.
XTurn the fuel filler cap counterclockwise and
remove it.
XInsert the fuel filler cap into the holder on the
inside of the fuel filler flap.
XCompletely insert the filler neck of the fuel
pump nozzle into the tank, hook in place and
refuel.
XOnly fill the tank until the pump nozzle
switches off.
Do not add any more fuel after the pump stops
filling for the first time. Otherwise, fuel may
leak out.
Opening the fuel filler flap (PLUG-IN
HYBRID vehicles)
XPull switch :.
Indicator lamp ;flashes and the Please
Wait Depressurizing Tankmessage
appears in the multifunction display.
If the fuel filler cap is open, indicator lamp ;
lights up.
The Tank is Depressurized Ready for
Refuelingmessage appears in the multi-
function display.
Please be sure to observe the information on
refueling on the fuel filler flap.
There is a malfunction if:
Rindicator lamp ;first flashes and then goes
out
Rthe yellow engine diagnostics warning lamp
lights up
iFrom a speed of 2 km/h, the fuel filler cap
can no longer be opened.
iThe opening process for the fuel filler cap
may take up to 15 minutes.
:To insert the fuel filler cap
;Tire pressure table
=Fuel type to be used
XTurn the fuel filler cap counterclockwise and
remove it.
XInsert the fuel filler cap into the holder on the inside of the fuel filler flap.
XCompletely insert the filler neck of the fuel
pump nozzle into the tank, hook in place andrefuel.
XOnly fill the tank until the pump nozzle
switches off.
Do not add any more fuel after the pump stopsfilling for the first time. Otherwise, fuel may
leak out.
Closing the fuel filler flap
XReplace the cap on the filler neck and turn
clockwise until it engages audibly.
XClose the fuel filler flap.
Close the fuel filler flap before locking the vehi-
cle.
If you drive at speeds above 1 mph (2 km/h)
with the fuel filler flap open, the Fuel Filler
Flap Openmessage is shown in the multifunc-
tion display.
If you are driving with the fuel filler cap open, the
8 reserve fuel warning lamp flashes. A mes-
sage appears in the multifunction display
(
Ypage 296).
In addition, the ;Check Engine warning
lamp may light up (
Ypage 320).
iFor further information on warning and indi-
cator lamps in the instrument cluster, see
(
Ypage 320).
Refueling179
Driving and parking
Z

Engine
Warning/
indicator
lampNSignal type
Possible causes/consequences and M
Solutions
;NThe yellow Check Engine warning lamp lights up while the engine is running.
There may be a malfunction, for example:
Rin the engine management
Rin the fuel injection system
Rin the exhaust system
Rin the ignition system
Rin the fuel system
The emission limit values may be exceeded and the engine may be in emergency
mode.
XVisit a qualified specialist workshop immediately.
iIn some states, you must immediately visit a qualified specialist workshop as
soon as the yellow Check Engine warning lamp lights up. This is due to the legal
requirements in effect in these states. If in doubt, check whether such legal
regulations apply in the state in which you are currently driving.
8N The yellow reserve fuel warning lamp lights up while the engine is running.
The fuel level has dropped into the reserve range.
XRefuel at the nearest gas station.
8N The yellow reserve fuel warning lamp flashes while the vehicle is in motion.
In addition, the ;Check Engine warning lamp may light up.
The fuel filler cap is not closed correctly or the fuel system is leaking.
XCheck that the fuel filler cap is correctly closed.
XIf the fuel filler cap is not correctly closed: close the fuel filler cap.
XIf the fuel filler cap is closed:visit a qualified specialist workshop.
?NThe red coolant warning lamp comes on while the engine is running. The coolant
temperature gauge is at the beginning of the cold range.
The temperature sensor for the coolant temperature gage is defective.
The coolant temperature is no longer being monitored. There is a risk of engine
damage if the coolant temperature is too high.
XPull over and stop the vehicle safely and switch off the engine, paying attention
to road and traffic conditions. Do not continue driving under any circumstances.
XSecure the vehicle against rolling away (Ypage 189).
XConsult a qualified specialist workshop.
320Warning and indicator lamps in the instrument cluster
On-board computer and displays

Useful information
i
This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
iRead the information on qualified specialist
workshops (Ypage 28).
Important safety notes
GWARNING
If wheels and tires of the wrong size are used, the wheel brakes or suspension components
may be damaged. There is a risk of an acci-
dent.
Always replace wheels and tires with those
that fulfill the specifications of the original
part.
When replacing wheels, make sure to use the
correct:
Rdesignation
Rmodel
When replacing tires, make sure to use the
correct:
Rdesignation
Rmanufacturer
Rmodel
GWARNING
A flat tire severely impairs the driving, steer-
ing and braking characteristics of the vehicle.
There is a risk of accident.
Tires without run-flat characteristics:
Rdo not drive with a flat tire.
Rimmediately replace the flat tire with your
emergency spare wheel or spare wheel, or
consult a qualified specialist workshop.
Tires with run-flat characteristics:
Rpay attention to the information and warn-
ing notices on MOExtended tires (tires with
run-flat characteristics).
Accessories that are not approved for your vehi-
cle by Mercedes-Benz or are not being used cor-
rectly can impair the operating safety.
Before purchasing and using non-approved
accessories, visit a qualified specialist work-
shop and inquire about:
Rsuitability
Rlegal stipulations
Rfactory recommendations
Information on the sizes and types of wheels and
tires for your vehicle can be found under
"Wheel/tire combinations" (
Ypage 410).
Information on tire pressure can be found:
Ron the vehicle's Tire and Loading Information
placard on the B-pillar (Ypage 394)
Rin the tire pressure table in the fuel filler flap
(Ypage 189)
Runder "Tire pressure" (Ypage 387)
Operation
Information on driving
Check the tire pressure when the vehicle is
heavily laden and adjust prior to a trip.
While driving, pay attention to vibrations, noises
and unusual handling characteristics, e.g. pull-
ing to one side. This may indicate that the
wheels or tires are damaged. If you suspect that
a tire is defective, reduce your speed immedi-
ately. Stop the vehicle as soon as possible to
check the wheels and tires for damage. Hidden
tire damage could also be causing the unusual
handling characteristics. If you find no signs of
damage, have the tires and wheels checked at a
qualified specialist workshop.
When parking your vehicle, make sure that the
tires do not get deformed by the curb or other
obstacles. If they cannot be avoided, drive over obstacles such as curbs slowly and at an obtuse
angle. Otherwise, you may damage the wheels
or tires.
384Operation
Wheels and tires

manufacture, starting with "01" for the first cal-
endar week. Positions three and four represent
the year of manufacture. For example, a tire that
is marked with "3208", was manufactured in
week 32 in 2008.
iTire data is vehicle-specific and may deviate
from the data in the example.
Tire characteristics
This information describes the type of tire cord
and the number of layers in sidewall :and
under tire tread ;.
iTire data is vehicle-specific and may deviate
from the data in the example.
Definition of terms for tires and loading
Tire ply composition and material used
Describes the number of plies or the number of
layers of rubber-coated fabric in the tire tread
and sidewall. These are made of steel, nylon,
polyester and other materials.
Bar
Metric unit for tire pressure. 14.5038 pounds
per square inch (psi) and 100 kilopascals (kPa)
are the equivalent of 1 bar.
DOT (Department of Transportation)
DOT-marked tires fulfill the requirements of the
U S Department of Transportation.
Normal occupant weight
The number of occupants for which the vehicle
is designed multiplied by 68 kilograms (150 lbs).
Uniform Tire Quality Grading Standards
A uniform standard to grade the quality of tires
with regards to tread quality, tire traction and
temperature characteristics. The quality grad-
ing assessment is made by the manufacturer
following specifications from the U.S. govern-
ment. The ratings are molded into the sidewall of the tire.
Recommended tire pressures
The recommended tire pressure applies to the
tires mounted at the factory.
The Tire and Loading Information placard con-
tains the recommended tire pressures for cold
tires on a fully loaded vehicle and for the maxi-
mum permissible vehicle speed.
The tire pressure table contains the recommen-
ded pressures for cold tires for various operat-
ing conditions, i.e. differing load and speed con-
ditions.
Increased vehicle weight due to optional
equipment
The combined weight of all standard and
optional equipment available for the vehicle,
regardless of whether it is actually installed on
the vehicle or not.
Rim
This is the part of the wheel on which the tire is
mounted.
GAWR (Gross Axle Weight Rating)
The GAWR is the maximum gross axle weight
rating. The actual load on an axle must never
exceed the gross axle weight rating. The gross
axle weight rating can be found on the vehicle
identification plate on the B-pillar on the driver's
side.
Speed rating
The speed rating is part of the tire identification.
It specifies the speed range for which the tire is
approved.
GVW (Gross Vehicle Weight)
The gross vehicle weight includes the weight of
the vehicle including fuel, tools, the spare wheel,
accessories installed, occupants, luggage and
the drawbar noseweight, if applicable. The gross
vehicle weight must not exceed the gross vehi-
cle weight rating GVWR as specified on the vehi-
cle identification plate on the B-pillar on the
driver's side.
All about wheels and tires403
Wheels and tires
Z

GVWR (Gross Vehicle Weight Rating)
The GVWR is the maximum permissible gross
weight of a fully loaded vehicle (the weight of thevehicle including all accessories, occupants,
fuel, luggage and the drawbar noseweight, if
applicable). The gross vehicle weight rating is
specified on the vehicle identification plate on
the B-pillar on the driver's side.
Maximum loaded vehicle weight
The maximum weight is the sum of:
Rthe curb weight of the vehicle
Rthe weight of the accessories
Rthe load limit
Rthe weight of the factory installed optional
equipment
Kilopascal (kPa)
Metric unit for tire pressure. 6.9 kPa corre-
sponds to 1 psi. Another unit for tire pressure is
bar. 100 kilopascals (kPa) are the equivalent of
1 bar.
Load index
In addition to the load-bearing index, the load
index may also be imprinted on the sidewall of
the tire. This specifies the load-bearing capacity
more precisely.
Curb weight
The weight of a vehicle with standard equipment
including the maximum capacity of fuel, oil and
coolant. It also includes the air-conditioning sys-
tem and optional equipment if these are instal-
led in the vehicle, but does not include passen-
gers or luggage.
Maximum load rating
The maximum tire load is the maximum permis-
sible weight in kilograms or lbs for which a tire is
approved.
Maximum permissible tire pressure
Maximum permissible tire pressure for one tire.
Maximum load on one tire
Maximum load on one tire. This is calculated bydividing the maximum axle load of one axle by
two.
PSI (pounds per square inch)
A standard unit of measure for tire pressure.
Aspect ratio
Relationship between tire height and tire width
in percent.
Tire pressure
This is pressure inside the tire applying an out-
ward force to each square inch of the tire's sur-
face. The tire pressure is specified in pou

nds per
square inch (psi), in kilopascal (kPa) or in bar.
The tire pressure should only be corrected when
the tires are cold.
Cold tire pressure
The tires are cold:
Rif the vehicle has been parked with the tires
out of direct sunlight for at least three hours
and
Rif the vehicle has not been driven further than
1 mile (1.6 km)
Tread
The part of the tire that comes into contact with
the road.
Bead
The tire bead ensures that the tire sits securely
on the wheel. There are several steel wires in the
bead to prevent the tire from coming loose from
the wheel rim.
Sidewall
The part of the tire between the tread and the
bead.
Weight of optional extras
The combined weight of those optional extras
that weigh more than the replaced standard
parts and more than 5 lbs (2.3 kg). These
optional extras, such as high-performance
brakes, level control, a roof rack or a high-per-
formance battery, are not included in the curb
weight and the weight of the accessories.
TIN (Tire Identification Number)
This is a unique identifier which can be used by
a tire manufacturer to identify tires, for example
for a product recall, and thus identify the pur-
chasers. The TIN is made up of the manufactur- er's identity code, tire size, tire type code and
the manufacturing date.
404All about wheels and tires
Wheels and tires

XTighten the wheel bolts evenly in a crosswisepattern in the sequence indicated (: toA).
The tightening torque must be 110 lb-ft
(150 Nm).
XTurn the jack back to its initial position.
XStow the jack and the rest of the vehicle tools
in the trunk again.
XMercedes-AMG vehicles and vehicles
with AMG equipment: insert the cover into
the outer sill.
XCheck the tire pressure of the newly mounted
wheel and adjust it if necessary.
Observe the recommended tire pressure
(
Ypage 387).
iVehicles with a tire pressure control system:
all mounted wheels must be equipped with
functioning tire pressure control sensors.
Wheel and tire combinations
General notes
!
For safety reasons, Mercedes-Benz recom-
mends that you only use tires and wheels
which have been approved by Mercedes-Benz
specifically for your vehicle.
These tires have been specially adapted for
use with the control systems, such as ABS or
ESP
®, and are marked as follows:
RMO = Mercedes-Benz Original
RMOE = Mercedes-Benz Original Extended
(tires featuring run-flat characteristics)
RMO1 = Mercedes-Benz Original (only cer-
tain AMG tires)
Mercedes-Benz Original Extended tires may
only be used on wheels that have been spe-
cifically approved by Mercedes-Benz.
Only use tires, wheels or accessories tested
and approved by Mercedes-Benz. Certain
characteristics, e.g. handling, vehicle noise
emissions or fuel consumption, may other-
wise be adversely affected. In addition, when
driving with a load, tire dimension variations
could cause the tires to come into contact
with the bodywork and axle components. This
could result in damage to the tires or the vehi- cle.
Mercedes-Benz accepts no liability for dam-
age resulting from the use of tires, wheels or accessories other than those tested and
approved.
Information on tires, wheels and approved
combinations can be obtained from any quali-
fied specialist workshop.
!Retreaded tires are neither tested nor rec-
ommended by Mercedes-Benz, since previ-
ous damage cannot always be detected on
retreaded tires. As a result, Mercedes-Benz
cannot guarantee vehicle safety if retreaded
tires are mounted. Do not mount used tires if
you have no information about their previous
usage.
Overview of abbreviations used in the following
tire tables:
RBA: both axles
RFA: front axle
RRA: rear axle
The recommended pressures for various oper-
ating conditions can be found:
Ron the Tire and Loading Information placard
on the B-pillar on the driver's side
Rin the tire pressure table in the fuel filler flap
Observe the notes on recommended tire pres-
sures under various operating conditions
(
Ypage 387).
Check tire pressures regularly, and only when
the tires are cold. Comply with the maintenance
recommendations of the tire manufacturer in
the vehicle document wallet.
Notes on the vehicle equipment – always equip
the vehicle with:
Rwith tires of the same size on a given axle (left
and right)
Rthe same type of tires at a given time (summer
tires, winter tires, MOExtended tires)
Exception: it is permissible to install a differ-
ent type or make in the event of a flat tire.
Observe the "MOExtended tires (tires with
run-flat characteristics" section (
Ypage 368).
Vehicles equipped with MOExtended tires are
not equipped with a TIREFIT kit at the factory. It
is therefore recommended that you additionally
equip your vehicle with a TIREFIT kit if you mount
tires that do not feature run-flat properties, e.g.
winter tires. A TIREFIT kit may be obtained from a qualified specialist workshop.
iNot all wheel and tire combinations are
available at the factory for all countries.
410Wheel and tire combinations
Wheels and tires