warning MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

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In this Operator's Manual you will find the fol-
lowing symbols:
GWARNING
Warning notes make you aware of dangers
which could pose a threat to your health or
life, or to the health and life of others.
HEnvironmental note
Environmental notes provide you with infor-
mation on environmentally aware actions or
disposal.
!Notes on material damage alert you to dan-
gers that could lead to damage to your vehi-
cle.
iPractical tips or further information that
could be helpful to you.
X This symbol indicates an instruction
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As at 26.03.2015

Welcome to the world of Mercedes-Benz
We urge you to read this Operator's Manual
carefully and familiarize yourself with the vehi-
cle before driving. For your own safety and a
longer vehicle life, follow the instructions and
warning notices in this manual. Ignoring them
could result in damage to the vehicle or personal
injury to you or others.
Vehicle damage caused by failure to follow
instructions is not covered by the Mercedes-
Benz Limited Warranty.
The equipment or product designation of your
vehicle may vary depending on:
RModel
ROrder
RCountry specification
RAvailability
Mercedes-Benz therefore reserves the right to
introduce changes in the following areas:
RDesign
REquipment
RTechnical features
The equipment in your vehicle may therefore
differ from that shown in the descriptions and
illustrations.
The following are integral components of the
vehicle:
RPrinted Operator's Manual
RMaintenance Booklet
REquipment-dependent supplements
Keep these documents in the vehicle at all
times. If you sell the vehicle, always pass all
documents on to the new owner.
You can also use the Mercedes-Benz Guides
App:
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Please note that the Mercedes-Benz Guides App may not yet be available in your country.
Mercedes-Benz USA, LLC
Mercedes-Benz Canada, Inc.
A Daimler Company
2225842905
É2225842905sËÍ

1, 2, 3 ...
4ETS (Electronic Traction System)see ETS/4ETS (Electronic Trac-
tion System)
4MATIC (permanent four-wheel
drive) .................................................. 213
12 V socket
see Sockets
115 V socket ...................................... 337
360° camera
Cleaning ........................................ .363
Function/notes .............................2 24
A
ABS (Anti-lock Braking System)
Display message ............................ 278
Function/notes ................................ 68
Warning lamp ................................. 316
Accident
Automatic measures after an acci-
dent ................................................. 61
Activating/deactivating cooling
with air dehumidification ................. 146
Activating/deactivating Night
View Assist Plus
With spotlight function ................... 232
Active Blind Spot Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 234
Active Body Control (ABC)
Display message ............................ 300
Function/notes ............................. 210
Active Lane Keeping Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 237
Active multicontour seat .................. 117
Active Parking Assist
Detecting parking spaces .............. 217
Display message ............................ 302
Exiting a parking space .................. 219
Function/notes ............................. 216
Important safety notes .................. 216 Parking .......................................... 218
ADAPTIVE BRAKE ................................. 75
Adaptive Brake Assist
Function/notes ................................ 72
Adaptive Damping System (ADS) ..... 212
Adaptive Highbeam Assist Plus
Display message ............................ 293
Function/notes ............................. 133
Switching on/off ........................... 133
Additional speedometer ................... 274
Additives (engine oil) ........................ 430
Air bags
Belt bags .......................................... 48
Cushion air bags .............................. 53
Deployment ..................................... 57
Display message ............................ 289
Front air bag (driver, front
passenger) ....................................... 52
Important safety notes .................... 50
Introduction ..................................... 50
Knee bag .......................................... 52
Occupant Classification System
(OCS) ............................................... 53
PASSENGER AIR BAG i
ndicator
lamps ............................................... 46
Side impact air bag .......................... 52
Window curtain air bag .................... 53
Air vents
Glove box ....................................... 159
Important safety notes .................. 158
Rear ............................................... 160
Setting ........................................... 158
Setting the center air vents ........... 159
Setting the side air vents ............... 159
Air-conditioning system
see Climate control
AIRMATIC
Display message ............................ 299
Function/notes ............................. 212
Alarm
ATA (Anti-Theft Alarm system) ......... 78
Switching off (ATA) .......................... 78
Switching the function on/off
(ATA) ................................................ 78
Alarm system
see ATA (Anti-Theft Alarm system)
Anti-lock braking system
see ABS (Anti-lock Braking System)
Index3

Brake Assistsee BAS (Brake Assist System)
Brake fluid
Display message ............................ 283
Notes ............................................. 430
Brake force distribution
see EBD (electronic brake force
distribution)
Brake lamps
Display message ............................ 291
Brake pedal
Pedal resistance/pedal travel .......... 44
Brakes
ABS .................................................. 68
Adaptive Brake Assist ...................... 72
BAS .................................................. 69
BAS PLUS with Cross-Traffic
Assist ............................................... 69
Brake fluid (notes) ......................... 430
Display message ............................ 278
EBD .................................................. 75
High-performance brake system .... 196
Hill start assist ............................... 165
HOLD function ............................... 208
Important safety notes .................. 194
Maintenance .................................. 195
Parking brake ................................ 190
RBS warning lamp .......................... 315
Recuperative Brake System ............. 44
Riding tips ...................................... 194
Warning lamp ................................. 315
Breakdown
Where will I find...? ........................ 367
see Flat tire
see Towing away
Brightness control (instrument
cluster lighting) ................................... 35
Buttons on the steering wheel ......... 257
C
California
Important notice for retail cus-
tomers and lessees .......................... 25
Calling up a malfunction
see Display messages
Camera
see 360° camera see Rear view camera
Car
see Vehicle
Care
360° camera ................................. 363
Car wash ........................................ 359
Carpets .......................................... 366
Display ........................................... 364
Exhaust pipe .................................. 363
Exterior lights ................................ 362
Gear or selector lever .................... 365
General notes ................................ 359
Interior ........................................... 364
Matte finish ................................... 361
Night View Assist Plus ................... 364
Paint .............................................. 361
Plastic trim .................................... 364
Power washer ................................ 360
Rear view camera .......................... 363
Roof lining ...................................... 366
Seat belt ........................................ 366
Seat cover ..................................... 365
Sensors ......................................... 362
Steering wheel ............................... 365
Trim pieces .................................... 365
Washing by hand ........................... 360
Wheels ........................................... 361
Windows ........................................ 362
Wiper blades .................................. 362
Wooden trim .................................. 365
CD player (on-board computer) ........ 266
Center console
Overview .......................................... 37
Stowage space .............................. 326
Center console in the rear com-
partment
Stowage compartment .................. 327
Central locking
Locking/unlocking (SmartKey) ........ 79
Changing the media source ............. 265
Charging
see Charging the high-voltage bat-
tery (important safety notes)
Charging cable
Connecting .................................... 185
Controls ......................................... 183
Important safety notes .................. 183
Indicator lamp ................................ 184
Index5

Removing...................................... .185
Storing ...........................................1 83
Warming up ................................... 182
Charging the high-voltage battery
(important safety notes) ................... 180
Chauffeur mode
Display message ............................ 310
Fully reclined position .................... 114
General notes ................................ 111
Installing the head restraint ........... 113
Moving front-passenger seat into
the chauffeur position .................... 112
Moving the front-passenger seat
into the normal position ................. 113
Removing the head restraint .......... 113
Child
Restraint system .............................. 62
Child seat
Forward-facing restraint system ...... 66
LATCH-type (ISOFIX) child seat
anchors ............................................ 63
On the front-passenger seat ............ 65
Rearward-facing restraint system .... 66
Top Tether ....................................... 64
Child-proof locks
Important safety notes .................... 66
Rear doors ....................................... 67
Children
Special seat belt retractor ............... 62
Cigarette lighter ................................ 335
Cleaning
Mirror turn signal ........................... 362
Climate control
Automatic climate control ............. 141
Controlling automatically ............... 147
Cooling with air dehumidification .. 146
Defrosting the windows ................. 151
Defrosting the windshield .............. 151
ECO start/stop function ................ 145
General notes ................................ 140
Immediate pre-entry climate con-
trol ................................................. 158
Indicator lamp ................................ 147
Ionization ....................................... 155
Notes on using the automatic cli-
mate control .................................. 145
Overview of systems ...................... 140
Perfume atomizer .......................... 153 Pre-entry climate control at
departure time ............................... 157
Pre-entry climate control via
key ... 155
P

roblem with the rear window
defroster ........................................ 152
Problems with cooling with air
dehumidification ............................ 147
Rear control panel ......................... 141
Refrigerant ..................................... 432
Refrigerant filling capacity ............. 432
Setting the air distribution ............. 149
Setting the air vents ...................... 158
Setting the airflow ......................... 150
Setting the climate mode ............... 148
Setting the temperature ................ 148
Switching air-recirculation mode
on/off ............................................ 152
Switching on/off ........................... 145
Switching residual heat on/off ...... 152
Switching the rear window
defroster on/off ............................ 151
Switching the synchronization
function on and off ........................ 150
Climate control system
Climate control .............................. 145
Cockpit
Overview .......................................... 32
COLLISION PREVENTION ASSIST
PLUS
Activating/deactivating ................. 270
Display message ............................ 284
Operation/notes .............................. 71
COMAND display
Cleaning ......................................... 364
Combination switch .......................... 131
Consumption statistics (on-board
computer) .......................................... 262
Convenience closing feature .............. 96
Convenience opening feature ............ 95
Coolant (engine)
Checking the level ......................... 356
Display message ............................ 294
Displaying the temperature (on-
board computer) ............................ 269
Filling capacity ............................... 431
Important safety notes .................. 431
Temperature gauge ........................ 257
Warning lamp ................................. 320
6Index

Coolbox.............................................. 339
Cooling
see Climate control
Copyright ............................................ .31
Cornering light function
Display message ............................ 291
Function/notes ............................ .132
Crash-responsive emergency light-
ing ....................................................... 135
Crosswind Assist (vehicles with
MAGIC BODY CONTROL) ................... 210
Crosswind Assist (vehicles with-
out MAGIC BODY CONTROL) ...............75
Cruise control
Calling up the speed last stored .... 198
Cruise control lever ....................... 197
Deactivating ................................... 199
Display message ............................ 305
Driving system ............................... 197
Function/notes ............................. 197
General notes ................................ 197
Important safety notes .................. 197
Setting a speed .............................. 198
Storing and maintaining current
speed ............................................. 198
Cup holder
Center console .............................. 331
Important safety notes .................. 330
Rear compartment ......................... 331
Temperature controlled ................. 332
Cushion air bags .................................. 53
Customer Assistance Center
(CAC) ..................................................... 29
Customer Relations Department ....... 29
D
Data
see Technical data
Data carrier
Selecting ........................................ 266
Daytime running lamps
Display message ............................ 293
Function/notes ............................. 130
Switching on/off (on-board com-
puter) ............................................. 274
Declarations of conformity ................. 28
Diagnostics connection ...................... 28Digital speedometer
......................... 263
DIRECT SELECT lever
Automatic transmission ................. 170
Display
see Display messages
see Warning and indicator lamps
Display message
Hybrid drive system ....................... 297
Display messages
ASSYST PLUS ................................ 357
Calling up (on-board computer) ..... 277
Driving systems ............................. 299
Engine ............................................ 294
General notes ................................ 277
Hiding (on-board computer) ........... 277
Introduction ................................... 277
Lights ............................................. 291
Safety systems .............................. 278
SmartKey ....................................... 312
Tires ............................................... 306
Vehicle ........................................... 308
Distance recorder
see Odometer
see Trip odometer
Distance warning (warning lamp) .... 322
Distance warning function
Function/notes ................................ 71
DISTRONIC PLUS
Activating ....................................... 201
Activation conditions ..................... 201
Cruise control lever ....................... 201
Deactivating ................................... 205
Display message ............................ 303
Displays in the instrument cluster .. 204
Driving tips .................................... 205
Driving with DISTRONIC PLUS ....... 202
Function/notes ............................. 199
Important safety notes .................. 200
Setting a speed .............................. 203
Setting the specified minimum
distance ......................................... 204
Stopping ........................................ 203
with Steering Assist and Stop&Go
Pilot ............................................... 207
Doors
Automatic locking (switch) ............... 87
Central locking/unlocking
(SmartKey) ....................................... 79
Index7

Control panel ...................................40
Display message ............................ 310
Emergency locking ........................... 88
Emergency unlocking ....................... 87
Important safety notes .................... 85
Opening (from inside) ...................... 86
Power closing .................................. 87
Drinking and driving ......................... 193
Drive program
Automatic ...................................... 174
Manual ........................................... 174
Manual (Mercedes-AMG vehi-
cles) ............................................... 175
SETUP (on-board computer) .......... 276
Driver's door
see Doors
Driving abroad
Mercedes-Benz Service ................. 358
Driving Assistance package ............. 234
Driving on flooded roads .................. 196
Driving safety systems
ABS (Anti-lock Braking System) ....... 68
ADAPTIVE BRAKE ............................. 75
Adaptive Brake Assist ...................... 72
BAS (Brake Assist System) .............. 69
BAS PLUS with Cross-Traffic
Assist ............................................... 69
COLLISION PREVENTION ASSIST
PLUS ................................................ 71
Distance warning function ............... 71
EBD (electronic brake force distri-
bution) ............................................. 75
ESP
®(Electronic Stability Pro-
gram) ............................................... 73
Important safety information ........... 68
Overview .......................................... 68
PRE-SAFE
®Brake ............................. 75
Recuperative Brake System ............. 44
STEER CONTROL ............................. 77
Driving systems
360°camera .................................. 224
Active Blind Spot Assist ................. 234
Active Body Control ABC ............... 210
Active Lane Keeping Assist ............ 237
Active Parking Assist ..................... 216
AIRMATIC ...................................... 212
ATTENTION ASSIST ........................ 228 Cruise control ................................ 197
Display message ............................ 299
DISTRONIC PLUS ........................... 199
DISTRONIC PLUS with Steering
Assist and Stop&Go Pilot ............... 207
Driving Assistance package
........... 234
HOLD fu

nction ............................... 208
Night View Assist Plus ................... 230
PARKTRONIC ................................. 214
Rear view camera .......................... 220
Traffic Sign Assist .......................... 229
Driving tips
AMG ceramic brakes ..................... 196
Automatic transmission ................. 173
Brakes ........................................... 194
Break-in period .............................. 161
DISTRONIC PLUS ........................... 205
Downhill gradient ........................... 194
Drinking and driving ....................... 193
Driving in winter ............................. 196
Driving on flooded roads ................ 196
Driving on wet roads ...................... 196
Exhaust check ............................... 193
Fuel ................................................ 192
General .......................................... 192
Hydroplaning ................................. 196
Icy road surfaces ........................... 196
Limited braking efficiency on sal-
ted roads ....................................... 195
Snow chains .................................. 386
Subjecting brakes to a load ........... 194
The first 1000 miles (1500 km) ..... 161
Wet road surface ........................... 194
DVD video
Operating (on-board computer) ..... 267
E
EASY-ENTRY featureFunction/notes ............................. 122
EASY-EXIT feature
Crash-responsive ........................... 123
Function/notes ............................. 122
EBD (electronic brake force distri-
bution)
Display message ............................ 280
Function/notes ................................ 75
8Index

ECO displayFunction/notes ............................ .193
On-board computer ....................... 262
ECO start/stop function
Automatic engine start .................. 167
Automatic engine switch-off .......... 166
Deactivating/activating ................. 167
General information ....................... 166
Important safety notes .................. 166
Introduction ................................... 166
Electronic Stability Program
see ESP
®(Electronic Stability Program)
Emergency
Automatic measures after an acci-
dent ................................................. 61
Emergency release
Driver's door ....................................8 7
Trunk ............................................... 94
Vehicle ............................................. 87
Emergency Tensioning Devices
Activation ......................................... 57
Emissions control
Service and warranty information ....2 5
Engine
Check Engine warning lamp .......... .320
Display message ............................ 294
ECO start/stop function ................ 166
Engine number ............................... 427
Irregular running ............................ 169
Jump-starting ................................. 376
Starting (important safety notes) ... 164
Starting problems .......................... 169
Starting the engine with the
SmartKey ....................................... 164
Starting via smartphone ................ 164
Starting with the Start/Stop but-
ton ................................................. 164
Switching off .................................. 190
Switching off with the Start/Stop
button ............................................ 190
Switching off with the vehicle key .. 190
Tow-starting (vehicle) ..................... 381
Engine electronics
Problem (malfunction) ................... 169
Engine oil
Adding ...........................................3 55
Additives ........................................ 430
Checking the oil leve l ..................... 353 C
hecking the oil level using the
dipstick .......................................... 353
Checking the oil level using the
on-board computer ........................ 355
Display message ............................ 296
Filling capacity ............................... 430
General notes ................................ 429
Notes about oil grades ................... 429
Notes on oil level/consumption .... 353
Temperature (on-board computer,
Mercedes-AMG vehicles) ...............2 75
Viscosity ........................................ 430
ESP
®(Electronic Stability Pro-
gram)
AMG menu (on-board computer) ... 276
Characteristics ................................. 73
Deactivating/activating ................. 269
Deactivating/activating (notes) ....... 74
Display message ............................ 278
Function/notes ................................ 73
General notes .................................. 73
Important safety information ........... 73
Trailer stabilization ........................... 74
Warning lamp ................................. 317
ETS/4ETS (Electronic Traction Sys-
tem) ...................................................... 73
Exhaust
see Exhaust pipe
Exhaust check ................................... 193
Exhaust pipe
Cleaning ......................................... 363
Exhaustive discharging (high-volt-
age battery) ....................................... 374
Exterior lighting
Cleaning ......................................... 362
see Lights
Exterior mirrors
Adjusting ....................................... 123
Dipping (automatic) ....................... 124
Folding in/out (automatically) ....... 124
Folding in/out (electrically) ........... 124
Out of position (troubleshooting) ... 124
Setting ........................................... 124
Storing settings (memory func-
tion) ............................................... 126
Storing the parking position .......... 125
Eyeglasses compartment ................. 326
Index9

F
Features............................................ .330
Filling capacities (Technical data) ... 427
Flat tire
Changing a wheel/mounting the
spare wheel ................................... 405
MOExtended tires .......................... 368
Preparing the vehicle ..................... 367
TIREFIT kit ...................................... 369
Floormats ...........................................3 50
Folding table ...................................... 328
Frequencies
Mobile phone ................................. 425
Two-way radio ................................ 425
Front-passenger seat
Adjusting from the driver's seat ..... 108
Adjusting from the rear compart-
ment .............................................. 108
Fuel
Additives ........................................ 429
Consumption statistics .................. 262
Displaying the current consump-
tion ................................................ 261
Displaying the range ......................2 61
Driving tips ....................................1 92
Fuel gauge ....................................... 33
Grade (gasoline) ............................ 428
Important safety notes .................. 428
Problem (malfunction) ................... 180
Refueling ........................................ 177
Tank content/reserve fuel ............. 428
Fuel level
Calling up the range (on-board
computer) ...................................... 261
Fuel tank
Capacity ........................................ 428
Problem (malfunction) ................... 180
Fuses
Allocation chart ..................... 381, 383
Before changing .............................3 82
Dashboard fuse box ....................... 382
Fuse box in the engine compart-
ment .............................................. 383
Fuse box in the front-passenger
footwell .......................................... 382
Fuse box in the trunk ..................... 383
Important safety notes .................. 381
G
Garage door opener
Clearing the memory ..................... 350
General notes ................................ 347
Important safety notes .................. 348
Opening/closing the garage door .. 350
Problems when programming ........3 49
Programming (button in the rear-
view mirror) ................................... 348
Synchronizing the rolling code ....... 349
Gasoline ............................................. 428
Gear indicator (on-board com-
puter, Mercedes-AMG vehicles) ....... 275
Genuine parts ...................................... 24
Glove box ...........................................3 26
H
Handbrake
see Parking brake
HANDS-FREE ACCESS .......................... 91
Hazard warning lamps ......................132
Head restraints
Adjusting ....................................... 114
Adjusting (manually) ......................1 15
Adjusting (rear) .............................. 116
EASY ADJUST luxury head
restraint ......................................... 115
Luxury ............................................ 115
Supplementary cushion ................. 116
Head-up display
Adjusting the brightness ................ 273
Displays and operating .................. 259
Function/notes .............................2 59
Important safety notes .................. 259
Selecting displays .......................... 273
Setting the position ....................... 273
Headlamps
Fogging up ..................................... 134
see Automatic headlamp mode
Heating
see Climate control
High beam flasher .............................1 32
High-beam headlamps
Adaptive Highbeam Assist PLUS .... 133
Display message ............................ 292
Switching on/off ........................... 132
10Index

High-voltage batteryBattery care ................................... 182
Charging (charging station) ............ 186
Charging (mains socket) ................1 83
Charging (wallbox) ......................... 185
Charging cable warming ................ 182
Cruise range .................................. 182
Energy consumption ......................1 82
General notes .................................. 43
Method of operation ......................1 81
Outside temperatures .................... 182
Overvoltage protection .................. 182
Problems with the charging proc-
ess ................................................. 187
Terms of use .................................. 182
Vehicle fire ....................................... 43
Hill start assist .................................. 165
HOLD function
Activating ....................................... 209
Activation conditions ..................... 209
Deactivating ................................... 209
Display message ............................ 303
Function/notes .............................2 08
General notes ................................ 208
Hood
Closing ...........................................3 53
Display message ............................ 310
Important safety notes .................. 352
Opening ......................................... 352
Horn ...................................................... 32
HUD
see Head-up display
Hybrid drive system
Automatic switch off ........................ 42
Danger of electric shock .................. 42
Display message ............................ 297
General notes .................................. 42
High-voltage battery ........................ 43
Important safety notes .................... 42
Manual switch off ............................ 42
Opening the hood ............................ 43
Warning lamp ................................. 315
Hybrid vehicles
Important safety notes .................... 42
Hydroplaning ..................................... 196I
Ignition lock
see Key positions
Immobilizer .......................................... 78
Indicator and warning lamps
COLLISION PREVENTION ASSIST
PLUS .............................................. 322
Indicator lamps
see Warning and indicator lamps
Indicators
see Turn signals
Instrument cluster
Overview .......................................... 33
Warning and indicator lamps ........... 34
Instrument cluster lighting .............. 256
Interior lighting
Control ...........................................1 35
Emergency lighting ........................ 135
Overview ........................................ 134
Reading lamp ................................. 134
J
Jack
Using ............................................. 406
Jump starting (engine) ......................376
K
Key positions
SmartKey ....................................... 162
Start/Stop button .......................... 162
KEYLESS-GO
Convenience closing feature ............ 96
Deactivation ..................................... 80
Locking ............................................ 80
Start function ................................... 81
Unlocking ......................................... 80
Kickdown
Driving tips ....................................1 73
Knee bag .............................................. 52
L
Lamps
see Warning and indicator lamps
Lane Keeping Assist
see Active Lane Keeping Assist
Index11