Octane MERCEDES-BENZ S-Class 2011 W221 Owner's Manual

O
Occupant Classification System
(OCS) Faults ............................................... 52
Operation ......................................... 48
System self-test ............................... 51
Occupant safety
Children in the vehicle .....................60
System overview .............................. 42
Octane number (fuel) ........................ 512
Odometer ........................................... 368
Off-map .............................................. 171
Off-road .............................................. 171
4MATIC .......................................... 339
Oil
see Engine oil
On-board computer
AMG menu ..................................... 371
Assistance menu ........................... 375
Audio menu ................................... 370
Display messages ..........................380
Important safety notes ..................364
Instrument cluster submenu ..........377
Lighting submenu .......................... 377
Message memory .......................... 380
Navigation menu ............................ 369
Operating video DVD .....................371
Operation ....................................... 365
Overview of menus ........................367
Service menu ................................. 377
Settings menu ............................... 377
Standard display submenu ............368
Telephone menu ............................ 374
Trip menu ...................................... 368
Opening height restriction for
trunk lid .............................................. 261
Operating system see On-board computer
Orientation in direction of travel ..... 181
Outside lighting Delayed switch-off (COMAND) .......259
Outside temperature
Display ........................................... 365
Overhead control panel
Overview .......................................... 36
Override feature
Rear side windows ...........................65P
Paint code number ............................ 509
Paintwork (cleaning instructions) ... 454
Panic alarm .......................................... 66
Panorama roof with power tilt/
sliding panel Opening/closing .............................. 95
Resetting ......................................... 97
Parking ............................................... 316
Parking aid Parking Guidance ........................... 342
PARKTRONIC ................................. 339
Rear view camera .......................... 346
Parking brake
Display message ............................ 389
Electric parking brake ....................317
Parking Guidance .............................. 342
Display message ............................ 405
Parking lamp (display message) ...... 396
Parking position Exterior mirror on the front-
passenger side ............................... 111
Exterior mirrors (COMAND) ...........258
PARKTRONIC
Activating/deactivating .................341
Function/notes ............................. 339
Malfunction .................................... 342
Problem ......................................... 342
Range of the sensors .....................340
Warning display ............................. 341
Passcode
Entering ................................. 147, 194
Pause function ................................... 220
Pedals ................................................. 319
Permanent four-wheel drive see 4MATIC
Phone book
Calling up ....................................... 201
Creating an entry ........................... 203
Deleting an entry ........................... 204
Introduction ................................... 200
Plastic trim (cleaning instructions) . 458
Playback options .............. 224, 229, 234
Point of interest Category ........................................ 161
Entering ......................................... 160
Entering a name ............................. 160Index15

If you sell your Mercedes, please leave all
literature with the vehicle to make it available
to the next operator.
If you bought this vehicle used, be sure to
send in the "Notice of Purchase of Used Car"
found in the Service and Warranty
Information Booklet, or call the Mercedes-
Benz Customer Assistance Center (in the
USA) at 1-800-FOR-MERCedes
(1-800-367-6372) or Customer Service (in
Canada) at 1-800-387-0100.
Vehicle operation outside the USA
and Canada
If you plan to operate your vehicle in foreign
countries, please be aware that:
R Service facilities or replacement parts may
not be readily available.
R Unleaded gasoline for vehicles with
catalytic converters may not be available.
The use of leaded fuels can damage the
catalytic converter.
R Gasoline may have a considerably lower
octane rating. Improper fuel can cause
engine damage.
Certain Mercedes-Benz models are available
for delivery in Europe under our European
Delivery Program. For details, consult an
authorized Mercedes-Benz Center or write to
one of the following addresses:
In the USA
Mercedes-Benz USA, LLC
European Delivery Department
One Mercedes Drive
Montvale, NJ 07645-0350
In Canada
Mercedes-Benz Canada, Inc.
European Delivery Department
98 Vanderhoof Avenue
Toronto, Ontario M4G 4C9
Operating safety
Safety notes
GWarning
Work improperly carried out on electronic
components and associated software could
cause them to cease functioning. Because the
vehicle's electronic components are
interconnected, any modifications made may
produce an undesired effect on other
systems. Electronic malfunctions could
seriously impair the operating safety of your
vehicle.
Contact an authorized Mercedes-Benz Center
for repairs or modifications to electronic
components.
Other improper work or modifications on the
vehicle could also have a negative impact on
the operating safety of the vehicle.
Some safety systems only function when the
engine is running. You should therefore never
turn off the engine while driving.
GWarning
Heavy blows against the vehicle underbody or
tires/wheels may cause serious damage and
impair the operating safety of your vehicle.
Such blows can be caused, for example, by
running over an obstacle, road debris or a
pothole. If you feel a sudden significant
vibration or ride disturbance, or you suspect
that damage to your vehicle has occurred:
R turn on your hazard warning flashers.
R slow down carefully.
R drive with caution to an area which is a safe
distance from the road.
Inspect the vehicle underbody and tires/
wheels for possible damage. If the vehicle
appears unsafe, have it towed to the nearest
authorized Mercedes-Benz Center or other
qualified maintenance or repair facility for
further inspection or repairs.
26Introduction

GWarning
Hybrid vehicles: ensure that you read the
"HYBRID" supplement. You may otherwise fail
to recognize dangers.
! Do not use diesel to refuel vehicles with a
gasoline engine. Even small amounts of the
wrong fuel result in damage to the fuel
system and engine.
! Do not switch on the ignition if you
accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel lines.
Notify a qualified specialist workshop and
have the fuel tank and fuel lines drained
completely.
Gasoline
Fuel grade
! You should only refuel with unleaded
premium-grade gasoline as this avoids
damaging the catalytic converter.
If engine running problems are apparent,
have the cause checked immediately and
repaired. Excess unburned fuel can
otherwise enter the catalytic converter,
leading to overheating and possibly
causing a fire.
iOnly refuel with unleaded premium-grade
gasoline with a specified minimum octane
number of 91 (average value of 96 RON/
86 MON).
Usually you will find information about the
fuel grade on the pump. If you cannot find
the label on the gasoline pump, ask the gas
station staff.
You can find further information under
"Fuel" (Y page 512), by consulting an
authorized Mercedes-Benz Center or
visiting http://www.mbusa.com (USA
only).
Refueling
Fuel filler flap
The fuel filler flap is unlocked or locked
automatically when you open or close the
vehicle with the key or using KEYLESS-GO.
The fuel filler flap is located to the rear on the
right. The position of the fuel filler cap is
displayed in the instrument cluster 8. The
arrow next to the filling pump indicates the
side of the vehicle.
:To open the fuel filler flap;To insert the fuel filler cap=Tire pressure table?Fuel type
Opening
XSwitch off the engine.
iWhen the engine is running and the fuel
filler flap is open, the ; engine
diagnostics warning lamp may light up.
For further information on warning and
indicator lamps in the instrument cluster,
see (Y page 418).
XRemove the SmartKey from the ignition
lock.
KEYLESS-GO: open the driver's door. This
returns the ignition to position 0, which
corresponds to the SmartKey being
314RefuelingDriving and parking

CapacitiesVehicle modelCapacityFuel, coolant,
lubricants etc.Engine oil and
filterS 550 41
S 550 4MATIC 41
S 63 AMG9.0 US qt (8.5 l)Approved engine
oilsS 600
S 65 AMG9.5 US qt (9.0 l)Power steeringAll modelsApproximately 1.6 US qt
(1.5 l)PentosinCooling systemS 550 41
S 550 4MATIC 41Approximately 14.5 US qt
(13.7 l)MB 326.0
Anticorrosion/
AntifreezeS 600Approximately 17.4 US qt
(16.5 l)S 63 AMGApproximately 12.2 US qt
(11.5 l)S 65 AMGApproximately 14.7 US qt
(13.9 l)Tank capacityS 550 41
S 550 4MATIC 4121.9 US gal. (83 l)Premium-grade
unleaded gasoline
(at least 91 octane,
average value
between 96 RON/
86 MON)S 600
S 63 AMG
S 65 AMG23.8 US gal. (90 l)ReserveAll models except
AMG vehicles2.9 US gal. (11 l)AMG vehicles3.7 US gal. (14 l)41 BlueEFFICIENCY.Service products and capacities511Technical dataZ

Vehicle modelCapacityFuel, coolant,
lubricants etc.Air-
conditioning
systemAll models—Refrigerant R134a
and special PAG
lubricant (never
R 12)Windshield/
headlamp
cleaning
systemAll models6.9 US qt (6.5 l)MB windshield
washer
concentrate 42
( Y page 515)
Mixing ratio for
washer fluid
( Y page 515)Fuel
Important safety notesGWarning
Gasoline is highly flammable and poisonous.
It burns violently and can cause serious
personal injury.
Never allow sparks, flames or smoking
materials near gasoline.
Turn off the engine before refueling.
Whenever you are around gasoline, avoid
inhaling fumes and any skin or clothing
contact.
Direct skin contact with fuels and the
inhalation of fuel vapors are damaging to your
health.
Premium-grade unleaded gasoline
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline must be used.
If premium-grade unleaded gasoline is
unavailable and regular gasoline is used,
observe the following precautions:
R only fill the fuel tank to half full with
regular unleaded gasoline and add the
rest as soon as possible with premium-
grade unleaded gasoline.
R do not drive at the maximum speed.
R avoid sudden acceleration.
R when the vehicle is carrying a light cargo,
e.g. two passengers without luggage, do
not allow the engine to rev above
3000 rpm.
R when the vehicle is fully loaded or being
operated in mountainous terrain, do not
depress the accelerator pedal further
than 2
/ 3 of the pedal travel.
Fuel requirements
Use only premium-grade unleaded gasoline.
The octane number should be at least 91.
Details can be found on the gas pump. The
octane number is the average value of the
Research Octane Number (RON) and Motor
Octane Number (MON): (RON + MON) / 2,
also known as knock resistance.
Reformulated Gasoline (RFG) and/or
unleaded gasoline with additives can be used
if the concentration of the additives in the fuel
does not exceed 10%, e.g.:
R Ethanol
R TAME
42Mixed with water or premixed washer fluid with antifreeze protection.512Service products and capacitiesTechnical data