MERCEDES-BENZ S-Class 2014 W222 Owner's Manual

S 63 AMG 4MATIC
Summer tires
R 19
Tires Alloy wheels
FA: 255/45 ZR19 (104 Y) XL
4
RA: 285/40 ZR19 (107 Y) XL 4, 5 FA: 8.5 J x 19 H2
Wheel offset: 1.50 in (38 mm)
RA: 9.5 J x 19 H2
Wheel offset: 1.50 in (38 mm)
FA: 255/45 ZR19 (104 Y) XL
4
RA: 285/40 ZR19 (107 Y) XL 4, 5 FA: 8.5 J x 19 H2
Wheel offset: 1.54 in (39 mm)
RA: 9.5 J x 19 H2
Wheel offset: 1.54 in (39 mm)
R 20
Tires Alloy wheels
FA: 255/40 ZR20 (101 Y) XL
6
RA: 285/35 ZR20 (104 Y) XL 5, 6 FA: 8.5 J x 20 H2
Wheel offset: 1.50 in (38 mm)
RA: 9.5 J x 20 H2
Wheel offset: 1.50 in (38 mm)
FA: 255/40 ZR20 (101 Y) XL
6
RA: 285/35 ZR20 (104 Y) XL 5, 6 FA: 8.5 J x 20 H2
Wheel offset: 1.54 in (39 mm)
RA: 9.5 J x 20 H2
Wheel offset: 1.54 in (39 mm)
Winter tires
R 19
Tires Alloy wheels
BA: 255/45 R19 104 V XL M+S004D
4 BA: 8.5 J x 19 H2
Wheel offset: 1.50 in (38 mm)
BA: 255/45 R19 104 V XL M+S004D
4 BA: 8.5 J x 19 H2
Wheel offset: 1.54 in (39 mm)
4
Not in combination with a ceramic brake system.
5 The use of snow chains is not permitted. Observe the notes in the "Snow chains" section.
6 Observe notes on "Large wheels" under "General notes" in "Wheel/tire combination". Wheel and tire combinations
419Wheels and tires Z

R 20
Tires Alloy wheels
BA: 255/40 R20 101 V XL M+S
004D6 BA: 8.5 J x 20 H2
Wheel offset: 1.50 in (38 mm)
BA: 255/40 R20 101 V XL M+S
004D6 BA: 8.5 J x 20 H2
Wheel offset: 1.54 in (39 mm)
FA: 255/40 R20 101 V XL M+S
004D6
RA: 285/35 R20 104 V XL M+S 004D5, 6 FA: 8.5 J x 20 H2
Wheel offset: 1.50 in (38 mm)
RA: 9.5 J x 20 H2
Wheel offset: 1.50 in (38 mm)
FA: 255/40 R20 101 V XL M+S
004D6
RA: 285/35 R20 104 V XL M+S 004D5, 6 FA: 8.5 J x 20 H2
Wheel offset: 1.54 in (39 mm)
RA: 9.5 J x 20 H2
Wheel offset: 1.54 in (39 mm)
6
Observe notes on "Large wheels" under "General notes" in "Wheel/tire combination".
5 The use of snow chains is not permitted. Observe the notes in the "Snow chains" section. 420
Wheel and tire combinationsWheels and tires

Useful information
............................422
Information regarding technical
data .................................................... 422
Identification plates .........................422
Service products and filling capaci-
ties ..................................................... 423
Vehicle data ...................................... 429 421Technical data

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible. Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Read the information on qualified
specialist workshops: (Y page 27).Information regarding technical data
i The data stated here specifically refers to
a vehicle with standard equipment. Consult
an authorized Mercedes-Benz Center for
the data for all vehicle variants and trim
levels. Identification plates
Vehicle identification plate with
vehicle identification number (VIN)
X
Open the driver's door.
You will see vehicle identification plate 0043. USA only
0044 VIN
0087 Paint code Canada only
0044 VIN
0087 Paint code
i The data shown on the vehicle
identification plate is used only as an
example. This data is different for every
vehicle and can deviate from the data
shown here. You can find the data
applicable to your vehicle on the vehicle
identification plate. 422
Identification platesTechnical data

VIN
X
Open the front right-hand door.
X Fold cover 0043down and remove it.
You will see the VIN.
The VIN can also be found in the following
locations:
R on the lower edge of the windshield
(Y page 423)
R on the vehicle identification plate
(Y page 422) Engine number
0043
Engine number (stamped into the
crankcase)
0044 VIN (on the lower edge of the windshield)
0087 Emission control information plate,
including the certification of both federal
and Californian emissions standards Service products and filling
capacities
Important safety notes
G
WARNING
Comply with all valid regulations with respect
to handling, storing and disposing of service
fluids. Otherwise, you could endanger
persons or the environment.
Keep service fluids out of the reach of
children.
For health reasons, you should prevent
service fluids from coming into direct contact
with your skin or clothing.
If a service fluid is swallowed, contact a
physician immediately. H
Environmental note
Dispose of service products in an
environmentally responsible manner.
Service products include the following:
R Fuels
R Lubricants (e.g. engine oil, transmission oil)
R Coolant
R Brake fluid
R Windshield washer fluid
R Climate control system refrigerant
Components and service products must be
matched. You should therefore only use
products that have been tested and approved
by Mercedes-Benz.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved
by Mercedes-Benz by the following
inscription on the containers:
R MB-Freigabe (e.g. MB-Freigabe 229.51)
R MB Approval (e.g. MB Approval 229.51)
Other designations or recommendations
indicate a level of quality or a specification in
accordance with an MB Sheet number (e.g. Service products and filling capacities
423Technical data Z

MB 229.5). They have not necessarily been
approved by Mercedes-Benz. Fuel
Important safety notes G
WARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and
explosion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before
refueling. G
WARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come
into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
R Wash away fuel from skin immediately
using soap and water.
R If fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance
without delay.
R If fuel is swallowed, seek medical
assistance without delay. Do not induce
vomiting.
R Immediately change out of clothing which
has come into contact with fuel.
Tank capacity Model Total capacity
AMG vehicles
20.6 US gal
(78.0 l) All other models
21.1 US gal
(80.0 l) Model Of which
reserve AMG vehicles
Approx.
3.7 US gal (14.0 l) All other models
Approx.
2.1 US gal (8.0 l) Gasoline
Fuel grade
!
Do not use diesel to refuel vehicles with a
gasoline engine. Do not switch on the
ignition if you accidentally refuel with the
wrong fuel. Otherwise, the fuel will enter
the fuel system. Even small amounts of the
wrong fuel could result in damage to the
fuel system and the engine. Notify a
qualified specialist workshop and have the
fuel tank and fuel lines drained completely.
! Only refuel using unleaded gasoline with
a minimum octane rating of 91.
! Only use the fuel recommended.
Operating the vehicle with other fuels can
lead to engine failure.
! Do not use the following:
R E85 (gasoline with 85% ethanol)
R E100 (100% ethanol)
R M15 (gasoline with 15% methanol)
R M30 (gasoline with 30% methanol)
R M85 (gasoline with 85% methanol)
R M100 (100% methanol)
R Gasoline with metalliferous additives
R Diesel
Do not mix such fuels with the fuel
recommended for your vehicle. Do not use
additives. This can otherwise lead to engine
damage. This does not include cleaning
additives for the removal and prevention of
residue build-up. gasoline may only be
mixed with cleaning additives
recommended by Mercedes-Benz; see 424
Service products and filling capacitiesTechnical data

"Additives". You can obtain further
information from any authorized Mercedes-
Benz Center.
! To ensure the longevity and full
performance of the engine, only premium-
grade unleaded gasoline must be used.
If standard unleaded gasoline is
unavailable and you have to refuel with
unleaded gasoline of a lower grade,
observe the following precautions:
R Only fill the fuel tank to half full with
regular unleaded gasoline and fill the rest
with premium-grade unleaded gasoline
as soon as possible.
R Do not drive at the maximum speed.
R Avoid sudden acceleration and engine
speeds over 3,000 rpm.
Using mixtures of methanol and ethanol is not
permitted. E10 fuel or E15 fuel (unleaded
gasoline with 10% or 15% ethanol) can be
used.
You will usually find information about the fuel
grade on the pump. If you cannot find the
label on the pump, ask the staff for
assistance.
i For further information, consult a
qualified specialist workshop or visit
http://www.mbusa.com (USA only).
Information on refueling (Y page 188).
AMG vehicles
Additives
! Operating the engine with fuel additives
added later can lead to engine failure. Do
not mix fuel additives with fuel. This does
not include additives for the removal and
prevention of residue buildup. gasoline
must only be mixed with additives
recommended by Mercedes-Benz. Comply
with the instructions for use on the product
label. More information about
recommended additives can be obtained
from any authorized Mercedes-Benz
Center. Mercedes-Benz recommends that you use
branded fuels that have additives.
The quality of the fuel available in some
countries may not be sufficient. Residue
could build up in the injection system as a
result. In such cases, and in consultation with
an authorized Mercedes-Benz Center, the
gasoline may be mixed with the cleaning
additive recommended by Mercedes-Benz.
You must observe the notes and mixing ratios
specified on the container. Engine oil
General notes !
Never use engine oil or an oil filter of a
specification other than is necessary to
fulfill the prescribed service intervals. Do
not change the engine oil or oil filter in
order to achieve longer replacement
intervals than those prescribed. You could
otherwise cause engine damage or damage
to the exhaust gas aftertreatment.
Follow the instructions in the service
interval display regarding the oil change.
Otherwise, you may damage the engine and
the exhaust gas aftertreatment.
When handling engine oil, observe the
important safety notes on service products
(Y page 423).
The engine oils are matched to the
performance of Mercedes-Benz engines and
service intervals. You should therefore only
use engine oils and oil filters that are
approved for vehicles with maintenance
systems.
For a list of approved engine oils and oil filters,
consult an authorized Mercedes-Benz
Center. Or visit the website
http://bevo.mercedes-benz.co m.
The table shows which engine oils have been
approved for your vehicle. Service products and filling capacities
425Technical data Z

Missing values were not available at time of
going to print. Model Engine
model MB
Approval AMG vehicles
157 229.5
All other models
278 229.5
i
MB approval is indicated on the oil
containers.
Filling capacities The following values refer to an oil change
including the oil filter.
Model Capacity
AMG vehicles
Without external oil
cooler: 9.0 US qt (8.5 l) All other models
8.5 qt (8.0 l)
Additives
!
Do not use any additives in the engine oil.
This could damage the engine.
Engine oil viscosity Viscosity describes the flow characteristics
of a fluid. If an engine oil has a high viscosity,
this means that it is thick; a low viscosity
means that it is thin.
Select an engine oil with an SAE classification
(viscosity) suitable for the prevailing outside
temperatures. The table shows you which SAE classifications are to be used. The low-
temperature characteristics of engine oils
can deteriorate significantly, e.g. as a result
of aging, soot and fuel deposits. It is therefore
strongly recommended that you carry out
regular oil changes using an approved engine
oil with the appropriate SAE classification.
Brake fluid
G
WARNING
Over a period of time, the brake fluid absorbs
moisture from the air; this lowers its boiling
point.
If the boiling point of the brake fluid is too low,
vapor pockets may form in the brake system
when the brakes are applied hard (e.g. when
driving downhill). This would impair braking
efficiency.
You should have the brake fluid renewed at
regular intervals. The brake fluid change
intervals can be found in the Maintenance
Booklet.
Only use brake fluid approved by Mercedes-
Benz according to MB Approval 331.0.
Information about approved brake fluid can
be obtained at any qualified specialist
workshop or on the Internet at
http://bevo.mercedes-benz.com.
i Have the brake fluid renewed regularly at
a qualified specialist workshop. Coolant
Important safety notes G
WARNING
If antifreeze comes into contact with hot
components in the engine compartment, it
may ignite. There is a risk of fire and injury.
Let the engine cool down before you add
antifreeze. Make sure that antifreeze is not
spilled next to the filler neck. Thoroughly 426
Service products and filling capacitiesTechnical data

clean the antifreeze from components before
starting the engine.
! Only add coolant that has been premixed
with the desired antifreeze protection. You
could otherwise damage the engine.
Further information on coolants can be
found in the Mercedes-Benz Specifications
for Service Products, MB Specifications for
Service Products 310.1, e.g. on the
Internet at
http://bevo.mercedes-benz.com. Or
contact a qualified specialist workshop.
! Always use a suitable coolant mixture,
even in countries where high temperatures
prevail.
Otherwise, the engine cooling system is not
sufficiently protected from corrosion and
overheating.
i Have the coolant regularly replaced at a
qualified specialist workshop and the
replacement confirmed in the Maintenance
Booklet.
The coolant is a mixture of water and
antifreeze/corrosion inhibitor. It performs
the following tasks:
R corrosion protection
R antifreeze protection
R raising the boiling point
If the coolant has antifreeze protection down
to -35 ‡ (-37 †),the boiling point of the
coolant during operation is approximately
266 ‡ (130 †).
The an tifreeze/corrosion inhibitor
concentration in the engine cooling system
should:
R be at least 50%. This will protect the engine
cooling system against freezing down to
approximately -35 ‡ (-37 †).
R no t exceed 55% (antifreeze protection
down to -49 ‡ [-45 †]). Otherwise, heat
will no t be dissipated as effectively.
Mercedes-Benz recommends an antifreeze/
corrosion inhibitor concentrate in accordance with
MB Specifications for Service Products 310.1.
i
When the vehicle is first delivered, it is
filled with a coolant mixture that ensures
adequate antifreeze and corrosion
protection.
i The coolant is checked with every
maintenance interval at a qualified
specialist workshop.
Filling capacities Missing values were not available at time of
going to print.
Model Capacity
AMG vehicles
12.6 US qt (11.5 l)
All other models
12.8 US qt (12.1 l)
i
Use MB 325.0 or MB 326.0 corrosion
inhibitor/antifreeze. Washer fluid
Important safety notes G
WARNING
Windshield washer concentrate is highly
flammable. If it comes into contact with hot
engine components or the exhaust system it
could ignite. There is a risk of fire and injury.
Make sure that no windshield washer
concentrate is spilled next to the filler neck.
! Only use washer fluid that is suitable for
plastic lamp lenses, e.g. MB SummerFit or
MB WinterFit. Unsuitable washer fluid
could damage the plastic lenses of the
headlamps.
! Do not add distilled or de-ionized water to
the washer fluid container. Otherwise, the
level sensor may be damaged.
! Only MB SummerFit and MB WinterFit
washer fluid should be mixed together. The Service products and filling capacities
427Technical data Z

spray nozzles may otherwise become
blocked.
At temperatures above freezing:
X Fill the washer fluid reservoir with a mixture
of water and windshield washer fluid, e.g.
MB SummerFit.
Add 1 part MB SummerFit to 100 parts water.
At temperatures below freezing:
X Fill the washer fluid reservoir with a mixture
of water and washer fluid, e.g. MB
WinterFit.
Adapt the mixing ratio to the outside
temperature.
R Down to 14 ‡ (00F810 †): mix 1 part MB
WinterFit to 2 parts water.
R Down to 00F84 ‡ (00F820 †): mix 1 part MB
WinterFit to 1 part water.
R Down to 00F820.2 ‡ (00F829 †): mix 2 parts MB
WinterFit to 1 part water.
i Add windshield washer fluid, e.g. MB
SummerFit or MB WinterFit, to the washer
fluid all year round. Climate control system refrigerant
Important safety notes The climate control system of your vehicle is
filled with refrigerant R-134a.
The instruction label regarding the refrigerant
type used can be found on the radiator cross
member.
! Only the refrigerant R-134a and the PAG
oil approved by Mercedes-Benz may be
used. The approved PAG oil may not be
mixed with any other PAG oil that is not
approved for R-134a refrigerant.
Otherwise, the climate control system may
be damaged.
Service work, such as topping-up refrigerant
or replacing components, may only be carried
out by a qualified specialist workshop. All applicable regulations must be adhered to,
SAE standard J639 included.
Always have work on the climate control
system carried out at a qualified specialist
workshop.
Refrigerant instruction label
Example: refrigerant instruction label
0043
Warning symbol
0044 Refrigerant filling capacity
0087 Applicable SAE standards
0085 PAG oil part number
0083 Type of refrigerant
Warning symbols 0043indicate:
R possible dangers
R having service work carried out at a
qualified specialist workshop
Filling capacities Vehicles without rear-
compartment air
conditioning system Capacity
Refrigerant
23.3 ± 0.4 oz
(660 ± 10 g) PAG oil
3.9 oz
(110 g) 428
Service products and filling capacitiesTechnical data