MERCEDES-BENZ S-CLASS SEDAN 2012 Owners Manual

Setting the temperature in the rear
compartment using the front control
panelXTurn the SmartKey to position 2 in the
ignition lock.XActivate the "rear Y" function via
COMAND ( Y page 273).
Using the "rear Y" function, the rear-
compartment climate control can be
controlled via the front control panel.XTo increase/reduce: press the w
rocker switch up or down.
Only change the temperature setting in
small increments. Start at 72 ‡ (22 † ).
i To return to the standard display, activate
the front climate control function via
COMAND ( Y page 273).
i The rear display changes to the standard
display automatically after five seconds.
Setting the temperature in the rear
compartment using the rear control
panel
XTurn the SmartKey to position 2 in the
ignition lock.XTo increase/reduce: press rocker
switch H or M up or down ( Y page 295).
Only change the temperature setting in
small increments. Start at 72 ‡ (22 † ).
Setting the footwell temperature
The footwell temperature can be set via
COMAND ( Y page 272).
Setting the air distribution
Air distribution settings
The air distribution can be set individually for
the driver's and front-passenger sides.
¯Directs air through the defroster ventsPDirects air through the center and side
air ventsODirects the airflow through the
footwell air ventsSDirects air through the center, side and
footwell ventsaDirects air through the defroster and
footwell vents_Directs air through the defroster,
center, side and footwell ventsbDirects air through the defroster,
center and side air ventsWSets the air distribution to automatic
Setting the air distribution in the front/
rear compartment using COMAND
The air distribution can be set using COMAND
( Y page 270).
Setting the air distribution in the rear
compartment using the rear control
panel
XTurn the SmartKey to position 2 in the
ignition lock.XPress rocker switch I or L up or down
repeatedly ( Y page 295) until the desired
air distribution symbol is shown in the
display.
Setting the airflow
Setting the front-compartment airflow
using the front control panel
You can select different airflow settings for
the driver's and front-passenger sides as well
as for the rear compartment.
You can also use COMAND to set the airflow
( Y page 271).
XTurn the SmartKey to position 2 in the
ignition lock.XTo increase/reduce: press the K
rocker switch up or down.Operating the climate control systems299Climate controlZ

Setting the rear-compartment airflow
using the front control panelXTurn the SmartKey to position 2 in the
ignition lock.XActivate the Y rear compartment
function via COMAND ( Y page 273).
The rear-compartment climate control can
be controlled via the front control panel
using the Y rear compartment function.XTo increase/reduce: press the K
rocker switch up or down.
Setting the rear-compartment airflow
using the rear control panel
XTurn the SmartKey to position 2 in the
ignition lock.XTo increase/reduce: press rocker switch
J up or down ( Y page 295).
Defrosting the windshield
You can use this function to defrost the
windshield or to defrost the inside of the
windshield and the side windows.
i You should only select the defrosting
function until the windshield is clear again.
XTurn the SmartKey to position 2 in the
ignition lock.XTo switch on: press the ¬ rocker
switch up or down.
The indicator lamp in the ¬ rocker
switch lights up.
The climate control system switches to the
following functions:
R cooling with air dehumidification on
R high airflow 17
R high temperature 17
R air distribution to the windshield and
front side windows
R air-recirculation mode offXTo deactivate: press the ¬ rocker
switch up or down.
The indicator lamp in the ¬ rocker
switch goes out. The previously selected
settings come into effect again. The cooling
with air dehumidification function remains
on. Air-recirculation mode remains
deactivated.
or
XPress the w rocker switch up or down.
or
XPress the K rocker switch up or down.
MAX COOL maximum cooling
The MAX COOL function is only available in
vehicles for the USA.
MAX COOL is only operational when the
engine is running.
The MAX COOL function is activated
automatically:
R if climate control is set to automatic
( Ã ) on both sides
R if additional cooling is used
The display shows MAX COOL.
This is the quickest way to cool the vehicle
interior when the sliding sunroof and the side
windows are closed.
Defrosting the windows
Windows fogged up on the inside
XActivate the cooling with air
dehumidification function via COMAND
( Y page 271).XActivate automatic mode Ã.XIf the windows continue to fog up, activate
the defrosting function ( Y page 300).
i
You should only select this setting until
the windshield is clear again.
17 Depending on the outside temperature.300Operating the climate control systemsClimate control

Windows fogged up on the outsideXSwitch on the windshield wipers.XActivate automatic climate control.
iYou should only select this setting until
the windshield is clear again.
Rear window defroster
Activating/deactivating
GWARNING
Any accumulation of snow and ice should be
removed from the rear window before driving.
Visibility could otherwise be impaired,
endangering you and others.
The rear window defroster has a high current
draw. You should therefore switch it off as
soon as the window is clear. Otherwise, the
rear window defroster switches off
automatically after several minutes.
If the battery voltage is too low, the rear
window defroster may switch off.
XTurn the SmartKey to position 2 in the
ignition lock.XPress the ¤ rocker switch up or down.
The indicator lamp in the ¤ rocker
switch lights up or goes out.
Problems with the rear window
defroster
The rear window defroster has deactivated
prematurely or cannot be activated.
XSwitch off any consumers that are not
required, e.g. reading lamps or interior
lighting.
When the battery is sufficiently charged,
the rear window defroster is activated
again automatically.Activating/deactivating air-
recirculation mode
You can deactivate the flow of fresh air if
unpleasant odors are entering the vehicle
from outside. The air already inside the
vehicle will then be recirculated.GWARNING
Fogged windows impair visibility,
endangering you and others. If the windows
begin to fog on the inside, switching off the
air recirculation mode immediately should
clear interior window fogging. If interior
window fogging persists, make sure the air
conditioning is activated, or press the ¬
button.
XTurn the SmartKey to position 2 in the
ignition lock.XTo activate: press the g rocker switch
up or down.
The indicator lamp in the g rocker
switch lights up.
i Air-recirculation mode is activated
automatically at high outside
temperatures. The indicator lamp in the
g rocker switch is not lit when
automatic air-recirculation mode is
activated.
Outside air is added after about
30 minutes.
X To deactivate: press the g rocker
switch up or down.
The indicator lamp in the g rocker
switch goes out.Operating the climate control systems301Climate controlZ

iAir-recirculation mode deactivates
automatically:
R after approximately five minutes at
outside temperatures below
approximately 41 ‡ (5 †)
R after approximately five minutes if
cooling with air dehumidification is
deactivated
R after approximately 30 minutes at
outside temperatures above
approximately 41 ‡ (5 †)
Activating/deactivating the residual
heat function
It is possible to make use of the residual heat
of the engine to continue heating the
stationary vehicle for up to 30 minutes after
the engine has been switched off. The heating
time depends on the temperature that has
been set.
i The blower will run at a low speed
regardless of the airflow setting.
i If you activate the residual heat function
at high temperatures, only the ventilation
will be activated. The blower runs at
medium speed.
XTurn the SmartKey to position 0 in the
ignition lock or remove it.XTo activate: press the Ì rocker switch
up or down.
The indicator lamp in the Ì rocker
switch lights up.XTo deactivate: press the Ì rocker
switch up or down.
The indicator lamp in the Ì rocker
switch goes out.
i Residual heat is deactivated
automatically:
R after about 30 minutes
R when the ignition is switched on
R if the battery voltage drops
R if the coolant temperature is too low
Setting the air vents
Important safety notes
GWARNING
When operating the climate control, the air
that enters the passenger compartment
through the air vents can be very hot or very
cold (depending on the set temperature). This
could cause burns or frostbite to unprotected
skin in the immediate area of the air vents.
Always keep sufficient distance between
unprotected parts of the body and the air
vents. If necessary, use the air distribution
adjustment to direct the air to air vents in the
vehicle interior that are not in the immediate
area of unprotected skin.
In order to ensure the direct flow of fresh air
through the air vents into the vehicle interior,
please observe the following notes:
R keep the air intake grille on the hood free
of blockages, such as ice, snow or leaves
R never cover the air vents or air intake grille
in the vehicle interior.
i For virtually draft-free ventilation, adjust
the sliders of the air vents to the center
position.
Setting the center air vents
:Fixed center air vent;Center air vent, right=Center vent thumbwheel, right302Setting the air ventsClimate control

?Center vent thumbwheel, leftACenter air vent, leftXTo open/close: turn thumbwheels =
and ? up or down.
Setting the side air vents
XTo open/close: turn thumbwheel = up or
down.
i Side window defroster vent : is never
completely shut, even if side air vent ; is
shut.
Setting the glove box air vent
When automatic climate control is activated,
the glove box can be ventilated, for instance
to cool its contents. The level of airflow
depends on the airflow and air distribution
settings.
! Close the air vent when heating the
vehicle.
At high outside temperatures, open the air
vent and activate the "cooling with air
dehumidification" function. Otherwise,
temperature-sensitive items stored in the
glove box could be damaged.
XTo open: turn thumbwheel : counter-
clockwise from position 3 to position 2.XTo close: turn thumbwheel : clockwise
from position 2 to position 3.
Setting the rear-compartment air
vents
Setting the center vents in the rear
compartment
:Rear-compartment air vent, left;Rear-compartment air vent, right=Rear-compartment air vent thumbwheel,
right?Rear control panel for automatic climate
controlARear-compartment air vent thumbwheel,
leftXTo open/close: turn thumbwheel = or
A to the right or left.
i
In vehicles without rear-compartment air-
conditioning system: close the rear-
Setting the air vents303Climate controlZ

compartment air vents when heating mode
is activated, as no warm air flows through
the rear vents in the basic heating setting.
Setting the B-pillar air vents:B-pillar air vent;Thumbwheel for B-pillar air ventXTo open/close: turn thumbwheel ; to the
left or right.304Setting the air ventsClimate control

Useful information ............................306
Breaking-in notes .............................. 306
Driving ............................................... 306
Automatic transmission ...................314
Refueling ............................................ 321
Parking ............................................... 327
Driving tips ........................................ 330
Driving systems ................................ 334305Driving and parking

Useful information
i This Operator's Manual describes all
models and all standard and optional
equipment of your vehicle available at the
time of publication of the Operator's
Manual. Country-specific differences are
possible. Please note that your vehicle may
not be equipped with all features
described. This also applies to safety-
related systems and functions.
i Please read the information on qualified
specialist workshops ( Y page 31).
Breaking-in notes
The first 1,000miles (1,500 km)
The more you look after the engine when it is
new, the more satisfied you will be with its
performance in the future.
R You should therefore drive at varying
vehicle and engine speeds for the first
1,000miles (1,500km).
R Avoid overstraining the vehicle during this
period, e.g. driving at full throttle.
R Change gear in good time, before the
tachometer needle is Ô of the way to the
red area of the tachometer.
R Do not manually shift to a lower gear to
brake the vehicle.
R If possible, do not depress the accelerator
pedal past the point of resistance
(kickdown).
R Only select shift ranges 3, 2 or 1 when
driving slowly, e.g. in mountainous terrain.
R If possible, for the first 1,000miles
(1,500km), drive in drive program E (in
AMG vehicles in drive program C).
After 1,000 miles (1,500km), you can
increase the engine speed gradually and bring
the vehicle up to full speed.
Additional breaking-in notes for AMG
vehicles:
R do not drive faster than 85 mph
(140 km/h) for the first 1,000 miles
(1,500 km).
R only allow the engine to reach a maximum
engine speed of 4,500 rpm briefly.
R change gear in good time.
i You should also observe these breaking-
in notes if the engine or parts of the drive
train on your vehicle have been replaced.
i Always observe the respective speed
restrictions.
Driving
Important safety notes
GWARNING
Make sure absolutely no objects are
obstructing the pedals' range of movement.
Keep the driver's footwell clear of all
obstacles. If there are any floormats or
carpets in the footwell, make sure the pedals
still have sufficient clearance.
During sudden driving or braking maneuvers
the objects could get caught between the
pedals. You could then no longer brake or
accelerate. This could lead to accidents and
injury.
GWARNING
On slippery road surfaces, never downshift in
order to obtain braking action. This could
result in drive wheel slip and reduced vehicle
control. Your vehicle's ABS will not prevent
this type of loss of control.
GWARNING
It is dangerous to shift the automatic
transmission out of parking position P or
neutral position N if the engine speed is
higher than idle speed. If your foot is not firmly
on the brake pedal, the vehicle could
accelerate quickly forward or in reverse. You
306DrivingDriving and parking

could lose control of the vehicle and hit
someone or something. Only shift into gear
when the engine is idling normally and when
your right foot is firmly on the brake pedal.GWARNING
HYBRID vehicles: It is imperative that you read
the HYBRID Supplemental Operating
Instructions included in your vehicle literature
portfolio. You may otherwise not receive all
necessary safety information and warning for
the operation of your vehicle.
! Warm up the engine quickly. Do not use
the engine's full performance until it has
reached operating temperature.
Only shift the automatic transmission to
the desired drive position when the vehicle
is stationary.
Where possible, avoid spinning the drive
wheels when pulling away on slippery
roads. You could otherwise damage the
drive train.
! S 63 AMG: at low engine oil temperatures
below 68 ‡ (+20 † ), the maximum engine
speed is restricted in order to protect the
engine. To protect the engine and maintain
smooth engine operation, avoid driving at
full throttle when the engine is cold.
SmartKey positions
SmartKeygTo remove the SmartKey1Power supply for some consumers, such
as the windshield wipers2Ignition (power supply for all consumers)
and drive position3To start the engine
i The SmartKey can be turned in the
ignition lock even if it is not the correct
SmartKey for the vehicle. The ignition is not
switched on. The engine cannot be started.
KEYLESS-GO
General information
Vehicles with KEYLESS-GO are equipped with
a SmartKey featuring an integrated KEYLESS-
GO function and a detachable Start/Stop
button.
The Start/Stop button must be inserted into
the ignition lock and the SmartKey must be in
the vehicle.
Pressing the Start/Stop button several times
in succession corresponds to the different
SmartKey positions in the ignition lock. This
is only the case if you are not depressing the
brake pedal.
If you depress the brake pedal and press the
Start/Stop button, the engine starts
immediately.
The Start/Stop button can be removed from
the ignition lock. Then, you can insert the
SmartKey into the ignition lock.
Driving307Driving and parkingZ

iYou do not have to remove the Start/Stop
button from the ignition lock when you
leave the vehicle. However, you should
always take the SmartKey with you when
leaving the vehicle. The vehicle can be
started with the Start/Stop button and the
electrical equipment can be operated while
the SmartKey is in the vehicle.:Start/Stop button;Ignition lockXInsert Start/Stop button : into ignition
lock ;.
i
When you insert Start/Stop button :
into ignition lock ;, the system requires a
detection time of approximately
two seconds before you can use Start/
Stop button :.
Start/Stop button
=USA only?Canada onlyXPosition 0: if Start/Stop button : has not
yet been pressed, this corresponds to the
SmartKey being removed from the ignition.XPosition 1: press Start/Stop button :.
You can now activate the windshield
wipers, for example.
i If you then open the driver's door when in
this position, the power supply is
deactivated.
XPosition 2 (ignition): press Start/Stop
button : twice.
i
If you press Start/Stop button : once
when in this position and the driver's door
is open, the power supply is deactivated
again.
As soon as the ignition is switched on, all the
indicator lamps in the instrument cluster light
up. If an indicator lamp does not go out after
the engine is started or if it lights up while the
vehicle is in motion, see ( Y page 424).
Starting the engine
Important safety notes
GWARNING
Inhalation of exhaust gas is hazardous to your
health. All exhaust gas contains carbon
monoxide (CO), and inhaling it can cause
unconsciousness and possible death.
Do not run the engine in confined areas (such
as a garage) which are not properly ventilated.
If you think that exhaust gas fumes are
entering the vehicle while driving, have the
cause determined and corrected
immediately. If you must drive under these
conditions, drive only with at least one
window fully open at all times.
! Do not depress the accelerator pedal
when starting the engine.
308DrivingDriving and parking