AUX MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

Problems with the transmission
ProblemPossible causes/consequences andMSolutions
The transmission has
problems shifting gear.The transmission is losing oil.
XHave the transmission checked at a qualified specialist workshop
immediately.
The acceleration ability
is deteriorating.
The transmission no lon-
ger changes gear.The transmission is in emergency mode.
7G-TRONIC:it is only possible to shift into secondgear and reverse
gear.
9G-TRONIC: it is only partly possible to engage the gears or the trans-
mission is in position N.
XStop the vehicle.
XShift the transmission to position P.
XSwitch off the engine.
XWait at least ten seconds before restarting the engine.
XShift the transmission to positionDor R.
7G-TRONIC: IfD is selected, the transmission shifts into second
gear, if Ris selected, the transmission shifts into reverse gear.
XHave the transmission checked at a qualified specialist workshop
immediately.
Problems with PLUG-IN HYBRID operation (Ypage 254).
Transfer case
This section is only valid for vehicles with 4-
wheel drive (4MATIC). Power is always trans-
mitted to both axles.
!Performance tests may only be carried out
on a 2-axle dynamometer. The brake system
or transfer case could otherwise be damaged. Contact a qualified specialist workshop for a
performance test.
!Since ESP®engages automatically, the igni-
tion must be switched off (the SmartKey or
Start/Stop button must be in position 0or 1)
if:
Rthe electric parking brake is being tested
on a brake dynamometer
Rthe vehicle is being towed with only one
axle raised (not permitted for vehicles with
4MATIC).
The brake system could otherwise be dam-
aged.
!Vehicles with 4MATIC must not be towed
with either the front or the rear axle raised, as doing so will damage the transmission.
Refueling
Important safety notes
GWARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and explo-
sion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before refueling.
GWARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come into contact with your skin, eyes or clothing
Refueling177
Driving and parking
Z

sponds to an equivalent quality standard. Brake
fluid which has not been approved for
Mercedes-Benz vehicles or which is not of an
equivalent quality could affect your vehicle's
operating safety.
AMG high-performance and ceramic
brakes
The high-performance brake system is only
available on Mercedes-AMG vehicles.
The AMG brake systems are designed for heavy
loads. This may lead to noise when braking. Thiswill depend on:
RSpeed
RBraking force
REnvironmental conditions, such as tempera-
ture and humidity
The wear of individual components of the brake
system, such as the brake pads/linings or brake
discs, depends on the individual driving style
and operating conditions.
For this reason, it is impossible to state a mile-
age that will be valid under all circumstances. An
aggressive driving style will lead to high wear.
You can obtain more information on this from a
qualified specialist workshop.
New and replaced brake pads and discs only
reach their optimum braking effect after several
hundred kilometers of driving. Compensate for
this by applying greater force to the brake pedal.
Keep this in mind, and adapt your driving and
braking accordingly during this break-in period. Excessive heavy braking results in correspond-
ingly high brake wear. Observe the brake wear
warning lamp in the instrument cluster and note
any brake status messages in the multifunction
display. Especially for high performance driving,
it is important to maintain and have the brake
system checked regularly.
Driving on wet roads
Hydroplaning
If water has accumulated to a certain depth on
the road surface, there is a danger of hydro-
planing occurring, even if:
Ryou drive at low speeds
Rthe tires have adequate tread depth For this reason, in the event of heavy rain or in
conditions in which hydroplaning may occur,
you must drive in the following manner:
Rlower your speed
Ravoid ruts
Ravoid sudden steering movements
Rbrake carefully
Driving on flooded roads
!Do not drive through flooded areas. Check
the depth of any water before driving through
it. Drive slowly through standing water. Oth-
erwise, water may enter the vehicle interior or
the engine compartment. This can damage
the electronic components in the engine or
the automatic transmission. Water can also
be drawn in by the engine's air suction nozzles
and this can cause engine damage.
Winter driving
GWARNING
If you shift down on a slippery road surface in an attempt to increase the engine's braking
effect, the drive wheels could lose their grip.
There is an increased danger of skidding and
accidents.
Do not shift down for additional engine brak-
ing on a slippery road surface.
GDANGER
If the exhaust pipe is blocked or adequate
ventilation is not possible, poisonous gases
such as carbon monoxide (CO) may enter the vehicle. This is the case, e.g. if the vehicle
becomes trapped in snow. There is a risk of
fatal injury.
If you leave the engine or the auxiliary heating
running, make sure the exhaust pipe and area
around the vehicle are clear of snow. To
ensure an adequate supply of fresh air, open a
window on the side of the vehicle that is not
facing into the wind.
Have your vehicle winter-proofed at a qualified
specialist workshop at the onset of winter.
196Driving tips
Driving and parking

Automa tic engine start
The automatically switched-off internal combus -
tio nengin estart sautomatically in certai nsitua-
tions ,if:
Rth epower demand from th edriver via th e
accelerato rpedal is greate rthan th eelectric
motor alon ecan provide
Rth edriver switches to driv eprogram Sor M
Rthecondition of charge of th ehigh-voltage
battery has reached th elower limit
Rth esettings of th eautomatic climat econtrol
require it, e.g. at external temperatures abov e
30 †
Overru nmod e
In overrun mode, th ecombustio nengin eis
switched off and is disconnected from th edriv e
train. The electric motor:
Rgenerates low thrust ,whic hcorrespond sto
th eoverrun mod eof an active combustio n
engin e
Rfunction sas agenerator and produce sth e
necessary energ yfor th eauxiliary consumer s
and charge sth ehigh-voltage battery
Ove rrun mod eis possible in th efollowin gspee d
range:
Rin driv eprogram Ebelow 81 mph (13 0km/h)
Rin driv eprogram E+below 11 2mph
(18 0km/h)
In driv eprogram E+,after th eaccelerato rpedal
has been released th ecoasting characteristic s
of th evehicl eare adapted to th etraffic condi-
tions .Further information about th ehaptic
accelerato r
p
edal (Ypage 251).
Route-based operating strategy
Forth eroute-based operating strategy, th esys-
te m factors in information about th eexpecte d
rout ewhen rout eguidance is active.
The information on th erout eis provide dby th e
multimedia system and includes th efollowing:
Rroad categories
Rspee dlimitation s
Rdataon downhill gradients The use of electric energ
yis automatically opti-
mally distributed from th ebeginnin gto th een d
of th ejourney, usin ginformation about th e
route. The distribution is pre-emptive and takes
int oconsideration :
Rthesections of th ejourney ahead
Rth eenerg yconsumption on th ewhole rout e
The condition of charge of th ehigh-voltage bat -
tery is thus systematically controlled. In addi-
tion, th econtrol function takes int oaccoun t
that:
Rth efuel saving sthroug hth euse of electrical
energ ycan vary, depending on th erout e(e.g.
urban ,interurban or highway)
Rth euse of electrical energ yis held available in
particular for electric operation (e.g. urban
routes)
The vehicl ethus automatically select sth eopti-
mum driving mod efor th erespectiv esectio nof
th eroute.
The route-based operating strategy is available
under th efollowin gconditions:
Rdriv eprogram E+is selected
RHYBRID driving mod eis selected
Ractive rout eguidance is activated
Rsuitable map dat ais available
When th eroute-based operating strategy is
bein gused, th earea in fron tof th evehicl eis
shown as green in th emultifunction display.
Parking
XApply th eelectric parking brake.
The red !indicator lamp in th einstrumen t
cluste rlight sup.
XUse th eDIRECT SELECT leve rto shif tth e
automatic transmission to P.
XSwitch theignition off .
The READY indicator in th einstrumen tcluste r
goes out .
Further information on parking and switching off
th einternal combustio nengin e (
Ypage 190).
PLUG‑ IN HYBRID operation253
Driving and parking
Z

You can change the media source and playback
mode (audio, video or TV) at any time in the
Media
menu.
XSwitch on the multimedia system (see sepa-
rate operating instructions).
XPress theòbutton on the steering wheel
to open the menu list.
XPress :or9 on the steering wheel to
select the Mediamenu.
XConfirm by pressing aon the steering
wheel.
XTo open/close the media sources list:
press abriefly.
The list shows the following media sources,
for example:
RDisc (CD/DVD)
RSD memory card
RMedia Register
RUSB storage device
RBluetooth®capable audio device
Please observe further information on media
support and media operation in the multimedia
system (see separate operating instructions).
Operating an audio player or audio
media
:Media source, e.g. name of current CD
;Current title
=Name of artist
?Name of album
AFolder name Audio data from various audio devices or media
can be played, depending on the equipment
installed in the vehicle.
XSwitch on the multimedia system (see sepa-
rate operating instructions).
XPress the
òbutton on the steering wheel
to open the menu list.
XPress :or9 on the steering wheel to
select the Mediamenu.
XConfirm by pressing aon the steering
wheel.
XTo select an audio player or data carrier:
press abriefly.
The list containing the media sources
appears.
XPress :or9 to select the correspond-
ing audio player or media.
XPress ato confirm the selection.
XTo open the track list: press the:or
9 button briefly.
XTo select the next or previous track in the
track list: press the:or9 button
briefly.
XTo select a track from the track list using rapid scrolling: press and hold:or9
until the desired track is reached.
If you press and hold the button, the speed of
rapid scroll increases after a short time. Not
all audio drives or data carriers support this
function.
If the corresponding track information is stored
on the audio drive or audio media, the multi-
function display may display the following:
Rtrack number
Rtrack name
Rartist
Ralbum
The track information is not available in audio
AUX mode (Auxiliary audio mode: external
audio source connected).
266Menus and submenus
On-board computer and displays

Display messagesPossible causes/consequences andMSolutions
ServiceRequiredDoNot Shift GearsVisit Dealer
You canno tchang eth etransmission position due to amalfunction .
A warning tone also sounds.
If transmission position Dis selected:
XDrive to aqualified specialist workshop without shifting th etrans -
mission from position D.
If transmission position R,N or Pis selected:
XSecur eth evehicl eagainst rollin gaway (Ypage 189).
XNotify aqualified specialist workshop or breakdown service.
ReversingNotPossi‐bleServic eRequiredYou canno tshift int oth etransmission position Rdue to amalfunction .
The transmission position sP,N or Dcontinu eto be available.
A warning tone also sounds.
XVisit aqualified specialist workshop .
Transmission Mal‐function StopAmalfunction has occurred in th emechanical transmission compo -
nents.
A warning tone also sounds. The gearbox automatically shift sto posi-
tion N.
XPull ove rand stop th evehicl esafely as soo nas possible, payin g
attention to roa dand traffic conditions.
XShift th etransmission to position P.
XSecureth evehicl eagainst rollin gaway (Ypage 189).
XNotify aqualified specialist workshop or breakdown service.
Sto pVehicl eLeaveEngineRunnin gWaitTransmission Cool‐ing
PLUG-I NHYBRID vehicles:
The transmission has overheated. Pullin gaway can be temporarily
impaire dor no tpossible.
XPull ove rand stop th evehicl esafely as soo nas possible, payin g
attention to roa dand traffic conditions. Do no tcontinu edrivin g
under any circumstances.
XWait until th edisplay message disappear sbefore pullin gaway.
Auxiliary Batter yMalfunctionThe auxiliary battery for th etransmission is no longer bein gcharged.
XVisit aqualified specialist workshop .
XUntilthen ,set th etransmission to position Pbefore you switch off
th eengine.
XBefor eleaving th evehicle, apply th eelectric parking brake.
NThe trunk lid is open .
XCloseth etrunk lid.
Display messages30 9
On-board computer and displays
Z

Stowage compartment under the armrest
XTo open:press button :or; and fold the
armrest to the left or right.
Depending on the vehicle's equipment, a USB
port, an AUX-IN jack or a Media Interface are
installed in the stowage compartment. A Media Interface is a universal interface for portable
audio or video equipment, e.g. for an iPod
®,
iPhone®or MP3 player (see the separate multi-
media system operating instructions).
Stowage compartments in the doors
You can store items such as a rolled up fluores-
cent jacket and a small umbrella in stowage
compartment ;in the doors.
In doors :you can store bottles with a capacity
of up to 34 fl. oz. (1.0 liter).
Stowage space in the rear
Stowage compartment in the rear seat
armrest
Vehicles with a rear bench seat:
XTo open: fold down the seat armrest.
XPull handle :and fold the armrests upwards.
Vehicles with electrically adjustable outer seats:
XTo open: fold down the seat armrest.
XPull up on handle :and fold the armrest
upwards.
Stowage compartment in the rear-com-
partment center console
Stowage areas327
Stowage and features
Z

Vehicles with individual seats and center con-
sole in the rear
XPull up on handle:and fold the armrest
upwards.
Depending on the vehicle's equipment, a USB
port, an AUX-IN jack, a mobile phone bracket or
a 115 V or 230 V socket are installed in the
stowage compartment.
Stowage box in the rear seat backrest
!Do not sit on or support your body weight on
the rear seat armrest when it is folded down,
as you could otherwise damage it.
Vehicles with a rear bench seat:
XTo open: fold down the rear armrest.
XPull handle :and fold down cover ;.
Vehicles with electrically adjustable outer seats:
XTo open:fold down the rear armrest.
XPull handle :and fold down cover ;.
Vehicles with individual seats and center con-
sole in the rear:
XTo open:fold down the rear armrest.
XPull handle :and fold down cover ;.
Depending on the vehicle's equipment, a DVD
player is installed instead of a stowage com-
partment.
Folding table
GWARNING
If the folding table is folded out while the vehi-
cle is in motion, passengers can be thrown
against it, particularly in the event of an acci-
dent, heavy braking or a sudden change of
direction. There is a risk of injury.
Fold the folding table away before each jour-
ney.
XTo fold out: open rear armrest :
(Ypage 327).
XPull the folding table forwards and upwards by
recess ;or= and swing outwards.
XFold the table panels apart.
XTo fold in: fold the table panels together and
swing in the folding table.
328Stowage areas
Stowage and features

Other identifications, for example:
R0 W-30
R5 W-30
R5 W-40
Fuel
Important safety notes
GWARNING
Fuel is highly flammable. If you handle fuel
incorrectly, there is a risk of fire and explo-
sion.
You must avoid fire, open flames, creating
sparks and smoking. Switch off the engine
and, if applicable, the auxiliary heating before refueling.
GWARNING
Fuel is poisonous and hazardous to health.
There is a risk of injury.
You must make sure that fuel does not come into contact with your skin, eyes or clothing
and that it is not swallowed. Do not inhale fuel
vapors. Keep fuel away from children.
If you or others come into contact with fuel,
observe the following:
RWash away fuel from skin immediately
using soap and water.
RIf fuel comes into contact with your eyes,
immediately rinse them thoroughly with
clean water. Seek medical assistance with-
out delay.
RIf fuel is swallowed, seek medical assis-
tance without delay. Do not induce vomit-
ing.
RImmediately change out of clothing which
has come into contact with fuel.
Tank capacity
Missing values were not available at time of
going to print.
ModelTotal capacity
S 400 4MATIC
PLUG-IN HYBRID vehi-
cles16.6 US gal (63.0 l)
Allot her models21.1 US gal
(80.0 l)
ModelOf which
reserve
S 400 4MATIC
Mercedes‑AMG vehiclesApprox.
3.2 US gal (12.0 l)
Allot her modelsApprox.
2.1 US gal (8.0 l)
Gasoline
Fuel grade
!Do not use diesel to refuel vehicles with a
gasoline engine. Do not switch on the ignition
if you accidentally refuel with the wrong fuel.
Otherwise, the fuel will enter the fuel system.
Even small amounts of the wrong fuel could
result in damage to the fuel system and the
engine. Notify a qualified specialist workshop
and have the fuel tank and fuel lines drained
completely.
!Only refuel using unleaded premium grade
gasoline with at least 91 AKI/95 RON.
iE10 fuel contains up to 10% bioethanol.
Your vehicle is E10-compatible. You can
refuel your vehicle using E10 fuel.
!Only use the fuel recommended. Operating
the vehicle with other fuels can lead to engine
failure.
!Do not use the following:
RE15 (gasoline with 15% ethanol)
RE85 (gasoline with 85% ethanol)
RE100 (100% ethanol)
RM15 (gasoline with 15% methanol)
428Service products and filling capacities
Technical data