Passenger MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

1, 2, 3 ...
4ETS (Electronic Traction System)see ETS/4ETS (Electronic Trac-
tion System)
4MATIC (permanent four-wheel
drive) .................................................. 213
12 V socket
see Sockets
115 V socket ...................................... 337
360° camera
Cleaning ........................................ .363
Function/notes .............................2 24
A
ABS (Anti-lock Braking System)
Display message ............................ 278
Function/notes ................................ 68
Warning lamp ................................. 316
Accident
Automatic measures after an acci-
dent ................................................. 61
Activating/deactivating cooling
with air dehumidification ................. 146
Activating/deactivating Night
View Assist Plus
With spotlight function ................... 232
Active Blind Spot Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 234
Active Body Control (ABC)
Display message ............................ 300
Function/notes ............................. 210
Active Lane Keeping Assist
Activating/deactivating (on-
board computer) ............................ 271
Display message ............................ 301
Function/information .................... 237
Active multicontour seat .................. 117
Active Parking Assist
Detecting parking spaces .............. 217
Display message ............................ 302
Exiting a parking space .................. 219
Function/notes ............................. 216
Important safety notes .................. 216 Parking .......................................... 218
ADAPTIVE BRAKE ................................. 75
Adaptive Brake Assist
Function/notes ................................ 72
Adaptive Damping System (ADS) ..... 212
Adaptive Highbeam Assist Plus
Display message ............................ 293
Function/notes ............................. 133
Switching on/off ........................... 133
Additional speedometer ................... 274
Additives (engine oil) ........................ 430
Air bags
Belt bags .......................................... 48
Cushion air bags .............................. 53
Deployment ..................................... 57
Display message ............................ 289
Front air bag (driver, front
passenger) ....................................... 52
Important safety notes .................... 50
Introduction ..................................... 50
Knee bag .......................................... 52
Occupant Classification System
(OCS) ............................................... 53
PASSENGER AIR BAG i
ndicator
lamps ............................................... 46
Side impact air bag .......................... 52
Window curtain air bag .................... 53
Air vents
Glove box ....................................... 159
Important safety notes .................. 158
Rear ............................................... 160
Setting ........................................... 158
Setting the center air vents ........... 159
Setting the side air vents ............... 159
Air-conditioning system
see Climate control
AIRMATIC
Display message ............................ 299
Function/notes ............................. 212
Alarm
ATA (Anti-Theft Alarm system) ......... 78
Switching off (ATA) .......................... 78
Switching the function on/off
(ATA) ................................................ 78
Alarm system
see ATA (Anti-Theft Alarm system)
Anti-lock braking system
see ABS (Anti-lock Braking System)
Index3

Removing...................................... .185
Storing ...........................................1 83
Warming up ................................... 182
Charging the high-voltage battery
(important safety notes) ................... 180
Chauffeur mode
Display message ............................ 310
Fully reclined position .................... 114
General notes ................................ 111
Installing the head restraint ........... 113
Moving front-passenger seat into
the chauffeur position .................... 112
Moving the front-passenger seat
into the normal position ................. 113
Removing the head restraint .......... 113
Child
Restraint system .............................. 62
Child seat
Forward-facing restraint system ...... 66
LATCH-type (ISOFIX) child seat
anchors ............................................ 63
On the front-passenger seat ............ 65
Rearward-facing restraint system .... 66
Top Tether ....................................... 64
Child-proof locks
Important safety notes .................... 66
Rear doors ....................................... 67
Children
Special seat belt retractor ............... 62
Cigarette lighter ................................ 335
Cleaning
Mirror turn signal ........................... 362
Climate control
Automatic climate control ............. 141
Controlling automatically ............... 147
Cooling with air dehumidification .. 146
Defrosting the windows ................. 151
Defrosting the windshield .............. 151
ECO start/stop function ................ 145
General notes ................................ 140
Immediate pre-entry climate con-
trol ................................................. 158
Indicator lamp ................................ 147
Ionization ....................................... 155
Notes on using the automatic cli-
mate control .................................. 145
Overview of systems ...................... 140
Perfume atomizer .......................... 153 Pre-entry climate control at
departure time ............................... 157
Pre-entry climate control via
key ... 155
P

roblem with the rear window
defroster ........................................ 152
Problems with cooling with air
dehumidification ............................ 147
Rear control panel ......................... 141
Refrigerant ..................................... 432
Refrigerant filling capacity ............. 432
Setting the air distribution ............. 149
Setting the air vents ...................... 158
Setting the airflow ......................... 150
Setting the climate mode ............... 148
Setting the temperature ................ 148
Switching air-recirculation mode
on/off ............................................ 152
Switching on/off ........................... 145
Switching residual heat on/off ...... 152
Switching the rear window
defroster on/off ............................ 151
Switching the synchronization
function on and off ........................ 150
Climate control system
Climate control .............................. 145
Cockpit
Overview .......................................... 32
COLLISION PREVENTION ASSIST
PLUS
Activating/deactivating ................. 270
Display message ............................ 284
Operation/notes .............................. 71
COMAND display
Cleaning ......................................... 364
Combination switch .......................... 131
Consumption statistics (on-board
computer) .......................................... 262
Convenience closing feature .............. 96
Convenience opening feature ............ 95
Coolant (engine)
Checking the level ......................... 356
Display message ............................ 294
Displaying the temperature (on-
board computer) ............................ 269
Filling capacity ............................... 431
Important safety notes .................. 431
Temperature gauge ........................ 257
Warning lamp ................................. 320
6Index

F
Features............................................ .330
Filling capacities (Technical data) ... 427
Flat tire
Changing a wheel/mounting the
spare wheel ................................... 405
MOExtended tires .......................... 368
Preparing the vehicle ..................... 367
TIREFIT kit ...................................... 369
Floormats ...........................................3 50
Folding table ...................................... 328
Frequencies
Mobile phone ................................. 425
Two-way radio ................................ 425
Front-passenger seat
Adjusting from the driver's seat ..... 108
Adjusting from the rear compart-
ment .............................................. 108
Fuel
Additives ........................................ 429
Consumption statistics .................. 262
Displaying the current consump-
tion ................................................ 261
Displaying the range ......................2 61
Driving tips ....................................1 92
Fuel gauge ....................................... 33
Grade (gasoline) ............................ 428
Important safety notes .................. 428
Problem (malfunction) ................... 180
Refueling ........................................ 177
Tank content/reserve fuel ............. 428
Fuel level
Calling up the range (on-board
computer) ...................................... 261
Fuel tank
Capacity ........................................ 428
Problem (malfunction) ................... 180
Fuses
Allocation chart ..................... 381, 383
Before changing .............................3 82
Dashboard fuse box ....................... 382
Fuse box in the engine compart-
ment .............................................. 383
Fuse box in the front-passenger
footwell .......................................... 382
Fuse box in the trunk ..................... 383
Important safety notes .................. 381
G
Garage door opener
Clearing the memory ..................... 350
General notes ................................ 347
Important safety notes .................. 348
Opening/closing the garage door .. 350
Problems when programming ........3 49
Programming (button in the rear-
view mirror) ................................... 348
Synchronizing the rolling code ....... 349
Gasoline ............................................. 428
Gear indicator (on-board com-
puter, Mercedes-AMG vehicles) ....... 275
Genuine parts ...................................... 24
Glove box ...........................................3 26
H
Handbrake
see Parking brake
HANDS-FREE ACCESS .......................... 91
Hazard warning lamps ......................132
Head restraints
Adjusting ....................................... 114
Adjusting (manually) ......................1 15
Adjusting (rear) .............................. 116
EASY ADJUST luxury head
restraint ......................................... 115
Luxury ............................................ 115
Supplementary cushion ................. 116
Head-up display
Adjusting the brightness ................ 273
Displays and operating .................. 259
Function/notes .............................2 59
Important safety notes .................. 259
Selecting displays .......................... 273
Setting the position ....................... 273
Headlamps
Fogging up ..................................... 134
see Automatic headlamp mode
Heating
see Climate control
High beam flasher .............................1 32
High-beam headlamps
Adaptive Highbeam Assist PLUS .... 133
Display message ............................ 292
Switching on/off ........................... 132
10Index

Operation ......................................... 54
System self-test ...............................56
Occupant safety
Air bags ...........................................5 0
Automatic measures after an acci-
dent ................................................. 61
Children in the vehicle ..................... 61
Important safety notes .................... 45
Introduction to the restraint sys-
tem .................................................. 44
Occupant Classification System
(OCS) ............................................... 53
PASSENGER AIR BAG indicator
lamps ............................................... 46
Pets in the vehicle ........................... 67
PRE-SAFE
®(anticipatory occu-
pant protection) ............................... 59
PRE-SAFE
®PLUS (anticipatory
occupant protection PLUS) .............. 60
Restraint system warning lamp ........ 45
OCS
Conditions ....................................... 53
Faults ............................................... 57
Operation ......................................... 54
System self-test ............................... 56
Odometer ........................................... 261
Oil
see Engine oil
On-board computer
AMG menu ..................................... 275
Assistance graphic menu ............... 268
Assistance menu ........................... 269
Display messages .......................... 277
Displaying a service message ........ 358
DISTRONIC PLUS ........................... 204
Factory settings ............................. 275
Head-up display ............................. 259
HYBRID menu ................................ 272
Important safety notes .................. 256
Instrument cluster menu ............... 274
Lights menu ................................... 274
Media menu ................................... 265
Menu overview .............................. 261
Message memory .......................... 277
Navigation menu ............................ 263
Operation ....................................... 257
Radio menu ................................... 265 Service menu ................................. 269
Settings menu ............................... 269
Standard display ............................ 261
Telephone menu ............................ 267
Trip menu ...................................... 261
Video DVD operation ..................... 267
Online access to the vehicle
Data protection .............................. 188
Functions ....................................... 189
General informa tion ....................... 188
Inte

rnet .......................................... 189
Opening the fuel filler flap
(PLUG-IN HYBRID vehicles) ............ 179
Operating safety
Declaration of conformity ................ 28
Important safety notes .................... 27
Operating system
see On-board computer
Operator's Manual
Overview .......................................... 25
Vehicle equipment ........................... 25
Outside temperature display ........... 257
Overhead control panel ...................... 39
Override feature
Rear side windows ........................... 67
P
Paint code number ............................ 426
Paintwork (cleaning instructions) ... 361
Panic alarm .......................................... 44
Panorama roof with power tilt/
sliding panel
Important safety notes .................... 97
Opening/closing the roller sun-
blind ............................................... 100
Operating ......................................... 98
Operating the roller sunblinds for
the sliding sunroof ........................... 99
Problem (malfunction) ................... 103
Rain closing feature ......................... 99
Resetting ....................................... 102
Reversing feature ............................. 98
Parcel net hooks ............................... 329
Parking
Important safety notes .................. 189
Parking brake ................................ 190
14Index

Position of exterior mirror, front-
passenger side ...............................125
Rear view camera .......................... 220
Switching off the engine ................ 190
see PARKTRONIC
Parking aid
see 360° camera
see Active Parking Assist
see Exterior mirrors
see PARKTRONIC
see Rear view camera
Parking assistance
see PARKTRONIC
Parking brake
Applying automatically ................... 191
Applying or releasing manually ...... 191
Display message ............................ 281
Electric parking brake .................... 190
Emergency braking ........................ 192
General notes ................................ 190
Releasing automatically ................. 191
Warning lamp ................................. 319
Parking lamps
Switching on/off ........................... 131
PARKTRONIC
Deactivating/activating ................. 215
Driving system ............................... 214
Function/notes .............................2 14
Important safety notes .................. 214
Problem (malfunction) ................... 216
Range of the sensors ..................... 214
Warning display ............................. 215
PASSENGER AIR BAG
Display message ............................ 289
Indicator lamps ................................ 46
Problem (malfunction) ................... 289
Perfume atomizer
Operating ....................................... 153
Problem (malfunction) ................... 155
Vial ................................................ 153
Pets in the vehicle ............................... 67
Plastic trim (cleaning instruc-
tions) .................................................. 364
PLUG-IN HYBRID operating
Electrical energy generated ........... 249
PLUG-IN HYBRID operation
Automatic engine start (ECO
start/stop function) ....................... 253 Automatic engine switch-off (ECO
start/stop function) ....................... 252
Charge level of the high-voltage
battery ........................................... 245
Charging the high-voltage battery .. 246
Displaying the total range and
electric range ................................. 248
Driving tip
s .................................... 251
EC

O start/stop function ................ 252
Electric motor (power display) ....... 242
Electrical energy generated
(COMAND) ..................................... 249
Energy flow display ........................ 245
Fuel consumption .......................... 249
Fuel consumption (COMAND) ........ 249
General notes ................................ 240
Haptic accelerator pedal ................ 251
High-voltage battery (condition of
charge) .......................................... 245
Hybrid drive system overview ........ 241
HYBRID menu ................................ 272
Important safety notes .................. 240
Instrument cluster (power dis-
play) ............................................... 242
Instrument cluster overview .......... 242
Manual drive program .................... 250
Noiseless start ............................... 249
Operating (on-board computer) ..... 245
Operating mode ............................. 243
Overrun mode ................................ 253
Parking .......................................... 253
Power display ................................ 244
Power display (electric motor) ....... 242
Problems ....................................... 254
Problems with SRS (supplemental
restraint system) ............................ 255
Problems with the combustion
engine ............................................ 254
Problems with the hybrid drive
system ........................................... 255
Problems with the Recuperative
Brake System ................................ 254
Program selector button ................ 250
Pulling away ................................... 250
READY display ............................... 249
Recuperative Brake System ........... 240
Resetting the values (COMAND) .... 249
Route-based operating strategy ..... 253
Index15

Refuelingprocess (PLUG-IN
HYBRID vehicles) .......................... .178
see Fuel
Remote control
Garage door opener ....................... 347
Programming (garage door
opener) .......................................... 348
Replacing bulbs
General notes ................................ 135
Reporting safety defects .................... 29
Rescue card ......................................... 29
Reserve (fuel tank)
see Fuel
Reserve fuel
Display message ............................ 296
Warning lamp ................................. 320
Residual heat (climate control) ........ 152
Restraint system
Display message ............................ 287
Introduction ..................................... 44
Warning lamp ................................. 319
Warning lamp (function) ................... 45
Reversing feature
Panorama sliding sunroof ................ 98
Roller sunblinds ............................... 99
Side windows ................................... 94
Trunk lid ........................................... 89
Reversing lamps (display mes-
sage) ................................................... 292
ROAD SURFACE SCAN ....................... 211
Roadside Assistance (breakdown) .... 26
Roller sunblind
Panorama roof with power tilt/
sliding panel ..................................... 99
Rear side windows ......................... 333
Rear window .................................. 334
Roller sunblind of the panorama
roof with power tilt/sliding panel
Operating (front roller sunblind) .... 100
Operating (rear roller sunblind) ...... 100
Roof carrier ........................................ 330
Roof lining and carpets (cleaning
guidelines) ......................................... 366
Roof load (maximum) ........................ 433S
Safety
Children in the vehicle ..................... 61
Hybrid drive system ......................... 42
see Occupant safety
see Operating safety
Safety notes
Hybrid vehicles ................................ 42
Safety system
see Driving safety systems
SD memory card
Selecting ........................................ 266
Seat
Adjusting the front-passenger
seat from the driver's seat ............. 108
Multicontour seat in the rear com-
partment ........................................ 117
Seat belt buckle extender
Display message ............................ 285
Seat belt extender
Function/notes ................................ 49
Seat belts
Adjusting the driver's and front-
passenger seat belt ......................... 50
Adjusting the height ......................... 49
Cleaning ......................................... 366
Correct usage .................................. 48
Fastening ......................................... 49
Important safety guidelines ............. 47
Introduction ..................................... 46
Releasing ......................................... 50
Seat belt extender ........................... 49
Warning lamp ................................. 313
Warning lamp (function) ................... 50
Seating
Seating comfort package ............... 117
Seating comfort package ................. 117
Seats
Active multicontour seat ................ 117
Adjusting (electrically) ................... 106
Adjusting (rear compartment) ........ 107
Adjusting the 4-way lumbar sup-
port ................................................ 118
Adjusting the head restraint .......... 114
Calling up a stored setting (mem-
ory function) .................................. 127
Chauffeur mode ............................. 111
Index17

V
Vanity mirror (in the sun visor)........ 333
Vehicle
Correct use ...................................... 29
Data acquisition ............................... 29
Display message ............................ 308
Equipment ....................................... 25
Individual settings .......................... 269
Limited Warranty ............................. 29
Loading .......................................... 394
Locking (in an emergency) ............... 88
Locking (SmartKey) .......................... 79
Lowering ........................................ 409
Maintenance .................................... 26
Operating safety .............................. 27
Parking .......................................... 189
Parking for a long period ................ 192
Pulling away ................................... 165
Raising ........................................... 406
Reporting problems ......................... 29
Securing from rolling away ............ 406
Towing away .................................. 379
Transporting .................................. 381
Unlocking (in an emergency) ........... 87
Unlocking (SmartKey) ...................... 79
Vehicle data ................................... 433
Vehicle dimensions ........................... 433
Vehicle emergency locking ................ 88
Vehicle identification number
see VIN
Vehicle identification plate .............. 426
Vehicle level
Active Body Control ABC ............... 210
AIRMATIC ...................................... 212
Display message ............................ 300
Vehicle tool kit .................................. 367
Video
Operating the DVD ......................... 267
VIN
Type plate ...................................... 426
W
WarningStickers ........................................... 42
Warning and indicator lamps
ABS ................................................ 316 Brakes ........................................... 315
Check Engine ................................. 320
Coolant .......................................... 320
Distance warning ........................... 322
ESP
®.............................................. 317
ESP®OFF ....................................... 319
Fuel tank ........................................ 320
General notes ................................ 313
Hybrid drive system ....................... 315
Overview .......................................... 34
Parking brake ................................ 319
PASSENGER AIR BAG ...................... 46
RBS (Recuperative Brake Sys-
tem) ............................................... 315
Reserve fuel ................................... 320
Restraint system ............................ 319
Seat belt ........................................ 313
Steering ......................................... 324
Tire pressure monitor .................... 323
Warranty .............................................. 25
Washer fluid
Display message ............................ 311
Wheel and tire combinations
Tires ............................................... 412
Wheel bolt tightening torque ........... 409
Wheel chock ...................................... 406
Wheels
Changing a wheel .......................... 405
Checking ........................................ 385
Cleaning ......................................... 361
General notes ................................ 410
Important safety notes .................. 384
Information on driving .................... 384
Interchanging/changing ................ 405
Mounting a new wheel ................... 409
Mounting a wheel .......................... 406
Removing a wheel .......................... 408
Snow chains .................................. 386
Storing ........................................... 405
Tightening torque ........................... 409
Wheel size/tire size ....................... 410
Window curtain air bag
Display message ............................ 288
Operation ......................................... 53
Windows
see Side windows
22Index

These data memories temporarily or perma-
nently store technical information about:
Rvehicle's operating state
Rincidents
Rmalfunctions
In general, this technical information docu-
ments the state of a component, a module, a
system or the surroundings.
These include, for example:
Roperating conditions of system components,
e.g. fluid levels
Rthe vehicle's status messages and those of its
individual components, e.g. number of wheel
revolutions/speed, deceleration in move-
ment, lateral acceleration, accelerator pedal
position
Rmalfunctions and defects in important system
components, e.g. lights, brakes
Rvehicle reactions and operating conditions in
special driving situations, e.g. air bag deploy-
ment, intervention of stability control sys-
tems
Rambient conditions, e.g. outside temperature
This data is of an exclusively technical nature
and can be used to:
Rassist in recognizing and rectifying malfunc-
tions and defects
Ranalyze vehicle functions, e.g. after an acci-
dent
Roptimize vehicle function
The data cannot be used to trace the vehicle's
movements.
When your vehicle is serviced, technical infor-
mation can be read from the event data memory
and malfunction data memory.
Services include, for example:
Rrepair services
Rservice processes
Rwarranties
Rquality assurance
The vehicle is read out by employees of the ser-
vice network (including the manufacturer) using
special diagnostic testers. More detailed infor-
mation is obtained from it, if required.
After a malfunction has been rectified, the infor-
mation is deleted from the malfunction memory or is continually overwritten.
When operating the vehicle, situations are con-
ceivable in which this technical data, in connec- tion with other information (if necessary, under
consultation with an authorized expert), could
be traced to a person.
Examples include:
Raccident reports
Rdamage to the vehicle
Rwitness statements
Further additional functions that have been con-
tractually agreed upon with the customer allow
certain vehicle data to be conveyed by the vehi-
cle as well. The additional functions include, for
example, vehicle location in case of an emer-
gency.
COMAND/mbrace
If the vehicle is equipped with COMAND or
mbrace, additional data about the vehicle's
operation, the use of the vehicle in certain sit-
uations, and the location of the vehicle may be
compiled through COMAND or the mbrace sys-
tem.
For additional information please refer to the
COMAND User Manual or the Digital Operator's
Manual and/or the mbrace Terms and Condi-
tions.
Event data recorders
This vehicle is equipped with an event data
recorder (EDR). This vehicle is equipped with an
event data recorder (EDR). The main purpose of
an EDR is to record, in certain crash or near
crash-like situations, such as an air bag deploy-
ment or hitting a road obstacle, data that will
assist in understanding how a vehicle's systems
performed. The EDR is designed to record data
related to vehicle dynamics and safety systems for a short period of time, typically 30 seconds
or less.
The EDR in this vehicle is designed to record
such data as:
RHow various systems in your vehicle were
operating
RWhether or not the driver and passenger
safety belts were buckled/fastened
RHow far (if at all) the driver was depressing theaccelerator and/or brake pedal and
RHow fast the vehicle was traveling.
30Introduction

Cockpit
FunctionPage
:Steering wheel paddle shift-
ers174
;Combination switch131
=Horn
?Instrument cluster33
ADIRECT SELECT lever170
BOverhead control panel39
CControl panel for:
ÜLowering the rear seat
head restraints116
u Extending/retracting
the rear roller sunblind334
PASSENGER AIR BAG indica-
tor lamp46
Adjusting the brightness of
the instrument lighting and
the multimedia system dis-
play
DIgnition lock162
Start/Stop button162
FunctionPage
EClimate control systems140
FAdjusts the steering wheel120
Steering wheel heating120
GCruise control lever197
HElectric parking brake190
IDiagnostics connection28
JOpening the hood352
KLight switch130
LControl panel for:
Activating Steering Assist
and Stop&Go Pilot207
Switching on Active Lane
Keeping Assist237
Deactivating PARKTRONIC214
Switching on the 360° cam-
era224
Activating Night View Assist230
Switching on the head-up
display259
32Cockpit
At a glance

Door controlpanel
FunctionPage
:s Seat ventilation119
;c Seat heatin g118
=w Adjust sth efront-
passenger seat from th edriv-
er' sseat
10 8
?r 45=
Stores settings for the seat,
exterior mirrors and steering
wheel
126
AAdjusts the seats electrically106
B7Zª\
Adjusts and folds the exterior
mirrors in/out electrically
123
CW Opens/closes the right
side window94
DW Opens/closes the rear
right side window94
FunctionPage
E6 Unlocks fuel filler flap179
FpOpens/closes the
trunk lid92
Gn Override feature for the
controls in the rear compart-
ment
67
HOpens the door86
I%&Unlocks/locks
the vehicle86
JW Opens/closes the rear
left side window94
KW Opens/closes the left
side window94
40Door control panel
At a glance