Refrigerant MERCEDES-BENZ S-Class SEDAN 2016 W222 Owner's Manual

Removing...................................... .185
Storing ...........................................1 83
Warming up ................................... 182
Charging the high-voltage battery
(important safety notes) ................... 180
Chauffeur mode
Display message ............................ 310
Fully reclined position .................... 114
General notes ................................ 111
Installing the head restraint ........... 113
Moving front-passenger seat into
the chauffeur position .................... 112
Moving the front-passenger seat
into the normal position ................. 113
Removing the head restraint .......... 113
Child
Restraint system .............................. 62
Child seat
Forward-facing restraint system ...... 66
LATCH-type (ISOFIX) child seat
anchors ............................................ 63
On the front-passenger seat ............ 65
Rearward-facing restraint system .... 66
Top Tether ....................................... 64
Child-proof locks
Important safety notes .................... 66
Rear doors ....................................... 67
Children
Special seat belt retractor ............... 62
Cigarette lighter ................................ 335
Cleaning
Mirror turn signal ........................... 362
Climate control
Automatic climate control ............. 141
Controlling automatically ............... 147
Cooling with air dehumidification .. 146
Defrosting the windows ................. 151
Defrosting the windshield .............. 151
ECO start/stop function ................ 145
General notes ................................ 140
Immediate pre-entry climate con-
trol ................................................. 158
Indicator lamp ................................ 147
Ionization ....................................... 155
Notes on using the automatic cli-
mate control .................................. 145
Overview of systems ...................... 140
Perfume atomizer .......................... 153 Pre-entry climate control at
departure time ............................... 157
Pre-entry climate control via
key ... 155
P

roblem with the rear window
defroster ........................................ 152
Problems with cooling with air
dehumidification ............................ 147
Rear control panel ......................... 141
Refrigerant ..................................... 432
Refrigerant filling capacity ............. 432
Setting the air distribution ............. 149
Setting the air vents ...................... 158
Setting the airflow ......................... 150
Setting the climate mode ............... 148
Setting the temperature ................ 148
Switching air-recirculation mode
on/off ............................................ 152
Switching on/off ........................... 145
Switching residual heat on/off ...... 152
Switching the rear window
defroster on/off ............................ 151
Switching the synchronization
function on and off ........................ 150
Climate control system
Climate control .............................. 145
Cockpit
Overview .......................................... 32
COLLISION PREVENTION ASSIST
PLUS
Activating/deactivating ................. 270
Display message ............................ 284
Operation/notes .............................. 71
COMAND display
Cleaning ......................................... 364
Combination switch .......................... 131
Consumption statistics (on-board
computer) .......................................... 262
Convenience closing feature .............. 96
Convenience opening feature ............ 95
Coolant (engine)
Checking the level ......................... 356
Display message ............................ 294
Displaying the temperature (on-
board computer) ............................ 269
Filling capacity ............................... 431
Important safety notes .................. 431
Temperature gauge ........................ 257
Warning lamp ................................. 320
6Index

Starting .......................................... 249
When the vehicle is stationary ....... 251
Power locks ......................................... 87
Power washers .................................. 360
Power windows
see Side windows
Pre-entry climate control (via
SmartKey)
Problems (malfunctions) ................ 157
Pre-entry climate control at depar-
ture time
General notes ................................ 157
Pre-entry climate control at time of
departure
Setting departure time ................... 158
Pre-entry climate control via key
General notes ................................ 155
PRE-SAFE
®(anticipatory occupant
protection)
Display message ............................ 284
Operation ......................................... 59
PRE-SAFE
®Brake
Activating/deactivating ................. 271
Display message ............................ 284
Function/notes ................................ 75
Important safety notes .................... 76
Warning lamp ................................. 322
PRE-SAFE
®PLUS (anticipatory
occupant protection PLUS)
Display message ............................ 284
Operation ......................................... 60
Program selector button .................. 173
Protection against theft
ATA (Anti-Theft Alarm system) ......... 78
Immobilizer ...................................... 78
Protection of the environment
General notes .................................. 24
Pulling away
Automatic transmission ................. 165
General notes ................................ 165
Hill start assist ............................... 165
Q
QR codeMercedes-Benz Guide App ................. 1
Rescue card ..................................... 29
Qualified specialist workshop ........... 28
R
Radio
Selecting a station ......................... 265
Radio-wave reception/transmis-
sion in the vehicle
Declaration of conformity ................ 28
Rain closing feature
Panorama sliding sunroof ................ 99
RBS (Recuperative Brake System)
Warning lamp ................................. 315
Reading lamp ..................................... 134
Rear compartment
Activating/deactivating climate
control ........................................... 145
Setting the air distribution ............. 149
Setting the air vents ...................... 160
Setting the airflow ......................... 150
Setting the temperature ................ 148
Stowage compartment .................. 327
Rear lamps
see Lights
Rear seats
Adjusting ....................................... 107
Adjusting a rear reclining seat ....... 107
Overview .......................................... 41
Setting the reclined position .......... 107
Rear view camera
Cleaning instructions ..................... 363
Displays in the COMAND display ... 221
Function/notes ............................. 220
Rear window blind ............................ 334
Rear window defroster
Problem (malfunction) ................... 152
Switching on/off ........................... 151
Rear-view mirror
Anti-glare (manual) ........................ 123
Dipping (automatic) ....................... 124
Recuperative Brake System
Driving safety systems ..................... 44
Important safety notes .................... 44
Refrigerant (air-conditioning sys-
tem)
Important safety notes .................. 432
Refueling
Fuel gauge ....................................... 33
Important safety notes .................. 177
16Index

Cleaning the cover .........................365
Correct driver's seat position ........1 04
Display message ............................ 310
EASY-ENTRY/EXIT system ............. 122
Important safety notes .................. 105
Multicontour seat .......................... 117
Seat heating .................................. 118
Seat heating problem .................... 119
Seat ventilation .............................. 119
Seat ventilation problem ................ 120
Storing settings (memory func-
tion) ............................................... 126
Switching seat heating on/off ....... 118
Switching seat ventilation on/off .. 119
Section
Wheels and tires ............................ 384
Securing a load
see Securing cargo
Securing cargo .................................. 329
Selector lever
Cleaning ......................................... 365
see Automatic transmission
Sensors (cleaning instructions) ....... 362
Service menu (on-board com-
puter) ..................................................2 69
Service message
see ASSYST PLUS
Service products
Brake fluid ..................................... 430
Coolant (engine) ............................ 431
Engine oil ....................................... 429
Fuel ................................................ 428
Important safety notes .................. 427
Refrigerant (air-conditioning sys-
tem) ............................................... 432
Washer fluid ................................... 431
Setting the charge current (on-
board computer) ............................... 272
Setting the departure time (on-
board computer) ............................... 272
Settings
Factory (on-board computer) ......... 275
On-board computer ....................... 269
SETUP (on-board computer) ............. 276
Side impact air bag .............................5 2
Side marker lamp (display mes-
sage) ................................................... 292 Side windows
Cleaning ........................... .............. 362
Convenience closing feature ............ 96
Convenience opening feature ..........9 5
Importa

nt safety information ........... 94
Opening/closing .............................. 95
Problem (malfunction) .....................9 7
Resettin g........................................ .96
Reversin gfeature ............................ .94
Sliding sunroof
see Panorama roof with power
tilt/sliding panel
SmartKey
Changing the battery ....................... 82
Changing the programming .............8 1
Checking the battery ...................... .82
Convenience closing feature ............ 96
Convenience opening feature .......... 95
Display message ............................ 312
Door central locking/unlocking ...... .79
Important safety notes .................... 79
KEYLESS-GO start function .............. 81
Loss .................................................8 4
Mechanical key ................................ 81
Overview .......................................... 79
Positions (ignition lock) ................. 162
Problem (malfunction) ..................... 84
Starting the engine ........................ 164
Smartphone
Starting the engine ........................ 164
Snow chains ...................................... 386
Sockets
Center console .............................. 336
General notes ................................ 336
Rear compartment .........................3 37
Trunk ............................................. 337
Special seat be
lt retractor
.................. 62
Specialist workshop ............................ 28
Speed, controlling
see Cruise control
Speedometer
Activating/deactivating the addi-
tional speedometer ........................ 274
Digital ............................................ 263
In the Instrument cluster ................. 33
Selecting the display unit ...............2 74
Standing lamps
Display message ............................ 292
18Index

Useful information
i
This Operator's Manual describes all models
and all standard and optional equipment of
your vehicle available at the time of publica-
tion of the Operator's Manual. Country-spe-
cific differences are possible. Please note
that your vehicle may not be equipped with all
features described. This also applies to
safety-related systems and functions.
iRead the information on qualified specialist
workshops (Ypage 28).
Overview of climate control systems
General notes
Observe the settings recommended on the fol-
lowing pages. The windows could otherwise fog
up.
To prevent the windows from fogging up:
Rswitch off climate control only briefly
Rswitch on air-recirculation mode only briefly
Rswitch on the cooling with air dehumidifica-
tion function
Rswitch on the defrost windshield function
briefly, if required
Climate control regulates the temperature and
air humidity in the vehicle interior. The air filter
cleans the air, thus improving the interior cli-
mate.
For vehicles with a combustion engine, the
"Cooling with air dehumidification" function is
only available when the engine is running. For
hybrid vehicles, the "Cooling with air dehumidi-
fication" function is also available via the elec-
tric refrigerant compressor when the engine is
not running. Optimum climate control is only
achieved with the side windows and roof closed.
If you start the engine using your smartphone,
the last selected climate control setting is reac-
tivated (
Ypage 164).
The residual heat function can only be activated
or deactivated with the ignition switched off
(
Ypage 152).
iVentilate the vehicle for a brief period during
warm weather, e.g. using the convenience
opening feature (
Ypage 95). This will speed
up the cooling process and the desired inte- rior temperature will be reached more
quickly.
iThe integrated filter filters out most parti-
cles of dust and soot and completely filters
out pollen. It also reduces gaseous pollutants
and odors. A clogged filter reduces the
amount of air supplied to the vehicle interior.
For this reason, you should always observe
the interval for replacing the filter, which is
specified in the Maintenance Booklet. As it
depends on environmental conditions, e.g.
heavy air pollution, the interval may be
shorter than stated in the Maintenance Book- let.
iIt is possible that the blower may be activa-
ted automatically 60 minutes after the Smart-
Key has been removed depending on various
factors, e.g. the outside temperature. The
vehicle is then ventilated for 30 minutes to dry
the climate control system.
140Overview of climate control systems
Climate control

Hybrid system overview
:12 V battery
;Transmission with electric motor
=Electric heater
?High-voltage electrical system cables
AHigh-voltage battery
BRecuperative Brake System
CElectric refrigerant compressor
DVehicle socket
ECharger
FVoltage transformer
GPower electronics
You can switch off the hybrid drive system manually. For further information on the high-voltage
switch-off device, see (
Ypage 42).
PLUG‑IN HYBRID operation241
Driving and parking
Z

iThe data shown on the vehicle identification
plate is used only as an example. This data is
different for every vehicle and can deviate
from the data shown here. You can find the
data applicable to your vehicle on the vehicle
identification plate.
Vehicle identification number (VIN)
XOpen the front right-hand door.
XFold cover :down and remove it.
You will see the VIN.
The VIN can also be found in the following loca-
tions:
Ron the lower edge of the windshield
(Ypage 427)
Ron the vehicle identification plate
(Ypage 426)
Engine number
:Engine number (stamped into the crank-
case)
;VIN (on the lower edge of the windshield)
=Emission control information plate, includ-
ing the certification of both federal and Cali-
fornian emissions standards
Service products and filling capaci-
ties
Important safety notes
GWARNING
Service products may be poisonous and haz-
ardous to health. There is a risk of injury.
Comply with instructions on the use, storage
and disposal of service products on the labels
of the respective original containers. Always
store service products sealed in their original
containers. Always keep service products out
of the reach of children.
HEnvironmental note
Dispose of service products in an environ-
mentally responsible manner.
Service products include the following:
RFuels
RLubricants (e.g. engine oil, transmission oil)
RCoolant
RBrake fluid
RWindshield washer fluid
RClimate control system refrigerant
Components and service products must be
matched. Only use products recommended by
Mercedes-Benz. Damage which is caused by the
use of products which have not been recom-
mended is not covered by the Mercedes-Benz
warranty or goodwill gestures. They are listed in
this Mercedes-Benz Operator's Manual in the
appropriate section.
Information on tested and approved products
can be obtained at an authorized Mercedes-
Benz Center or on the Internet at
http://bevo.mercedes-benz.com.
You can recognize service products approved by
Mercedes-Benz by the following inscription on
the containers:
RMB-Freigabe (e.g. MB-Freigabe 229.51)
RMB-Approval (e.g. MB-Approval 229.51)
Other designations or recommendations indi-
cate a level of quality or a specification in
accordance with an MB Sheet Number (e.g. MB 229.5). They have not necessarily been
approved by Mercedes-Benz.
Service products and filling capacities427
Technical data
Z

spray nozzles may otherwise become
blocked.
At temperatures above freezing:
XFill the washer fluid reservoir with a mixture of
water and windshield washer fluid, e.g. MB
SummerFit.
Add 1 part MB SummerFit to 100 parts water.
At temperatures below freezing:
XFill the washer fluid reservoir with a mixture of
water and washer fluid, e.g. MB WinterFit.
For the correct mixing ratio refer to the infor-
mation on the antifreeze reservoir.
iAdd windshield washer fluid, e.g. MB Sum-
merFit or MB WinterFit, to the washer fluid all
year round.
Climate control system refrigerant
Important safety notes
The climate control system of your vehicle is fil-
led with refrigerant R‑134a.
The instruction label regarding the refrigerant
type used can be found on the radiator cross
member.
!Only the refrigerant R‑134a and the PAG oil
approved by Mercedes-Benz may be used.
The approved PAG oil may not be mixed with
any other PAG oil that is not approved for
R-134a refrigerant. Otherwise, the climate
control system may be damaged.
Service work, such as topping up refrigerant or
replacing components, may only be carried out
by a qualified specialist workshop. All applicable
regulations, as well as SAE standard J639, must
be adhered to.
Always have work on the climate control system
carried out at a qualified specialist workshop.
Refrigerant instruction label
Example: refrigerant instruction label
:
Warning symbol
;Refrigerant filling capacity
=Applicable SAE standards
?PAG oil part number
AType of refrigerant
Warning symbols :indicate:
Rpossible dangers
Rhaving service work carried out at a qualified
specialist workshop
Filling capacities
ModelRefrigerant
S 550 e
Mercedes‑AMG vehicles25.0 ± 0.4 oz
(710 ± 10 g)
ModelPAG oil
S 550 e
Mercedes‑AMG vehicles4.3 oz
(120 g)
Vehicles without rear-com-
partment air-conditioning
systemCapacity
Refrigerant23.3 ± 0.4 oz (660 ± 10 g)
PAG oil3.9 oz
(110 g)
432Service products and filling capacities
Technical data

Vehicles with rear-com-
partment air-conditioning
systemCapacity
Refrigerant27.1 ± 0.4 oz(770 ± 10 g)
PAG oil4.2 oz
(120 g)
Vehicle data
General notes
Please note that for the specified vehicle data:
Rthe heights specified may vary as a result of:
-tires
-load
-condition of the suspension
-optional equipment
Roptional equipment reduces the maximum
payload.
Dimensions and weights
Trunk lid opening dimensions (example:
Mercedes‑Maybach)
Missing values were not available at time of
going to print.
Model:Opening height
S 400 4MATIC
S 550 4MATIC
S 55071.0 in
(1803 mm)
Model:Opening height
Mercedes ‑AMG
vehicles71.2 in
(1808 mm)
All other models71.1 in
(1806 mm)
S-Class with a short wheelbase
All models
Vehicle length201.4 in (5116 mm)
Vehicle width
including exterior
mirrors83.9 in (2130 mm)
Vehicle height59.0 in (1499 mm)
Wheelbase119.5 in (3035 mm)
Turning radius39.0 ft (11.90 m)
Maximum roof load220 lb (100 kg)
Maximum trunk
load220 lb (100 kg)
S-Class with a long wheelbase
Missing values were not available at time of
going to print.
S 400 4MATIC
Vehicle length
Vehicle height
Vehicle width
including exterior
mirrors
Wheelbase
Turning radius
Maximum roof load
Maximum trunk
load
Vehicle data433
Technical data
Z